Wear resistance of filled epoxypolyamide composites in aggressive media

The authors investigate the influence of certain aggressive media (toxic chemicals) on the wear resistance of filled epoxypolyamide composites. The presence of toxic chemicals in the zone of friction causes a sharp fall in the wear of the polymers. The maximum wear resistance is displayed by epoxypolyamide composites filled with iron powder, cement, or graphite.     

Experimental study of the contribution of interfacial friction to the deformation resistance of particle-reinforced polymers

A study has been made of the dissipative properties of heavily filled elastomers as influenced by friction of the elastic matrix on the surface of the solid filler particles. In order to model the frictional surface, specimens were predamaged by cyclic deformation, with strain amplitudes sufficient to cause separation of the matrix from the filler. The predeformation operation was performed by means of a mechanical system having individual particle-matrix bonds, so that it was possible to evaluate the contribution of interfacial friction to the resistance of the polymer. When external pressure was applied to the specimens, the width of the hysteresis loop increased with increasing pressure, obviously reflecting an increase of the surface friction in the matrix. It was established that for a given volumetric fill, the dissipation of mechanical energy increased with decreasing particle size (with increasing frictional surface area). The significant influence of interfacial friction on the level and rate of strain relaxation was demonstrated experimentally.Paper presented at the 9th International Conference on the Mechanics of Composite Materials (Riga, October 1995).Translated from Mekhanika Kompositnykh Materialov, Vol. 31, No. 5, pp. 579–583, September–October, 1995.     

Effect of filler on relaxation-time spectra of filled polymers

The frequency and temperature dependence of the complex shear modulus G* and tan δ of epoxide compositions with various fillers have been studied. Relaxation-time spectra of filled polymers with various fillers have been plotted by the Ninomi-Ferry method. The principles governing changes in the shape of the spectrum curves with increase in filler concentration have been observed, enabling conclusions to be drawn on the effect of the filler on the change in properties of a polymer matrix and the deformation conditions of the polymer layers between the filler particles.     

Dynamic model for a magnetorheological damper

A lumped mass thermo-mechanical model for the dynamics of a damper filled with a magnetorheological fluid is described, analyzed, and numerically simulated. The model includes friction and temperature effects, and consists of a differential inclusion for the piston displacements coupled with the energy balance equation for the temperature. The fluid viscosity is assumed to be a function the temperature and electrical current, which in practice may be used as the control variable. Numerical simulations of the system behavior are presented. In particular, the simulations of an initial impact show how the subsequent oscillations can be effectively damped.     

Numerical simulation of the rheological properties of granular composites by using a structural approach

Composites with an elastomeric matrix containing rigid particles of diameter 10–1000 μm are studied. One of possible mechanisms of the rheological behavior of such filled systems, related to the origination and growth of vacuoles near the rigid inclusions in a viscous matrix, is considered. For simulating the mechanism of formation of rheological properties of the filled elastomers, we use a structural cell in the form of an elastomeric cylinder, whose height and diameter are equal in magnitude, with a rigid spherical inclusion at its center. Deformation of the cells is examined with the observance of boundary conditions providing the preservation of their close packing. The inclusion is assumed to be rigid, and the matrix properties are described by equations of the linear hereditary viscoelasticity theory. The formation of vacuoles is described by using the approach suggesting that an initial debonding begins to propagate when the energy accumulated in the extended matrix reaches a value sufficient to create a new interface. The heterogeneity of the composite is simulated by taking into account the variability of the local filler concentration. Creep curves obtained for composite cells with different content of the solid phase are presented. Comparisons between the numerical and experimental results show a satisfactory agreement. Translated from Mekhanika Kompozitnykh Materialov, Vol. 44, No. 6, pp. 895–906, November–December, 2008.     

Behavior of filled polyphenylquinoxalines during friction

Conclusion 1. It has been established that, as the chain of polyphenylquinoxalines becomes more rigid by addition of aromatic nuclei of the naphthylimide group to the macromolecule part, the wear resistance of graphite-filled polymer systems increases.2. It has been demonstrated that during friction with filled polyphenylquinoxalines in the polymer binder there occur complex destructive-structurizing processes whose penetration depth is determined by the chemical constitution of the selected polymers.3. It has been established that in the rigid-chain polyphenylquinoxaline during friction at high temperatures, just below the glass-transition point but within the range of faster relaxation processes, the destructive-structurizing processes abate and then at temperatures above 250°C active gelling occurs.Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 6, pp. 1049–1054, November–December, 1978.     

Polymer friction at low velocities and high loads

The results of an investigation of the dependence of the coefficient of polymer friction on the normal load and the chemical purity and roughness of the contact surfaces are described. It is shown that in dry friction for a series of polymers the surface deformation is predominantly forced-elastic. The nature of the dry friction mechanism as it relates to polymers is discussed.Mekhanika Polimerov, Vol. 4, No. 3, pp. 494–498, 1968     

Modeling of the Interphase of Polymer-Matrix Composites: Determination of Its Structure and Mechanical Properties

In this work, a model is developed which allows one to determine the thickness and properties of the interphase layer in unidirectional and filled composites, assuming that the materials of the interphase, matrix, and fillers may have a fractal structure, and to predict the properties of composites with interphases. Using a set of computer programs elaborated, the corresponding calculations are carried out for glass-epoxy composites, epoxy carboplastics, and graphite-filled epoxy polymers.     

The kinetics of some structural changes in the surface layers of polymers during friction

It is established that in sliding friction there is a change in the dimensions of the elementary crystalline regions and the degree of crystallinity of the surface layers of polymers. The laws governing these structural changes in the surface layers of PTFE in relation to the conditions and time of polymer-metal contact are given. The results supplement and refine existing concepts on the mechanism of friction involving polymers.Mekhanika Polimerov, Vol. 1, No. 6, pp. 114–119, 1965     

Friction of polymeric materials

The dry friction between a polymeric and a metallic surface is considered on the assumption that the friction power is such that heating of the surfaces can be neglected. The effect of the dimensionless specific load (ratio of nominal stress to elastic hardness of the polymer) on the friction process of elastomers and rigid polymers is analyzed and expressions are given for calculating the coefficients of friction of these materials at large values of the nominal stress.

     

Effect of a filler on the strength properties of thermosets

The effect of a filler on the strength properties of polymers in tension is investigated. The thermostructural stresses that develop in the composite during cure are taken into account. Relations are given for the strength of the filled polymer as a function of the percentage filler content. In the process of analyzing the thermostructural stresses an analytic expression is obtained for the linear expansion coefficient of the composite with allowance for the structural distribution of the components. Calculated values of the strength and thermostructural stresses are presented for composites with different filler contents. The theoretical determination of the strength of filled polymers is compared with the results of experimental investigations of composites based on epoxy resin filled with quartz dust.Leningrad Mechanical Institute. Translated from Mekhanika Polimerov, No. 1, pp. 97–101, January–February, 1973.     

Effect of the surface activity of polymers during degradation on the friction and wear of plastic-metal and metal-metal pairs

The results of studies on the reasons why degradation products of polymers migrate into the metal and the metal is transferred into the plastic material during friction are discussed. Saturation of the steel surfaces with the degradation products of the polymers has been shown in the case of electropositive plastic counterbody, and decarbonization of steel surfaces in the case of the electronegative polymeric counterbody; a hypothesis has been put forward on the triboelectric and mechanochemical phenomena for the friction and wear processes of the plastic-metal and metal-metal pairs.Rostov-on-Don Institute of Railway Transport Engineers. Translated from Mekhanika Polimerov, Vol. 9, No. 3, pp. 520–525, May–June, 1973.     

Some problems connected with 2D modeling of geosynthetic tubes

Some problems connected with 2D modeling of geosynthetic tubes on rigid foundations are studied. Basic equations are derived and analyzed. The analysis of the equations is based on the implicit function theorem. Geosynthetic tubes are made of a special fabric and then filled with water or slurry. After being filled tubes take certain shapes and tensions are induced in the geosynthetic. The modeling is based on the following hypotheses: the problem is two dimensional; the geosynthetic is flexible, inextensible and has negligible weight; the foundation is rigid; and there is no friction between the foundation and the geosynthetic.     

列满矩阵元素扰动秩的稳定性(英文)

秩是矩阵的重要数值特征之一 .本文运用矩阵的范数 ,分析、研究列满矩阵 ,提出并证明了列满矩阵元素扰动秩的稳定性定理及两个推论 .     

The Effects of Poisson Contraction on Matrix Cracking in Brittle-Matrix Composites

The effects of Poisson contraction on matrix cracking in unidirectional fiber-reinforced brittle-matrix composites are studied in this paper. The fibers, initially held in the matrix by a compressive pressure due to the thermal expansion mismatch, are subjected to frictional slipping over the matrix as soon as a fiber-bridged crack is formed. The friction between the fibers and the matrix is assumed to follow the Coulomb friction law. A shear-lag model, which includes the Poisson contraction and the friction due to the relative fiber/matrix slipping, is adopted to calculate the stress and strain fields in the fibers and matrix. Using the energy balance approach, a relation for the critical matrix cracking stress for propagating of a semi-infinite fiber-bridged crack is derived. The results obtained show that the Poisson contraction has a strong effect on the predicted matrix cracking stress in brittle-matrix composites, especially in composites with a stiff matrix.     

The scattering of an harmonic elastic wave by a volume inclusion with a thin interlayer

The boundary element method is used to investigate the propagation of harmonic elastic waves in an infinite matrix with a volume inclusion with a thin interlayer between the inclusion and the matrix. A boundary-integral formulation of the problem is based on a consideration of a two-phase medium, consisting of the matrix and the inclusion, on the contact surface of which conditions of proportional dependence between the forces and jumps in the displacements, which model the interlayer, are satisfied. These conditions are taken into account implicitly in the boundary integral equations obtained, which are subsequently regularized and discretized on the grid of boundary elements introduced. The numerical results obtained demonstrate the effect of the interlayer on the dynamic contact stresses for a spherical inclusion in the field of a plane longitudinal wave.     

Electron-microscope investigation of the type of fracture of filled polymers

An electron microscope was used to study the type of fracture of filled compositions based on SKN-40, SKMS-30, and SKS-85 polymers with TeG-10 thermal-decomposition black, DG-100 channel black, and chalk fillers. It is shown that in all the cases investigated the filled systems fracture along the polymer-filler interphase boundary.Mekhanika Polimerov, Vol. 3, No. 2, pp. 291–295, 1967     

Dynamic proper colorings of a graph

We solve an axisymmetric problem of the interaction of harmonic waves with a thin elastic circular inclusion located in an elastic isotropic body (matrix). On both sides of the inclusion, between it and the body (matrix), conditions of smooth contact are realized. The method of solution is based on the representation of displacements in the matrix in terms of discontinuous solutions of Lamé equations for harmonic vibrations. This enables us to reduce the problem to Fredholm integral equations of the second kind for functions related to jumps of normal stress and radial displacement on the inclusion.     

Effect of Coulomb friction on the fiber/matrix debonding and matrix cracking in unidirectional fiber-reinforced brittle-matrix composites

A model for a macroscopic crack transverse to bridging fibers is developed based upon the Coulomb friction law, instead of the hypothesis of a constant frictional shear stress usually assumed in fiber/matrix debonding and matrix cracking analyses. The Lamé formulation, together with the Coulomb friction law, is adopted to determine the elastic states of fiber/matrix stress transfer through a frictionally constrained interface in the debonded region, and a modified shear lag model is used to evaluate the elastic responses in the bonded region. By treating the debonding process as a particular problem of crack propagation along the interface, the fracture mechanics approach is adopted to formulate a debonding criterion allowing one to determine the debonding length. By using the energy balance approach, the critical stress for propagating a semi-infinite fiber-bridged crack in a unidirectional fiber-reinforced composite is formulated in terms of friction coefficient and debonding toughness. The critical stress for matrix cracking and the corresponding stress distributions calculated by the present Coulomb friction model is compared with those predicted by the models of constant frictional shear stress. The effect of Poisson contraction caused by the stress re distribution between the fiber and matrix on the matrix cracking mechanics is shown and discussed in the present analysis. Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 43, No. 2, pp. 171–190, March–April, 2007.     

A fractal model of reinforcement of elastoplastic nanocomposites

Within the framework of fractal analysis and percolation theory, an alternative model of reinforcement of filled polymers is offered. Practically, this model can be used only to describe the reinforcement of nanocomposites, because, according to the treatment considered, a pronounced reinforcement can be reached only at ratios of filler particle diameter to the statistical segment length of about 10 and less. A theoretical calculation showed a good qualitative and quantitative agreement with experiments. The type of reinforcement mechanism of composites is determined by the type of the space (fractal or Euclidean) in which the structure of the polymeric matrix is formed. __________ Translated from Mekhanika Kompozitnykh Materialov, Vol. 42, No. 6, pp. 797–802, November–Decem ber, 2006.