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A. Subbiah Pandi V. Rajakannan D. Velmurugan Masood Parvez Moon‐Jib Kim A. Senthilvelan S. Narasinga Rao 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(3):o164-o167
N‐(2‐Chlorobenzyl)‐1,2,3,4‐tetrahydroisoquinoline‐1,3‐dione, C16H12ClNO2, crystallizes in P21/n with three crystallographically independent molecules in the asymmetric unit, which differ slightly in conformation, N‐(2‐bromo‐4‐methylphenyl)‐1,2,3,4‐tetrahydroisoquinoline‐1,3‐dione, C16H12BrNO2, crystallizes in P21/n with one molecule in the asymmetric unit andN‐(2,3‐dichlorophenyl)‐1,2,3,4‐tetrahydroisoquinoline‐1,3‐dione, C15H9Cl2NO2, crystallizes in P21/c with one molecule in the asymmetric unit. In all three structures, the heterocyclic rings adopt approximately planar conformations. The pyridine rings are orthogonal to the substituted phenyl rings. In all three structures, the crystal packing is stabilized by intermolecular C—H?O hydrogen bonds. 相似文献
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M. Lipovská H.-G. Schmidt V. Roháč V. Rů ičkav G. Wolf M. Zábranský 《Journal of Thermal Analysis and Calorimetry》2002,68(3):753-766
Isobaric heat capacities C
p in the liquid and in the solid phase of 1,2-dichlorobenzene, 1,3-dichlorobenzene, 1,2,4-trichlorobenzene, 3-chlorophenol
and 4-chlorophenol and in the liquid phase of 2-chlorophenol were measured by commercial Setaram heat conduction and power
compensated calorimeters. Results obtained cover the following temperature range (depending on the compound and state of aggregation):
1,2-dichlorobenzene 208 to 323 K,1,3-dichlorobenzene 183 to 323 K, 1,2,4-trichlorobenzene 133 to 323 K, 2-chlorophenol from293
to 353 K, 3-chlorophenol and 4-chlorophenol from 133 to 353 K. The heat capacity data obtained in this work were merged with
available experimental data from literature, critically assessed and sets of recommended data were developed by correlating
selected data as a function of temperature. Temperature and enthalpy of fusion of two isomeric chlorophenols and of 1,2,4-trichlorobenzene
were also determined.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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Sutapa Ghosh Jason D. Jennissen Yaguo Zheng Fatih M. Uckun 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(10):1254-1257
The title compounds, 1‐cyano‐2‐hydroxy‐N‐[4‐(methylsulfonyl)phenyl]but‐2‐enamide, C12H12N2O4S, PHI492, 1‐cyano‐2‐hydroxy‐N‐[3‐(methylsulfonyl)phenyl]but‐2‐enamide, C12H12N2O4S, PHI493, and N‐[3‐bromo‐4‐(trifluoromethoxy)phenyl]‐1‐cyano‐2‐hydroxybut‐2‐enamide, C12H8BrF3N2O3, PHI495, are potent inhibitors of Bruton's tyrosine kinase (BTK). The molecular structures of these compounds are similar and they display similar hydrogen‐bonding networks and crystal packing. Examination of the crystal‐packing interaction in the three compounds reveals an alternating direction of adjacent molecules in the crystalline lattice due to intermolecular cyano–amide hydrogen bonding. PHI492, a positional isomer of PHI493, does not form intermolecular O—H?O hydrogen bonds between molecules and crystallizes in a space group different from that of PHI493 and PHI495. The aromatic ring and the amide group of each molecule form a conjugated π‐system which ensures planarity, with further stabilization gained from intramolecular O—H?O hydrogen bonds. 相似文献
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Ray Jones 《Acta Crystallographica. Section C, Structural Chemistry》2014,70(1):60-66
The structures of 6‐nitro‐1,3λ4δ2,5,2,4‐trithiadiazepine [C2HN3O2S3, ( 1 )], 6,7‐dinitro‐1,3λ4δ2,5,2,4‐trithiadiazepine [C2N4O4S3, ( 2 )], 1,3λ4δ2,5,2,4‐trithiadiazepine‐6,7‐dicarbonitrile [C4N4S3, ( 3 )] and 7‐acetyl‐1,3λ4δ2,5,2,4,6‐trithiatriazepine [C3H3N3OS3, ( 4 )] presented here include the most precise determinations of these seven‐membered 10 π‐electron aromatic ring systems published to date. Both ( 2 ) and ( 3 ) are sited around crystallographic twofold axes with half a molecule per asymmetric unit. Comparison with other published derivatives of these rings reveals the effect of substituents on bonding, conformations and intermolecular interactions, including π‐stacking. The deformation density analysis of ( 2 ) is consistent with the expected bonding electron density from other theoretical and experimental studies. 相似文献
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Miguel Harvey Sergio Baggio Alvaro Mombrú Ricardo Baggio 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(7):771-774
The three zinc sulfate complexes presented herein display three completely different coordination modes, viz triaqua(1,10‐phenanthroline‐N,N′)(sulfato‐O)zinc(II) hydrate, [Zn(SO4)(C12H8N2)(H2O)3]·H2O (octahedral, monomeric), bis(μ‐sulfato‐O:O′)bis[(2,9‐dimethyl‐1,10‐phenanthroline‐N,N′)zinc(II)], [Zn2(SO4)2(C14H12N2)2] (tetrahedral, dimeric), and catena‐poly[[diaqua(2,2′‐bipyridyl‐N,N′)zinc(II)]‐μ‐(sulfato‐O:O′)], [Zn(SO4)(C10H8N2)(H2O)2]n (octahedral, polymeric, twofold crystallographic symmetry). In the first, the sulfate is monodentate, while in the other two it acts as a bidentate bridge between two different Zn centers. There is a variety of sulfate S—O bond lengths, depending on the different coordination conditions and hydrogen‐bonding interactions. 相似文献
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A. Durif M. T. Averbuch-pouchot 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4)
Abstract The present work is more intended to illustrate three very different ways for the preparation of cyclotriphosphates than to describe three new types of such compounds. 相似文献
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Yuanjian Deng 《The Chemical Educator》2002,7(4):205-206
The system—surroundings concept is one of the most important in thermodynamics. Precisely defining a system is of critical importance to thermodynamic analysis. Even when studying the same problem, different individuals may opt to select different systems; therefore, choosing the correct system requires skill. In order to help students understand the various systems and their differences, a simple distillation setup is used to demonstrate the three thermodynamic systems: open, closed, and isolated. 相似文献
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Marilyn M. Olmstead James C. Fettinger Soya Gamsey Jacob W. Clary Bakthan Singaram 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(6):o333-o335
The structures of three chiral vinyldioxazaborocanes are reported, namely (2E)‐ and (2Z)‐6‐benzyl‐2‐buten‐2‐yl‐1,3,6,2‐dioxazaborocane, C27H30BNO2, (II) and (III), respectively, and (2Z)‐2‐buten‐2‐yl‐6‐isobutyl‐1,3,6,2‐dioxazaborocane, C24H32BNO2, (IV). These compounds may be useful in asymmetric reactions. In the structures reported here, the N—B donor–acceptor bond is longer than in any previously reported analogous compounds. 相似文献