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1.
The reaction behavior of the title complexes have been investigated by means of in situ IR in nitrogen atmosphere. It has been found that they enabled the acetic acid to convert to acetone and methane in different temperatures. The results indicate that the sequence of the ketonization reaction activity for the clusters was [V3OAT] > [VFe2OAT], [V2CrOAT] > [Fe3OAT], [VCr2OAT] > [Cr3OAT] [OAT = (mu 3-O) (mu-O2CCH3)6 (THF)3], and the sequence of the methanation reaction activity for the clusters was [Cr3OAT] > [VCr2OAT], [V2CrOAT] > [V3OAT] > [VFe2OAT], [Fe2OAH]. The ketonization reaction activity of [Fe3OAT] were obviously lower than that of [Fe3OAH] [OAH = (mu 3-O) (mu-O2CCH3)6 (H2O)3] and the methanation reaction activity of [Cr3OAT] were also much lower than that of [Cr3OAH]. The difference between [Fe3OAH], [Cr3OAT] and [Fe3OAH], [Cr3OAH] mentioned above were discussed. 相似文献
2.
A. Ekers M. Głódź J. Szonert B. Bieniak K. Fronc T. Radelitski 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2000,8(1):49-58
The results of an experimental study of population dynamics following excitation of [0pt] and [0pt] states of rubidium are reported. Excitation transfer and quenching cross-sections in collisions with ground state rubidium
atoms, and natural lifetimes have been measured. The experiment was performed in a vapour cell, using pulsed two-photon excitation
and photon counting detection. The analysis of time dependent signals was based on a rate equation model in which transitions
induced by thermal radiation have been accounted for. The measurements yielded following results: (1) [0pt] state J-mixing cross-section: [0pt] ; (2) cross-sections for [0pt] excitation transfer process: [0pt] ; (3) quenching cross-sections: [0pt] , [0pt] , [0pt] ; [0pt](4) radiative lifetimes: [0pt] ns, [0pt] ns, [0pt] ns.
Received 1st December 1998 and Received in final form 17 May 1999 相似文献
3.
Kaoru Nakajima Shinichi Oshima Motofumi Suzuki Kenji Kimura 《Surface science》2012,606(21-22):1693-1699
Surface structures of equimolar mixtures of imidazolium-based ionic liquids (ILs) having a common cation (1-butyl-3-methylimidazolium ([C4MIM]) or 1-hexyl-3-methylimidazolium ([C6MIM])) and different anions (bis(trifluoromethanesulfonyl)imide ([TFSI]), hexafluorophosphate ([PF6]) or chlorine) are studied using high-resolution Rutherford backscattering spectroscopy (HRBS). Both cations and anions have the same preferential orientations at the surface as in the pure ILs. In the mixture, the larger anion is located shallower than the smaller anion. The [TFSI] anion is slightly enriched at the surface relative to [PF6] with coverage of ~ 60% for the equimolar mixtures of [C4(6)MIM] [TFSI] and [C4(6)MIM] [PF6]. No surface segregation is observed for [C6MIM] [TFSI]0.5[Cl]0.5 and [C6MIM] [PF6]0.5[Cl]0.5. These results are different from the recent TOF-SIMS measurement where very strong surface segregation of [TFSI] was concluded for the mixture of [C4MIM] [TFSI] and [C4MIM] [PF6]. 相似文献
4.
S G Revoile L Kozma-Spytek L Holden-Pitt J M Pickett J Droge 《The Journal of the Acoustical Society of America》1991,89(1):457-460
Moderately to profoundly hearing-impaired (n = 30) and normal-hearing (n = 6) listeners identified [p, k, t, f, theta, s] in [symbol; see text], and [symbol; see text]s tokens extracted from spoken sentences. The [symbol; see text]s were also identified in the sentences. The hearing-impaired group distinguished stop/fricative manner more poorly for [symbol; see text] in sentences than when extracted. Further, the group's performance for extracted [symbol; see text] was poorer than for extracted [symbol; see text] and [symbol; see text]. For the normal-hearing group, consonant identification was similar among the syllable and sentence contexts. 相似文献
5.
The 1H and 13C NMR spectra of sugar (5-methyl [1, 2, 4]-triazino [5, 6-b] indol-3-yl) hydrazones (1), per-0-acetyl aldehydo sugar 1-acetyl-1-(5-methyl [1, 2, 4] triazino [5, 6-b]-indol-3-yl) hydrazones (2), l- (penta-0-acetyl-pentitol-1-yl)-10-methyl [l, 2, 4] triazolo [3′, 4′:3, 4] [l, 2, 4] triazino [5, 6-b]-indoles (3) have been investigated. The 2 D NMR (H, C COSY) spectrum of 2a has been studied. 相似文献
6.
The effect of the orientation on the magnetostriction in Fe 81 Ga 19 alloy has been investigated experimentally and theoretically.The Fe 81 Ga 19 [001] and [110] oriented crystals were prepared and the magnetostriction was measured under different pre-stress.The saturation magnetostriction of the [001] oriented crystal increases from 170×10-6 to 330×10-6 under the pre-stress from 0 to 50 MPa.The [110] oriented crystal has a saturation magnetostriction from 20×10-6 to 140×10-6 with the compressive pre-stress from 0 to 40 MPa.The magnetostriction of [001] and [110] oriented crystals has been simulated based on the phenomenological theory.The domain rotation path has been determined and the resultant magnetostriction calculated under different pre-stress.The experimental and simulated results both show that the [001] oriented crystal exhibits better magnetostriction than [110] oriented crystal.The enhancement of the saturation magnetostriction by the compressive pre-stress in the [110] oriented crystal is higher than that in the [001] oriented crystal. 相似文献
7.
Previous reports have seldom concerned about the RTILs (Room temperature ionic liquids), and their effects on derivatization
reaction or derivatives. In this study, we reported that the effects of four different RTILs, i.e., [EMIM]PF6, [BMIM]PF6, [HMIM]PF6 and [OMIM]PF6, on fluorescence spectra of 17 β-estradiol (E2), and its derivatization solvent dansyl chloride (DNSCl) and the derivative.
[BMIM]PF6 had a significant quenching effect on the fluorescence intensity of E2, suggesting the formation of [BMIM]PF6/E2 complexes and possible buried E2 molecular in a more hydrophobic microenvironment. The estimated Stern-Volmer quenching
constant (Ksv = 0.3519) proved that E2 quenching caused by [BMIM]PF6 was a dynamic quenching process. Four RTILs, with different alkyl chain-length in imidazolium cation, resulted in different
quenching intensities to E2 as follows: [EMIM]PF6 > [BMIM]PF6 > [HMIM]PF6 > [OMIM]PF6. At 5 mg L−1 of DNSCl, [BMIM]PF6, [HMIM]PF6 and [OMIM]PF6 increased the fluorescence intensities of E2 in water by 8.5, 7.6 and 6.1 times, respectively, and a 37-nm hypsochromic shift
occurred. The fluorescence intensity for [BMIM]PF6-extracted derivative of E2 increased more than two times compared with that for the control. In conclusion, this study demonstrated
that above four hexafluorophosphate salt ionic liquids could be used in derivatization reaction to enhance fluorescent sensitivity
in E2 trace residual analysis. 相似文献
8.
G. Carlsson E. Karlsson å. G. Svensson R. å. Windahl M. R. el Asser 《Hyperfine Interactions》1983,15(1-4):85-87
Properties of the [512] 5/2?, [633] 7/2+ and [514] 7/2? bands have been studied by experiments on the magnetic moments of the [512] 5/2? 7/2? (79 keV; g=0.058(19)), [512] 5/2? 9/2? (179 keV; g=+0.06(8)) and [633] 7/2 7/2 (351 keV; g=?0.13(13)) states. 相似文献
9.
A. N. Aleshin I. P. Shcherbakov I. N. Trapeznikova V. N. Petrov 《Physics of the Solid State》2016,58(9):1882-1890
Organic field-effect transistor (OFET) structures with the active layers on the basis of composite films of semiconductor polymer poly(3-hexylthiophene) (P3HT), fullerene derivatives [60]PCBM, [70]PCBM, and nickel (Ni) nanoparticles are obtained, and their optical, electrical, and photoelectrical properties are studied. It is shown that introducing Ni nanoparticles into P3HT: [60]PCBM and P3HT: [70]PCBM films leads to an increase in the absorption and to quenching of photoluminescence of the composite in the 400–600 nm spectral band due to the plasmon effect. In P3HT: [60]PCBM: Ni and P3HT: [70]PCBM: Ni OFET structures at the P3HT: [60]PCBM and P3HT: [70]PCBM concentrations of ~1: 1 and Ni concentrations of ~3–5 wt %, current–voltage (I–V) characteristics typical of ambipolar OFETs with the dominant hole conduction are observed. The charge-carrier (hole) mobilities calculated from the I–V characteristic at VG =–10 V were found to be ~0.46 cm2/(V s) for P3HT: [60]PCBM: Ni and ~4.7 cm2/(V s) for P3HT: [70]PCBM: Ni, which means that the mobility increases if [60]PCBM in the composition is replaced with [70]PCBM. The effect of light on the I–V characteristics of P3HT: [60]PCBM: Ni and P3HT: [70]PCBM: Ni OFETs is studied. 相似文献
10.
Orientation dependence of structural transition in fcc Al driven under uniaxial compression by atomistic simulations 下载免费PDF全文
By molecular dynamics simulations employing an embedded atom method potential,we have investigated structural transformations in single crystal Al caused by uniaxial strain loading along the [001],[011] and [111] directions. We find that the structural transition is strongly dependent on the crystal orientations. The entire structure phase transition only occurs when loading along the [001] direction,and the increased amplitude of temperature for [001] loading is evidently lower than that for other orientations. The morphology evolutions of the structural transition for [011] and [111] loadings are analysed in detail. The results indicate that only 20% of atoms transit to the hcp phase for [011] and [111] loadings,and the appearance of the hcp phase is due to the partial dislocation moving forward on {111} fcc family. For [011] loading,the hcp phase grows to form laminar morphology in four planes,which belong to the {111} fcc family; while for [111] loading,the hcp phase grows into a laminar structure in three planes,which belong to the {111} fcc family except for the (111) plane. In addition,the phase transition is evaluated by using the radial distribution functions. 相似文献
11.
S. Libovický 《Czechoslovak Journal of Physics》1973,23(4):462-467
A non-planar dissociation of non-screw 1/2[¯111] (110) dislocations is proposed. The dissociation is possible for dislocations of [1¯11] and [1¯10] directions and the dislocations of these directions become sessile. The [1¯11] and [1¯10] directions are in agreement with experimentally observed shape of dislocations in the (110) glide plane. 相似文献
12.
R. A. Bark H. Carlsson S. J. Freeman G. B. Hagemann F. Ingebretsen H. J. Jensen T. L nnroth M. J. Piiparinen I. Ragnarsson H. Ryde H. Schnack-Petersen P. B. Semmes P. O. Tj m 《Nuclear Physics A》1998,630(3-4):603-630
Six rotational bands in the odd-odd nucleus 174Ta have been populated with the 160Gd(19F,5n) reaction. High-spin states were identified using the NORDBALL array. Both signatures of the doubly decoupled π1/2− [541] ν1/2− [521] band and semi-decoupled π1/2− [541] ν7/2− [633] band are observed, in addition to the high-K couplings of the π9/2− [514] ν7/2+ [633], π9/2− [514] ν5/2− [512], π7/2+ [404] ν7/2+ [633], and π5/2+ [402] ν5/2− [512] configurations. The signature splitting of the π1/2− [541] ν7/2+ [633] band is inverted from the expected splitting, and this is interpreted as being due to a residual proton-neutron interaction. It is shown empirically that this interaction, together with deformation changes, can account for the increased crossing frequency associated with the alignment of i13/2 neutrons in the π1/2− [541] bands of odd-Z nuclei. 相似文献
13.
通过介绍六粒子纠缠态的新应用研究,提出了一个二粒子任意态的信息分离方案.在这个方案中,发送者Alice、控制者Charlie和接受者Bob共享一个六粒子纠缠态,发送者先执行两次Bell基测量|然后控制者执行一次Bell基测量|最后接受者根据发送者和控制者的测量结果,对自己拥有的粒子做适当的幺正变换,从而能够重建要发送的二粒子任意态.这个信息分离方案是决定性的,即成功概率为100%.与使用相同的量子信道进行二粒子任意态的信息分离方案相比,本文提出的方案只需要进行Bell基测量而不需要执行多粒子的联合测量,从而使得这个方案更简单、更容易,并且在目前的实验室技术条件下是能够实现的. 相似文献
14.
The rate of surface self-diffusion on a Pt(110) single crystal in the [10] and [001] directions was measured at 1200–1750 K by monitoring the decay of a sinusoidal surface profile. The surface diffusion rate in the [1o] direction was much faster than in the [001] direction. The activation energy of surface self-diffusion was 1.70 and 3.16 eV for the [10] and [001] directions, respectively, in good agreement with theoretical estimates. For large amplitudes of the profile the decay rate for the [001] direction was also dependent on the amplitude. This behavior can be explained by the appearance of (111) facets on the profile, which cause a retardation of the profile decay. 相似文献
15.
《Surface science》1997,373(1):L350-L356
The experimental results of Masson et al. [Surf. Sci. 27 (1971) 463] were further interpreted with regard to the rotation behavior of non-epitaxy Au crystallites on a KCl(100) substrate, which developed into primary epitaxy ([111]Au 6 [100]KCl; [11̄0]Au 6 [010]KCl), and “second” epitaxy (in fact [100]Au 6 [100]KCl; [010]Au 6 [010]KCl and [100]Au 6 [100]KCl; [010]Au 6 [011]KCl) upon annealing at 94°C. These epitaxy orders were clarified to be nonsequential events on the basis of the development of electron diffractions (220), (111) and (200) of Au. The “second” epitaxy can be attributed to the later formation of a (100)Au|(100)KCl contact in comparison with the preferred (111)Au|(100)KCl contact in the as-deposited state. The Au crystallites with irrational contact plane should have rotated and changed shape before bifurcating into (111)Au|(100)KCl and (100)Au|(100)KCl contact, upon which viscous rotation was still feasible, until the primary and “second” epitaxy were reached, respectively. 相似文献
16.
The multi-structured zero phonon transitions of the 0.839eV emission observed in SI GaAs:Cr have been investigated by Zeeman measurements. Magnetic splittings for the directions [111], [110] and [100] as well as angular dependence studies in the (110) plane show that the centre has a symmetry axis along [111] with a small orthorhombic distortion. The emissions cannot be due to the isolated [100] Jahn-Teller distorted Cr2+ ions observed in magnetic resonance but to [111] centres such as the (Cr2+-donor) pairs as suggested by White. 相似文献
17.
Ambika Prasad JenaMoshiour Rahaman Abhijit Mookerjee 《Physica B: Condensed Matter》2011,406(20):3810-3815
In this communication we propose a method for the study of disorder-order transitions in FexAl1−x binary alloys. We turn to our earlier development [1] of a combination of the recursion method introduced by Haydock et al. [2] and our augmented space approach [3] with the orbital peeling technique proposed by Burke [4] to determine the small energy differences required in obtaining the pair energies which go as input to the generalized perturbation technique [5] of studying disorder-order transitions. 相似文献
18.
Pressure effects in AlAs/Inx Ga1-xAs/GaAs resonant tunnelling diodes for application in micromachined sensors 下载免费PDF全文
This paper reports the current-voltage characteristics of [001]-oriented AlAs/InxGa1-xAs/GaAs resonant tunnelling diodes (RTDs) as a function of uniaxial external stress applied parallel to the [110] and the [1^-10] orientations, and the output characteristics of the GaAs pressure sensor based on the pressure effect on the RTDs. Under [110] stress, the resonance peak voltages of the RTDs shift to more positive voltages. For [1^-10] stress, the peaks shift toward more negative voltages. The resonance peak voltage is linearly dependent on the [110] and [1^-0] stresses and the linear sensitivities are up to 0.69 mV/MPa, -0.69 mV/MPa respectively. For the pressure sensor, the linear sensitivity is up to 0.37 mV/kPa. 相似文献
19.
The purpose of this study was to determine whether children give more perceptual weight than do adults to dynamic spectral cues versus static cues. Listeners were 10 children between the ages of 3;8 and 4;1 (mean 3;11) and ten adults between the ages of 23;10 and 32;0 (mean 25;11). Three experimental stimulus conditions were presented, with each containing stimuli of 30 ms duration. The first experimental condition consisted of unchanging formant onset frequencies ranging in value from frequencies for [i] to those for [a], appropriate for a bilabial stop consonant context. The second two experimental conditions consisted of either an [i] or [a] onset frequency with a 25 ms portion of a formant transition whose trajectory was toward one of a series of target frequencies ranging from those for [i] to those for [a]. Results indicated that the children attended differently than the adults on both the [a] and [i] formant onset frequency cue to identify the vowels. The adults gave more equal weight to the [i]-onset and [a]-onset dynamic cues as reflected in category boundaries than the children did. For the [i]-onset condition, children were not as confident compared to adults in vowel perception, as reflected in slope analyses. 相似文献
20.
A.J. Freeman T.J. Watson-Yang J. Rath 《Journal of magnetism and magnetic materials》1979,12(2):140-148
The generalized susceptibility, χ(q), in Pd and Pt for q along the [100], [110], [111], and [120] directions was determined from their APW and RAPW energy band structures, respectively, using the analytic tetrahedron linear energy scheme of Rath and Freeman. The band structures were previously found to yield Fermi surface radii, temperature dependencies of the static magnetic susceptibility, χ(T), resistivity, and a spin lattice relaxation, T1T, in very good agreement with experiment. In the χ(q) calculations, we used 2048 tetrahedra in 1/48th irreducible BZ and the energy eigenvalues for bands 4, 5, and 6 which cross the Fermi energy as fitted to a Fourier series representation. The intraband parts of χ(q) at q = 0 for both metals are found to agree with the density of states at the Fermi energy to without 0.5%. Our results show that the dominant contribution to χintra arises from the dominant band 5 whose “jungle-gym” FS has strong nesting features; the main peak for Pd occurs at the same q value (= 0.65π/a) for q along the [0q0], [q, q, 0], and [q, q, q] directions. The locus of this main peak is a square in the (0, 0, 1) plane. The maximum of χintra for q along the [110] and [111] directions are 23% and 13%, respectively, higher than the value of χ(q) at q = 0. For q along the [010] and [120] directions, the peak is, however, lower than the value of χintra at q = 0. Hence, while phonon anomalies are predicted for the [110] and [111] directions, no anomaly is predicted for either the [100] or [120] direction. The predicted q value for the [110] anomaly, is close to the experimental value of ~0.7 π/a. Although there may be a hint of an anomaly at 0.56 [111] in the measurements, a more detailed investigation of this region is called for. For platinum, χintra for q along the [010], [110] and [111] directions has main peaks which occur at q = 0.68 π/a, 0.75 π/a, and 0.85 π/a, respectively. Here too, this main peak comes from the nesting of the jungle-gym Fermi surface which is not, however, as flat as that of palladium. Anomalies are predicted (although weaker in Pt than in Pd) along [110] and [111] but not along [100] and [120]. The [110] anomaly is close to the measured q value (~0.7–0.8 π/a). Also in agreement with experiment, we predict a weaker [110] anomaly for Pt than for Pd. In both Pd and Pt, weaker anomalies are predicted for the [111] direction than for the [110] direction. 相似文献