RbVO_3的光谱分析及能带结构研究

采用杂化前驱体的湿化学合成法制备了偏钒酸铷(RbVO3)发光材料。利用粉末X射线衍射(XRD)、红外光谱仪(IR)等对RbVO3的结构进行了表征,利用紫外-可见(UV-Vis)吸收光谱、光致发光光谱等研究了该发光材料的光致发光性能,并采用基于密度泛函理论的CASTEP程序计算了RbVO3的能带。结果表明,在357 nm紫外光的激发下,RbVO3产生发光峰在525 nm附近、色坐标为(0.318 0,0.430 9)的绿白光发射,发光亮度高;RbVO3计算的光学带隙为2.67 eV,与实验值较为吻合。     

Spectral hole burning for wideband, high-resolution radio-frequency spectrum analysis

We present experimental results for what is to our knowledge the first spectral-hole-burning based rf spectrum analyzer to cover 10 GHz of rf analysis bandwidth. The rf signal of interest is modulated onto an optical carrier, and the resultant optical sidebands are burned into the inhomogeneously broadened absorption band of a Tm3+:YAG crystal. At the same time a second, frequency-swept laser reads out the absorption profile, which is a double-sideband replica of the rf spectrum, and thus the rf spectrum can be deduced after spectral calibration of the nonlinear readout chirp. This initial demonstration shows spectral analysis covering 10 GHz of bandwidth with >5500 spectral channels and provides 43 dB of dynamic range.     

Spectral transformations of wideband fields and their coherence functions

Transformations are examined that allow the field and its coherence function to be related to the spectral-angular amplitude density and mean-power flux density of a distributed source, respectively.Kharkov Aviation Institute. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 36, No. 11, pp. 1061–1063, November, 1993.     

Possible approach to overcome the doping asymmetry in wideband gap semiconductors

The asymmetry doping problem has severely hindered the potential applications of many wideband gap (WBG) materials. Here, we propose a possible approach to overcome this long-standing doping asymmetry problem for WBG semiconductors. Our approach is based on the reduction of the ionization energies of dopants through introduction and effective doping of mutually passivated impurity bands, which can be realized by doping the host with passive donor-acceptor complexes or isovalent impurities. Our density-functional theory calculations demonstrate that this approach provides excellent explanations for the n-type doping of diamond and p-type doping of ZnO, which could not be understood by previous theories. In principle, this approach can be applied to any WBG semiconductors and therefore will open a broad vista for the application of WBG materials.     

Spectral differences in the ability of temporal gaps to reset the mechanisms underlying overshoot

When very brief tonal signals are presented immediately after the onset of a gated noise masker, detectability can be 10-20 dB worse than when the signal is delayed by several hundred milliseconds, an effect known as the overshoot. It has long been known that, when an "onset" is created in an otherwise continuous, broadband masker by briefly turning it off and on again, the detectability of a brief signal presented soon after this temporal gap will decline gradually as the gap is increased from a few milliseconds to a few hundred milliseconds. In other words, the auditory system recovers to its quiescent, resting state following an adequate silent interval. Here, the broadband maskers consisted of three adjacent spectral bands--one centered on the frequency of the tonal signal, one low passed below the lower edge of the center band, and one high passed above the upper edge of the center band. The signal was a 2500-Hz tone having a total duration of 6 ms. In different blocks of trials, either all three bands, only the center band, or only the two flanking bands were temporally gapped by a duration ranging from 10-300 ms. When the center band was about 750 Hz wide (about 2.5 critical bandwidths), this differential gapping process resulted in typical recovery functions when all three bands (the entire spectrum) or when just the two flanking bands were gapped. However, when only the center band was gapped, there was no evident recovery--rather, detectability remained near the signal level required with a continuous masker, even for a gap duration of 300 ms.(ABSTRACT TRUNCATED AT 250 WORDS)     

Spectral integration of speech bands in normal-hearing and hearing-impaired listeners

This investigation examined whether listeners with mild-moderate sensorineural hearing impairment have a deficit in the ability to integrate synchronous spectral information in the perception of speech. In stage 1, the bandwidth of filtered speech centered either on 500 or 2500 Hz was varied adaptively to determine the width required for approximately 15%-25% correct recognition. In stage 2, these criterion bandwidths were presented simultaneously and percent correct performance was determined in fixed block trials. Experiment 1 tested normal-hearing listeners in quiet and in masking noise. The main findings were (1) there was no correlation between the criterion bandwidths at 500 and 2500 Hz; (2) listeners achieved a high percent correct in stage 2 (approximately 80%); and (3) performance in quiet and noise was similar. Experiment 2 tested listeners with mild-moderate sensorineural hearing impairment. The main findings were (1) the impaired listeners showed high variability in stage 1, with some listeners requiring narrower and others requiring wider bandwidths than normal, and (2) hearing-impaired listeners achieved percent correct performance in stage 2 that was comparable to normal. The results indicate that listeners with mild-moderate sensorineural hearing loss do not have an essential deficit in the ability to integrate across-frequency speech information.     

Spectro-temporal integration in signal detection

This paper is concerned with aspects of temporal integration and across-frequency integration in signal detection. Previous experiments on the detection of brief broadband signals (clicks) in continuous broadband noise revealed efficient spectral integration. The extent to which this effect is restricted to a critical time window was investigated by manipulating the temporal relations among the signal components in different frequency regions. In a typical experiment, the signal consists of nine brief Gaussian-shaped tone pulses, equally distributed at 1/3-oct intervals, each with a spectral width of about 1/3 oct, and each equally detectable in white noise. In the synchronized condition (i.e. coinciding peaks of the nine Gaussian envelopes), the detection threshold is reached when the levels of the nine individual tone pulses are about 8 dB below their individual threshold levels (efficient spectral integration). When the signal is progressively desynchronized (i.e. noncoinciding peaks of the Gaussian envelopes), detection threshold is found to increase. This suggests that efficient spectral integration in signal detection is confined to a narrow time window, with a typical value of 30 ms. Similar experiments were performed with respect to the efficiency of temporal integration. For constant-duration signals (100 ms), the detection threshold is found to increase when progressively widening signal bandwidth. The data indicate that the efficient temporal integration in signal detection is confined to a narrow frequency window, which, not surprisingly, corresponds to the critical bandwidth.     

Spectral integration in bands of modulated or unmodulated noise

Spectral integration was measured for pure-tone signals masked by unmodulated or modulated noise bands centered at the signal frequencies. The bands were typically 100 Hz wide, and when modulated, they were sinusoidally amplitude modulated at a rate of 8 Hz and a depth of 100%. In experiment 1, thresholds were first measured for each individual pure tone of a triplet in the presence of its respective masker band, and then for those three tones added together at their respective threshold levels, masked by their respective masker bands. Four sets of triplets were used: 250, 1000, 4000 Hz; 354, 1000, 2828 Hz; 500, 1000, 2000 Hz; and 800, 1000, 1200 Hz. When the masker bands were unmodulated, the amount of spectral integration was about 2.4 dB for all triplets, consistent with the integration expected based on the multiband energy detector model. When the bands were modulated, the amount of integration depended upon the spacing between masker bands; for the two widest spacings, the integration was between about 0 and 3 dB, whereas for the two closest spacings, the integration was approximately 5 dB. Experiments 2 and 3 addressed the cause of this greater spectral integration in the presence of the modulated masker bands with closer spacing. The second experiment demonstrated that sensitivity (d') was proportional to signal power regardless of whether the background noise was modulated or not, and thus the greater integration in dB in the presence of the modulated noise bands could not be accounted for by shallower psychometric functions in those conditions. Instead, the third experiment showed that the greater integration was likely due to the fact that the masker bands were comodulated. In other words, it was probably due to cues related to comodulation masking release when all three bands (and signals) were present.     

Spectral gap and logarithmic Sobolev inequality for Kawasaki and Glauber dynamics

We prove that the spectral gap of the Kawasaki dynamics shrink at the rate of 1/L ² for cubes of sizeL provided that some mixing conditions are satisfied. We also prove that the logarithmic Sobolev inequality for the Glauber dynamics in standard cubes holds uniformly in the size of the cube if the Dobrushin-Shlosman mixing condition holds for standard cubes.Research partially supported by U.S. National Science Foundation grant 9101196, Sloan Foundation Fellowship and David and Lucile Packard Foundation Fellowship     

Temporal integration in amplitude modulation detection

Thresholds for detecting sinusoidal amplitude modulation (AM) of a wideband noise carrier were measured as a function of the duration of the modulating signal. The carrier was either; (a) gated with a duration that exceeded the duration of modulation by the combined stimulus rise and fall times; (b) presented with a fixed duration that included a 500-ms carrier fringe preceding the onset of modulation; or (c) on continuously. In condition (a), the gated-carrier temporal modulation transfer functions (TMTFs) exhibited a bandpass characteristic. For AM frequencies above the individual subject's TMTF high-pass segment, the mean slope of the integration functions was - 7.46 dB per log unit duration. For the fringe and continuous-carrier conditions [(b) and (c)], the mean slopes of the integration functions were, respectively, - 9.30 and - 9.36 dB per log unit duration. Simulations based on integration of the output of an envelope detector approximate the results from the gated-carrier conditions. The more rapid rates of integration obtained in the fringe and continuous-carrier conditions may be due to "overintegration" where, at brief modulation durations, portions of the unmodulated carrier envelope are included in the integration of modulating signal energy.     

Within- and across-channel gap detection in cochlear implant listeners

This study examined within- and across-electrode-channel processing of temporal gaps in successful users of MED-EL COMBI 40+ cochlear implants. The first experiment tested across-ear gap duration discrimination (GDD) in four listeners with bilateral implants. The results demonstrated that across-ear GDD thresholds are elevated relative to monaural, within-electrode-channel thresholds; the size of the threshold shift was approximately the same as for monaural, across-electrode-channel configurations. Experiment 1 also demonstrated a decline in GDD performance for channel-asymmetric markers. The second experiment tested the effect of envelope fluctuation on gap detection (GD) for monaural markers carried on a single electrode channel. Results from five cochlear implant listeners indicated that envelopes associated with 50-Hz wide bands of noise resulted in poorer GD thresholds than envelopes associated with 300-Hz wide bands of noise. In both cases GD thresholds improved when envelope fluctuations were compressed by an exponent of 0.2. The results of both experiments parallel those found for acoustic hearing, therefore suggesting that temporal processing of gaps is largely limited by factors central to the cochlea.     

Efficient across-frequency integration in short-signal detection

A series of experiments was performed on the influence of bandwidth on the masked threshold of brief deterministic signals in continuous broadband noise. The signal bandwidth is quantified by the number (n) of constituent 1/3-oct bands. For n increasing from 1 to typically 9, the masked-threshold level in the constituent 1/3-oct bands is found to decrease by 8 log(n). This integration rule is obtained when each of the 1/3-oct bands covered by the signal equally contributes to detection, i.e., that, for each of these 1/3-oct bands, the difference between signal level and the individual masked-threshold level is the same. It was found that this integration rule also applies to noncontiguous signal spectra and that it remains intact over a broad range of masker levels. Commonly, the masked threshold of compound signals (for instance, n frequency components with a spacing of typically 1/3 oct), relative to the masked threshold of single-component signals, has been described by a 5 log(n) integration rule. However, this rule was obtained for signal durations of typically 100 ms or more. For the present brief signals (typically 10 ms or less), the across-frequency integration is found to be more effective.     

Spectral and thermodynamic properties of electrons in mobility gap states of covalent glasses

Spectral and thermodynamic properties of electrons (holes) in covalent semiconducting glasses are considered in which self-trapping of electron (hole) pairs is realized with negative effective correlation energy U^?. Unlike the Anderson model, electron (hole) pairing is restricted to a small part of the glass bonds. Ranges of the U^? values are found in which either pair effects (suppression of paramagnetism etc.) or single-particle effects predominate; the concentration of the pair states and of the occupied ones can roughly be estimated and can be fairly high. The problem of the coexistence of the Fermi level pinning and effective diamagnetism in glasses is discussed. Some related effects are briefly considered.     

宽带参量阵技术在近海探测中的研究

文章针对非线性声学宽带参量阵技术应用于近海海底剖面绘制及掩埋物探测进行了分析研究。对于宽带参量阵声呐产生的差频信号利用Berktay包络解调理论和KZK(Khokhlov-Zabolotskaya-Kuznetsov)方程,对其进行了理论分析,水池实验研究和时域数值模拟,并结合声呐方程计算,说明该技术用于近海探测的可行性。本文同时结合脉冲压缩技术对产生的宽带差频信号做匹配处理,用于提高设备的垂直分辨率。最后在海试实验中,利用文中设计的参量阵声呐,分别使用宽带差频信号和单频差频信号对浅海海底沉积层和海底掩埋管线进行探测,取得了清晰的剖面图和掩埋物探测结果,验证了宽带参量阵技术在海底探测中的有效性和实用性。     

Spectral integration of broadband signals in diotic and dichotic masking experiments.

The method of G?ssler [Acustica 4, 408-414 (1954)] was used to measure the audibility of multicomponent signals as a function of their bandwidth against a broadband, white-noise masker. Test signals were composed of 1 to 41 sinusoids with a spectral spacing of 10 Hz and were always spectrally centered around 400 Hz. Masker duration was 400 ms and the 300-ms signals were centered within the noise intervals. A three-interval forced-choice procedure with adaptive level adjustment was applied. NoSo, NoSm, NoS pi, and N pi So masked thresholds were obtained for four subjects. A comparison of the diotic and the three dichotic conditions yields no significant difference in the bandwidth dependence and suggests equal integration bandwidths for all conditions. However, the original results of G?ssler could not be replicated: Neither were the overall levels of signals with a bandwidth below the critical bandwidth constant nor were the results for broadband signals in accordance with a single-band model of detection. The narrow-band data are much better described by calculating the overall signal level at the output of a rounded exponential filter [Patterson et al., J. Acoust. Soc. Am. 72, 1788-1803 (1982)] with an equivalent rectangular bandwidth of 65 Hz. For broader signal bandwidths, the signal level at threshold increases as predicted by a multiband model.     

Spectral interference in a binaural detection task

Several investigations suggest that sensitivity to changes in interaural disparities within select spectral regions may be degraded by the presence of energy at other, even remote, spectral regions. This study assessed whether similar degradations would be observed in an MLD paradigm. Detection thresholds were measured for NoSo and NoS pi. The signal, an 800-Hz tone (100-ms), was presented in continuous, broadband noise. Thresholds were also measured in the presence of a 400-Hz tone (the interferer) presented with an interaural phase disparity of 180 degrees and gated simultaneously with the signal or presented continuously. NoS pi thresholds increased by about 7 dB with the gated interferer at 80 dB SPL. Smaller increases were observed with lower levels of the interferer. Presenting the interferer continuously reduced substantially its effect. NoSo thresholds were affected only slightly by the interferer. Reversing the roles of the signal and interferer (400-Hz signal, 800-Hz interferer) led to smaller, but reliable degradations in performance. Diotic interferers had, in general, smaller effects on performance. The possible relation between the mechanisms that produce interference and those that foster an ability to segregate sources of sound is discussed.     

Gap detection for similar and dissimilar gap markers

Detection thresholds for temporal gaps between markers of dissimilar frequency are usually elevated with respect to thresholds for gaps between markers of similar frequency. Because gaps between markers of dissimilar frequency represent both a spectrally based perceptual discontinuity as well as a temporal discontinuity, it is not clear what factors underlie the threshold elevation. This study sought to examine the effects of perceptual dissimilarities on gap detection. The first experiment measured gap detection for configurations of narrow-band gap markers comprised of pure tones, frequency-modulated tones, and amplitude-modulated tones. The results showed that gap thresholds for frequency-disparate pure-tone markers were elevated with respect to isofrequency tonal markers, but that perceptual discontinuities between markers restricted to the same frequency region did not uniformly elevate threshold. The second experiment measured gap detection for configurations of markers where the leading and trailing markers could differ along the dimensions of bandwidth, duration, and pitch. The results showed that, in most cases, gap detection deteriorated when the bandwidth of the two markers differed, even when the spectral content of the narrower-band marker was completely subsumed by the spectral content of the wider-band marker. This finding suggests that gap detection is sensitive to spectral dissimilarity between markers in addition to spectral discontinuity. The effects of marker duration depended on the marker bandwidth. Pitch differences across spectrally similar markers had no effect.     

Relationships among age-related differences in gap detection and word recognition

The relationships among age-related differences in gap detection and word recognition in subjects with normal hearing or mild sensorineural hearing loss were explored in two studies. In the first study, gap thresholds were obtained for 40 younger and 40 older subjects. The gaps were carried by 150-ms, modulated, low-pass noise bursts with cutoff frequencies of 1 or 6 kHz. The noise bursts were presented at an overall level of 80 dB SPL in three background conditions. Mean gap thresholds ranged between 2.6 and 7.8 ms for the younger age group and between 3.4 and 10.0 ms for the older group. Mean gap thresholds were significantly larger for the older group in all six conditions. Gap thresholds were not significantly correlated with audiometric thresholds in either age group but the 1-kHz gap thresholds increased with age in the younger group. In the second study, the relationships among gap thresholds, spondee-in-babble thresholds, and audiometric thresholds of 66 subjects were examined. Compared with the older subjects, the younger group recognized the spondees at significantly lower (more difficult) spondee-to-babble ratios. In the younger group, spondee-in-babble thresholds were significantly correlated with gap thresholds in conditions of high-frequency masking. In the older group, spondee-in-babble thresholds, gap thresholds, and audiometric thresholds were not significantly correlated, but the spondee-in-babble thresholds and two audiometric thresholds increased significantly with age. These results demonstrate that significant age-related changes in auditory processing occur throughout adulthood. Specifically, age-related changes in temporal acuity may begin decades earlier than age-related changes in word recognition.     

Spectral integration versus multiple looks in the sample discrimination of intensity

A fundamental property of hearing is that signals become more detectable as their bandwidth is increased. Two models have been proposed to account for this result. The integration model assumes that detection is mediated by the output of a single frequency channel matched in bandwidth to the signal. The multiple-looks model assumes that detection is based on the combination of outputs from multiple channels matched to the individual frequencies of the signal. Results are reported supporting the integration model.     

Psychometric functions for gap detection in a yes-no procedure

To examine models of temporal resolution and to investigate the decision processes underlying the detection of a brief pause in a bandpass noise, psychometric functions for gap detection were measured at octave frequencies from 0.25 to 8 kHz. Three normal listeners were tested using a constant-stimulus procedure with a cued Yes-No paradigm. The Minimum Detectable Gap (MDG) estimated from the midpoint of the psychometric functions decreased systematically with increasing frequency. The slopes of the psychometric functions generally increased as the test frequency increased up to 2 kHz, but remained constant at the higher frequencies. Two models were investigated: an energy-detector model and a loudness-detector model. Both consisted of auditory filtering, a nonlinearity, and short-term integration. In the energy-detector model, the nonlinearity was a square law. In the loudness-detector model, it was a compressive power law. Using the usual Gaussian approximations, the energy-detector model fails at low frequencies because the probability distributions of short-term energy differ from Gaussian distributions. The probability distributions of short-term loudness closely follow Gaussian distributions. The loudness-detector model predicts the frequency dependence of the MDG quite accurately, except at 0.25 kHz. It also predicts psychometric functions that resemble the data at low frequencies, but the predicted slopes increase much less with frequency than the measured slopes. This result may indicate that the onset response to the trailing marker of the gap provides an important cue for detection of gaps with durations exceeding the MDG.