Critical field and specific heat of the anisotropic superconductor Nb3S4

We report on the first measurements of the critical field B_c2 and the specific heat of Nb₃S₄, which is a linear structured compound with a superconducting transition temperature of 3.65 K. The angular dependence of B_c2 is well described by the effective-mass model. The ratio of the critical fields parallel and perpendicular to the c-axis gives a value of 4.6. The small value of the specific heat jump at $\text{T}{}_{\mathrm{c}}\text{(}\text{Δc}\text{γT}{}_{\mathrm{c}}\text{= 0.95)}$ can be explained with an anisotropic gap function.     

A numerical estimate of deviations from the exponential decay law for the transition 2P12→1S12 in hydrogen

The deviations from the exponential decay law of the $\text{2}\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ states of the Dirac hydrogen atom with respect to the transition $\text{2}\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{→1}\text{S}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ are numerically estimated. We find |a₀(t) ? exp(?λt)|?2.5 × 10^?4 for all t, where a₀(t) is the “exact” decay amplitude and λ is a complex constant such that (2Re λ)^?1 is the “natural lifetime” of the $\text{2}\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ states with respect to the spontaneous transition to $\text{1}\text{S}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$.     

Pressure dependence of superconductivity in the pseudo-one-dimensional compound Tl2Mo6Se6

Measurements of the temperature and pressure dependences of the resistivity of the pseudo-one-dimensional ternary compound Tl₂Mo₆Se₆ are presented. We find that the conductivity parallel to the highly conducting c-axis is enhanced by pressure and the superconducting transition temperature T_c is suppressed by pressure at a rate $\text{?T}{}_{\mathrm{c}}\text{?P}\text{=?7.6×10}{}^{\mathrm{?5}}$ kbar^?1. These results are discussed in relation to the current models of transport in one-dimensional conductors.     

Electrical conductivity of the system Y2O3CeO2

The electrical conductivity of the system Y₂O₃CeO₂ was measured in the temperature range 500–1100°C and P_o2 range 10^–7?10^?1 atm. Possible defect models were suggested on the basis of conductivity data, which were investigated as a function of temperature and of P_o2. The observed activation energies were 0.40 eV and 1.79 eV in the low- and high-temperature regions, respectively. The observed conductivity dependences on P_o2 were in the temperature range 500–750°C and at temperatures from 750–1100°C. It is suggested that the system Y₂O₃CeO₂ shows a mixed ionic plus hole conduction due to an O^″_i defect and an electronic hole conduction due to a V^'''_Y defect in the low- and high-temperature regions, respectively.     

Phase transitions in ferroelectric ceramics of the type Sr0.5Ba0.5Nb2O6

The ferro-paraelectric transition in Sr_0.5Ba_0.5Nb₂O₆ ceramics has been studied by measuring the dielectric pennitivity as a function of temperature at different frequencies. Experimental results in the transition region over ?'_max fit the relation $\text{1}\text{?'}\text{?}\text{1}\text{?'}{}_{\max }\text{= A(T ?}\text{T}{}_0\text{)}{}^{\mathrm{\gamma }}$ with γ > 1, as is typical for dif transitions. In an interval of temperatures of 17°C over T₀ (=Tfor?'_max), γ = 2. Using the relaxors' model of Kirillov-Isupov an equation is inferred in order to compute the activation energy of the relaxors as a function of parameters directly obtained from the experimental results.     

The A-X system of Br2+ radical cations

The ²Π_u-X²Π_g transition in Br₂⁺ was reexamined using dispersed laser-induced fluorescence, and emission spectroscopy in a seeded molecular beam. New constants are derived, confirming the large difference between $\text{A}{}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ and $\text{A}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, and reconciling the emission spectrum with photoelectron data.     

Measurement of the 2S12−2P12 splitting in the (μ−4He)+ muonic ion

The measurement of the $\text{2S}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{→ 2P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ energy transition in muonic helium is presented. The energy difference S¹ is found to be S_exp¹ = 1381.3±0.5 meV. This result agrees with the expected value $\text{S}\text{?}{}^1\text{= 1381.2±0.3}\text{meV}$ obtained assuming the previously measured value for the $\text{2S}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{→ 2P}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ energy difference.     

A theoretical model for the interacting upper states of the ν1, ν3, 2ν2, ν2 + ν4, and 2ν4 bands in methane

The effective vibration-rotation Hamiltonians complete to fourth order in the Amat-Nielsen scheme for the upper states of the ν₁, ν₃, 2ν₂, ν₂ + ν₄, and 2ν₄ bands in methane are reviewed, and the major vibration-rotation interactions (H₃₀, $\text{H}\text{?}{}_{40}$, $\text{H}\text{?}{}_{21}$, $\text{H}{}_{31}$, $\text{H}\text{?}{}_{22}$) connecting the different vibrational states are discussed. Explicit matrix elements in a basis of harmonic oscillator-symmetric rotor basis functions are given for the purely vibrational terms and for the vibration-rotation interactions. Expressions for spectral intensities of infrared and Raman spectra are presented, and the selection rules and transition moment matrix elements are stated. A computer program is described which, incorporating all these features, can be used for prediction of infrared and Raman spectra and for determination of molecular constants from observed spectra by a least-squares routine. As an example the program is applied to the 2ν₄ isotropic Raman spectrum of ¹²CH₄, leading to a very good agreement between the experimental and calculated spectra.     

Magnetic circular dichroism of transition metal ions in solids—II K2NaGaF6: Cr3+

The absorption and MCD spectra of the ${}^4\text{A}{}_{\mathrm{2g}}\text{→}{}^4\text{T}{}_{\mathrm{2g}}$, ${}^4\text{A}{}_{\mathrm{2g}}$, ${}^4\text{A}{}_{\mathrm{2g}}\text{→}{}^4\text{T}{}_{\mathrm{1g}}{}^{\mathrm{a}}$ and ${}^4\text{A}{}_{\mathrm{2g}}\text{→}{}^4\text{T}{}_{\mathrm{1g}}{}^{\mathrm{b}}$ spin-allowed transitions of Cr³⁺ in K₂NaGaF₆ are reported. It is shown that transitions to the ${}^4\text{T}{}_{\mathrm{1g}}$. states are induced by T_1u vibratio the other spin-allowed transition, ${}^4\text{A}{}_{\mathrm{2g}}\text{→}{}^4\text{T}{}_{\mathrm{2g}}$, there are three competing intensity mechanisms: electric dipole induced by T_1u vibrations, electric dipole induced by T_2u vibrations and magnetic dipole, and an estimate is made of the relative importance of these. The magnetic dipole ${}^4\text{A}{}_{\mathrm{2g}}\text{→}{}^2\text{E}{}_{\mathrm{g}}$ zero-phonon line is observed to be accompanied by a vibrational sideband for which the coupling is predominantly with T_2u vibrations. Other weak transitions are observed in MCD spectra and their origin briefly discussed.     

Charge density wave commensurability in 2H-TaS2 and AgxTaS2

The charge density wave transition in 2H-TaS₂near 75 K has been observed to be incommensurate, using electron diffraction, with $\text{q}{}^1\text{= (}\text{0.338}\text{±}\text{0.002}\text{)a}{}^1{}_0$ along the 〈10.0〉 directions which, within the experimental uncertainty, remains temperature independent to about 14 K. Incommensurate charge density formation is also observed in Ag_xTaS₂ samples for $\text{x?}\text{0.26}$ with an increase in q¹ to $\text{(}\text{0.347}\text{±}\text{0.002}\text{)a}{}^1{}_0$ when x?0.26. Within the experimental error q¹ appears to be temperature independent to 25 K.     

Infrared optical properties of MoSe2

The infrared absorption spectrum of a single crystal of MoSe₂ is reported. A damped oscillator fit to the fundamental band gives the transverse optic frequency, $\text{Ω}{}_{\mathrm{TO}}\text{= 277}\text{cm}{}^{-1}$ at 300° K and $\text{Ω}{}_{\mathrm{TO}}\text{= 283}\text{cm}{}^{-1}$ at 77° K. The static and high frequency dielectric constants have been determined as K_s = 16.81 and K_∞ = 10.24 respectively. An absorption band appears in the i.r. spectrum at 482 cm^-1, and has been attributed to the oxygen impurity in the crystal.     

The γ-decay of the 1g92 and 2p inner-hole states in 111Sn via the 112Sn(3He, αγ) reaction at 32 MeV

The γ-decay of the deeply-bound hole states in ¹¹¹Sn has been investigated at 32 MeV incident energy by means of the ¹¹²Sn(³He, αγ) reaction. The α-particles emitted near 0° were detected in a Si counter located at the image plan of the superconducting solenoidal spectrometer SOLENO. The γ-rays in coincidence with the α-particles were detected by two Ge(Li) detectors located at 90° and 142° with respect to the beam direction, respectively. Energies, spins and decay schemes have been established for the low-lying states up to 2.5 MeV excitation energy in ¹¹¹Sn. The γ-decay of the broad bump, located around 4.2 MeV and previously attributed to neutron pick-up from the inner $\text{1}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{, 2}\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{,}\text{and}\text{2}\text{p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ neutron. Subshells, reveals the importance of quasiparticle-phonon m the spreading mechanism of the inner-hole strengths. The $\text{1}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ and 2p strength functions have been deduced from the α-decay of the enhanced structures (3 ≦ E_x≦ 8 MeV). They are compared to the ones measured in previous inclusive neutron pick-up experiments and to those calculated in the framework of the quasiparticle-phonon nuclear model.     

Critical slowing down of fluctuations in squaric acid (H2C4O4) at the phase transition observed by 13C spin-lattice relaxation

Spin lattice relaxation T₁ of naturally abundant ¹³C nuclei in squaric acid was measured close to the antiferroelectric-paraelectric phase transition temperature T_c = 373 K. A rapid increase in $\text{1}\text{T}{}_1$ is observed close to T_c coming from above, which follows the power law $\text{1}\text{T}{}_1\text{～ ε}{}^{\mathrm{?1.4}}$ where $\text{ε =}\text{(T ? T}{}_{\mathrm{c}}\text{)}\text{T}{}_{\mathrm{c}}$. This behaviour is explained on the basis of the two-dimensional character of the fluctuations.     

Study of the 91Zr(d, 3He)90Y reaction

The ⁹¹Zr(d, ³He) reaction was studied at a deuteron energy of 28 MeV. Angular distributions were measured from 13° to 47°; l_p values were extracted for the prominent lines of ⁹⁰Y. The l_p values and transition strengths were determined by DWBA analysis. The angular distributions for the $\text{(π}\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)(ν}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)}$ doublet (g.s. and 0.20 MeV state) exhibit the characteristic l = 1 shape. States at 1.42, 1.57, 1.64 and 1.81 MeV were also populated strongly in the (d, ³He) reaction; the 1.42, 1.57 and 1.81 MeV levels contain l= 1 transition strength and are most likely members of the $\text{(π}\text{p}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}\text{)(ν}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)}$ multiplet. The 2.03 MeV state has a characteristic l = 3 angular distribution and is suggested to be the only member of the $\text{(π}\text{f}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}\text{)(ν}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)}$ sextet to be unambiguously observed in this study, most probably the 5^? or 4^? member. The members of the $\text{(π}\text{g}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)(ν}\text{d}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}$ sextet were populated weakly (less than 100 μb/sr) in this reaction.     

Model calculation of the electronic structure and spectroscopy of Hg2

Energy curves and transition moments of the excited valence states of Hg₂ were obtained in a model calculation based on calculated Mg₂ energy levels and the assumption that the asymptotic spin-orbit matrix elements for the Hg atom are applicable to the molecular states. The spin-orbit and orbital-rotational interaction of the excited states of Hg₂ is analyzed in both a Hund's case (c) and (a) representation. The intermediate (a) → (c) transition moments are obtained as a function of the internuclear distance. The effect of the orbital-rotational interaction which introduces Hund's case (b) and (e) couplings is found to be small for transitions among excited states under the conditions normally encountered for populating excimer states.Using the energy level positions and transition moments, the observed spectra and predicted spectra are compared for both radiative transitions including the ground state and among the excited states. The lifetime of the $\text{1}{}_{\mathrm{u}}\text{(}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{)}$ excimer state is calculated to be 1.4 μsec with the 335 nm band assigned to the $\text{1}{}_{\mathrm{u}}\text{→ X}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ transition. The 485 nm bands cannot be assigned to any Hg₂ transitions. Strong bound-continuum absorptions are predicted for the 485 nm bands. On the other hand, the 335 nm emission is predicted to be absorbed by bound-bound transitions only.     

Magnetostriction of antiferromagnetic FeGe2

The anisotropic magnetostriction of FeGe₂ is measured for magnetic field along the [1 0 0] and [1 1 0] axes at temperature 4.2 K and along [1 0 0] from 77 to 300 K. The behaviour is consistent with spin reorientation in the basal plane. The saturation magnetostriction and the characteristic field required to produce saturation decrease with increasing temperature and approach zero at the lower transition temperature, $\text{T}{}_{\mathrm{K}}\text{? 265}$ K. This suggests that the spins flip from the basal plane into the direction of the tetragonal [0 0 1] axis at T_K.     

Microwave spectrum of acetylene-d2

Eight P-branch transitions from the $\text{ν}{}_5{}^1\text{-ν}{}_4{}^1$ difference band of C₂D₂ have been observed in the microwave region. Significant improvements in the spectroscopic constants for the two states involved in the difference band have been obtained by combining infrared and microwave data. The Stark shifts for the observed C₂D₂ lines are discussed in some detail. The vibrational transition moment is found to be μ_vib = 0.0358 ± 0.0020 D.     

Laser magnetic resonance spectrum of BrO (2Π12 ← 2Π32)

Magnetic dipole transitions between the ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and ${}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ components of the ground electronic state of BrO have been detected using the technique of laser magnetic resonance on three CO₂ laser lines between 964 and 970 cm^?1. This is the first direct observation of the ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ state in BrO. The spin-orbit splitting parameter, A, is determined to be ?967.9831(2) cm^?1 for ⁷⁹Br¹⁶O and ?967.9981(2) cm^?1 for ⁸¹Br¹⁶O. Accurate values for the rotational constant $\text{B}{}^{\mathrm{<mtext>eff</mtext>}}\text{(}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)}$, the hyperfine parameters ($\text{b}{}_{\mathrm{F}}\text{+}\text{2c}\text{3}$) and d, the Λ-doubling parameter p, and the Zeeman parameter g| are also determined from an analysis of the measured spectra.     

Transition moment variation in the A2Σ+ → X2Πi transition of HCl+, DCl+ and HBr+

Relative emission intensities of sixteen bands of HCl⁺ (A²Σ⁺ - X²Π_i), four bands of DCl⁺ (A²Σ⁺ - X²Π_i), and 5 bands of HBr⁺ (A²Σ - X²Π_i) have been made using both ion-beam excitation and microwave discharge sources. Intensities were determined by comparison with computer-generated spectra. Treatment of the data within the r-centroid approximation shows that in HCl⁺ the electronic transition moment decreases strongly at large $\text{r}{}_{\mathrm{v\prime v″}}$ [$\text{Re}\text{α}\text{exp}\text{(?3.6}\text{r}{}_{\mathrm{v\prime v″}}\text{)}\text{for 1.44}\text{A}\text{?}\text{< r}{}_{\mathrm{v\prime v″}}\text{< 1.82}\text{A}\text{?}$] but levels off at shorter $\text{r}{}_{\mathrm{v\prime v″}}$. DCl⁺ data agree quantitatively with HCl⁺. The variation in the HBr⁺ moment is similar, with $\text{R}\text{e}\text{α}\text{exp}\text{[?4.5}\text{r}{}_{\mathrm{v\prime v″}}\text{]}\text{for 1.58}\text{A}\text{?}\text{<}\text{r}{}_{\mathrm{v\prime v″}}\text{< 1.78}\text{A}\text{?}$.     

Structure magnetique en champ applique nul de l'acetate de manganese tetrahydrate Mn(CH3COO)2, 4H2O

The magnetic structure of manganous acetate Mn(CH₃COO)₂, 4H₂O has been solved by neutron diffraction. Manganous acetate crystallizes in the space group $\text{P2}{}_1\text{c}$ with Z = 6. Manganese atoms (in position 2a and 4e) are located in (100) planes. Below T_N = 3.18 K this compound is antiferromagnetic in a zero applied field with the k vector [$\text{1}\text{2}$ 00]. The plane (100) is ferromagnetic. The magnetic group is $\text{P}{}_{\mathrm{2a}}\text{2}{}_1\text{c}$.