Magnon Raman scattering in CoBr2

The one-magnon Raman spectrum of CoBr₂ has been investigated as a function of temperature, and peak frequency, integrated intensity and width parameters obtained. The results obtained for the band energy at low temperature (22.2 ± 0.2 cm^-1 at 5.7.K) are in good agreement with AFMR and neutron scattering results. The one-magnon energy renormalises relatively slowly with increasing temperature and is about 15 cm^-1 at T_N = 19 K, whereas the integrated intensity approaches zero like the magnetization at T_N and the width diverges. A low intensity band at 26.8 ± 1 cm^-1 (7.6K) may be due to two-magnon scattering from spin waves along the c-axis.     

Zeitliches Abklingen und Anisotropie von p-Terphenyl- undp-Terphenyl-Anthrazen-Mischkristallen bei Beschuß mit α-Teilchen

The time dependence of scintillation intensity from single crystals ofp-terphenyl and mixed crystals ofp-terphenyl and anthracene after bombarding with α-particles was investigated at the two temperaturesT=296 °K andT=92 °K. For the crystals ofp-terphenyl the time dependence of the scintillation anisotropy was also measured. Using the formulas given byKing andVoltz the decay curves ofp-terphenyl were decomposed into two components. Good agreement between experiment and theory was found. The ratio of the prompt intensity to the delayed intensity was determined to be 1∶2 atT=296 °K and 1∶3 atT=92 °K. The diffusion constants for triplet excitons were calculated to beD _T(296 °K)≈10^?5 cm² sec^?1 andD _T(92 °K)≈ 2×10^?6 cm² sec^?1, and the triplet-triplet interaction rate constantsχ _tt(296 °K)≈ 2.5×10^?11 cm³ sec^?1 andχ _tt(92 °K)≈0.5×10^?11 cm³ sec^?1.     

Optical investigation of DyFeO3

Optical absorption spectra of DyFeO₃ have been investigated at 1.2≦T≦4.2 °K, andT=77 °K From the temperature dependent lineshift a Néel temperature ofT _N=(3.8±0.5) °K is deduced for the dysprosium sublattices. The groundstate splitting due to the iron-dysprosium interactions is about 1.5 cm^?1 and due to the dysprosiumdysprosium interactions (5.0±1.4) cm^?1. Zeeman studies give the magnetic moment of the dysprosium ions asμ=(9.2±1.0)μ _B.     

Mößbauereffekt in Eisenstilben und FeCl2·H2O

Using Mößbauer effect measurements in the temperature range between 3 °K and 310 °K the magnetic fields at the nucleus in iron-stilbene, FeCl₂·H₂O and FeCl₃ are determined to beH _T=0=(250±10) kOe, (252±18) kOe and (468±10) kOe; a Néel-temperature ofT _N=(23±1) °K is measured for iron-stilbene. The electric quadrupole splittings atT=0 °K for iron-stilbene and FeCl₂ ·H ₂ O, ΔE=(+2.52±0.02) mm/sec and (+2.50±0.05) mm/sec, yield electric field gradients at the iron nucleus ofq _z=+9.7·10¹⁷ V/cm² and +9.6·10¹⁷ V/cm², whereq _z⊥H; Debyetemperatures of θ=162 °K and 188 °K are obtained. The energy of the excited 3d-electron levels in iron-stilbene is estimated to Δ₁=309 cm^?1 and Δ₂=618cm^?1 as deduced from the temperature dependence ofΔE. In contrast to the suggestion ofEuler andWillstaedt bivalence of the iron in ironstilbene is found; its composition is shown to be 4(FeCl₂ ·H ₂O)·stilbene.     

Halleffekt und anisotropie der beweglichkeit der elektronen in ZnO

Hallconstant, conductivity and Hall mobility of ZnO crystals were measured as function of temperature (4 °K < T < 370 °K) and orientation. Value and anisotropy of mobility can be explained (50 °K < T < 370 °K) by polar optical scattering, deformation potential sc., piezoelectric sc. and sc. by ionized impurities. The anisotropy of mobility is caused only by piezoelectric sc. Maximum values of μ_H are reached for μ_H ⊥ c, with 2400 cm²/V sec at 40 °K and for μ_H ¦ c with 1350cm²/Vsec at 60 °. Below 50 °K Hallconstant, conductivity and Hall mobility are influenced by impurity band conduction processes. The crystals have impurity concentration in the 10¹⁶ cm^?3 range, but they show different donor activation energies depending on growth conditions: Type I: 38,4 meV (50 °K < T < 100 °K) and Type II: 20,3 meV (50 °K < T < 100 °K) and 6 meV (25 °K < T < 50 °K).     

Optical investigation of HoFeO3

The absorption spectra of HoFeO₃ were investigated in the near infrared spectral region at temperatures of 1.2, 4.2, 20 and 77 °K respectively. At every temperatureT≦20 °K all the absorption lines show the same splitting which is attributed to the groundstate; this splitting is (7.2±0.5) cm^?1 at 20 °K and decreases to (4.9±0.8) cm^?1 extrapolated to 0 °K. From these splittings the holmium-iron and the holmiumholmium interactions can be deduced. Measurements with an external magnetic field yield a magnetic moment ofμ=(7.6±0.7)μ _B per holmium ion. The moments are directed at angles of ?28° and ?152° with respect to theb-axis.     

Shock-tube study of HCN self-broadening and broadening by argon for the P(10) line of the ν1 band at 3 μm

A tunable infrared diode laser was used to measure the fully resolved absorption line shape of the P(10) line in the ν₁ band (10°0–00°0) of HCN for shock-heated mixtures of HCN-Ar at temperatures of 1000, 1500 and 2000 K. The temperature dependence of the collision-broadening coefficients 2γ (cm^-1 atm^-1, FWHM) were inferred for both self-broadening and broadening by argon. For the assumed form 2γ = 2γ₀(T₀/T)ⁿ the exponent n was determined to be 0.63 ± 0.06 with 2γ₀ = 0.11 cm^-1atm^-1 and T₀ = 300 K for argon-broadening in the range 300 < T < 2000 K, and 1.2 ± 0.6 with 2γ₀ = 0.68 cm^-1atm^-1 and T₀ = 1000 K for self-broadening in the range 1000 < T < 2000 K.     

Intensity measurements in the v4-fundamental of methane

The absolute intensities of all the J-multiplets between R(13) at 1375cm^-1 and P(12) at 1225 cm^-1, in the v₄-fundamental of ¹²CH₄, have been measured at 300°K. Our values are consistent with published band-intensity measurements and also with the theoretical line strength tabulation by Fox. Spectral transmittance computation using a Lorentz line shape with a hydrogen-broadened half-width of 0.075 cm^-1 atm^-1 at 300°K for all the lines in the band is in excellent agreement with our experimental data measured with a spectral resolution of 0.2 cm^-1. Our best estimate for the absolute intensity of the band is 145±8 cm^-2 atm^-1 at STP.     

Self-density frequency shift measurements of Raman N2 Q-branch transitions

We report stimulated Raman investigations of N₂ Q-branch transitions in view to measure the self-density frequency shift. These measurements performed at 295 K over the density range 0.02-0.8 Amagat lead to a mean shift value equal to -5.5×10^-3 cm^-1/Amagat. Moreover, our data extrapolated at zero density allowed new refinements of the N₂ molecular constants: v₀=2329.91165 (17) cm^-1, B₁–B₀=-0.0173714 (22) cm^-1 and D₁–D₀=(7.6±5.0)×10^-9 cm^-1.     

High-temperature absorption coefficient of methane at 3.392μ

The spectral absorption coefficient of methane at 3.392μ has been measured in the temperature range 965 ?T, °K≤2710 behind incident and reflected shock waves. It is given by the relation P'=P'₀(T₀/T)ⁿ where P'₀=(1.34±0.58)x10²cm^-1atm^-1 at T₀=300°K and n=2.88±0.21. The empirically determined temperature exponent n may be approximately accounted for by a simplified theoretical analysis.     

Effect of antiferromagnetic ordering on the optical transitions in MnF2

Two optical absorption bands (viz. C and F) in MnF₂, whose line positions are nearly temperature-independent above T_N = 67.3 K, are investigated for the effect of magnetic ordering. Both bands are blue-shifted by ΔE (≌90 cm^?1 for C and 120 cm^?1 for F at 10 K) and the lines show additional narrowing on cooling through T_N. It is found that ΔE varies as the sublattice lattice magnetization below T_N and nearly as the magnetic energy above T_N.     

COMBINED EFFECTS OF SUBCOOLING AND SURFACE ORIENTATION ON POOL BOILING OF HFE-7100 FROM A SIMULATED ELECTRONIC CHIP

The effects of orientation and subcooling on pool boiling of the HFE-7100 dielectric liquid near atmospheric pressure (0.085 MPa) from a 10 × 10 mm smooth copper surface are investigated experimentally. Results are obtained for inclination angles θ = 0° (upward-facing), 30°, 60°, 90°, 120°, 150°, and 180° (downward-facing) and liquid subcoolings ΔT_sub = 0, 10, 20, and 30 K. Increasing θ decreases the saturation nucleate boiling heat flux at high surface superheats (ΔT_sat > 20 K), but increases it only slightly at lower surface superheats. The critical heat flux (CHF) decreases slowly with increasing θ from 0° to 90°, and then deceases faster with increasing θ to 180°. CHF increases linearly with increased subcooling, but the rate increases from 0.016 K^?1 at 0° to 0.048 K^?1 at 180°. At θ = 0° and ΔT_sub = 30 K, CHF is ～ 36 W/cm² and 24.45 W/cm² for saturation boiling, while at θ = 180° CHF = 10.85 W/cm² at ΔT_sub = 30 K and only 4.30 W/cm² at saturation. The developed correlation for CHF of HFE-7100, as a function of θ and ΔT_sub, is within ±10% of the present data. The recorded still photographs of the boiling surface in the experiments illustrate the effects of liquid subcooling and surface orientation at different nucleate boiling heat fluxes and surface superheats on vapor bubble accumulation and/or induced mixing at the surface.     

Absorption of CO laser radiation by NO

Absorption of CO i.r. laser radiation by NO has been studied over the temperature range 300°–4000°K using a grating-tunable CO laser in conjunction with a room-temperature absorption cell and a shock tube. The CO laser line with strongest absorption at elevated temperatures was determined to be the V = 7 → 6, J = 12 → 13 line at 1935.4817 cm^-1, which is nearly coincident with the ²Π_{$\text{3}\text{2}$}V = 0 → 1, J = 37/2 → 39/2 transition in NO. The absorption cell measurements (300°K) were used to infer the position of the NO absorption line (a Λ-doublet at 1935.492 and 1935.497 cm^-1) as well as collision-broadening parameters in pure NO and NO dilute in foreign gases: 2γ° (collision-broadened full width at half maximum in cm^-1 atm^-1 at 300°K) = 0.110, NO-NO; 0.072, NO in Ar; 0.069, NO in Kr; 0.109, NO in N₂. Calculations of the NO absorption coefficient at 1935.4817 cm^-1 are presented for a range of conditions applicable to current studies in combustion and NO_x kinetics. Shock tube measurements (630°–4000°K) supporting these calculations are also reported.     

Exciton spectra and electrical conductivity of epitaxial silicon-doped GaN layers

Optical spectra and electrical conductivity of silicon-doped epitaxial gallium nitride layers with uncompensated donor concentrations N _D — N _A up to 4.8 × 10¹⁹ cm^?3 at T ≈ 5 K have been studied. As follows from the current-voltage characteristics, at a doping level of ～3 × 10¹⁸ cm^?3 an impurity band is formed and an increase of donor concentration by one more order of magnitude leads to the merging of the impurity band with the conduction band. The transformation of exciton reflection spectra suggests that the formation of the impurity band triggers effective exciton screening at low temperatures. In a sample with N _D — N _A = 3.4 × 10¹⁸ cm^?3, luminescence spectra are still produced by radiation of free and bound excitons. In a sample with N _D — N _A = 4.8 × 10¹⁹ cm^?3, Coulomb interaction is already completely suppressed, with the luminescence spectrum consisting of bands deriving from impurity-band-valence band and conduction-band-valence band radiative transitions.     

Stark broadening of lines from multiply-charged carbon ions in a high-density arc plasma

Profiles of C(III) and C(IV) lines emitted in the VUV and visible regions from a pulsed arc (N_e=1.5×10¹⁸ cm^-3, T_e=5.3×10⁴K) have been measured with time resolution. The experimental results are in satisfactory agreement with the predictions of electron impact theory for (3-3) and (3-4) transitions for which the energy separation between the upper level and the nearest perturbing level is smaller than the electron thermal energy. For lines from (2-2) transitions for which the plasma is optically thick, damping constants determined experimentally agree with theoretical values within a factor of two.     

Synthesis and electric properties of perovskite Pr0.6Ca0.4Fe0.8Co0.2O3 for SOFC applications

In this study, polycrystalline powder Pr_0.6Ca_0.4Fe_0.8Co_0.2O₃ (PCFC) was synthesized by a sol–gel process. This oxide was analyzed by X-ray powder diffraction. Synthesized Pr_0.6Ca_0.4Fe_0.8Co_0.2O₃ showed up to be single phase and belongs to the orthorhombic crystalline system with a Pbnm space group. The microstructural features of the synthesized products display particles having an irregular morphology and a size in the range of 50–100 nm. X-ray diffraction (XRD) analysis shows the chemical compatibility between the PCFC cathode and the electrolyte Sm-doped ceria since no reaction products were honored when the material was mixed and co-fired at 1,000 °C for 168 h. The thermal expansion coefficient of PCFC 16.9?×?10^?6 °C^?1 is slightly higher than that of Ce_0.8Sm_0.2O_1.9 (SDC) over the studied temperature range. The greater contribution to the total resistance of the electrode is the electrochemical resistance associated with oxygen exchange in the cathode surface (0.96 Ωcm²). The dc four-probe measurement indicated that PCFC exhibits fairly high electrical conductivity, over 100 S cm^?1 at T?≥?500 °C, making this material promising as a cathode material for intermediate temperature solid oxide fuel cells.     

Stepwise ionization in a non-equilibrium,steady-state hydrogen plasma

The paper considers a non-equilibrium, steady-state hydrogen plasma with 10¹⁰ ? N_e, cm^-3 ? 10¹⁷ and 8000 ? T_e, °K ? 64,000. The following two cases are analyzed: (1) the plasma is optically thin for all atomic lines and (2) the plasma is optically thick towards the Lyman lines and optically thin for all other lines. Analytical expressions have been obtained for populations and ionization frequencies of excited levels. Populations of the excited levels obtained from the analytical formulas are in good agreement with numerical calculations.     

Spectroscopic diagnostics of R.F. discharges at moderate pressure and chemical applications—I. Pure nitrogen

A vibro-rotational analysis has been performed of the second positive system (SPS) of N₂ and of the first negative system (FNS) of N⁺₂ emitted by 35 MHz discharges in flowing nitrogen operated at pressures of 5–50 torr and power densities of the order of 1–10 W-cm^-3. The distributions of the vibrational and of the rotational levels follow Boltzmann's law in both the SPS and the FNS with T_v = 4000°K and T_R = 2800°K for the N₂(C³Π_u) state and T_v = 5100°K and T_R = 5800°K for the N⁺₂(B²Σ⁺_g) state and independent of pressure. Kinetic gas temperatures are between 1200 and 2000°K and increase with pressure; electron temperatures are in the range 15,000–9,500°K. The reversal of line intensities of the SPS and of the FNS observed with increasing pressure has been tentatively interpreted. Possible chemical implications of these results have been examined.