Dual yielding in capillary suspensions

Rheological measurements were performed to examine the yielding behavior of capillary suspensions prepared by mixing cocoa powder as dispersed phase, vegetable oil as the continuous primary fluid, and water as the secondary fluid. Here, we investigated the yielding behavior of solid-fluid-fluid systems with varying particle volume fraction, ?, spanning the regime from a low volume fraction (? = 0.25) to a highly filled regime (? = 0.65) using dynamic oscillatory measurements. While for ? ≤ 0.4 with a fixed water volume fraction (? _w ) of 0.06 as the secondary fluid, capillary suspensions exhibited a single yield point due to rupturing of aqueous capillary bridges between the particles, while capillary suspensions with ? ≥ 0.45 showed a two-step yielding behavior. On plotting elastic stress (G^′ γ) as a function of applied strain (γ), two distinct peaks, indicating two yield stresses, were observed. Both the yield stresses and storage modulus at low strains were found to increase with ? following a power law dependence. With increasing ? _w (0 – 0.08) at a fixed ? = 0.65, the system shifted to a frustrated, jammed state with particles strongly held together shown by rapidly increasing first and second yield stresses. In particular, the first yield stress was found to increase with ? _w following a power law dependence, while the second yield stress was found to increase exponentially with ? _w . Transient steady shear tests were also performed. The single stress overshoot for ? ≤ 0.4 with ? _w = 0.06 reflected one-step yielding behavior. In contrast, for high ? (≥ 0.45) values with ? _w = 0.06, two stress overshoots were observed in agreement with the two-step yielding behavior shown in the dynamic oscillatory measurements. Experiments on the effect of resting time on microstructure recovery demonstrated that aggregates could reform after resting under quiescent conditions.     

Wall slip and extrudate instability of 4-arm star polybutadienes in capillary flow

This paper presents experimental research on wall slip and extrusion instability behavior of a series of monodisperse 4-arm star polybutadienes (PBD) of different molecular weights during fast capillary flow. The star PBDs reveal a slope of 3.0 in the capillary flow curve, showing a faster non-linear response than linear PBDs. The global stick-slip transition of star PBD is weaker than linear PBD of the same molecular weight, as indicated by a smaller extrapolation length b of star PBD. The sharkskin fracture takes place without a global stick-slip transition for a star PBD with molecular weight of 200 K, suggesting the sharkskin instability may not originate from an oscillating stick-slip transition at die exit. The flow splitting, i.e., the phenomenon that the extrudate breaks into two or more branches after the die exit, is observed in star PBDs with molecular weights higher than 200 K. The flow splitting, accompanied by a precession motion, is found to be an exit instability behavior. The flow splitting is related to the long bulk relaxation time of the star polymers and more likely to occur in a solid-like state, where the storage modulus G is higher than the loss modulus G. A rotating-breaking hypothesis is proposed to explain the flow splitting and sharkskin instability behavior of star PBDs based on a stretch induced rupture at die exit in a rotating pattern.     

Wall slip of mayonnaises in viscometers

The shear flow of mayonnaise is generally characterized by an apparent yield stress, shear thinning in steady flow, stress overshoots upon inception of flow and other time-dependent effects. These observations are usually understood to be the result of structural rearrangement within the material. Additionally and separately, the possibility that emulsions may exhibit apparent wall slip on a microscopic scale at a solid-liquid boundary has been reported by some researchers. Thus, observed rheological behavior is likely to be the result of the interplay between these two phenomena. In the present work, it is demonstrated that when measurements are sought to be made on mayonnaise using rotational viscometers visible wall slip occurs, rendering such instruments ineffective for the purpose of making viscosity measurements even at shear rates as low as 10^–3s^–1. The factors that influence the onset and extent of slip are investigated with the help of parallel plate viscometers, and it is concluded that the observed “yielding” of mayonnaise is actually an artifact of the onset of macroscopic slip. Slip effects are also found in capillary flow but are ameliorated with increasing shear rate. To circumvent these problems, it is proposed that extensional viscometry be employed for determining the flow behavior of mayonnaises. Received: 18 August 1997 Accepted: 1 April 1998     

Thixotropy, yielding and ultrasonic Doppler velocimetry in pulp fibre suspensions

This paper reports thixotropy in concentrated pulp fibre suspensions and studies their transient flow behaviour using conventional rheometry coupled with a velocimetry technique. Specifically, an ultrasonic Doppler velocimeter is used in conjunction with a rate-controlled rheometer to deduce the local velocity profiles of pulp fibre suspensions. Pulp suspensions are found to exhibit a plateau in their flow curves where a slight increase in the shear stress generates a jump in the corresponding shear rate, implying the occurrence of shear banding. The velocity profiles were found to be discontinuous in the vicinity of the yielding radius where the Herschel–Bulkley model failed to predict the flow. Shear history and the time of rest prior to the measurement were found to play a significant role on the rheology and the local velocity profiles of pulp suspensions.     

Flow instabilities in capillary flow of concentrated suspensions

The development of flow instabilities during the capillary flow of two concentrated suspensions filled with 76.5 and 65.6% by volume solids was investigated. The flow instabilities manifested themselves by the development of concentration gradients as a result of the filtering of the binder, superimposed on the bulk motion of the suspension. The effects of apparent shear rate, capillary diameter and the surface roughness of the particles were investigated. The use of the comparison of the filtration rate with the bulk velocity of the suspension during flow is shown to be promising for the prediction of the apparent shear rate at which filtration-based flow instabilities occur.     

Breakup of a capillary bridge of suspensions

The breakup of liquid bridges under the action of capillary forces is used for studying the rheology of suspensions under stretching. The experiments were performed with suspensions of finegrained (3–30 μm) sand in glycerin for sand volume fractions up to 0.465. The bridge thinning process was registered using an electro-optical measuring device and videofilming. The results were analyzed on the basis of a theory developed earlier for the thinning of a liquid bridge under the action of capillary forces. It is found that, for fairly slow stretching realized in the initial stage of the thinning, the rheological behavior of the suspensions considered agrees with the model of a Newtonian viscous fluid. Along with this, the measured effective viscosity of the suspension turned out to be approximately two-fold greater than the suspension viscosity under shear. The origin of this discrepancy is analyzed. With increase in the stretching rate, in the final stage of the thinning, the weakening of the suspension occurs, which is manifested in the formation of a local rapidly thinning neck in the bridge, similar to that observed in the breakup of plastic materials.     

Wall slip phenomena in concentrated ionic liquid-based magnetorheological fluids

Ionic liquids (ILs) have been recently proposed as carrier for magnetorheological (MR) fluids. Their special properties, such as very low vapor pressure and high thermal stability, make ILs highly suitable dispersion media to increase the broad range of technological applications that magnetorheological fluids already have. It has been just reported that using ILs as carriers in MR fluids an improvement in the colloidal stability and suspension redispersibility is obtained. In this work, the magnetorheological behavior of highly concentrated suspensions in ILs is studied. Two kinds of suspensions were analyzed: using an ionic liquid of low conductivity and a mineral oil as carriers. In both cases, silica-coated iron microparticles were used as solid phase, being the solid volume concentration of 50% vol. A complete magnetorheological analysis focused on the wall slip phenomenon was performed. Steady-state and oscillatory experiments were carried out. In order to study wall slip effects, all experiments were performed with a plate–plate system, using both smooth and rough measuring surfaces. A significant effect of wall slip was observed when the experiments were performed using smooth surfaces. The novelty of this paper is mainly based on (1) the use of an ionic liquid as carrier to prepare magnetic suspensions, and?(2) the analysis of wall slip phenomena in MR fluids with a particle content close to the maximum packing fraction.     

Apparent wall slip velocity measurements in free surface flow of concentrated suspensions

In this work we have experimentally measured the apparent wall slip velocity in open channel flow of neutrally buoyant suspension of non-colloidal particles. The free surface velocity profile was measured using the tool of particle imaging velocimetry (PIV) for two different channels made of plane and rough walls. The rough walled channel prevents wall slip, whereas the plane wall showed significant wall slip due to formation of slip layer. By comparing the velocity profiles from these two cases we were able to determine the apparent wall slip velocity. This method allows characterization of wall slip in suspension of large sized particles which cannot be performed in conventional rheometers. Experiments were carried out for concentrated suspensions of various particle volume concentrations and for two different sizes of particles. It was observed that wall slip velocity increases with particle size and concentration but decreases with increase in the viscosity of suspending fluid. The apparent wall slip velocity coefficients are in qualitative agreement with the earlier measurements. The effect of wall slip on free surface corrugation was also studied by analyzing the power spectral density (PSD) of the refracted light from the free surface. Our results indicate that free surface corrugation is a bulk flow response and it does not arise from boundary problem such as development of slip layer.     

Rheology of shear thickening suspensions and the effects of wall slip in torsional flow

The rheological characterisation of concentrated shear thickening materials suspensions is challenging, as complicated and occasionally discontinuous rheograms are produced. Wall slip is often apparent and when combined with a shear thickening fluid the usual means of calculating rim shear stress in torsional flow is inaccurate due to a more complex flow field. As the flow is no longer “controlled”, a rheological model must be assumed and the wall boundary conditions are redefined to allow for slip. A technique is described where, by examining the angular velocity response in very low torque experiments, it is possible to indirectly measure the wall slip velocity. The suspension is then tested at higher applied torques and different rheometer gaps. The results are integrated numerically to produce shear stress and shear rate values. This enables the measurement of true suspension bulk flow properties and wall slip velocity, with simple rheological models describing the observed complex rheograms.     

Wall slip and melt fracture of poly(lactides)

The wall slip and melt fracture behaviour of several commercial polylactides (PLAs) as well as their rheological properties under shear and extensional have been investigated. The PLAs have had weight-average molecular weights in the range of 10⁴–10⁵ g/mol and studied in the temperature range of 160–200°C. The solution properties and linear viscoelastic behaviour of melts indicate linear microstructure behaviour. PLAs with molecular weights greater than a certain value were found to slip, with the slip velocity to increase with decrease of molecular weight. The capillary data were found to agree well with linear viscoelastic envelope once correction for slip effects was applied. The onset of melt fracture for the high molecular weight PLAs was found to occur at about 0.2 to 0.3 MPa, depending on the geometrical characteristics of the dies and independent of temperature. Addition of 0.5 wt.% of a polycaprolactone (PCL) into the PLA that exhibits melt fracture was found to be effective in eliminating and delaying the onset of melt fracture to higher shear rates. This is due to significant interfacial slip that occurs in the presence of PCL.     

滑滚表面间的流体膜壁面滑移和流体动力学

经典雷诺润滑理论建立在无壁面滑移的假设基础之上。近年来许多试验报告了发生在流体膜流动的壁面滑移证据。本文研究了两固体表面间的流体膜流动特性和流体动力学,发现壁面滑移显著影响膜的流体动力学问题,流体动压力不仅受黏度和几何间隙的影响,而且还由壁面滑移和表面运动强力控制,通过控制表面的吸附性质,甚至可以得到零摩擦表面。另一方面,如果两个表面具有相同的滑移特性,存在一个临界滑动速度使得流体动压效应完全消失;但是在纯滚动条件下,即使界面极限剪应力很小,仍然有相当可观的流体动压效应。     

Rheo-PIV of a yield-stress fluid in a capillary with slip at the wall

An analysis of the yielding and flow behavior of a model yield-stress fluid, 0.2 wt% Carbopol gel, in a capillary with slip at the wall has been carried out in the present work. For this, a study of the flow kinematics in a capillary rheometer was performed with a two-dimensional particle image velocimetry (PIV) system. Besides, a stress-controlled rotational rheometer with a vane rotor was used as an independent way to measure the yield stress. The results in this work show that in the limit of resolution of the PIV technique, the flow behavior agrees with the existence of a yield stress, but there is a smooth solid?Cliquid transition in the capillary flow curve, which complicates the determination of the yield stress from rheometrical data. This complication, however, is overcome by using the solely velocity profiles and the measured wall shear stresses, from which the yield-stress value is reliably determined. The main details of the kinematics in the presence of slip were all captured during the experiments, namely, a purely plug flow before yielding, the solid?Cliquid transition, as well as the behavior under flow, respectively. Finally, it was found that the slip velocity increases in a power-law way with the shear stress.     

In situ flow visualization of capillary flow of concentrated alumina suspensions

A new approach was taken to understand the flow behavior of concentrated particle suspensions in pressure-driven capillary flow. The flow of concentrated alumina suspensions in a slit channel was visualized and quantitatively analyzed with modified capillary rheometer. The suspensions showed complex flow behaviors; unique solid–liquid transition and shear banding. At low flow rates, 55 vol% alumina suspension showed a unique transient flow behavior; there was no flow at first and continuous change of flow profile was observed with time. At low shear rates in particular, the suspensions exhibited shear-banded flow profile which could be divided into three regions: the region with low flow rate near the wall, the region with rapid increase of flow velocity to maximum, and the region of velocity plateau. Based on both flow visualization and measurement of shear stress, it was found that the shear-banded flow profile in pressure-driven slit channel flow was strongly correlated with shear stress. The banding in pressure-driven flow was different from that in Couette flow. The banding of concentrated alumina suspensions was unique in that sluggish velocity profile was pronounced and two inflection points in velocity profile was exhibited. In this study, shear banding of concentrated alumina suspensions in slit channel flow was visualized and quantitatively analyzed. We expect that this approach can be an effective method to understand the flow behavior of particulate suspensions in the pressure-driven flow which is typical in industrial processing.     

The rheological characterization of HPG gels: Measurement of slip velocities in capillary tubes

Measurements are reported for the properties of two hydroxypropyl guar (HPG) gels. The flow curves are composed of three distinct regions: a yield value at low stress levels, a quasi-linear region at intermediate stress or deformation rate levels, and a broad region at high deformation rate levels in which the flow is entirely dominated by slip phenomena.     

Influence of contact-perimeter slip and heat transfer processes on oscillating hydrodynamic flows of immiscible liquids in capillary tubes

The hydrodynamic flows which arise in the presence of mechanical vibrations of a capillary tube filled with immiscible liquids are investigated. At the hermetically sealed ends of the tube there are air bubbles. It is assumed that the interfacial contact perimeters of the immiscible liquids can slip relative to the walls of the tube. The results of numerical calculations are given for a mercury electrocapillary transducer [1–4], which is a capillary tube filled with water and mercury. The calculated and experimental amplitude—frequency characteristics (the dependences of the amplitude of the electric potential difference on the vibration frequency) are compared.Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 3, pp. 36–45, May–June, 1993.     

Estimation of the parameters of Herschel-Bulkley fluid under wall slip using a combination of capillary and squeeze flow viscometers

The determination of the parameters of viscoplastic fluids subject to wall slip is a special challenge and accurate results are generally obtained only when a number of viscometers are utilized concomitantly. Here the characterization of the parameters of the Herschel-Bulkley fluid and its non-linear wall slip behavior is formulated as an inverse problem which utilizes the data emanating from capillary and squeeze flow rheometers. A finite element method of the squeeze flow problem is employed in conjunction with the analytical solution of the capillary data collected following Mooneys procedure, which uses dies with differing surface to volume ratios. The uniqueness of the solution is recognized as a major problem which limits the accuracy of the solution, suggesting that the search methodology should be carefully selected.