锑掺杂氧化锡粉体的太赫兹透射特性

以SnCl45H2O和SbCl3为原料,采用液相化学共沉淀法制备锑掺杂氧化锡（ATO）粉体。分析了不同Sb掺杂质量分数条件下,ATO粉体的禁带宽度变化,并对材料在0.2~1.6 THz波段的透射时域和频域谱,以及吸收和屏蔽参数进行了对比分析。结果表明,ATO粉体的禁带宽度随着Sb掺杂量的增加先减小后增大;同时,ATO粉体对THz波的吸收系数随着Sb掺杂量的增加先增大后减小,当Sb掺杂质量分数为9%时,ATO的吸收系数在1.25 THz处达到最大值156.5 cm-1,屏蔽效能在1.24~1.60 THz范围内最高达到45.0 dB。     

锑掺杂氧化锡粉体的太赫兹透射特性

以SnCl45H2O和SbCl3为原料,采用液相化学共沉淀法制备锑掺杂氧化锡（ATO）粉体。分析了不同Sb掺杂质量分数条件下,ATO粉体的禁带宽度变化,并对材料在0.2~1.6 THz波段的透射时域和频域谱,以及吸收和屏蔽参数进行了对比分析。结果表明,ATO粉体的禁带宽度随着Sb掺杂量的增加先减小后增大;同时,ATO粉体对THz波的吸收系数随着Sb掺杂量的增加先增大后减小,当Sb掺杂质量分数为9%时,ATO的吸收系数在1.25 THz处达到最大值156.5 cm-1,屏蔽效能在1.24~1.60 THz范围内最高达到45.0 dB。     

热辐射研究综合实验平台的设计

设计了一个测量热辐射多个基本特性的综合实验平台,定量研究了辐射反平方定律、斯特藩-玻尔兹曼辐射定律、兰贝特余弦定律,且得到的数据与理论符合得较好,同时利用该平台还定性研究了基尔霍夫定律,揭示了物体的辐射能力与吸收能力的正相关性.该平台具有功能多、成本低、操作简便等优点,可引入大学物理实验教学中.     

热辐射基础实验

利用PASCO热辐射实验装置，进行了辐射体辐射出射度、反平方定律、斯特藩-玻尔兹曼辐射定律等基本实验的研究，并对测量结果进行了数据拟合，实验结果和理论模拟符合得很好。     

Surface and catalytic properties of doped tin oxide nanoparticles

Mixed oxides composed of Zn-Sn, Ti-Sn and V-Sn were prepared by a co-precipitation method and evaluated as catalysts for methanol oxidation in an ambient fixed-bed reactor. Surface analysis by X-ray photoelectron spectroscopy (XPS) revealed an electronic interaction between dopant and Sn atoms in the oxide structure and showed the formation of surface states associated with the dopants. Oxygen vacancies were present on the Zn-doped oxide, and the oxidation of methanol to carbon oxides was favored. The Ti-doped oxide exhibited a favorable selectivity to dimethyl ether, related to the oxygen anions near Ti centers. Vanadium dopants not only dramatically increased the catalytic activity but also promoted the partial oxidation of methanol to formaldehyde. Results demonstrate that the bridging dopant-O-Sn bond acts as active sites and influences product distribution.     

基于黑体辐射感温薄膜的瞬态高温传感器的设计

针对瞬态高温的测量难题,采用辐射式测温技术和接触式测温技术有机结合的方法,设计了由黑体辐射温度敏感体、圆柱状高强度金属外壳以及壳内信号调理电路构成的瞬态高温测量装置。通过对感温薄膜特殊材料的恰当选取以及整体结构的合理设计,并利用ANSYS软件对其黑体感温薄膜进行了瞬态高温热传导分析。分析表明,施加的温度载荷为2 000 ℃、2 500 ℃、3 000 ℃时,此温度传感器响应时间分别为487.001 s、545.001 s、590.001 s,能够克服传统瞬态温度传感器体积大、响应慢、安装不方便以及易受恶劣环境因素影响等不足,在测温技术领域具有良好的应用价值。     

Neutron radiation on tin anodes of lithium-ion batteries

Abstract

The operating durability of lithium-ion batteries is a principal problem in universe exploration or rescuing work in the nuclear radiation area. In the study, the neutron irradiation experiments were conducted on film-tin electrodes using the radiation dose of 10¹¹, 10¹², 10¹³ and 10¹⁴?n?cm^?2, respectively. The results show that the particle size grows with the increasing radiation does by atomic force microscopy (AFM) and scanning electron microscope (SEM). In addition, the degressive trend of specific capacity of tin anodes after neutron radiations increases with the increasing radiation dose. The fade of electrochemical performances may be attributed to the increasing particle size and defects induced by neutron radiation.     

反射率测量中的热辐射影响及其消除方法

 反射率测量过程中,被激光加热的材料发出热辐射光,对探测器测量存在明显干扰,给测量结果带来了较大误差,该现象普遍存在于以往的测试工作中。通过深入分析热辐射特性,在反射率测量装置中加入透过波长不同于加载激光波长的探测器,探测热辐射在该透过波长下的光强信号,并利用比对法消除了反射率测量过程中的热辐射干扰,使高温段的反射率测量精度得到较大提高。     

Effect of fabrication conditions on the properties of indium tin oxide powders

This paper reports that indium tin oxide （ITO） crystalline powders are prepared by coprecipitation method. Fabrication conditions mainly as sintering temperature and Sn doping content are correlated with the phase, microstructure, infrared emissivity c and powder resistivity of indium tin oxides by means of x-ray diffraction, Fourier transform infrared, and transmission electron microscope. The optimum sintering temperature of 1350℃ and Sn doping content 6～8wt% are determined. The application of ITO in the military camouflage field is proposed.     

Electrical, structural and surface properties of fluorine doped tin oxide films

Fluorine (F) incorporated polycrystalline SnO₂ films have been deposited onto glass substrates by ultrasonic spray pyrolysis technique. To possess information about the electrical properties of all films, their electrical conductivities were investigated depending on the temperature, and their activation and trap energies were analyzed. The crystalline structure, surface properties and elemental analysis of the SnO₂ films were examined to determine the effect of the F element. After all investigations, it was concluded that each fluorine incorporation rate has a different and important effect on the physical properties, and SnO₂:F (3 at%) films were found to be the most promising sample for energy conversion devices, especially as conducting electrode in solar cells with its improved structural and electrical properties as compared to others.     

水基ZnO纳米流体电导和热导性能研究

利用水热法生成了形状规则、粒径均匀的球形ZnO纳米颗粒, 并超声分散于水中, 制备得到稳定的水基ZnO纳米流体. 实验测量水基ZnO纳米流体在体积分数和温度变化时的电导率, 并测试室温下水基ZnO纳米流体在不同体积分数下的热导率. 实验结果表明, ZnO纳米颗粒的添加较大地提高了基液(纯水)的热导率和电导率, 水基ZnO纳米流体的电导率随纳米颗粒体积分数增加呈非线性增加关系, 而电导率随温度变化呈现出拟线性关系; 纳米流体的热导率与纳米颗粒体积分数增加呈近似线性增加关系. 本文在经典Maxwell热导模型和布朗动力学理论的基础上, 同时考虑了吸附层、团聚体和布朗运动等因素对热导率的影响, 提出了热导率修正模型.将修正模型预测值与实验值对比, 结果表明修正模型可以较为准确地计算出纳米流体的热导率. 关键词： 水热法 电导率 热导率 热导模型     

氧化锌锡薄膜晶体管的研究

在ITO玻璃基底上用射频磁控溅射技术生长氧化锌锡(ZnSnO)沟道有源层、用PECVD生长SiO₂薄膜作为薄膜晶体管的栅绝缘层研制了薄膜晶体管(TFT), 器件的场效应迁移率最高达到μ_n=9.1 cm²/(V ·s),阈值电压-2 V,电流开关比为10⁴. 关键词： 氧化锌锡 薄膜晶体管 场效应迁移率     

反射率测量中的热辐射影响及其消除方法

反射率测量过程中,被激光加热的材料发出热辐射光,对探测器测量存在明显干扰,给测量结果带来了较大误差,该现象普遍存在于以往的测试工作中。通过深入分析热辐射特性,在反射率测量装置中加入透过波长不同于加载激光波长的探测器,探测热辐射在该透过波长下的光强信号,并利用比对法消除了反射率测量过程中的热辐射干扰,使高温段的反射率测量精度得到较大提高。     

Electrical and optical properties of indium tin oxide/epoxy composite film

The electrical and optical properties of the indium tin oxide(ITO)/epoxy composite exhibit dramatic variations as functions of the ITO composition and ITO particle size. Sharp increases in the conductivity in the vicinity of a critical volume fraction have been found within the framework of percolation theory. A conductive and insulating transition model is extracted by the ITO particle network in the SEM image, and verified by the resistivity dependence on the temperature.The dependence of the optical transmittance on the particle size was studied. Further decreasing the ITO particle size could further improve the percolation threshold and light transparency of the composite film.     

Direct calculation of energy streamlines in near-field thermal radiation

Accurate prediction of the energy propagation direction and the associated lateral shift is very important for the design of efficient energy conversion devices and sensors based on nanoscale thermal radiation. This paper concerns the direction of energy flow during near-field radiative transfer between two parallel plates separated by a vacuum gap. An improved formulation, fully consistent with fluctuational electrodynamics, is developed to correctly trace the energy streamlines inside the emitter, receiver, and the vacuum gap. The influence of surface waves on the direction of energy propagation as well as on the lateral shift of energy streamlines is elucidated. An important finding with the improved formulation is that the lateral shift in the emitter may exceed that in the vacuum gap. The method can be extended for tracing the energy streamlines in multilayered structures.     

Structural and optoelectronic properties of antimony tin sulphide thin films deposited by thermal evaporation techniques

Thin films of SnSb₂S₄ have been prepared on glass substrate by using thermal evaporation techniques. The films were annealed in argon gas at low pressure in sealed glass ampoules at 85 °C, 150 °C, 275 °C and 325 °C. XRD of the films reveal that the low temperature annealed films are poly crystalline while the as deposited films and high annealed films are in amorphous states. There is no adequate variation in the photoconductivity response of the amorphous and crystalline phases. The transmittance of the films is low and having no transmittance below 740 nm. The band gap calculated by ellipsometry technique is in the range of 1.82–3.1 eV. The films have n-type conductivity but the film annealed at 325 °C show p-type conductivity.     

质子辐照对MQ硅树脂增强的加成型硅橡胶质损及热性能的影响

采用空间综合辐照模拟设备研究了100 keV和150 keV能量的质子辐照对MQ硅树脂增强的加成型硅橡胶的损伤及其对硅橡胶热性能的影响。试验结果表明：质子辐照后,硅橡胶表面出现损伤裂纹,随辐照能量和剂量的增加,裂纹的数量增多,裂纹增大;质子辐照后,硅橡胶的质量有所损失,其质损率随辐照能量和剂量的增加而增加;质子辐照后硅橡胶的耐热性随辐照剂量的增加先略有增加而后下降,经辐照后的硅橡胶在玻璃态和玻璃转变区的温度区间内收缩率降低,而在高弹态的温度区间内膨胀率增加。     

Dual solutions in boundary layer flow of a moving fluid over a moving permeable surface in presence of prescribed surface temperature and thermal radiation

An analysis of the heat transfer for a boundary layer forced convective flow past a moving permeable flat surface parallel to a moving fluid is presented. Prescribed surface temperature at the boundary is considered. A thermal radiation term in the energy equation is considered. The similarity solutions for the problem are obtained and the reduced ordinary differential equations are solved numerically. To support the validity of the numerical results, a comparison is made with the available results for some particular cases of this study. Dual solutions exist when the surface and the fluid move in the opposite directions.     

气动光学头罩热辐射效应数值仿真研究

气动热环境下高速飞行器的光学头罩由于受气动热效应作用,其温度急剧升高,产生严重的气动热辐射效应。为评估气动热环境下高速飞行器光学头罩热辐射对探测系统性能的影响,采用有限光线代表连续辐射的方法,并引入热瞳概念建立了气动光学头罩热辐射传输计算模型并对气动光学头罩自身干扰辐射光线在光学系统内的传输进行了数值仿真,考察了光学头罩温度场为非均匀分布时其自身干扰辐射在探测器接收面的辐照度分布。研究结果表明:由头罩顶点求得的热瞳是光学头罩热辐射能的公共入口,它可将光线追迹的时间减小至追迹全部光线所需时间的十几分之一;根据探测器接受面干扰辐射随时间的变化趋势可知在飞行数秒后头罩干扰辐射将淹没目标信号,气动光学头罩热辐射效应不容忽视。     

热控涂层光学性能退化模型研究

在实验研究成果的基础上,给出了热控涂层在空间辐照作用下的退化模型,接着用渐变折射率的概念对复折射率材料热控涂层的光学性能进行了分析,得到了退化前后热控涂层光学性能变化的表达式,最后对热控涂层光学性能退化模型的应用进行了探讨. 关键词： 热控涂层 渐变折射率 辐照 退化