Wave nature of moving striations in a longitudinal magnetic field

Wave nature of stationary moving striations in helium and neon discharges in a uniform longitudinal magnetic field is studied. With the increase of the magnetic field, the frequency of natural striations decreases, while the wave length increases, and they damp out at high field region. Artificial excitations in these gases show that the wave length is proportional to the excitation frequency for given magnetic field and the slope of linear lines increases with the field. These wave nature of striations is explained following the dispersion relation derived from the consideration of waves of ionization and including effects of the magnetic field on the ionization.     

Field ionization within the forbidden zone

Mass spectra of helium and neon obtained by field ionization in the presence of hydrogen or another low ionization potential gas contain lines indicating noble gas ions with energies exceeding those of the ordinary field ions by 16 or 13 eV, respectively. These ions originate from the apex-adsorbed state within the forbidden zone following excitation by impinging electrons from free-space ionization of the auxiliary gas.     

Hydrogen adsorption and absorption on evaporated Nb films: Study by measurements of work function changes

The field ionization of He-Ne, He-A, He-Kr, He-Xe and Ne-A gas mixtures is investigated. Only for the first three gas mixtures mentioned, an increased ionization rate (image promotion) is observed. The influence of field adsorbed neon on the image contrast in a helium field ion microscope is described. The best image voltage (BIV) for a He-Ne mixture corresponds to a minimum in image contrast. Furthermore, a number of rules governing the field ionization of rare gas mixtures are stated.     

The potential above field adsorbed gas atoms

The potential for a helium atom above field adsorbed helium and neon atoms near a tungsten surface has been calculated. The resulting binding energies at a field of 4.5 V/Å are in the order of 0.03 eV. In addition, the resulting dwelling probabilities for 20 and 80 K are given.     

Field evaporation end forms of tungsten

The anomalous field ion images consisting of bright bands of variable width parallel to the 〈111〉 zones, previously reported for tungsten pulse evaporated in helium at 78 K, have also been observed with neon as imaging gas. For both gases the upper limit to the pulse lengths for production of the bands is about 1 ms. The influence of the ratio, R, of pulse height to the total evaporation voltage on the intensity distribution in field ion images of tungsten has been studied for helium and neon together with the effect of residual gases peculiar to ion pumped stainless steel UHV systems (H₂, CH₄ and CO). It is found that when R is raised to a certain level traces of residual gases if present in sufficient quantities, can produce, with tungsten, images with intensity distributions similar to those found with molybdenum after slow evaporation. These are attributed to preferential adsorption of the residual gases on different parts of the specimen and, depending on the nature of the adsorbate, leading to a promotion or a reduction of the ionization probability of the imaging gas. It is pointed out that before an image can be described as typical of a particulaelement or alloy, the conditions of prior evaporation should be carefully controlled.     

Ion current generation in the field ion microscope: II. quasi-static approach

The field ion current is calculated for helium on tungsten, for various fields, and for various values of tip temperature and gas temperature on the basis of the balance equation developed by Van Eekelen. The expression of ion current by rate constants for ionization and for escape, the total supply and the capture probability is derived. The behaviour of ion current as a function of other parameters is discussed in the light of these equilibrium properties of the system. Field adsorption effects are also considered. The increase of the mass ratio of the gas atom to the metal atom causes the increase of ion current even if ionization probability is decreased by the field adsorption. Anomalous features of the field ion image at 4.2 K are discussed.     

Metal-neon compound ions in slow field evaporation

A magnetic sector atom-probe has been employed to study slow field evaporation of most of the transition metals in vacuum, in neon and in a mixture of neon and hydrogen. Various metals were found to form metal-neon molecular ions. Slow field evaporation and the presence of hydrogen are favorable for their formation. All the experiments were done at 78 K. The metals that evaporate as nei'des abundantly are Ti, Zn, Zr, Nb, Mo, Pd and Ta, of which Ti, Nb and Pd produce neïde ions as much as 80 to 90%. There were also some neïdes with W, Re, Ir and Rh, definitely above the detection limit estimated to be 3% of the field evaporating metal ions. The role of hydrogen is thought to be two-fold: At the surface, hydrogen adsorption is assumed to cause a stronger metal-neon bond, while the electron shower from free space ionization of the auxiliary gas excites or ionizes the complex by electron impact to allow evaporation at a reduced field.     

Field adsorption of helium and neon on metals: an integrated theory

Density functional theory has been used to carry out self-consistent calculations relating to the field adsorption of helium and neon on metal surfaces. The transition from physisorption in low electric fields to field-induced chemisorption in high electric fields is explicitly demonstrated with electron density maps. The higher binding energies of rare gases above protruding metal surface atoms are explained as resulting from local field enhancement, and an approximate formula for the helium-on-tungsten system is derived that gives the total short-range field-adsorption binding energy as a function of the external field and a local field-enhancement factor. A survey of earlier theoretical approaches to rare-gas adsorption in electric fields is included. The present treatment can be regarded as an integrated theory in which both covalent and polarisation effects have their place; it brings out the role of polarisation contributions to the total binding energy, and allows us to clarify the relationship between the earlier classical models and the present quantum theory of field-induced chemisorption.     

Townsend coefficient and efficiency of the formation of runaway electrons in neon

Basic ionization and drift properties are simulated for neon by the method of multiparticle dynamics. This calculation revealed that, in neon—in just the same way as in other gases that were studied previously—the Townsend ionization regime is realized even in strong fields if the distance between electrodes is rather large. The dependences of basic ionization and drift properties on the reduced electric-field strength are obtained. The results agree with available experimental data. The escape curve separating the region of efficient electron multiplication from the region in which electrons leave the discharge gap without undergoing multiplication is found for neon. The efficiency of the formation of a runaway-electron beam in helium and neon is simulated.     

On field adsorption,ionization rates and gas supply

The field ionization of a helium-neon mixture is analyzed to gain information about the imaging process in a field ion microscope. Quantitative measurements are performed on ionization rates, the number of jumps a helium atom performs before ionization and the fraction of helium atoms that escape ionization.     

Similarity Relations for Low Pressure Glow Discharges in Noble Gases

A simple three level atomic model that includes excitation, ionization, stepwise ionization, and diffusion is used to determine similarity relations for low pressure noble gas discharges. A two-temperature electron energy distribution is also included in the model. Similarity relations involving the reduced electric field, the electron main body temperature, the electron tail temperature, and the pressure-radius product are developed. It is found that the reduced electric field and the electron tail temperature depend on the discharge current as well as the pressure-radius product. Good agreement is obtained between the similarity relation predictions and experimental results in helium and neon discharges.     

Field ionization of free helium atoms: Correlation between the kinetic energy of ionized atoms and probability of their field ionization

In this paper the correlation between the kinetic energy of helium atoms and the probability of field ionization is investigated by exploiting the narrow velocity distribution of supersonic molecular beams. Field ionization measurements were carried out on supersonic helium beams at 298 K and 95 K corresponding to energies of about 65 meV and 20 meV, respectively, for the individual atoms. The field ionization was performed with a tungsten tip, radius of curvature 12 nm, kept at room temperature. The ionization probability was found to increase by about a factor 10 when the beam was cooled from 298 K to 95 K. The results presented in this paper are of importance for improving the understanding of field ionization and for the development of a new detector for helium and other molecular beams.     

Generation of an isolated sub-30 attosecond pulse in a two-color laser field and a static electric field

We theoretically investigate high-order harmonic generation(HHG) from a helium ion model in a two-color laser field,which is synthesized by a fundamental pulse and its second harmonic pulse.It is shown that a supercontinuum spectrum can be generated in the two-color field.However,the spectral intensity is very low,limiting the application of the generated attosecond(as) pulse.By adding a static electric field to the synthesized two-color field,not only is the ionization yield of electrons contributing to the harmonic emission remarkably increased,but also the quantum paths of the HHG can be significantly modulated.As a result,the extension and enhancement of the supercontinuum spectrum are achieved,producing an intense isolated 26-as pulse with a bandwidth of about 170.5 eV.In particular,we also analyse the influence of the laser parameters on the ultrabroad supercontinuum spectrum and isolated sub-30-as pulse generation.     

稀有气体在电离区压缩特性研究

采用Saha方程加Debye-Hückel修正简单近似模型,给出了稀有气体He, Ne, Ar, Kr, Xe在电离区的物态方程以及离化度.计算结果与已有实验和理论计算进行比较,验证了模型的可靠性.通过对稀有气体等温和冲击压缩特性理论分析,讨论了其压缩和电离的规律性.论证了在稀有气体He, Ne, Ar, Kr, Xe中,气体Xe具有较好的抗压缩性.     

Nonsequential two-photon double ionization of atoms: identifying the mechanism

We develop an approximate model for the process of direct (nonsequential) two-photon double ionization of atoms. Employing the model, we calculate (generalized) total cross sections as well as energy-resolved differential cross sections of helium for photon energies ranging from 39 to 54 eV. A comparison with results of ab initio calculations reveals that the agreement is at a quantitative level. We thus demonstrate that this complex ionization process can be described by the simple model, providing insight into the underlying physical mechanism. Finally, we use the model to calculate generalized cross sections for the two-photon double ionization of neon in the nonsequential regime.     

不同载气下气体相对电离度的光谱诊断

利用速度调制光谱技术,以N2+为分子探针,研究了N2在不同缓冲气体(氦和氖)下的电离行为.N2+某一振转吸收谱线的强度与速度调制的调制度和N2+浓度成正比,因而通过测量两种缓冲气体下光谱强度,即可推算出相对电离度.     

Enhanced field ionization of water adsorbed on a carbon monoxide-covered, platinum field emitter tip

The influence of carbon monoxide, adsorbed on a platinum field emitter tip, on field ionization of adsorbed water was examined. Ramped field desorption (RFD) measurements of water ionization were performed at 108 K for water layer thicknesses up to 80 ML on a clean or CO-saturated tip surface. In RFD the applied field is ramped linearly in time until water ionization is detected, giving the onset field of ionization. Water ionization yields hydrated hydroxide ions and protons; the hydroxide ions remain within the water layer on the tip, while the hydrated protons are emitted into vacuum. At a low water coverage of 1.5 ML, the CO adlayer substantially reduced the onset field of ionization (that is, facilitated ionization) of water by 40%, from a value of 0.43 V/Å for water on clean Pt to 0.26 V/Å for water on CO-covered Pt. The extent of the reduction gradually diminished with thicker coverages of water and was absent at coverages of 20 ML or greater. The characteristic decay length of the field enhancement was 4.7 ± 1 ML. The results were analyzed with the charge exchange model of ionization kinetics and changes in dipole moments of water adsorbed without and with CO. The analysis reveals that a change in water structure (dipole moment) caused by CO is an important contributor in field enhancement and that the dipole moment for hydrated hydroxide ion in an ice-like layer must be greater than that for bulk ice-like water. The significance of these results with respect to electrochemical oxidation of CO is discussed.     

Ionization of lithium in a strong laser field

In this work, we present ab initio computations of the interaction of helium and lithium with a strong laser field. By computing the two-and three-particle wave functions, we retain the full electron correlation and numerically integrate the time-dependent Schrödinger equation (TDSE) restricted to one dimension. The correlated nonsequential double ionization (NSDI) and the sequential double ionization (SDI) is studied. Our results show a clear transition from NSDI to SDI for increasing intensities. The correlated double ionization is found to be sensitive to the spin configuration of the ionized pair. Our model allows us to “measure” two different channels of double ionization (one with both spins aligned and one with spins antialigned).     

Total cross-sections for the scattering of positrons by helium,neon, and argon at intermediate energies

A slow positron beam time of flight system in which scattering is localised to a region of the flight path close to the slow positron source is described. Total cross-sections measured in helium, neon, and argon at intermediate energies are presented. The results for helium and neon are in agreement with the recent results of Brenton et al. While significant disagreement still exists in the argon data. The helium and neon data are in agreement with the sum rule predictions of Bransden et al.     

Interatomic electronic decay driven by nuclear motion

The interatomic electronic decay after inner-valence ionization of a neon atom by a single photon in a neon-helium dimer is investigated. The excited neon atom relaxes via interatomic Coulombic decay and the excess energy is transferred to the helium atom and ionizes it. We show that the decay process is only possible if the dimer's bond stretches up to 6.2 ?, i.e., to more than twice the equilibrium interatomic distance of the neutral dimer. Thus, it is demonstrated that the electronic decay, taking place at such long distances, is driven by the nuclear motion.