Pressure-induced dislocation amorphization of crystals

In terms of the isotropic elastic crystal model, it is shown that the formation of planar layers consisting of edge dislocation pileups is advantageous in energy if the shear modulus of the crystal is far lower than the bulk modulus. As pressure rises, the dislocation radius decreases, which can destroy the crystal structure.     

存在异性夹杂的位错塞积

本文采用位错连续分布方法,导出了在外应力作用下异性夹杂和障碍之间相对障碍的单螺位错塞积和双螺位错塞积的分布函数的解析表达式D₁(η),D₂(η)。在靠近障碍一端,D₁(η)和D₂(η)具有-1/2次幂的奇异性,在靠近夹杂一端,D₂(η)具有-ω次幂的奇异性。并用双位错塞积的情况表示了与异性夹杂相接触的反平面剪切裂纹问题,导出了应力强度因子。这些表达式对于02/G₁<∞完全适用。对所得的结果进行了讨论。 关键词：     

The effects of the finest grains on the mechanical behaviours of nanocrystalline materials

This article proposes a new constitutive model to account for effects of the finest grains, with sizes ranging from 2 to 4 nm, on the mechanical behaviours of nanocrystalline (NC) materials. In this model, the normal nanograins (ranging from 20 to 100 nm) were treated as though they were composed of a grain interior (GI) and a grain boundary (GB) affected zone (GBAZ). The finest grains were considered to be part of the GBAZ, denoted as super triple junctions (STJs). For the initial plastic deformation stage of the NC materials, a phenomenological constitutive equation was suggested to predict the deformation behaviours of the GBAZ. The formation of GB dislocation (GBD) pileups provides dramatic strain hardening in deformed NC materials and thereby enhances their ductility. Then, the constitutive equations to describe the plastic deformation of the GI and the GBAZ lattice region were established. In this stage, the GBAZ are already saturated with GBD pileups, and GI deformation is the dominant mechanism. Finally, the mechanical model for the NC materials with the finest grains was built using the self-consistent method, and an overall moderate “work hardening,” sustained over a long range of plastic strain, was predicted. The effects of TJs/STJs on the deformation mechanism were quantitatively analysed. The analysis demonstrated that the existence of the finest grains will simultaneously lead to good strength and good ductility.     

Specific features in the generation and motion of dislocations in heat-treated silicon wafers

The specific features in the generation and motion of dislocations in silicon single-crystal wafers after different heat treatments are investigated by the four-point bending technique. It is demonstrated that annealing of silicon single-crystal wafers at a temperature of 450°C leads to their substantial hardening as compared to the postgrowth state. The oxygen-containing precipitates and precipitate dislocation pileups formed in the silicon wafer bulk during multistage heat treatment are efficient heterogeneous nucleation sites of dislocations under the action of thermal or mechanical stresses. It is found that the multistage heat treatment of the silicon wafers under conditions providing the formation of an internal getter within their bulk results in considerable disordering of the wafer structure. The inference is made that the formation of the defect state in the crystal lattice of silicon and the strength characteristics of silicon wafers substantially depend on the temperature-time schedules of the low-temperature stage of multistage heat treatment.     

Dislocation motion in anisotropic multilayer materials

Line integral forms for the elastic field of dislocations in anisotropic, multilayer materials are developed and utilized in Parametric Dislocation Dynamics (PDD) computer simulations. Developed equations account for interface image forces on dislocations as a result of elastic modulus mismatch between adjacent layers. The method is applied to study dislocation motion in multilayer thin films. The operation of dislocation sources, dislocation pileups, confined layer slip (CLS), and the loss of layer confinement are demonstrated for a duplex Cu/Ni system. The strength of a thin film of alternating nanolayers is shown to increase with decreasing layer thickness, and that the maximum strength is determined by the Koehler barrier in the absence of coherency strains. For alternating Cu/Ni nanolayers, the dependence of the strength on the duplex layer thickness is found to be consistent with experimental results, down to a layer thickness of ≈10nm.     

In situ and tomographic observations of defect free channel formation in ion irradiated stainless steels

The effects of heavy-ion irradiation on dislocation processes in stainless steels were investigated using in situ irradiation and deformation in the transmission electron microscope as well as post mortem electron tomography to retrieve information on the three-dimensional dislocation state. Irradiation-induced defects were found to pose a strong collective barrier to dislocation motion, leading to dislocation pileups forming in grain interiors and at grain boundaries. The passage of multiple dislocations along the same slip plane removes the irradiation defects and leads to the eventual formation of a defect-free channel. These channels are composed of densely tangled dislocation networks which line the channel-matrix walls as well as residual dislocation debris in the channel interiors. The structures of the dislocation tangles were found to be similar to those encountered in later stages of deformation in unirradiated materials, with the exception that they developed earlier in the deformation process and were confined to the defect free channels. Also, defect free channels were found to widen through both source widening as well as complex cross-slip mechanisms.     

Numerical calculation of the rate of strain of interstitial solid solutions under irradiation. I. Model of radiation creep

A model of radiation creep of interstitial solid solutions is developed on the basis of the combined motion of dislocations, including their glide and climb past obstacles. The obstacles considered are forest dislocations and pileups of radiation-induced point defects. A computational formula for the rate of strain is derived which describes creep at high stresses, when the gliding dislocations overcome some of the barriers by force, and a method is described for determining the average distance traversed by a dislocation in the glide plane under the influence of the stress until it is stopped by barriers. The results are compared with those of other authors. It is shown that the formula obtained for the rate of strain goes over in particular cases to those given by the previously known SIPA, Gittus-Mansur, and glide-climb models of radiation creep. Zh. Tekh. Fiz. 69, 64–71 (January 1999)     

The elastic field of general-shape 3-D cracks

We extend here the Bilby-Eshelby approach of 2-D crack representation with dislocation pileups to treat 3-dimensional cracks of general geometry. Cracks of any specified external bounding 3-D contour under general loading conditions are represented by sets of parametric Somigliana loops that satisfy total (interaction, self, and external) force equilibrium. Loop positions are solved by using a time integration scheme till equilibrium is achieved. The local Burgers vector is suitably adjusted to be proportional to the local applied surface traction on the crack. The developed method is computationally advantageous, since accurate crack stress fields are obtained with very few concentric parametric loops that adjust to the external crack shape and the local force conditions. The method is tested against known elasticity solutions for 3-D cracks and found to be convergent with an increase in the number of pileup dislocation loops. The method is applied to the determination of the stress field around a 3-D Griffith crack under general loading and a grain boundary crack before and after branching.     

The influence of rest on the micromechanical properties of preliminarily deformed MgO single crystals

The influence of a prolonged rest at room temperature on the activity of acoustic emission upon microindentation of preliminarily deformed MgO single crystals is investigated. It is found that the number of acoustic emission signals after the specimens have rested increases at low loads P (～50 g) applied to an indenter and decreases at high loads P (～200 g). The change observed in the activity of acoustic emission depends on the degree of preliminary deformation. It is assumed that the observed effects are associated with the difference between the sources of acoustic pulses: the main contribution to the activity of acoustic emission comes from the breakaway of dislocation pileups at low loads P and from the formation of microcracks and macrocracks at high loads.     

Quantitative x-ray topographic analysis of the defects of 6H-SiC single crystals and homoepitaxial silicon carbide

Planar dislocation pileups (PDPs) and curvilinear dislocation segments (CDSs) are considered as indicators of the local elastic shear stress fields (LESSFs) that existed in the growing single crystals at the time of stabilization of their dislocation structure. Calculations using the theory of dislocations with the experimental parameters of PDPs and CDSs measured from the x-ray topograms (taken by the Lang and divergent-polychromatic-beam (DPB) methods) give values of the LESSFs in the range (0.2–1.5)×10⁶ Pa for thin single-crystal wafers of SiC (6H) grown by sublimation in a graphite container. A strong nonuniform bending of the single-crystal wafers is observed; for the x-ray topographic study of the dislocation structure in these wafers the DPB method is preferable to the Lang method on account of its low sensitivity to bending. Zh. Tekh. Fiz. 69, 64–67 (July 1999)     

Effect of ausforming temperature and strain on the bainitic transformation kinetics of a low carbon boron steel

The effect of ausforming temperature and strain on the bainitic transformation kinetics was investigated in a low carbon boron steel. A new mechanism, which is based on the competition between the increase in nucleation rate and the decrease in average volume of bainite sheaf after deformation, is proposed. The increase in nucleation rate is due to the decrease in boron concentration at the grain boundaries after small deformation and the formation of sub-grain boundaries at the grain interior after large deformation. The decrease in average volume of bainite sheaf is ascribed to the frequent impingement of bainite sub-units after deformation. The increase in nucleation rate after deformation results in the decrease in incubation time, which is confirmed from the experiment. The increase in nucleation rate overcomes the decrease in average volume of bainite sheaf, resulting in the increase in transformation velocity and volume fraction after small deformation. On the contrary, the decrease in the average volume of bainite sheaf overcomes the increase in nucleation rate after large deformation, leading to the decrease in transformation velocity and volume fraction of bainite.     

引出口的几何参数对团簇形成影响的DSMC研究

利用直接模拟蒙特卡洛方法(DSMC),模拟了气体凝聚团簇源的引出口尺寸和中心位置不同的条件下,Cu团簇的尺寸分布以及模拟了随着时间的增长,腔内团簇数目的变化.模拟结果表明:引出口的直径越大,产生大团簇的比例越小;在引出口的直径相同的情况下,引出口的中心位置偏离坐标原点比在原点产生的大团簇的比例要大;随着时间的增长,腔内团簇数目先变多后变少.     

Photostability of a C<Subscript>60</Subscript> fullerene coating as a solid-phase photosensitizer of singlet oxygen

The stability of the optical properties and the generation efficiency of singlet oxygen of a solidphase photosensitizer based on fullerene in an aqueous suspension subjected to prolonged intense irradiation with visible light are studied in comparison with a photosensitizer based on methylene blue in an aqueous solution. Changes in the absorption spectra show that, as a result of 20-min irradiation, the content of fullerene decreases by 2% from its initial value, while that of methylene blue decreases by 19%. In both cases, the dynamics of the decrease in the photosensitizing ability of the photosensitizers in the course of their irradiation correlates with the changes in their spectra, but the magnitude of this decrease in the case of the solid-phase photosensitizer is greater than the magnitude of its spectral changes because of the surface nature of the photosensitization process. The study of the absorption spectra of fullerene coatings shows that their irradiation in water or in air causes the same photodegradation of fullerene. At the same time, studies with the help of the electron spin resonance (ESR) technique reveal differences in the nature of processes undergone by fullerene in water and in air.     

Influence of X-ray on the autophagic-lysosomal system in rat pancreatic acini

Lysosomes have an important role in radiation injury of cells and tissues. Activation of autophagy is frequently observed in different types of pathological tissue degeneration. In radiation response it increases in some cases, and lysosomes are responsible for regulated degradation of the autophagic vacuoles. Lysosomes are also involved in ionizing radiation induced cell death. In apoptosis lysosomes degrade content of the phagocytotic vacuoles derived from engulfed apoptotic blebs. On the other hand lysosomal enzymes discharged from disintegrated cells have a key role in induction of necrotic changes. In this work we investigate autophagy and lysosomal protein degradation in the relatively radiation insensitive exocrine pancreatic acini in vivo and in vitro. Type of cell death induced by X-ray was also examined in relation to the changes of the lysosomal processes. In 5h after 16 Gy in vivo whole body irradiation we observed significant increase in the cytoplasmic volume fraction of autophagic vacuoles and in the number of apoptotic cells in vivo. But in the acini isolated from irradiated rats we could not detect a change in the lysosomal degradation of intracellular proteins. Therefore irradiation probably influences the autophagy in an earlier step than lysosomal degradation. Extended necrotic lesions were not observed in vivo as long as 48 h. Isolated pancreatic acini usually contain more autophagic vacuoles than in vivo, but we could not observe additional increase in autophagy after 8 Gy, in vitro irradiation. Lysosomal degradation of intracellular proteins was also unaltered after 8 Gy, in vitro irradiation. Other biochemical functional parameters of the isolated pancreatic acini, like protein synthesis and amylase secretion were not changed either after 8 Gy, in vitro X-ray treatment. These results indicate that pancreatic acinar cells in vitro have a high tolerance to irradiation. The observed in vivo radiation induced changes of the exocrine pancreas are possibly indirectly induced by injuries of more sensitive mechanisms.     

Spectral luminescence properties of indotricarbocyanine dye in biological tissues

We have established that the shape and position of the maximum in the fluorescence spectrum of an indotricarbocyanine dye in tumor and normal tissues in vivo change over time after intravenous injection of the dye. Based on analysis of the spectral properties of the dye in vivo and in blood plasma, the dependence of the properties on the time since injection has shown that in the living body, the environment of the dye molecule changes as the photosensitizer goes from the skin into the tissue. We have established that in tissues in vivo, the dye molecules are localized in a region with low dielectric constant of the medium. We have shown that the change in the ratio of the concentrations of the different forms of hemoglobin in the blood has an effect on the absorption and shape of the fluorescence spectrum of the dye in tissues in vivo.     

Self-assembled monolayer resists and nanoscale lithography of silicon dioxide thin films by chemically enhanced vapor etching (CEVE)

We report on the use of electron-beam exposed monolayers of undecylenic acid in the etch rate enhancement of silicon dioxide films in HF vapor for the formation of nanoscale features in the oxide. Variations of the etching characteristics with electron beam parameters are examined and the results analyzed in terms of proposed models of the etching mechanism. Apparent variations in the relative concentrations of etch initiator with the thermal history of the samples prior to etching provides support for the dominant etch initiator within this system as the carboxylic acid moiety bound at the oxide surface. Other variations in the etching characteristics are discussed in terms of differences in localized concentrations of hydrocarbon crosslinks and the effect that this has upon the etch initiation. The process has been employed in the production of features in silicon dioxide surface masks with sizes down to 50 nm.     

Certain general questions of fast-electron transport II. Kinetic equations and conditions governing the accelerated motion of fast electrons in dielectrics in an electric field

A general kinetic equation for the differential density of fast particles moving in a medium in an external field is derived on the basis of the continuity equation in phase space. An equation is written for the differential flux in the case of fixed target particles. This equation is used to derive equations for fast electrons; account is taken of the coupling of energy-loss and scattering events in an electric field for various particular problems analogous to those studied in the theory of electron transport in the absence of a field. The kinetic equations are used to analyze the conditions governing accelerated motion of electrons in a dielectric in an external electric field in the continuous-deceleration approximation. Account is taken of fluctuations in the energy loss and of multiple scattering. There are two energy ranges of particles moving in a dielectric in which accelerated motion can occur; in the case of an electron beam with a continuous energy spectrum, this acceleration would be accompanied by monochromatization of the beam.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 7–12, February, 1972.     

Waveguide modes of 1D photonic crystals in a transverse magnetic field

We analyze waveguide modes in 1D photonic crystals containing layers magnetized in the plane. It is shown that the magnetooptical nonreciprocity effect emerges in such structures during the propagation of waveguide modes along the layers and perpendicularly to the magnetization. This effect involves a change in the phase velocity of the mode upon reversal of the direction of magnetization. Comparison of the effects in a nonmagnetic photonic crystal with an additional magnetic layer and in a photonic crystal with magnetic layers shows that the magnitude of this effect is several times larger in the former case in spite of the fact that the electromagnetic field of the modes in the latter case is localized in magnetic regions more strongly. This is associated with asymmetry of the dielectric layers contacting with the magnetic layer in the former case. This effect is important for controlling waveguide structure modes with the help of an external magnetic field.     

Technological applications of Mössbauer spectroscopy

A brief review is given of some recent industrial applications of Mossbauer spectroscopy. One of the most desirable futures of the Mossbauer effect is the feasibility of performing in situ measurements. Such measurements are extremely important especially in the upgrading of coal derived liquids. Such applications have been very successful in understanding the role of iron sulfides stoichiometries in direct coal liquefaction. The use of in situ techniques in invaluable in the investigation of the metal support interaction and their relation to carburization processes in Fischer-Tropsch reactions. Some examples of such applications will be presented in this paper. In this paper, emphasis will be placed in the use of a multiple technique approach to elucidate scientific problems of industrial importance.