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N. C. Dang C. A. Bolme D. S. Moore S. D. McGrane 《Journal of Raman spectroscopy : JRS》2013,44(3):433-439
We have previously demonstrated the capability of femtosecond stimulated Raman scattering (FSRS) data to measure the temperature (T) of condensed matter at the molecular vibrational level. [Phys. Rev. Lett. 2011, 107, 43001] In this paper, we expand the theory for the FSRS temperature dependence by considering the effects of an isolated change of T as well as a coupled change of T and chemical concentration. We point out that the origin of the temperature sensitivity of the Stokes to anti‐Stokes ratio of FSRS lies in the exponential nonlinearity of the gain and loss. We establish that FSRS of two Raman modes can be used to simultaneously determine the vibrational temperature and the change in concentration of the species contributing to those two modes. Single‐shot experimental results using FSRS are presented to demonstrate over four orders of magnitude higher efficiency than spontaneous Raman in small volume samples with picosecond resolution. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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Resonance enhancement has been increasingly employed in the emergent femtosecond stimulated Raman spectroscopy (FSRS) to selectively monitor molecular structure and dynamics with improved spectral and temporal resolutions and signal-to-noise ratios. Such joint efforts by the technique-and application-oriented scientists and engineers have laid the foundation for exploiting the tunable FSRS methodology to investigate a great variety of photosensitive systems and elucidate the underlying functional mechanisms on molecular time scales. During spectral analysis, peak line shapes remain a major concern with an intricate dependence on resonance conditions. Here, we present a comprehensive study of line shapes by tuning the Raman pump wavelength from red to blue side of the ground-state absorption band of the fluorescent dye rhodamine 6G in solution. Distinct line shape patterns in Stokes and anti-Stokes FSRS as well as from the low to high-frequency modes highlight the competition between multiple third-order and higher-order nonlinear pathways, governed by different resonance conditions achieved by Raman pump and probe pulses. In particular, the resonance condition of probe wavelength is revealed to play an important role in generating circular line shape changes through oppositely phased dispersion via hot luminescence (HL) pathways. Meanwhile, on-resonance conditions of the Raman pump could promote excited-state vibrational modes which are broadened and red-shifted from the coincident ground-state vibrational modes, posing challenges for spectral analysis. Certain strategies in tuning the Raman pump and probe to characteristic regions across an electronic transition band are discussed to improve the FSRS usability and versatility as a powerful structural dynamics toolset to advance chemical, physical, materials, and biological sciences. 相似文献
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详细比较了磷酸二氢钾(KDP)晶体的自发拉曼散射和受激拉曼散射光谱,在受激拉曼散射(SRS)中观察到了自发拉曼散射中最强的振动模的三阶Stokes光(559.43,589.74,623.50nm),由于其他振动模的受激拉曼散射增益系数较小,其SRS光谱未观察到。另外,比较了传统生长的未退火和退火后的KDP晶体及快速生长的锥区和柱区KDP晶体的受激拉曼散射增益系数,结果表明生长方法和热退火对KDP晶体的受激拉曼散射增益系数无明显影响。 相似文献
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Stimulated Raman backscattering from an ultrashort laser interacting with underdense plasmas 总被引:2,自引:0,他引:2 下载免费PDF全文
We present experimental results of the stimulated Raman backscattering instability (BSRS) in an ultrashort intense (45fs, 5.7×1017Wcm-2) laser pulse interacting with an optically ionized helium gas. We have studied the stimulated Raman backscattering reflectivity and the phenomenon of the transition from strongly coupled BSRS to weakly coupled BSRS. We have obtained a good agreement between our experimental results and the theory of BSRS. 相似文献
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In this paper recent research progress on the use of Coherent Anti‐Stokes Raman Scattering (CARS) in Raman lasers and Raman wavelength converters is reviewed. The latest insights in the physical nature and behavior of CARS are addressed, and the recent performance breakthroughs in CARS‐based Raman wavelength conversion are discussed. Based on the new findings regarding the behavior of CARS, a physical explanation for apparent inconsistencies in various experimental observations of Raman wavelength conversion is provided. To conclude it is shown that these recent insights also pave the way to the development of a novel CARS‐based mechanism for reducing the heat dissipation in Raman lasers. 相似文献
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用2660(?)的紫外激光解离PbCl_2分子时,发现在3740(?)和3734(?)波长上有较强的受激辐射输出.根据它们的光谱特性和铅原子的能级结构判断,这些辐射是基于双光子解离PbCl_2分子得到的铅原子在6p~(23)P_2亚稳能级上的布居而产生的光泵共振激光辐射和受激喇曼散射.提出了描述整个过程的理论模型,通过拟合实验结果,确定了2660(?)激光双光子解离PbCl_2产生6p~(23)P_2亚稳态铅原子的光解系数.当PbCl_2分子密度为N_(00)=6.21×10~(16)cm~(-3)时,光解产生的铅原子在6p~(23)P_2和6p~(21)D_2这两个亚稳态的最大布居数近似相等,称为2.0×10~(16)cm~(-3). 相似文献
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Vladimir S. Gorelik Anna D. Kudryavtseva Nikolay V. Tcherniega 《Journal of Russian Laser Research》2008,29(6):551-557
The results of experimental studies of stimulated Raman scattering of light (SRS) excited in three-dimensional photonic crystals
— synthetic opal matrices infiltrated with Raman active media are presented. It is shown that the SRS threshold in such structures
decreases with respect to the SRS threshold in Raman active bulk materials. The influence of the photonic-band structure of
the active materials used on the SRS properties is estimated. 相似文献
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利用全量子理论和多模受激拉曼散射模型,研究了拉曼放大中,考虑泵浦光耗散时,斯托克斯光和泵浦光二阶量子关联函数随相互作用距离变化的特性,在不计及色散的影响时,斯托克斯光和泵浦光的二阶量子关联函数的变化主要取决于输入斯托克斯光和泵浦光的光强比,在极限情况下,本文的计算结果与拉曼产生的计算结果和经典耦合波理论的计算结果相符合。 相似文献
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由于部分离化激光等离子体中存在束缚电子,它可显著改变其参量不稳定性。本文分析了部分离化激光等离子体的受激喇曼散射的非线性色散关系,计算了钕玻璃倍频和三倍频激光受激喇曼散射的增长率,结果表明,前向受激喇曼散射显著增强,后向受激喇曼散射影响不大。 相似文献
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Siva Umapathy Adithya Lakshmanna Babita Mallick 《Journal of Raman spectroscopy : JRS》2009,40(3):235-237
This paper deals with a new form of nonlinear Raman spectroscopy called ‘ultrafast Raman loss spectroscopy (URLS)’. URLS is analogous to stimulated Raman spectroscopy (SRS) but is much more sensitive than SRS. The signals are background (noise) free unlike in coherent anti‐Stokes Raman spectroscopy (CARS) and it provides natural fluorescence rejection, which is a major problem in Raman spectroscopy. In addition, being a self‐phase matching process, the URLS experiment is much easier than CARS, which requires specific phase matching of the laser pulses. URLS is expected to be alternative if not competitive to CARS microscopy, which has become a popular technique in applications to materials, biology and medicine. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
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本文采用非稳腔输出的XeCl准分子激光,首次观察到高压氢高激发态之间的受激喇曼散射,并讨论了它们产生的条件. 相似文献
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受激拉曼散射(stimulated Raman scattering,SRS)具有激光的特性,并且容易获取不同波长的激光,从而成为调谐激光频率的重要途径之一。然而,由于其转化效率低,限制了它的实际应用。金属纳米粒子具有很强的表面增强效应,曾被广泛地用于增强拉曼散射而获得良好的效果。本文提出将金属纳米粒子的这种性质用于增强SRS。把Au纳米粒子混合于拉曼介质丙酮中,以532nm的纳秒脉冲激光作为激发光,研究了Au纳米粒子在丙酮中的浓度对丙酮SRS一阶Stokes光强的影响,并通过仿真计算对实验结果进行了解释和分析。 相似文献