共查询到20条相似文献,搜索用时 15 毫秒
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Congcong Wu Kai Wang Yongke Yan Dong Yang Yuanyuan Jiang Bo Chi Jianzhao Liu Alan R. Esker Jennifer Rowe Amanda J. Morris Mohan Sanghadasa Shashank Priya 《Advanced functional materials》2019,29(12)
Lead halide perovskite solar cells (PSCs) have demonstrated great potential for realizing low‐cost and easily fabricated photovoltaics. At this juncture, power conversion efficiency and long‐term stability are two important factors limiting their transition. PSCs exhibit rapid environmental degradation since the perovskite layer is very sensitive to factors such as humidity, temperature, and ultraviolet light. Here, a novel successful approach is demonstrated that simultaneously improves the efficiency and stability of PSCs. This approach relies on incorporation of a dual‐functional polymethyl methacrylate (PMMA)–fullerene complex into the perovskite layer. The fullerene within perovskite layer forms a localized dipole‐like electric field that favors electron–hole separation, resulting in significant improvement in current density and fill factor with conversion efficiency reaching 18.4%. The molecular‐scale coating of hydrophobic PMMA on the perovskite grain boundary effectively blocks moisture penetration into the perovskite, thereby, significantly improving the stability against moisture, heat, and light. The PSCs with PMMA–fullerene complex showed no photovoltaic performance degradation for 250 d and exhibited 60 times higher stability compared to the state‐of‐the‐art devices under continuous 1 sun illumination in ambient air. 相似文献
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Perovskite Solar Cells: Unique Seamlessly Bonded CNT@Graphene Hybrid Nanostructure Introduced in an Interlayer for Efficient and Stable Perovskite Solar Cells (Adv. Funct. Mater. 32/2018) 下载免费PDF全文
Xuanhua Li Tengteng Tong Qinjiang Wu Shaohui Guo Qiang Song Jian Han Zhixiang Huang 《Advanced functional materials》2018,28(32)
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Perovskite Solar Cells: All‐Carbon‐Electrode‐Based Endurable Flexible Perovskite Solar Cells (Adv. Funct. Mater. 11/2018) 下载免费PDF全文
Qiang Luo He Ma Qinzhi Hou Yingxiang Li Jing Ren Xuezeng Dai Zhibo Yao Yu Zhou Lichen Xiang Huayun Du Hongcai He Ning Wang Kaili Jiang Hong Lin Huaiwu Zhang Zhanhu Guo 《Advanced functional materials》2018,28(11)
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Solar Cells: Morphological Stabilization by Supramolecular Perfluorophenyl‐C60 Interactions Leading to Efficient and Thermally Stable Organic Photovoltaics (Adv. Funct. Mater. 10/2014) 下载免费PDF全文
Ming‐Hung Liao Che‐En Tsai Yu‐Ying Lai Fong‐Yi Cao Jhong‐Sian Wu Chien‐Lung Wang Chain‐Shu Hsu Ian Liau Yen‐Ju Cheng 《Advanced functional materials》2014,24(10):1492-1492
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Fengyou Wang Yuhong Zhang Meifang Yang Donglai Han Lili Yang Lin Fan Yingrui Sui Yunfei Sun Xiaoyan Liu Xiangwei Meng Jinghai Yang 《Advanced functional materials》2021,31(5):2008052
Organolead halide hybrid perovskite solar cells (PSCs) have become a shining star in the renewable devices field due to the sharp growth of power conversion efficiency; however, interfacial recombination and carrier-extraction losses at heterointerfaces between the perovskite active layer and the carrier transport layers remain the two main obstacles to further improve the power conversion efficiency. Here, novel field-effect passivation has been successfully induced to effectively suppress the interfacial recombination and improve interfacial charge transfer by incorporating interfacial polarization via inserting a high work function interlayer between perovskite and holes transport layer. The charge dynamics within the device and the mechanism of the field-effect passivation are elucidated in detail. The unique interfacial dipoles reinforce the built-in field and prevent the photogenerated charges from recombining, resulting in power conversion efficiency up to 21.7% with negligible hysteresis. Furthermore, the hydrophobic interlayer also suppresses the perovskite decomposition by preventing the moisture penetration, thereby improving the humidity stability of the PSCs (>91% of the initial power conversion efficiency (PCE) after 30 d in 65 ± 5% humidity). Finally, several promising research perspectives based on field-effect passivation are also suggested for further conversion efficiency improvements and photovoltaic applications. 相似文献
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Solar Cells: Inorganic Rubidium Cation as an Enhancer for Photovoltaic Performance and Moisture Stability of HC(NH2)2PbI3 Perovskite Solar Cells (Adv. Funct. Mater. 16/2017) 下载免费PDF全文
Yun Hee Park Inyoung Jeong Seunghwan Bae Hae Jung Son Phillip Lee Jinwoo Lee Chul‐Ho Lee Min Jae Ko 《Advanced functional materials》2017,27(16)
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Solar Cells: Highly Stable Colloidal “Giant” Quantum Dots Sensitized Solar Cells (Adv. Funct. Mater. 30/2017) 下载免费PDF全文
Gurpreet S. Selopal Haiguang Zhao Xin Tong Daniele Benetti Fabiola Navarro‐Pardo Yufeng Zhou David Barba François Vidal Zhiming M. Wang Federico Rosei 《Advanced functional materials》2017,27(30)
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Directional Motion: Electric Field and Gradient Microstructure for Cooperative Driving of Directional Motion of Underwater Oil Droplets (Adv. Funct. Mater. 44/2016) 下载免费PDF全文
Dongliang Tian Linlin He Na Zhang Xi Zheng Yuhai Dou Xiaofang Zhang Zhenyan Guo Lei Jiang 《Advanced functional materials》2016,26(44):8148-8148
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Perovskite Solar Cells: Heteroatom Effect on Star‐Shaped Hole‐Transporting Materials for Perovskite Solar Cells (Adv. Funct. Mater. 31/2018) 下载免费PDF全文
Inés García‐Benito Iwan Zimmermann Javier Urieta‐Mora Juan Aragó Joaquín Calbo Josefina Perles Alvaro Serrano Agustín Molina‐Ontoria Enrique Ortí Nazario Martín Mohammad Khaja Nazeeruddin 《Advanced functional materials》2018,28(31)
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