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We report a new type of separator film for application in rechargeable lithium and lithium-ion batteries. The films are made
of mainly alkaline calcium carbonate (CaCO3) and a small amount of polymer binder. Owing to porosity and capillarity, the composite films show excellent wettability
with non-aqueous liquid electrolytes. Typically, the composite films composed of CaCO3 and Teflon and wetted with 1 M LiPF6 dissolved in a solvent mixture of ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (30:70 wt%) exhibit an ionic conductivity
as high as 2.5–4 mS/cm at 20 °C, in a comparable range with that (3.4 mS/cm) of the commercial Celgard membrane. In the batteries,
the composite film not only serves as a physical separator but also neutralizes acidic products, such as HF formed by LiPF6 hydrolysis, as well as those formed by solvent oxidative decomposition. A Li/LiMn2O4 test cell was employed to examine the electrochemical compatibility of the composite film. We observed that the composite
film cell showed an improved cycling performance since the alkaline CaCO3 neutralizes the acidic products, which otherwise promote dissolution of the electrode active materials. More importantly,
the composite film cell displayed a superior performance on high-rate cycling, which was probably the result of the less resistive
interface formed between the electrode and the composite film. 相似文献