共查询到18条相似文献,搜索用时 65 毫秒
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稀土掺杂γ—Fe2O3气敏材料研究 总被引:7,自引:0,他引:7
采用化学共沉淀法合成了具有良好气敏特性的γ—Fe_2O_3微粉。通过稀土掺杂使γ—Fe_2O_3的显微结构得到改善,相转变温度得到提高,进而改善了γ-Fe_2O_3气敏材料的稳定性,提高了气体检测灵敏度。另外,不同稀土元素的掺杂使γ—Fe_2O_3气敏材料的气敏选择性得到改善。 相似文献
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氧化法制备纳米级α—Fe2O3气敏陶瓷粉体的比较 总被引:1,自引:0,他引:1
分别用空气氧化和H2O2氧化沉淀法制得了纳米级。α-Fe2O3气陶瓷粉料,对粉体进行了XRD物相分析及晶粒度,晶格畸变率的测定,以TEM观察其形貌并测得了平均粒径,采用迎头色谱法测定其比表面积。 相似文献
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Nd2O3掺杂对SnO2气敏性质的影响 总被引:1,自引:0,他引:1
SnO_2是目前应用最广的一种气敏材料。我们曾经报道掺入La_2O_3,CeO_2,Pr_6O_(11),和Nd_2O_3后可使半导体元件的灵敏度提高,尤以对乙醇、乙醚、丙酮为显著。掺Nd_2O_3元件对乙炔的灵敏度也有提高。本文考察了SnO_2粒度和被测气氛的物化性质对掺Nd_2O_3元件灵敏度的影响。SnO_2采用水解SnCl_4法制备,纯度经光谱分析测定合格,试样用标准筛分目。在SnO_2中加1wt%Nd_2O_3(光谱纯)和适量水及甲基纤维素,混磨15分钟。将制成的悬浊液滴在一对铂 相似文献
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气敏半导体材料Cd2Sb2O6.8的制备及其性能研究 总被引:1,自引:0,他引:1
采用化学共沉淀法,在较低温度(750℃)下制备了具有缺陷烧绿石结构的复合氧化物Cd2Sb2O6.8的纯相超微粉;研究了制备条件对物相、结构和气敏性能的影响,并对其反应过程机理进行了探讨,气敏性能测试结果表明,纯相Cd2Sb2O6.8气敏元件对乙炔气体有较高的灵敏度和较好的选择性. 相似文献
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在材料的合成与制备、组成与结构、性能及使用效能四者之间存在着强烈的相互依赖关系[1 ] 。一种材料的性质与其组成及结构息息相关 ,而组成与结构又是合成和制备的结果。合成与制备是提高材料质量的关键 ,也是开发新材料、新器件的中心环节。鉴于此 ,本文在前面工作[2~ 4] 的基础上 ,应用正交试验方法[5] ,探讨pH值、温度、搅拌速度三共沉淀反应条件对Sn Zn Fe复合氧化物气敏性能的影响。1 实验部分1 1 敏感材料的制备按表 1设计的正交试验方案 ,取物质的量相同的Sn、Zn、Fe氯化物混合液 ,在不同温度、搅拌速度条件下 ,… 相似文献
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用a-Fe_2O_3研制成的加热式气敏元件功耗大(约1.5W)。常温SnO_2-a-Fe_2O_3气敏元件功耗低(约0.1W),灵敏度高,响应恢复快,稳定,具有一定选择性。 气敏元件制备方法:按62.5%,6.2%和31.3%称取SnO_2,a-Fe_2O_3和硅胶,加水研磨2小时,使其呈浆糊状,点入模具内,放入一对φ0.05mm铂丝电极,晾干,脱模,在860~890℃空气中烧结95分钟。 相似文献
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Thermal oxide synthesis and characterization of Fe_3O_4 nanorods and Fe_2O_3 nanowires 总被引:1,自引:0,他引:1
JIAO Hua & YANG HeQing Key Laboratory of Macromolecular Science of Shaanxi Province School of Chemistry Materials Science Shaanxi Normal University Xi’an China Department of Chemistry Chemical Engineering Weinan Teacher’s University Weinan 《中国科学B辑(英文版)》2009,(5)
Fe3O4 nanorods and Fe2O3 nanowires have been synthesized through a simple thermal oxide reaction of Fe with C2H2O4 solution at 200-600℃ for 1 h in the air. The morphology and structure of Fe3O4 nanorods and Fe2O3 nanowires were detected with powder X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The influence of temperature on the morphology development was experimentally investigated. The results show that the polycrystals Fe3O4 nanorods with cubic structure and the av... 相似文献
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IntroductionTheaimofprcscllt\t-orbisthedot'clopmcntofcatal}-stsu'hicharchighl}'sclccti\'ctothes"nthcsisofCZandC3alcoholsfronls}'llgas.Cocatal}'stscanenhancetheproductionofCZalcohol.butthe}'arcalsoacti\'cfortheF-Ts}.nthcsisint'hichtheproductdistributionfol… 相似文献
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A spinel-type oxides ZnFe_2O_4 photocatalysts were prepared by citric acid complex method,and characterized with XRD,TG- DTA,FT-IR,TEM techniques.The photocatalytic activities were investigated by the degradation of C_3H_(22)N_6O_6S_2Na_2 by artificial visible Light.The results show that the photocatalytic activity of ZnFe_2O_4 is stable,under experimental conditions,the degradation rate of C3H22N6O6S2 is over 90% in 60min. 相似文献
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Enhancement of H2 Sensing Properties of In2O3-based Gas Sensor by Chemical Modification with SiO2 总被引:2,自引:0,他引:2
ZiLiZHAN DengGaoJIANG JiaQiangXU 《中国化学快报》2004,15(12):1509-1512
The sensitivity and selectivity to H2 of a new In203-based gas sensor were improved significantly by surface chemical modification. A dense layer of SiO2 near the surface of the porous In2O3 bead was formed by chemical vapor deposition (CVD) of diethoxydimethysilane (DEMS). The dense layer functioned as a molecular sieve, thereby the diffusion of gases with large molecular diameters, except for 1-12, was effectively controlled, resulting in a prominent selectivity and high sensitivity for H2. The working mechanism of the sensor was also presented. 相似文献
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WU Jin-Gang LI Shu-BenState Key Laboratory of Oxo Synthesis Selective Oxidation Lanzhou Institute of Chemical Physics Academia Sinica Lanzhou Gansu 《天然气化学杂志》1995,(3)
The oxidative coupling of methane over Mn2O3-Na2WO4/SiO2 catalyst has been investigated in the absence of dilute gas. 16.4% of C2 yield and 80.4% of the selectivity to C2 hydrocarbons were obtained at CH4/O2 = 8.5/1.5. The effect of flow rate on the selectivity to C2 hydrocarbons and CH4 conversion was different under the reaction condition of different ratio of CH4 to oxygen. The flow rate had a more remarkable effect on the selectivity at the lower ratio of methane to oxygen. The addition of steam into the reaction gas can increase C2 yield to some extent, but that of HC1 decrease the selectivity to C2 hydrocarbons. 相似文献
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水煤气变换催化剂Co—Mo—K/Al2O3的酸性对活性的影响 总被引:2,自引:1,他引:2
用吡啶吸附法研究了Co-Mo-K/Al_2O_3催化剂的酸性,K的加入,由于改变了催化剂的酸性,使其活性得以提高,硫的丢失也可改变酸性,但使催化剂的活性降低。初步探讨了催化剂酸性对活性影响的实质,提出了新的反应机理。 相似文献