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1.
The novel complex [K(18-C-6)]2[Cd(mnt)2][18-C-6-18-crown-6,nmt=1,2-dicyanoethene-1,2-dithiolate,C2S2-(CN)2^2-] was synthesized and characterized by elemental analysis,IR spectrum and X-ray diffraction analysis.The complex displays two-dimensional network structure of [K(18-C-6)] complex segments and [Cd(nmt)2] complex segment bridged by S-K-S,S-K-N and N-K-N interactions between adjacent[K(18-C-6)] and [Cd(mnt)2]units. 相似文献
2.
三维网状冠醚配合物(Bu4N){[K(18-C-6)][Cd4(dmit)2(dmt)3]}的合成与结构 总被引:5,自引:0,他引:5
研究了18-冠-6(18-C-6)与KSCN,CdCl2.2.5H2O,(Bu4N2)[Zn(dmit)2] (dmit=4,5-dimercapto-1,3-dithiole-2-thione,C3S5^2-)的反应,生成的标题配 合物(1)通过元素分析,红外光谱,单晶X射线衍射进行了表征,配合物属单斜晶 系,空间群C2/c,晶体学数据:a=3.4780(7)nm,b=1.5170(3)nm,c=2.8440(6)nm,β =105.93(3)°,V=14.427(3)nm^3,Z=8,F(000)=7872,R1=0.0425,wR2=0.0739,配合物 由一个Bu4N^+阳离子和一个{[K(18-C-6)][Cd4(dmit)2(dmt)3]}-(dmt=4,5- dimercapto-1,2-dithiole-3-thione,C3S5^2-)配阴离子组成,{[K(18-C-6)[Cd4 (dmit)2(dmt)3]}-通过K…S,S…S弱相互作用形成三维网状结构。 相似文献
3.
合成了苯并18-冠-6(B18-C-6)与K_2[Pd(SCN)_4]生成的配合物[K(B18-C-6 )]_(12) [Pd(SCN)_4] (1), [K(B18-C-6)]_2[Pt(SCN)_4] (2)和[K(B18-C-6)]_2 [Pt(SCN)_4]·C_2H_4Cl_2 (3),并通过元素分析、红外光谱、单晶X射线衍射进行 了表征。1和2为单斜晶系,空间群P2_l/n,晶体学数据:1, a = 1.00970(17) nm, b = 1.3157(2) nm, c = 1.7303(3) nm, β = 94.841(2)°, V = 2.2852(7) nm~3, Z = 2, F(000) = 1136, R_1 = 0.0257。3为三斜晶系,空间群P1,晶体学 数据:a = 0.95914(18) nm, b = 1.2137(2) nm, c = 2313(2) nm, α = 63.693 (2)°, β = 76.293(2)°, γ-1.2406(4) n~3, Z = 1 F(000)618,R_1 = 0.0366 。在固态,三个配合物相邻的两个[K(B18-C-6)]~+基团通过冠醚氧化原子与钾的 子的相边接而形成一维链状结构。 相似文献
4.
WANG Da qi HE Guo fang QIU Lin lin DOU Jian min * . Department of Chemistry Liaocheng University Liaocheng P. R. China . Department of Chemistry Taishan College Taian P. R. China 《高等学校化学研究》2003,19(3):263-268
IntroductionThe 1 ,2 - dicyanoethene- 1 ,2 - dithiolato anion isa bidentate ligand.It can form square- coplanarcomplexes with many transition metal ions and hasfound a lot of application in analytical chemistry,catalyst and biochemistry.In recent years,metalcomplexes containing mnt and its dithiolate analogligands have been extensively studied and have re-ceived considerable attention due to their potentialapplication in charge transfer and storage,molecu-lar metals,magnetic materials,supercon… 相似文献
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A novel Pd(II)-dibenzo-18-crown-6 (DB18C6) complex [K(DB18C6)]2[Pd(SCN)4] has been isolated and characterized by X-ray diffraction analysis. In the solid state, it displays a quasi-one-dimensional infinite chain of two [K(DB18C6)] + complex cations and a [Pd(SCN)4]2- anion bridged by K+-p interactions between adjacent [K(DB18C6)] + units. 相似文献
6.
用凝胶法合成了标题化合物[NH4(15-C-5)2][Cd2(SCN)5](15-C-5=C10H20O5)的晶体,并对其进行了红外光谱、元素分析等各项物理性质的测试,并经X射线单晶结构分析得到了配合物的全部晶体学数据:Mr=973.78,正交晶系,空间群Pnma,晶胞参数a=10.507(1)A,b=16.584(2)A,c=23.494(2)A,V=4093.8(3)A3,Z=4,Dc=2.580g/cm3,μ=13.31cm(-1),F(000)=1968,R=0.070,Rω=0.085。结构分析结果表明,配阳离子是由一个NH4+和两个15-C-5组成的,NH4+没有进入15-C-5空腔内,而是位于两个15-C-5之间,呈夹心结构;配阴离子是以[Cd2(SCN)5]为单元的阴离子长键,其中一组SCN-被四个Cd离子共享,其余两组SCN-被两个Cd离子共享,呈变形八面体构型。配阳离子[NH4(15-C5)2]+和配阴离子[Cd2(SCN)5]-间靠静电力结合成配合物晶体。 相似文献
7.
二苯并18-冠-6铵与硫氰酸银配合物的晶体结构 总被引:1,自引:0,他引:1
标题化合物[(NH_4)(DB18C6)]_2[Ag(SCN)_2]_2其晶体属三斜晶系,空间群为P1。晶胞参数:a=14.003(2),b=14.461(3),c=14.887(2),a=66.51(2),β=66.70(1),γ=76.09(2)°,V=2527.13 3,M_r=1205.0,Z=2,D_x=1.58g/cm~3,μ=9.88cm~(-1)。偏差因子R_w=0.081,独立可观测点数[I>3σ(I)]为3351个,在配合物分子中,二苯并18-冠-6与NH4~+形成配阳离子,Ag~+与硫氰酸根形成配阴离子,二者以静电力形成配合物。银原子被两个SCN~-的S原子桥联和硫氰酸根上的硫,氮杂配,使整个分子形成一条高分子长链。 相似文献
8.
标题化合物[(NH_4)(DB18C6)]_2[Ag(SCN)_2]_2其晶体属三斜晶系,空间群为P1。晶胞参数:a=14.003(2),b=14.461(3),c=14.887(2),a=66.51(2),β=66.70(1),γ=76.09(2)°,V=2527.13 3,M_r=1205.0,Z=2,D_x=1.58g/cm~3,μ=9.88cm~(-1)。偏差因子R_w=0.081,独立可观测点数[I>3σ(I)]为3351个,在配合物分子中,二苯并18-冠-6与NH4~+形成配阳离子,Ag~+与硫氰酸根形成配阴离子,二者以静电力形成配合物。银原子被两个SCN~-的S原子桥联和硫氰酸根上的硫,氮杂配,使整个分子形成一条高分子长链。 相似文献
9.
SynthesisandCrystalStructureof[Na(DB18C6)(H_2O)_2]_2Mo_6O_(19)·3DMF·2CH_3OHLuXiao-Ming;ZhaoYa-Ping;QuEr-Ling;XiaoLing-Mei;LiuShu... 相似文献
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1 INTRODUCTION Tetracyanoplatinate ion often forms one-dimen- sional chain compounds, and the Pt–Pt spacings are often only 0.01~0.3 ? longer than those in Pt metal (2.78 ?). The studies of room-temperature electrical conductivities of these complexes indicate that the shorter the Pt–Pt separations in the chains are, the higher the electrical conductivity is[1~3]. Tetracyano- platinate ion may also stack with suitable planar cations into one-dimensional materials such as [Pt- (CNR)4]… 相似文献
11.
研究了18-冠-6与NiCl·6H2O,K2dmit(dmit=4,5-dimercapto-1,3-dithiole- 2-thione,C3S5^2-)在不同溶剂中反应生成的两个标题配合物{[K(18-C-6)]2 (C2H4Cl2)}[Ni(dmit)2]2(1)和[K(18-C-6)][Ni(dmit)2](2)。通过元素分析、红 外光谱、单晶X射线衍射进行了表征。1和2均属三斜晶系,空间群P1^-.1的晶体学 数据:a=1.0272(2)nm,b=1.2282(3)nm,c=1.4205(3)nm,α=113.473(3)°,β=90. 609(3)°,γ=91.439(3)°,V=1.6430(6)nm^3,Z=2,F(000)=876,R1=0.0503。2的 晶体学数据:a=0.8502(2)nm,b=1.2178(4)nm,c=1.5118(4)nm,α=86.454(5)°,β =77.734(5)°,γ=85.364(5)°,V=1.5228(8)nm^3,Z=2,F(000)=774,R1=0.0565。配 合物1,2分别通过K…S,K…Cl,S…S和K…S,S…S弱相互作用形成二维、三维网状 结构。 相似文献
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WANG Hong-Mei LI Li-Cun SUN Bai-Wang LAIO Dai-Zheng JIANG Zong-Hui YAN Shi-Ping WANG Geng-Lin 《结构化学》1998,(4)
1INTRoDUCTIONMacrocycliccoordinationcomPOundshavebeenwidelyinvestigatedinthepastdecadesbecauseoftheirrelationshiptocomplexesofbiologicalsignificancesuchasthePorphyrinsandcorrins(lJ.Structuresofmanymacrocycliccompoundshavebeenre-ported,especiallythecompoundscontainingN4macrocyclicligands"'.However,toourknowledge,onlyafewcrystalstructuresofcomplexbimetallicsaltscontainingmacrocyclicligandshavebeendeterminedbyX-raydiffractionmethod.Inthispa-per,werePortthesynthesisandstructureofthetit1ecom… 相似文献
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1 INTRODUCTIONSince the first report on the reduction of lead by sodium to a green solution in 1891 by Johannis, polyanionic clusters of post-transition metals known as Zintl ions have attracted much attention in chemistry due to their beautiful molecules, diverse reactivity and potential applications[1, 2]. Polyphos- phide anions represent one of the most important classes of zintl ions. The binary alkali-metal poly- phosphides, such as MI4P6 (M = K, Rb, Cs)[3~5], MI3P7 (M = Li-Cs)… 相似文献
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用凝胶法生长了标题配合物[NH_4(B15C5)_2][Cd(SCN)_3]的晶体,并对其进行了红外光谱,元素分析等各项物理性质的测试。经X射线单晶结构分析得到了配合物的全部晶体学数据:M_r=841.31,正交晶系,空间群P2_12_12_1,晶胞常数a=10.970(3),b=21.834(3),c=15.563(4),V=3727(3),Z=4,D_x=1.50g/cm ̄3,F(000)=1736,μ=7.09cm ̄(-1),R=0.070,R_w=0.063。结构分析结果表明,配阳离子[NH_4(B15C5)_2] ̄+和配阴离子[Cd(SCN)_3] ̄-间靠静电力结合成配合物。 相似文献
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CrystalStructureof[La(NCS)_3(18-crown-6)(DMF)]MaoJiang-Gao(FujianInstituteofResearchontheStructureofMatter,AcademiaSinica,Fuzh?.. 相似文献
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Lan Ying ZHU Jian Min DOU Ying LIU De Zhi SUN Pei Ju ZHENG Chen Xia DU Yu ZHU Department of Biology Chemistry Liaocheng Teacher''''s University Liaocheng Research Center of Analysis Measurement Fudan University Shanghai Key 《中国化学快报》2000,(9)
The extensive pioneering study of Pedersen I has led to a vialal explosion of solutionand solid-state investigation of crown ethers and metal ions which include alkali metal,alkali earth metal, other main-group and transition-metal ions. It is shown that singlecrystal X-ray diffraction analysis is a most powerful technique for the characterization ofthese complexes and numerous solid-state structUral stIJdies have appeared through theyears. The reported B15CS complexes strllcturally charact… 相似文献
17.
合成了苯并 18 冠 6(B18C6)与M2 [Pt(SCN)6 ](M =Na,K)的配合物:{[Na(B18C6)]6 [Pt(SCN)6 ]}[Pt(SCN)6 ](SCN)2(1),[K(B18C6)]2 [Pt(SCN)6 ]·4H2 O(2).通过元素分析、红外光谱、单晶X射线衍射进行了表征.1为单斜晶系、空间群R3- ,a =b =1 9933(3)nm,c =2 9760 (6)nm,α =β =90°,γ =12 0°,V =10 2 40 (3)nm3,Z =3,Dcalcd=1 5 64g/cm3,F(0 0 0) =490 8,R1=0 0 5 35,wR2 =0 10 30.2为三斜晶系、空间群P1- ,a =1 1692 (3)nm,b =1 185 3(4)nm,c =1 2 381(5)nm,α =61 419(5)°,β =80 75 7(8)°,γ =89 0 0 3(5)°,V =1 4836(9)nm3,Z =1,Dcalcd=1 476g/cm3,F(0 0 0) =666,R1=0 0 696,wR2 =0 134 6. 1由 {[Na(B18C6)]6 [Pt(SCN)6 ]}4 +配阳离子、[Pt(SCN)6 ]2 -配阴离子和SCN-阴离子组成.相邻{[Na(B18C6)]6 [Pt(SCN)6 ]}4 +通过Na—O键形成三维网状结构.[Pt(SCN)6 ]2 -和SCN-仅起平衡电荷的作用.2由两个[K(B18C6)]+配阳离子和一个[Pt(SCN)6 ]2 -配阴离子组成.相邻[K(B18C6)]2 [Pt(SCN)6 ]离子对通过K—O键形成一维链状结构 相似文献
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IntroductionThesupramolecularcomplexeformedbytheweakinteractions (electrostaticinteraction ,hydrogenbonds ,vanderWaalsforce ,short rangeexclusionforce ,etc .)ofmorethantwosortsofspeciesisanorganizingentitythatusuallypossessesspecialstructureandfunction .1Sup… 相似文献
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SynthesisandCrystalStructureof[Na(DB18C6)(CH_3OH)]_2Mo_6O_(19)·(DB18C6)·(CH_3OH)¥ZhouYin-Zhuang;TuShu-Jie;JinXiang-Lin;LiuShun-... 相似文献
20.
IntroductionCrystalengineeringofsupramoleculararchitecturessustainedbycoordinatecovalentbondsorhydrogenbondsrepresentsarapidlyexpandingfieldthatofferspo tentialfordevelopmentofnewclassesoffunctionalsolids .1,2 Thearchitecturesofcoordinationpolymerscanbe… 相似文献