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K2Al2B2O7(KABO)晶体是近年发现的一种有应用前景的深紫外非线性光学晶体,也是目前唯一一种可以生长出大尺寸单晶的BO3基团非线性光学晶体.KABO有可能用于固态激光器的266nm及193nm高功率输出.本文对该晶体的物理化学性质及热学性质进行了研究,KABO晶体不潮解,不溶于水、酒精等溶剂,可溶于盐酸,硝酸和磷酸等强酸;测得莫氏硬度为5.5~6.5,用浮力法测得其密度为2.47g/cm3;用差热分析(DTA)方法测量其熔点为1109.7℃.用热重分析(TGA)方法结合分解产物的粉末X射线衍射(XRD)分析,确定KABO在900℃以上开始分解,分解产物主要为KAl11O17和K2Al24O37;用热机械分析仪测量了其热膨胀系数,沿物理学轴X、Y、Z方向分别为8.4×10-6/K、7.7×10-6/K、1.65×10-5/K.在室温至300℃温度范围内测量了KABO晶体的比热变化,比热随温度的升高线性增大.在47.6℃和294.6℃时比热分别为1.0084J/g℃与1.39J/g℃. 相似文献
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采用过冷熔体定向约束生长法生长了尺寸约为30 mm×14 mm×7 mm的块状4-氨基二苯甲酮晶体,并对生长晶体的光学均匀性、光学透过率、二次谐波转换效率以及激光损伤阈值等性能进行了测试.结果表明:定向生长的4-氨基二苯甲酮晶体在650~1200 nm波段内具有90;以上的光学透过率;最高二次谐波转换效率达到64.9;;单点激光脉冲损伤阈值分别为205.4 GW/cm2(输入光波为1064 nm)和267.2 GW/cm2(输入光波为532 nm).采用过冷熔体定向约束生长的4-氨基二苯甲酮晶体适合于用作Nd: YAG激光的二次倍频器件,也适合于用作650~1200 nm波段的光学调制器件. 相似文献
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Large single crystals of the non‐centrosymmetric hydrated tetraborates Na2[B4O5(OH)4] . 3H2O (Tincalconite) (point group 32) and K2[B4O5(OH)4] . 2H2O(point group 222) were grown from aqueous solutions and the linear optical properties (refractive indices between 365 nm and 1530 nm and unpolarized absorption spectra) as a basis for nonlinear optical investigations were determined. The uniaxial positive sodium salt is not phase matchable; in the orthorhombic potassium compound type I phase matching is possible in the near infrared region. Thermal investigations indicate a phase transition at ≈285 K for Na2[B4O5(OH)4] . 3H2O. 相似文献
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用提拉法沿a轴和c轴成功生长出质量优良的Nd:YbVO4新型单晶.采用HRXRD-D5005型高分辨X射线衍射仪测得晶体的摇摆曲线,可以测得(400)面的半峰宽为70.92″,(004)面的半峰宽为19.80″.测得掺杂浓度为1;原子分数Nd:YbVO4晶体中Nd离子的有效分凝系数Keff为0.54.在298.15~573.15K温度范围内测量了晶体的热膨胀系数,αa=2.6×10-6/K,αb=2.5×10-6/K,αc=8.7×10-6/K;测得比热值为0.45~0.65J/g·K.测量了晶体的热扩散系数a,从而得到了其热导率λ. 相似文献
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Nd:GdVO_4热常数的测量和激光性能研究 总被引:2,自引:0,他引:2
中频感应加热提拉法生长了低钕掺杂的GdVO_4晶体,用机械分析仪来测量Nd:GdVO_4晶体的热膨胀系数,沿c方向的热膨胀系数为7.42×10~(-6)/K,而沿α方向的热膨胀系数只有1.05×10~(-6)/K,比同比Nd_(0.0045)Y_(0.9946)VO_4晶体样品测量结果小。差示扫描热计法测量了Nd:GdVO_4晶体的比热,298K时为0.52J/g·K。首次用激光脉冲法测量了Nd:GdVO_4晶体的室温热导率。实验表明,Nd:GdVO_4晶体沿<001>方向的热导率数值达11.4W/m·K,比Nd:YAG晶体高(测得10.7W/m·K),其<100>方向的热导率为10.1W/m·K。激光实验显示在较高功率泵浦激光输出上Nd:GdVO_4晶体具有比Nd:YVO_4晶体更加优良的性能。 相似文献
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Y. Urata K. Akagawa S. Wada H. Tashiro S. J. Suh D. H. Yoon T. Fukuda 《Crystal Research and Technology》1999,34(1):41-45
Thulium-doped gadolinium vanadate (Tm:GdVO4) single crystal has been successfully grown by a modified Czochralski (CZ) technique. Effective distribution coefficient of Tm was determined to be 0.74. Absorption characterization was performed in the 800 nm region and the maximum absorption peak was found at 799 nm for p polarization. Fluorescence spectra for tuning at the maximum absorption were obtained around 1.8-2.0µm region with 100 nm bandwidth. This suggests that a Tm:GdVO4 crystal is expected as a new promising LD pumped solid-state laser in the 2µm region. 相似文献
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在LiNbO3中掺进ZnO和Fe2O3,以Czochralski技术生长Zn(7mol;):Fe(0.03;):LiNbO3,Zn(3mol;):Fe(0.03;):LiNbO3和Fe(0.03;):LiNbO3晶体.测试晶体的吸收光谱,Zn:Fe:LiNbO3晶体的吸收边相对Fe:LiNbO3晶体发生紫移.测试晶体的红外光谱,Zn(7mol;):Fe:LiNbO3晶体OH-吸收峰移到3529cm-1.测试晶体抗光致散射能力,Zn(3mol;):Fe:LiNbO3晶体抗光致散射能力比Fe:LiNbO3晶体提高一个数量级,Zn(7mol;):Fe:LiNbO3晶体比Fe:LiNbO3晶体高二个数量级.测试晶体的衍射效率和响应时间,Zn:Fe:LiNbO3晶体响应时间缩短,衍射效率降低.对吸收边和OH-吸收峰移动的机理,以及Zn:Fe:LiNbO3晶体抗光致散射能力增强的机理进行了研究. 相似文献
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Zh. X Cheng Sh.J. Zhang J.R. Han H.Ch. Chen X.S. Liu Y. Y Yang J. Yang 《Crystal Research and Technology》2001,36(2):135-140
NaY0.99Eu0.01(WO4)2 crystals were grown along <101> and <001> directions. Single crystals with high quality can be obtained when they were grown along <101> direction from a melt with a small deviation from stoichiometric composition. Eu ions exist in two valences in the as‐grown crystals, in one valence after annealing only. The fluorescence spectrum shows the Stark splitting of energy levels of Eu ions is in accordance with the site symmetry of S4. 相似文献
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X.‐Q. Wang D. Xu M.‐K. Lü D.‐R. Yuan G.‐H. Zhang F.‐Q. Meng S.‐Y. Guo M. Zhou 《Crystal Research and Technology》2001,36(1):73-84
Bimetallic thiocyanate complexes crystal materials belonging to ABTC structure type: ZnCd(SCN)4 and AHg(SCN)4 (A = Zn, Cd, Mn ) which are potentially useful in second harmonic generation (SHG) have been prepared. Their structural, optical and physicochemical properties are characterized by infrared spectroscopy, X‐ray powder diffraction, vis/UV/NIR spectroscopy, SHG measurements and thermal analysis. The states of crystal growth solutions are discussed in this article. The crystals belong to tetragonal system with the space group I‐4 and exhibit SHG efficiencies over one order of magnitude higher than that of Urea. Their transparency cutoffs lie in the UV region, and they possess good physicochemical stabilities. 相似文献
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Bridgman法生长的大尺寸钨酸铅晶体的光学和闪烁性能 总被引:2,自引:0,他引:2
本文报道了我们采用改进的Bridgman法为欧洲核子研究中心(CERN)大型强子对撞机(LHC)上的紧凑型μ子螺线管(CMS)实验生长的大尺寸掺Y3+钨酸铅闪烁晶体,给出了晶体的光学和闪烁性能,如光致发光谱、X射线致发光光谱、纵/横向的透射光谱、光产额以及辐照硬度.测试结果表明,掺Y2O3的钨酸铅晶体光产额很高(>13pe/MeV),且全为100ns以内的快发光,其辐照硬度已接近CMS电磁量能器(ECAL)端帽晶体的要求,同一批晶体彼此间的性能一致性好. 相似文献
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T. Lukasiewicz W. Ryba‐Romanowski J. Soklska M. Swirkowicz S. Golab Z. Galazka 《Crystal Research and Technology》2001,36(2):127-134
Single crystals of lithium tantalate (LiTaO3) doped with Pr, Nd + Yb and Tm were grown by the Czochralski method. A thermal system with 50 mm diameter iridium crucible and two different afterheaters (active and passive) was checked with respect to temperature distribution in a pulling region. The obtained crystals were up to 20 mm in diameter and up 50 mm in length. Crystals were poled, and the Curie temperature was determined for specimens cut of from different parts of single crystals. The polarized absorption spectra, time resolved emission spectra and emission lifetime of Pr3+ doped LiTaO3 crystals were measured. An intense emission from the 3P0 level was observed. Optical properties of the Yb3+ ions excited by energy transfer from Nd3+ ions have been researched for LiTaO3:Nd, Yb crystals. 相似文献
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X.Q. Wang D. Xu X.F. Cheng M.K. Lü D.R. Yuan J. Huang G.W. Lu T.X. Xie S.L. Wang G.T. Lü J.Q. Zhao Z.H. Yang Y. Chen Y.Q. Zhou 《Crystal Research and Technology》2002,37(6):551-563
In this article, diaquatetrakis (thiocyanato) manganese(II) mercury(II)‐N‐methyl‐2‐pyrrolidone, MnHg(SCN)4(H2O)2.2(C3H6CONCH3), (abbreviated as MMTWMP), a new organometallic nonlinear optical crystal material is reported. The structure, optical and thermal characterizations were determined by elemental analysis, infrared and Raman spectroscopy, X‐ray powder diffraction, thermogravimetric analysis, differential scanning calorimetry, special heat, SHG measurements and UV/Vis/NIR optical transmission spectra. It belongs to the tetragonal crystallographic system, with cell parameters: a = 12.1294, c = 8.2238Å, V = 1211.27Å3. Single crystals with dimensions up to 8 × 7 × 5 mm3 have been obtained. The morphology of the crystals was indexed. The MMTWMP crystal exhibits good physicochemical stability at normal temperature and pressure. Its UV transparency cutoff is 360 nm, which is shifted to the violet by 13 nm, as compared with MnHg(SCN)4 (MMTC); the optical transmission is 44.82% at 404 nm, which is by 17.46% higher than that of MMTC. 相似文献
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Sangen Zhao Guochun Zhang Kai Feng Jun Lu Yicheng Wu 《Crystal Research and Technology》2012,47(4):391-396
Bulk BPO4 crystals have been successfully grown from high temperature solution of BPO4, Li2O, and MoO3 in the molar ratio of 2.3:1:1.3 by the top‐seeded solution growth (TSSG) method using [101]c orientation seeds. There are no visible scattering centers and impurity of Mo in the as‐grown BPO4 crystals, whose optical homogeneity reaches up to 1.6×10–5/cm. BPO4 possesses a specific heat of 0.50–1.00 J·g–1·K–1 in the temperature range from 298 to 698 K and exhibits strong anisotropic thermal expansion behavior with αa = 14.2 × 10–6 K–1 and αc = ‐4.0 × 10–7 K–1. Moreover, the thermal conductivity coefficients are calculated to be κa = 62.4 W·m–1·K–1 and κc = 51.5 W·m–1·K–1, which are remarkably larger than those of some commonly used borates. The measured dielectric constants, εa and εc, are 4.8 and 6.1, respectively, and the ionic conductivity coefficients, σa = 4.3 × 10–8 S/cm and σc = 9.5 × 10–8 S/cm, are several orders of magnitude lower than that of LiB3O5 (LBO). (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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首次以LiF-H3BO3为助熔剂,用顶部籽晶法,生长出尺寸为12 mm×13mm×5mm的Ba2B5O9Cl透明单晶.通过热性能分析证实该晶体为非同成分熔融化合物,属于正交晶系,空间群Pnn2,晶胞参数为a=1.1576(2) nm,b=1.1619(2)nm,c =0.66874(13) nm,V=0.8994(3) nm3,Z=4.该晶体中含有BO3和BO3基团,具有三维网状的晶体结构.Ba2B5O9Cl粉末的非线性光学效应约为KDP的3.5倍,同时还进行了红外、漫反射光谱性能的研究. 相似文献