Operating Parameters Optimization of Miniature Optically Pumped Cavity NH3 Submillimeter Wave Laser

By means of the iteration method, the output power density of the miniature optically pumped NH₃ submillimeter wave (SMMW) laser was calculated based on the density matrix equations of a quantum system. Optimization of operating parameters including operating gas pressure, reflection coefficients of input and output meshes of the laser were studied systematically. In the paper, the concepts of the average activated length and the synthetical optimum value were defined, and some rules of the optimization were explained successfully. Experimentally, a cavity NH₃ SMMW laser that was composed of a pair of inductive metallic meshes and pumped by TEA-CO₂ 10R(8) line was used. The experimental results were in good agreement with our theoretical calculations.     

A New Model of Calculating Miniature Optically Pumped Far-Infrared Laser

Considering the broadening of infrared pumping laser, the spectrum of miniature optically pumped superradiant NH₃ far-infrared laser pumped by CO₂-10R(8) has been calculated by solving density matrix equations and using iteration method. It is first time that the theoretical spectrum has been in good agreement with experimental results.     

Effects of Buffer Gas N2 on Miniature Optically Pumped NH3 Submillimeter Wave Cavity Laser Emission at 67.2 μm

The effect of buffer gas N₂ on miniature optically pumped NH₃ submillimeter wave (SMMW) cavity laser emission at 67.2m was studied theoretically and experimentally. It has been found that: 1. N₂ had a positive effect on laser output of 67.2m, 2. sharp absorption in laser spectrum under certain gases mixture pressure corresponded to the threshold of 'bottleneck effect.     

Spikes in raman spectrum of miniature optically pumped NH3 fir laser

In this paper, the semiclassical density matrix equation was solved to calculate the spectral characteristics of V₂:a--sR(0,0) transition in a miniature optically pumped NH₃ far infrared laser (mini-NH₃-OPFIRL), which was pumped by CO₂-10R(6) line. The results of theoretical calculation showed that the spikes in Raman spectrum of V₂:a--sR(0,0) would appear when the operating NH₃ gas pressure was higher than a certain critical value or pumping power density was lower than a certain critical value, which was caused by Raman processes interaction of AC-Stark splitting. In our experiment, 298 µm FIR spetral line of a--sR(0,0) pumped by a TEA-CO₂ laser with 10R(6) line was observed but the spikes could not be observed owing to the limitation of the resolution of the F-P interferometer.Supported by the National Natural Sciences Foundation of P.R.China.     

Spectral Characteristics of Miniature Two-Longitudinal-Mode Optically Pumped FIR Laser

With the assumption that the pump source was two-longitudinal-mode, the semiclassical density matrix equation of a three-energy-level system was solved. By means of iteration method, the spectral characteristics of miniature two-longitudinal-mode optically pumped NH₃ far-infrared cavity laser, which was pumped by CO₂-9R(16) line, were calculated numerically. The influences of operating parameters on laser spectrum were studied intensively.     

The Optimum Operation of an Unified Mini-Optically Pumped NH3 Submillimeter Wave Laser

An unified miniature optically pumped NH₃ submillimeter wave laser (OPSMMWL), including a mini TEA-CO₂ pump laser, was developed. It lased successfully with coherent emission at 67.2m, 90.4m and 151.5m. The optimum operation of the unified mini-OPSMMWL was studied experimentally and the relations among SMMW laser output power, operating gas pressure, length and coupling condition of the cavity were measured. It has been found that buffer gas N₂ has significant effect on 67.2m and 151.5m emissions and very wide band SMMW laser emission was a common feature of the mini-OPSMMW cavity laser.     

Doppler-free optoacoustic spectroscopy of O-18 methanol

The Doppler-free optoacoustic spectrum of the oxygen-18 species of methanol has been investigated with a CO₂ laser. Seventeen coincidences have been found between infrared absorptions of CH¹⁸₃OH and CO₂ laser lines. The strongest feature seen, pumped by the 10R(20) CO₂ laser line, has two plausible alternative identifications, determined from a parallel high-resolution spectroscopic study of the C-O stretching band. Further experimental tests are suggested to resolve the assignment, and predicted far-infrared laser frequencies are given for the two possibilities.     

Comparison Between Single-Longitudinal-Mode and Two-Longitudinal-Mode Pumping Cavity OPSMMWL

A CO₂ infrared laser system with a etalon to be the longitudinal mode select equipment was set up to be the optically pump source, as well as a mini NH3 with 20cm long sample tube to be the sub-millimeter wave laser. CO2-9R(16) line was chose to pump the mini-NH3 SMMW laser, and 90.4um SMMW line was obtained by single-longtudinal-mode or two-longitudinal-mode pumping. Experimental comparison of output power and operating gas pressure between single and two-longitudinal-mode OPSMMWL were studied. It was found that the two-longitudinal-mode OPSMMWL could get higher output power and broader spectrum, existed a lower operating gas pressure and wider range of operating gas pressure. These experimental results verified the theoretical calculations before.     

Sub-millimeter wave spectroscopy of CHD2OH: a-type and asymmetry induced c-type transitions in the lowest three torsional sub-levels

The sub-millimeter wave (SMMW) spectral measurements using a fast scan backward wave oscillator based spectrometer have been carried out for asymmetrically deuterated methanol CHD₂OH (Methanol-D₂). Transition frequencies have an estimated uncertainty of about ±50 kHz. Albeit the complexity in the spectra, assignments were possible for a large number of a-type (ΔK = 0) transitions. In the course of the assignment process a strong c-type (ΔK = 1) Q-branch connecting two states of different symmetry species has been identified. This Q-branch assignment is significant because it is forbidden in the normal parent species CH₃OH. It becomes allowed in the current species due to the effects of the asymmetry introduced by the off-axis deuterium in the hindering potential to the internal rotation in the molecule. The assignments are rigorously confirmed using combination relations which required the measurement of some other related lines. To our knowledge this is the first time such symmetry breaking transitions are reported in CHD₂OH and in fact this is the first time the SMMW spectrum of CHD₂OH is being reported. Detailed spectral study of this molecule in the IR and FIR regions is in progress and will be reported elsewhere. Detailed study of the identification optically pumped FIR laser line is underway.     

Assignments of optically pumped CD3OH laser lines

Six FIR laser lines from CD₃OH pumped by the 10R(36) and the 10R(18) CO₂ laser lines are assigned to specific rotational energy levels in the excited C–0 stretch state. It is found that their upper laser levels are shifted by a Fermi resonance between the C–0 stretch vibration and the third and forth harmonics of the torsional mode. The Fermi resonance shifts are +0.332 cm^–1 and +2.251 cm^–1 for the upper laser levels pumped by the 10R(36) and the 10R(18) CO₂ laser lines, respectively. Calculated frequencies of the pump and the laser transitions agree with those of the pump CO₂ laser lines and the observed FIR laser lines within estimated accuracy.     

Stimulated rotational Raman scattering at multiwavelength under tea CO2 laser pumping with a multiple-pass cell

Stimulated rotational Raman scattering (SRRS) at multiwavelength pumped by TEA CO₂ laser was demonstrated in this paper. Raman mediums were cooled by liquid-N₂ and a multiple-pass cell (MPC) with 25 passes was designed and used. When the para-H2 was pumped by single-longitudinal-mode (SLM) circular polarized TEA CO₂ laser on 10P(20), 9P(20), and 10R(20), 50 mJ 16.95 μm, 350 mJ 14.44 μm, and 536 mJ 16.9 μm radiations were obtained, corresponding to energy conversion efficiency of 1.2, 11.7, and 13.4%, respectively. When the ortho-D₂ was pumped by CO₂ laser on 10R(18), 108 mJ 12.57 μm Raman laser was obtained with energy conversion efficiency of 2.9%.     

Measurements and assignments of new large offset CD3OH FIR laser lines

By using an acoustooptic modulator we extend the 300 MHz tunability of a waveguide CO₂ laser to 480 MHz. The CD₃OH was optically pumped by the 10R(32), 10R(34), and 10R(36) CO₂ laser lines, and 17 new FIR laser lines were discovered. The Stark effect on previously known FIR laser lines was investigated, and some tentative FIR laser lines assignments are suggested.     

Infrared and far-infrared laser emissions from a TE CO2 laser pumped NH3 gas

In this paper, infrared (IR) and far-infrared (FIR) laser emissions from a TE CO₂ laser pumped NH₃ gas are reported. 8 IR laser emissions near the wavelength of 12 μm were observed by using 4 different CO₂ laser lines for the pumping. 3 IR laser emissions in P-branch of vibrational-rotational band (ν₂ → G) oscillated simultaneously in two pumping cases, i.e. pumping with the R(30) or R(16) line of 9.4 μm band from the CO₂ laser. 26 FIR laser emissions (26.45 μm ～ 281.0 μm) were observed by using 12 different CO₂ laser lines, and the 10 FIR emissions of them may be new laser emissions as far as we know.     

Laser characteristics of a new crystal Nd:Sr5(PO4)3F at 1.059 μm

The absorption spectrum of a new crystal Nd : Sr₅(PO₄)₃F or Nd : S-FAP, was measured, its two strong absorption peaks and broad effective absorption band showed that Nd : S-FAP can be appropriately pumped at 575 nm and 805.4 nm as well as with a xenon flashlamp. By using a tunable dye-laser (570.0~600.0 nm), a laser-diode (805 nm) and a xenon flash lamp as pump sources, respectively, the performance of a low threshold and high efficiency Nd:S-FAP laser at 1.059 (μm) (including pulse run, cw run, free-run and Q-switch run) has been demonstrated. The laser characteristics, such as the emission spectrum, the output energy, the output power, the pulse width, etc, were measured. In addition, the prospect of a Nd:S-FAP crystal for low-threshold high-efficiency miniature lasers is discussed.     

Near-millimetre wave emission from trioxan

The laser-emission spectrum of trioxan, when pumped by a CO₂ laser, has been extended. The lowest frequency obtained from this molecule has been measured at 144.86(2) GHz.     

Interaction enhancement of Raman processes in miniature opfirl

In miniature optically pumped FIR laser, NH₃ molecules pumped by CO₂ 9R(16) produce a pair of FIR Raman transition: saP(7,0) and aaP(7,1), which are very close in frequency. When the operating gas pressure is high, the interaction enhancement effect occurs, making the FIR output enhance very much.     

Experimental study on miniature pulsed CH3OH far-infrared laser

Using a grating tuned TEA-CO₂ laser with 9P(16) line to pump a 10cm or 20cm long miniature Fabry-Perot cavity CH₃OH laser, pulsed far infrared(FIR) lines of 570.6um and 918um wavelengths were observed, the latter is a new line. Operation performance and spectral characteristics of the miniature CH₃OH laser were studied. The project was supported by the Special Research Foundation of Doctorate Station in University of P.R.C.     

光泵NH3分子远红外激光研究

运用量子系统的密度矩阵理论，采用迭代法计算了光泵ＮＨ３分子远红外超辐射和腔式激光的频谱特性和相应的最佳工作气压。理论计算表明相对于超辐射方式，光泵腔式ＮＨ３分子远红外激光具有宽带辐射以及纵向调谐特性，且总的输出光强在一定条件下得到提高，最佳工作气压也较低。在实验上对ＴＥＡＣＯ２－１０Ｒ（８）和９Ｒ（１６）泵浦的Ｎ 红外超辐射和腔式激光器产生的远红外辐射进行了测量。结果表明理论计算与实验结果相符。     

Study of miniature optically pumped NH3 fir cavity laser

A miniature NH₃ molecule FIR cavity laser of 15cm in length pumped by a TEA CO₂ laser was built. The spectral characteristics of the cavity laser and the optimum operating parameters were studied.Supported by the National Natural Sciences Foundation of China     

Spike Phenomenon in Raman Spectrum of Optically Pumped Ear-Infrared Laser

Based on the theory of semi-classical density matrix, spike phenomenon of multi-longitudinal-mode CO2-9R(30) optically pumped miniature NH₃ molecules far-infrared cavity laser was theoretically studied and the reason of forming spike phenomenon was approved as two aspects: one was the competitive effect caused by the process of AC Stack splitting two photons, which made that the output optical spectral intensity of one AC Stark splitting peak was stronger than that of the other AC Stark splitting peak; the other was the longitudinal-mode spectral characteristics of laser resonant cavity.