共查询到20条相似文献,搜索用时 46 毫秒
1.
The effect of shear strain on the iron α-ε phase transformation has been studied using a rotational diamond anvil cell (RDAC). The initial transition is observed to take place at the reduced pressure of 10.8?GPa under pressure and shear operation. Complete phase transformation was observed at 15.4?GPa. The rotation of an anvil causes limited pressure elevation and makes the pressure distribution symmetric in the sample chamber before the phase transition. However, it causes a significant pressure increase at the centre of the sample and brings about a large pressure gradient during the phase transformation. The resistance to the phase interface motion is enhanced due to strain hardening during the pressure and shear operations on iron and this further increases the transition pressure. The work of macroscopic shear stress and the work of the pressure and shear stress at the defect tips account for the pressure reduction of the iron phase transition. 相似文献
2.
We have investigated the pressure-induced phase transition of NiO and other structural properties using three-body potential
approach. NiO undergoes phase transition from B1 (rocksalt) to B2 (CsCl) structure associated with a sudden collapse in volume
showing first-order phase transition. A theoretical study of high pressure phase transition and elastic behaviour in transition
metal compounds using a three-body potential caused by the electron shell deformation of the overlapping ion was carried out.
The phase transition pressure and other properties predicted by our model is closer to the phase transition pressure predicted
by Eto et al.
相似文献
3.
《Solid State Ionics》2006,177(26-32):2687-2690
High pressure conductivity measurements have been carried out on P(EO)20LiBETI from 295 K to 368 K. The decrease of electrical conductivity with pressure is larger in the partially crystalline phase (low temperature and low pressure or high temperature and high pressure) than in the fully amorphous phase (high temperature and low pressure). It is found that if the phase transition is approached from the crystalline phase (decreasing pressure), the pressure of the phase transition varies from 0 to 0.23 GPa as the temperature increases from 336 K to 358 K. The shift of the phase transition temperature with pressure is approximately the same as the shift of the glass transition temperature with pressure for pure PEO. This can be understood in terms of the defect diffusion model. If the material is above 336 K and is in the fully amorphous phase, after pressure is increased above the critical pressure, the material remains in the amorphous phase for extended periods of time before transforming to the partially crystalline phase. This is reminiscent of a super-pressed state but may be an indication of slow crystallization kinetics. 相似文献
4.
5.
We report a pressure-dependent investigation of KMnF(3) by x-ray diffraction up to 30 GPa. The results are discussed in the framework of Landau theory and in relation to the isostructural phase transition in SrTiO(3). The phase transition temperature near 186 K in KMnF(3) shifts to room temperature at a critical pressure of P(c) = 3.4 GPa; the pressure dependence of the transition point follows ΔP(c)/ΔT(c) = 0.0315 GPa K(-1). The transition becomes second order under high pressure, close to the tricritical point. The phase transition is determined by the rotation of MnF(6) octahedra with their simultaneous expansion along the rotation axis. The rotation angle was found to increase to 10.5° at 24 GPa. An additional anomaly was observed at higher pressure around 25 GPa, suggesting a further phase transition. 相似文献
6.
It is shown that the driving force of a ferroelastic phase transition is internal pressure. The pressure gives rise to symmetric deformation, whose energy accumulates as pressure increases and, at the phase transition point, is partially transferred into the energy of antisymmetric deformations. 相似文献
7.
Y. Wang W.J. Chang J.Z. Jiang Y.C. Li T.D. Hu 《Journal of Physics and Chemistry of Solids》2005,66(10):1775-1778
Mn doping effect on a wurtzite-to-cubic phase transformation in ZnO has been investigated by in situ high pressure X-ray powder diffraction using synchrotron radiation. Unit cell expansion is clearly observed in Mn-doped ZnO samples. Mn ions sit at Zn site in the wurtzite structure. The onset transition pressure for the wurtzite-to-cubic phase transformation decreases from about 9.5 GPa for pure ZnO to 6 GPa for sintered 2at.% Mn-doped ZnO while the compressibility and volume collapse at transition pressures are not sensitive to the Mn doping in the wurtzite phase. The doping of Mn ions in ZnO increases the onset transition pressure for the cubic-to-wurtzite phase transformation. The results could be explained by a reduction of phase transformation barriers for both transition paths by the Mn doping. The observation of reduction of the wurtzite-to-cubic phase transformation pressure might point out a new direction to synthesize cubic wurtzite phase of ZnO by doping transition element(s). 相似文献
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9.
Pressure has a profound effect on the paraelectric and ferroelectric properties of perovskite crystals. In this paper we theoretically investigate the effect of pressure on the cubic-to-tetragonal phase transition and on the soft mode dynamics of some classical perovskite crystals: BaTiO(3), PbTiO(3), and KNbO(3). We use a model consisting of three subsystems: electrons, phonons, and off-center displacements treated as spins. Experiments show that pressure has a large effect on the tunneling and hopping of the off-center displacements, that in turn strongly affect the pressure dependence of the transition temperature and the soft mode frequency. This model, with a very small number of adjustable parameters, accounts quantitatively for the experimentally measured nonlinear pressure dependence of the cubic-to-tetragonal phase transition temperature, up to the critical pressure where the transition temperature is zero. It also accounts quantitatively for the pressure dependence of the soft mode frequency, which is finite at the phase transition in spite of the fact that the phase transition at elevated pressures is second order, and for the pressure dependence of the electronic gap energy. 相似文献
10.
Purvee Bhardwaj Sadhna Singh Neeraj Kumar Gaur 《Central European Journal of Physics》2008,6(2):223-229
In the present paper we have investigated the high-pressure, structural phase transition of Barium chalcogenides (BaO, BaSe
and BaTe) using a three-body interaction potential (MTBIP) approach, modified by incorporating covalency effects. Phase transition
pressures are associated with a sudden collapse in volume. The phase transition pressures and associated volume collapses
obtained from TBIP show a reasonably good agreement with experimental data. Here, the transition pressure, NaCl-CsCl structure
increases with decreasing cation-to-anion radii ratio. In addition, the elastic constants and their combinations with pressure
are also reported. It is found that TBP incorporating a covalency effect may predict the phase transition pressure, the elastic
constants and the pressure derivatives of other chalcogenides as well.
相似文献
11.
12.
研究了等静压和温度诱导掺镧La的Pb(Zr,Sn,Ti)O3(PLZST)陶瓷材料的铁电反铁电相变、介电压力谱和介电温度谱,研究了温度对压致相变和介电压力谱的影响,结果发现温度使铁电反铁电相变压力降低,介电压力谱具有明显的扩散相变和频率弥散的特点;研究了等静压对介电温度谱的影响,结果表明等静压使铁电反铁电相变温度降低,反铁电顺电相变温度升高.这些现象有利于丰富和拓宽人们对温度和压力诱导的多组元弛豫型铁电体和弛豫型反铁电体扩散相变和弛豫行为的认识和理解.
关键词:
等静压和压致相变
铁电反铁电相变
介电压力谱
介电温度谱 相似文献
13.
采用基于密度泛函理论的第一性原理方法, 分别研究了压力作用下Fe从体心立方 (bcc,α 相) 结构到六角密排(hcp, ε相) 结构相变的两种不同的相变机理: 相变过程中出现亚稳定的面心立方(fcc) 结构(bcc-fcc-hcp) , 以及相变过程中没有出现亚稳定的fcc结构(bcc-hcp) . 计算结果表明: 静水压力条件下, 相变过程中并不会产生亚稳定的fcc结构, 这与最近的原位XRD实验测量结果相一致. 随着压力的增加, fcc-hcp的相变势垒逐渐增加, 压力趋向于阻止Fe从fcc结构到hcp结构的相变. 计算得到了相变过程中原子磁性和结构的详细信息, 分析表明相变过程中涉及复杂的磁性转变, 并且讨论了原子磁性对结构转变影响的物理机理. 此外, 对分子动力学模拟中产生亚稳定的fcc结构的原因也进行了讨论.
关键词:
相变机理
静水压力
第一性原理
铁 相似文献
14.
采用金刚石对顶砧高压装置,在室温下对正辛烷(C8H18)进行了原位高压拉曼光谱研究,实验的最高压力为13GPa。在实验的压力范围内,正辛烷的拉曼峰位随压力的升高均向高频移动,峰强逐渐减弱,峰形变宽。常态为液态的正辛烷在0.8 GPa时,拉曼频移随压力的变化曲线出现了拐点,发生了液-固相变;在6.8 GPa时,伴随着原拉曼峰的消失或劈裂,以及新拉曼峰的出现,此时正辛烷可能发生了固-固相变。该相变压力低于已有的低碳数正烃烷的压致相变结果。正烃烷的压致相变压力点,具有随着结构链长的增加,其相变压力降低的规律。 相似文献
15.
Using the linear sigma model, we have
introduced the pion isospin chemical potential. The chiral phase
transition is studied at finite temperatures and finite isospin
densities. We have studied the μ-T phase diagram for the chiral
phase transition and found the transition cannot happen below
a certain low temperature because of the Bose-Einstein condensation
in this system. Above that temperature, the chiral phase
transition is studied by the isotherms of pressure versus density.
We indicate that the transition, in the chiral limit, is a first-order
transition from a low-density phase to a high-density phase
like a gas-liquid phase transition. 相似文献
16.
T. Suski J. Karpiński K.L.I. Kobayashi K.F. Komatsubara 《Journal of Physics and Chemistry of Solids》1981,42(6):479-482
The high pressure structural phase transition in the alloy series Pb1 ? xSnxTe has been investigated using resistivity and Hall coefficient measurements. With increasing of tin content the critical pressure decreases linearly and the phase transition becomes less drastic. The anomalous behavior of the resistivity in the phase transition region is explained by band structure changes. It is suggested that the high pressure phase transition in Pb1 ? xSnxTe is a metallic-covalent transition. 相似文献
17.
研究常温下200~1 100 MPa压力范围内石膏的Raman光谱,原位观测了随压力升高,石膏在水中的溶解现象,其过程中伴随着石膏的相变。结果表明:压力小于407 MPa时,石膏的形态无明显变化;随着压力的升高,石膏开始溶解,溶解至一定程度,石膏发生了向半水石膏转化的相变;相变完成后,半水石膏继续溶解至消失。石膏这一溶解相变过程表明在地球内部与压力相应的深部区域内,也可能会发生矿物的溶解相变。 相似文献
18.
Using the Raman technique we have studied the lattice vibrations of the prototype plastic crystal adamantane (C10H16). The measurements, as a function of temperature through the phase transition (208K), show splittings in certain lines. At room temperature using hydrostatic pressure, we also induced a phase transition. The transition is detected by Raman measurements, and we observe splittings of the very same vibrational lines. This indicates that the pressure induced phase transition yields the same crystal structure as the low temperature structure. Some analysis of the pressure and temperature derivatives of the vibrational modes is presented. 相似文献
19.
A. N. Vtyurin A. S. Krylov S. V. Goryaĭnov S. N. Krylova V. N. Voronov 《Physics of the Solid State》2006,48(6):1070-1072
The Raman spectra of Rb2KScF6 elpasolite crystals are studied in the pressure range up to 7 GPa. A phase transition is revealed at a pressure of approximately 1 GPa. Analysis of the changes in the spectral parameters shows that the phase transition is accompanied by a doubling of the volume of the primitive cell in the initial cubic phase. Judging from the character of the variations in the pressure dependences of the frequency of the observed vibrations, there can exist another transition to the phase with a lower symmetry at a pressure of approximately 2.1 GPa. 相似文献