A thermal and Raman investigation of the phase transitions above room temperature in anhydrous potassium acetate

Results using thermal and Raman techniques are presented on the phase transition in potassium acetate occurring above room temperature. Two phase transitions are observed at T_c1 = 349K and T_c2 = 413K. The magnitude of the entropy change at T_c1 and the Raman results suggest that this transition is orientational in nature and is due to rotation of the acetate ion about the c-c axis. The T_c2 transition is displacive in nature, and the Raman results show a marked softening of the lowest frequency mode as T_c2 is approached from below.     

Static and dynamical elastic behaviour of squaric acid around its phase transition

Ultrasonic velocity measurements could be performed on a good quality single crystal of squaric acid close to its transition temperature around 373 K. The behaviour of the stiffness componentsc ₃₃ andc ₄₄ clearly demonstrates a first-order transition. The temperature variation ofc ₁₁ andc ₆₆ can be fitted to a formula obtained from the Landau theory and assuming a strictive-type coupling between order parameter and strain. From attenuation measurements characteristic times for the order-parameter dynamics can be estimated, ranging from 10^?11 to several 10^?10s in a temperature range of about 12 K on either side of the transition.     

η-superconductivity in the one-dimensional Penson-Kolb model

Using exact Lanczos diagonalizations we have studied in detail the transition into the η-superconducting state in the Penson-Kolb model. We have shown that the transition occurs at any band filling and the critical value W _c varies between W _c ? ?1:8t at half-filling to W _c ? ?2t for two particles on the lattice. The transition corresponds to abrupt and drastic change in the ground-state structure. After the transition the contribution of the one-electron band to the ground-state energy is almost suppressed.     

Superconducting transition temperature in hafnium under pressures up to 64 GPa

The superconducting transition temperature T _c of hafnium is measured as a function of pressure up to 64 GPa. The character of the pressure dependence of T _c observed at α–ω–β transitions in Hf is found to be similar to that observed for Zr. In the regions of α and β phases, T _c increases with pressure with the slopes dT _c /dP=0.05 and 0.16 K/GPa, respectively. At the α–ω transition, T _c (P) exhibits a tendency to a decrease, while at the ω–β transition, T _c increases stepwise from 5.8 to 8.0 K. The α–ω transition occurs at pressures between 31.2 and 35.9 GPa, and the ω–β transition, at a pressure of 62±2 GPa.     

The vortex-like excitations detected by Nernst signals in high-T c superconductors

The nature of the pseudogap state and its relation to the d-wave superconductivity in high-T _c superconductors is still an open issue. The vortex-like excitations detected by the Nernst effect measurements exist in a certain temperature range above superconducting transition temperature T _c, which strongly support that the pseudogap phase is characterized by finite pairing amplitude with strong phase fluctuations and imply that the phase transition at T _c is driven by the loss of long-range phase coherence. We first briefly introduce the electronic phase diagram and pseudogap state of high-T _c superconductors, and then review the results of Nernst effect for different high-T _c superconductors. Related theoretical models are also discussed.     

Dielectric properties of CsH2PO4 and CsD2PO4

Orthorhombic CsH₂PO₄ undergoes a ferroelectric transition at T_c = ?119.5°C, whereas the ferroelectric transition temperature in isomorphous CsD₂PO₄ is T_c = ?5.55°C. The transitions are of first order in both cases. The rather large isotope effect demonstrates the importance of the OHO bonds in the transition mechanism.     

Nonlocal PNJL model beyond mean field

A nonlocal chiral quark model is consistently extended beyond mean field using a strict 1/N _c expansion scheme. It is found that the 1/N _c corrections lead to a lowering of the temperature of the chiral phase transition in comparison with the mean-field result. On the other hand, near the phase transition the 1/N _c expansion breaks down and a nonperturbative scheme for the inclusion of mesonic correlations is needed in order to describe the phase transition region.     

Test of scaling theories for metal-insulator transition in amorphous,superconducting BixKr1−x mixtures

Measurements of the d.c. electrical conductivity σ and the superconducting transition temperature T_c in amorphous Bi_xKr_1?x mixtures as a function of the Bi concentration x give clear evidence for the occurence of an Anderson or Anderson-Mott type metal-insulator transition at x_c = 0.55 ± 0.02. From our σ and T_c data we estimate two characteristic exponents which we compare with those derived from existing scaling theories for the metal-insulator transition in disordered systems.     

Esr study of (SO4)2− dynamics in relation to the ferroelectric phase transition in ammonium sulfate

Ferroelectric phase transition in ammonium sulfate has been studied by ESR of CrO₄^3? radical substituting for SO₄^2? ion in (NH₄)₂SO₄. In addition to discontinuous changes at T_c, certain continuous changes are observed in ESR parameters of this probe below T_c, which reflect the role of the sulfate ion in the phase transition. A microscopic mechanism of the phase transition is proposed and discussed in terms of the change of orientation of the sulfate tetrahedron through a finite angle. The degree of the change of orientation below T_c is thought to be the possible order parameter of the phase transition.     

Ferroelastic phase transition and anomalous elastic and thermal properties of betaine borate (CH3)3NCH2COO·H3BO3

The temperature and pressure derivatives of the elastic constants of orthorhombic betaine borate, (CH₃)₃NCH₂COO·H₃BO₃, have been determined by measuring temperature and stress induced shifts of resonance frequencies of thick plates at ca. 15 MHz in the range between 140 and 300 K and 0 and 3 kbar. The elastic ‘shear’ resistance c₄₄ exhibits a value as low as 0.0492×10¹⁰Nm^-2at 293 K. With decreasing temperature c₄₄ approaches zero at ca. 142.5 K, indicating an acoustic soft mode behaviour connected with a ferroelastic phase transition. The softening of c₄₄ is described in a good approximation by c₄₄(T)_p=0 =alogT/T₀ with a=0.0663×10¹⁰Nm^-2 and T₀ = 139.5 K. Further, c₄₄ decreases with increasing pressure according to the linear relation c₄₄(p)_{T=293 K} = 0.0492?0.184×10^-4p (p in bar, c₄₄ in 10¹⁰ Nm^-2). All other elastic constants show a quite normal temperature and pressure dependence. At 293 K the transition is induced by a pressure of 2.65 kbar. The transition temperature T_c depends linearly on pressure according to T_c = 142.5+0.0568 p (pinbar, T_cinK). Passing through the transition no discontinuous change of the lattice constants is observed. The three principal coefficients of thermal expansion and the pressure derivatives of the dielectric constants exhibit discontinuities at the transition. The transition is of strongly second order.     

Superconductivity and Peierls instability in coupled linear chain systems

We study the superconducting transition temperature (T_c) and the Peierls instability temperature (T_p) using Eliashberg type equations for both T_c and T_p self consistently with finite interchain coupling. We show that T_c > T_p below a critical electron-phonon coupling constant which depends on the bare phonon frequency. This determines an upper bound on T_c so that for higher transition temperatures T_p > T_c and superconductivity is unlikely. Higher values of T_c are possible if the interchain coupling is increased above a critical value where the Peierls instability is suppressed.     

Polarization properties of Li2−x Na x Ge4O9 (0.2 ≤ x ≤ 0.3) crystals

The polarization switching in sinusoidal fields and the pyroelectric properties of Li_2?x Na _x Ge₄O₉ (0.2 ≤ x ≤ 0.3) crystals are measured in the temperature range T _c ?T ≤ 40 K. The behavior of the P?E hysteresis loops with variations in temperature is investigated for crystals with phase transition temperatures T _c < 300 K and T _c > 300 K. It is shown that, for crystals with phase transition temperatures T _c < 300 K, the temperature dependence of the hysteresis loop exhibits a behavior typical of crystals with second-order phase transitions. The crystals with phase transition temperatures T _c > 300 K are characterized by double hysteresis loops in the temperature range T _c ?T ₁ ≈ 30 K. The correlation between the polarization properties and possible structural transformations of the Li_2?x Na _x Ge₄O₉ crystals due to the change in the concentration ratio of Na and Li ions is discussed.     

Compatibility of BCS pairing and the peierls distortion in two-band systems

The effect of the Peierls transition on superconductivity in a two-band system, where one of the bands is flat, is examined theoretically. We find that superconductivity appears at the background of the insulating phase (T_P >; T_c). At T_c > T_P only the superconducting transition is possible.     

Metal-nonmetal transition and superconductivity in frozen aluminium-hydrogen films

A study of the influence of the hydrogen concentration c_H on the superconducting transition temperature T_c and the d.c.-conductivity σ of Al-films has been performed. The samples were prepared by co-deposition of Al and H (H₂) onto a sapphire substrate held at a temperature of about 5 K. Within the experimental errors, there is no difference between the behaviour of Al-H and Al-H₂ respectively. σ shows a decrease with increasing c_H and a metal-insulator transition at c_H?0.68. The T_c values exhibit a maximum T_c ? 5.3 K for 0.22 ? c_H ? 0.5. Annealing experiments result in a decrease of T_c and an increase of σ. An analysis of the annealing experiments leads us to the conclusion that the as-prepared Al-H (Al-H₂) films have an amorphous structure, which transforms during annealing in a granular system of Al grains embedded in insulating AlH₃. No H-specific effect has been detected.     

Superconducting phase transitions in ErcY1−cRh4B4

The superconducting transition temperature T_c1 and the reentering temperature T_c2 to the normal ferromagnetically ordered state in the system Er_cY_1?cRh₄B₄ were determined as a function of the concentration of Er. Comparing our results with the recent theory of Maekawa et al., the exchange interactions J′ among local spins and I between local spins and superconducting electrons were estimated as J′ ? 0.30 K and I²N(0) ? 0.046 K, where N(0) is the density of states. A sudden decrease of H_c2 at T_c2 was observed in a high concentration region suggesting the first order transition.     

Superconductivity in polymeric sulfur nitride (SN)x at high pressure

Investigations of the pressure dependence of the superconducting transition temperature T_c up to 17 kbar, and of the normal conductivity up to 50 kbar are reported. It is observed that below 8 kbar, the value of T_c increases linearly with the pressure. In addition, there is a significant drop of T_c at about 9 kbar which may be due to a phase transition.     

Checkerboard patterns and magnetic resonance peak in cuprate superconductors

We investigate a kind of spin-Peierls transition (SP) in high T_c superconductivity. It is found the antiferromagnetic exchange integral of SP corresponds to the magnetic resonance peak. The kind of spin-Peierls transition applied to cuprate superconductors is that without dimerization of lattice ions and with dimerization of localized hole h_Cu attached to the ion. Absence of the magnetic resonance peak in La-Sr-Cu-O results from the dimerized state of localized hole, h_Cu below T_c into tetramerized phase above T_c in SP transition without dimerization of copper-ion. The checkerboard patterns with four unit cell period originate from the SP of electronic part without ion-dimerization and from charge occupation probability of oxygen-atom around Cu.     

Amorphous magnetic alloys near critical concentration: Low field reversible dc magnetization

Measurements of the reversible magnetization at low dc fields have been used to investigate the magnetic response near the multicritical point (x_c) of two sets of amorphous alloys. In both cases, the ferromagnetic (FM) to spin glass (SG) transition line is found to be non-monotonic. The collapse of the magnetization as x→x⁺_c and the rapid increase in the susceptibility as x→x^-_c are suggestive of a percolation transition in the magnetic network at x=x_c. From a study of the non-linear susceptibility in the most concentrated spin glass alloy in each system, we obtain scaling exponents in agreement with previous reports providing further support for a thermodynamic phase transition at the spin glass temperature. For the first time we find a divergence in the linear susceptibility in these samples similar to that expected for the non-linear susceptibility and attribute it to their proximity to the FM phase. Dramatic changes in the transition temperatures and a perceptible shift in x_c are observed when normal boron is replaced by enriched boron (≈100%¹¹B) in one series of alloys.     

NMR investigations of dynamical processes in orientationally ordered and disordered NaCN,RbCN and CsCN

The nuclear spin lattice relaxation timeT ₁ of the²³Na,⁸⁵Rb,⁸⁷Rb,¹³³Cs,¹⁴N nuclei is measured in NaCN, RbCN and CsCN as a function of temperature below and above the ferroelastic phase transition temperatureT _c. BelowT _c the behaviour ofT ₁ of the alkali nuclei renders possible to determine the flip frequency of the CN molecules and its temperature dependence. AboveT _c from the¹⁴NT ₁ the correlation time τ_c of the rotational motions of the CN molecules and its temperature dependence is determined. An empirical rule is verified demonstrating that atT _c the correlation times take nearly the same values for all cyanides. For the high and low temperature phases one obtains atT _c about τ_c=5·10^?13s and τ_c=5·10^?11s, respectively. The results are discussed with respect to the mechanism of the phase transition.     

Equilibrium properties of fast-rotating headed nuclei

We report on calculations of the equilibrium deformation in excited heated rotating nuclei. At A ～ 150–200 and temperature t > t_c ≈ 1.2 MeV the shell effects turn out to be small to compete with the variations of the liquid drop component of the energy. The transition from the shape of a “cool” nucleus to that of a “hot” nucleus takes place at t_c and in deformed nuclei resembles a phase transition. The stiffness parameter with respect to shape variations at t_c is anomalously low.