Formation of a narrow baryon resonance with positive strangeness in K + collisions with Xe nuclei

The data on the charge-exchange reaction K ⁺Xe → K ⁰ pXe′, obtained with the bubble chamber DIANA, are reanalyzed using increased statistics and updated selections. Our previous evidence for formation of a narrow pK ⁰ resonance with mass near 1538 MeV is confirmed. The statistical significance of the signal reaches some 8 (6) standard deviations when estimated as $ {S \mathord{\left/ {\vphantom {S {\sqrt B \left( {{S \mathord{\left/ {\vphantom {S {\sqrt {B + S} }}} \right. \kern-0em} {\sqrt {B + S} }}} \right)}}} \right. \kern-0em} {\sqrt B \left( {{S \mathord{\left/ {\vphantom {S {\sqrt {B + S} }}} \right. \kern-0em} {\sqrt {B + S} }}} \right)}} $ . The mass and intrinsic width of the Θ⁺ baryon are measured as m = 1538 ± 2 MeV and Γ = 0.39 ± 0.10 MeV.     

O(G μ 2 m t 4 ) electroweak radiative corrections to theZb \bar b vertex

The leading heavy-top two-loop corrections to theZb \(\bar b\) vertex are determined from a direct evaluation of the corresponding Feynman diagrams in the largem _t limit. The leading one-loop top-mass effect is enhanced by \([{{1 + G_\mu m_t^2 ({{9 - \pi ^2 } \mathord{\left/ {\vphantom {{9 - \pi ^2 } 3}} \right. \kern-0em} 3})} \mathord{\left/ {\vphantom {{1 + G_\mu m_t^2 ({{9 - \pi ^2 } \mathord{\left/ {\vphantom {{9 - \pi ^2 } 3}} \right. \kern-0em} 3})} {(8\pi ^2 \sqrt 2 )}}} \right. \kern-0em} {(8\pi ^2 \sqrt 2 )}}]\) . Our calculation confirms a recent result of Barbieri et al..     

Laser-Rf double-resonance studies of the hyperfine structure of metastable atomic states of55Mn

The hyperfine structure (hfs) of the metastable atomic states 3d⁶4s⁶ D _{1/2, 3/2, 5/2, 7/2, 9/2} of⁵⁵Mn was measured using theABMR- LIRF method (atomicbeammagneticresonance, detected bylaserinducedresonancefluorescence). The hfs constantsA andB, corrected for second order hfs perturbations, could be derived from these measurements. The theoretical interpretation of these correctedA- andB-factors was performed in the intermediate coupling scheme taking into account the configurations 3d ⁵4s ², 3d ⁶4s and 3d ⁷. Examining the influence of the composition of the eigenvectors on the hfs parameters \(\left\langle {r^{ - 3} } \right\rangle ^{k_s k_l } \) it was found, that for the configuration 3d ⁶4s the two-body magnetic interaction should be considered in the calculation of the eigenvectors. Investigating second order electrostatic configuration interactions and relativistic effects and using calculated relativistic correction factors we obtained for the nuclear quadrupole moment of the nucleus⁵⁵Mn a value ofQ=0.33(1) barn, which is not perturbed by a shielding or antishielding Sternheimer factor. The following hfs constants have been obtained: $$\begin{gathered} A\left( {{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 882.056\left( {12} \right)MHz \hfill \\ A\left( {{3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 469.391\left( 7 \right)MHzB\left( {{3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = - 65.091\left( {50} \right)MHz \hfill \\ A\left( {{5 \mathord{\left/ {\vphantom {5 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 436.715\left( 3 \right)MHzB\left( {{5 \mathord{\left/ {\vphantom {5 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = - 46.769\left( {30} \right)MHz \hfill \\ A\left( {{7 \mathord{\left/ {\vphantom {7 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 458.930\left( 3 \right)MHzB\left( {{7 \mathord{\left/ {\vphantom {7 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 21.701\left( {40} \right)MHz \hfill \\ A\left( {{9 \mathord{\left/ {\vphantom {9 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 510.308\left( 8 \right)MHzB\left( {{9 \mathord{\left/ {\vphantom {9 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 132.200\left( {120} \right)MHz \hfill \\ \end{gathered} $$      

Der Einfluß der Wärmebewegung auf die Breite einer Mössbauerlinie über den Dopplereffekt zweiter Ordnung

AtT=0 a perfect Mössbauer line has natural line widthΓ=?/τ _n . However, with rising temperature the width increases. The reason of the line broadening is the second order Doppler effect which causes a stochastic frequency modulation of theγ-radiation, reflecting the thermal motion of the Mössbauer atom. Following Josephson in treating the second order Doppler shift as a mass changeΔM=E _n/c² of theγ-emitting atom caused by the loss of nuclear excitation energy E _n , and using the well known relaxation formalism for calculating theγ-frequency spectrum, the line broadeningΔ Γ is evaluated within the framework of harmonic lattice theory. For a parabolic lattice frequency spectrum with Debye-temperature Θ one obtains $$\Delta {\Gamma \mathord{\left/ {\vphantom {\Gamma \Gamma }} \right. \kern-\nulldelimiterspace} \Gamma } = \left( {{{\tau _n } \mathord{\left/ {\vphantom {{\tau _n } {\tau _c }}} \right. \kern-\nulldelimiterspace} {\tau _c }}} \right) \cdot \left( {{{E_n } \mathord{\left/ {\vphantom {{E_n } {Mc^2 }}} \right. \kern-\nulldelimiterspace} {Mc^2 }}} \right) \cdot F\left( {{T \mathord{\left/ {\vphantom {T \Theta }} \right. \kern-\nulldelimiterspace} \Theta }} \right),where\tau _c = {{\rlap{--} h} \mathord{\left/ {\vphantom {{\rlap{--} h} k}} \right. \kern-\nulldelimiterspace} k}\Theta $$ is the correlation time of the lattice vibrations. The functionF(T/Θ) may be expanded in powers ofT/Θ, yielding $$F\left( {{T \mathord{\left/ {\vphantom {T \Theta }} \right. \kern-\nulldelimiterspace} \Theta }} \right) = 9720\pi \left( {{T \mathord{\left/ {\vphantom {T \Theta }} \right. \kern-\nulldelimiterspace} \Theta }} \right)^7 forT<< \Theta $$ and $$F\left( {{T \mathord{\left/ {\vphantom {T \Theta }} \right. \kern-\nulldelimiterspace} \Theta }} \right) = 2.7\pi \left( {{T \mathord{\left/ {\vphantom {T \Theta }} \right. \kern-\nulldelimiterspace} \Theta }} \right)^2 forT > > \Theta $$ , respectively. Although unavoidable, the line broadening is obviously too small to be observable by means of the present experimental technique.     

Polarization-optical and X-ray diffraction investigations on the symmetry of distorted phases of ammonium cryolite (NH4)3 ScF6

Single-crystal plates of different sections of the (NH₄)₃ScF₆ crystal have been investigated by polarization-optical microscopy and X-ray diffraction over a wide temperature range, including the temperatures of two known phase transitions and the third transition found recently. It is established that the symmetry of 5 phases changes in the following sequence: $\begin{gathered} O_h^5 - Fm3m(Z = 4) \leftrightarrow C_{2h}^5 - {{P12_1 } \mathord{\left/ {\vphantom {{P12_1 } {n1}}} \right. \kern-0em} {n1}}(Z = 2) \leftrightarrow C_{2h}^3 - {{I12} \mathord{\left/ {\vphantom {{I12} {m1}}} \right. \kern-0em} {m1}} \\ (Z = 16) \leftrightarrow C_i^1 - I\bar 1(Z = 16) \\ \end{gathered} $ .     

Isomeric states in134Ba

Several new levels including two isomeric states have been established in¹³⁴Ba. Spin and parity assignments of 10⁺ and 5^? are proposed for the isomers. The former may have a \(\left( {vh_{1 1/2} } \right)_{10^ + } \) configuration while the latter may be either \((vs_{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-0em} 2}} vh_{{{11} \mathord{\left/ {\vphantom {{11} 2}} \right. \kern-0em} 2}} )_{5 - } \) or \(\left( {vd_{3/2} vh_{1 1/2} } \right)_{5^ - } \) .     

Newest results from the Mainz neutrino-mass experiment

The Mainz neutrino-mass experiment investigates the endpoint region of the tritium β-decay spectrum with a MAC-E spectrometer to determine the mass of the electron antineutrino. By the recent upgrade, the former problem of dewetting T₂ films has been solved, and the signal-to-background ratio was improved by a factor of 10. The latest measurement leads to $m_\nu ^2 = - 3.7 \pm 5.3(stat.) \pm 2.1(syst.){{eV^2 } \mathord{\left/ {\vphantom {{eV^2 } {c^4 }}} \right. \kern-0em} {c^4 }}$ , from which an upper limit of $m_\nu < 2.8{{eV^2 } \mathord{\left/ {\vphantom {{eV^2 } {c^2 }}} \right. \kern-0em} {c^2 }}(95\% C.L.)$ is derived. Some indication for the anomaly, reported by the Troitsk group, was found, but its postulated half-year period is contradicted by our data. To push the sensitivity on the neutrino mass below 1 eV/c ², a new larger MAC-E spectrometer is proposed. Besides its integrating mode, it could run in a new nonintegration operation MAC-E-TOF mode.     

On (n,p) cross sections for 14 MeV neutrons

Using older compilations and recent data the (n, p) cross sections for neutron energies between 14 and 15 MeV have been collected and revised critically. The experimental data can be represented phenomenologically by the formula $$\log _{10} ({{\sigma _{np} } \mathord{\left/ {\vphantom {{\sigma _{np} } {mb}}} \right. \kern-\nulldelimiterspace} {mb}}) = 0.2 + 0.4A^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} - 4.6{{(N - Z)} \mathord{\left/ {\vphantom {{(N - Z)} {A^{{2 \mathord{\left/ {\vphantom {2 3}} \right. \kern-\nulldelimiterspace} 3}} }}} \right. \kern-\nulldelimiterspace} {A^{{2 \mathord{\left/ {\vphantom {2 3}} \right. \kern-\nulldelimiterspace} 3}} }}$$ . The compound part of the (n, p) reactions is described by a statistical model; the direct reactions are taken into account semiempirically.     

Reanalysis of the mass difference ofB_d^0 - \bar B_d^0 within the Minimal Supersymmetric Standard Modelwithin the Minimal Supersymmetric Standard Model

We present a detailed and complete calculation of the loop corrections to the mass difference $\Delta {{m_{B_d^0 } } \mathord{\left/ {\vphantom {{m_{B_d^0 } } {m_{B_d^0 } }}} \right. \kern-0em} {m_{B_d^0 } }}$ . We include charginos and scalar up quarks as well as gluinos and scalar down quarks on the relevant loop diagrams. We include the mixings of the charginos and of the scalar partners of the left and right handed quarks. We find that the gluino contribution to this quantity is important with respect to the chargino contribution only in a small part of phase space: mainly when the gluino mass is small (～100 GeV) and the symmetry-breaking parameterm _S is below 300 GeV. This contribution is also important for very large values of tanβ (～50) irrespective of the other parameters. Otherwise, the chargino contribution dominates vastly and can be roughly as large as that of the Standard Model. We also present the contribution of the charged Higgs to the mass difference $\Delta {{m_{B_d^0 } } \mathord{\left/ {\vphantom {{m_{B_d^0 } } {m_{B_d^0 } }}} \right. \kern-0em} {m_{B_d^0 } }}$ in the casem _b tanβ?m _t cotβ. This last contribution can be larger than the Standard Model contribution for small values of the Higgs mass and small values of tanβ.     

Neutrino production of dimuons

Neutrino interactions with two muons in the final state have been studied using the Fermilab narrow band beam. A sample of 18v _μ like sign dimuon events withP _μ>9 GeV/c yields 6.6±4.8 events after backgroud subtraction and a prompt rate of (1.0±0.7)×10^?4 per single muon event. The kinematics of these events are compared with those of the non-prompt sources. A total of 437v _μ and 31 \(\bar v_\mu \) opposite sign dimuon events withP _μ>4.3 GeV/c are used to measure the strange quark content of the nucleon: \(\kappa = {{2s} \mathord{\left/ {\vphantom {{2s} {\left( {\bar u + \bar d} \right) = 0.52_{ - 0.15}^{ + 0.17} \left( {or\eta _s \frac{{2s}}{{u + d}} = 0.075 \pm 0.019} \right) for 100< E_v< 230 GeV\left( {\left\langle {Q^2 } \right\rangle = {{23 GeV^2 } \mathord{\left/ {\vphantom {{23 GeV^2 } {c^2 }}} \right. \kern-0em} {c^2 }}} \right)}}} \right. \kern-0em} {\left( {\bar u + \bar d} \right) = 0.52_{ - 0.15}^{ + 0.17} \left( {or\eta _s \frac{{2s}}{{u + d}} = 0.075 \pm 0.019} \right) for 100< E_v< 230 GeV\left( {\left\langle {Q^2 } \right\rangle = {{23 GeV^2 } \mathord{\left/ {\vphantom {{23 GeV^2 } {c^2 }}} \right. \kern-0em} {c^2 }}} \right)}}\) using a charm semileptonic branching ratio of (10.9±1.4)% extracted from measurements ine ⁺ e ^? collisions and neutrino emulsion data.     

Transition from non-fermi liquid behavior to Landau–Fermi liquid behavior induced by magnetic fields

We show that a strongly correlated Fermi system with a fermion condensate which exhibits strong deviations from Landau–Fermi liquid behavior is driven into the Landau–Fermi liquid by applying a small magnetic field B at temperature T=0. This field-induced Landau–Fermi liquid behavior provides constancy of the Kadowaki–Woods ratio. A re-entrance into the strongly correlated regime is observed if the magnetic field B decreases to zero; the effective mass M* then diverges as \(M^* \propto {1 \mathord{\left/ {\vphantom {1 {\sqrt B }}} \right. \kern-\nulldelimiterspace} {\sqrt B }}\). At finite temperatures, the strongly correlated regime is restored at some temperature \(T^* \propto \sqrt B \). This behavior is of a general form and takes place in both three-dimensional and two-dimensional strongly correlated systems. We demonstrate that the observed \({1 \mathord{\left/ {\vphantom {1 {\sqrt B }}} \right. \kern-\nulldelimiterspace} {\sqrt B }}\) divergence of the effective mass and other specific features of heavy-fermion metals are accounted for by our consideration.     

Universal estimate of the gap for the Kac operator in the convex case

The aim of this paper is to prove that ifV is a strictly convex potential with quadratic behavior at ∞, then the quotient μ₂/μ₁ between the largest eigenvalue and the second eigenvalue of the Kac operator defined on L²(? ^m ) by exp ?V(x)/2 · exp Δ_x · exp ?V(x)/2 where Δ_x is the Laplacian on ? ^m satisfies the condition: $${{\mu _2 } \mathord{\left/ {\vphantom {{\mu _2 } {\mu _1 {{ \leqslant \exp - \cosh ^{ - 1} (\sigma + 1)} \mathord{\left/ {\vphantom {{ \leqslant \exp - \cosh ^{ - 1} (\sigma + 1)} {2,}}} \right. \kern-\nulldelimiterspace} {2,}}}}} \right. \kern-\nulldelimiterspace} {\mu _1 {{ \leqslant \exp - \cosh ^{ - 1} (\sigma + 1)} \mathord{\left/ {\vphantom {{ \leqslant \exp - \cosh ^{ - 1} (\sigma + 1)} {2,}}} \right. \kern-\nulldelimiterspace} {2,}}}}$$ where σ is such that HessV(x)≥σ>0.     

Superconductive superheating field for finiteκ

We have calculated analytically the superheating fieldH _sh for bulk superconductors, correct to second order in. We find , which agrees well with numerical computations for<0.5. The surface order parameter is , and the penetration depth is .     

A rigorous upper bound in electrostatics on a random lattice ensemble

We consider a Kirchhoff network on a random two-dimensional lattice with links and weights as previously specified, and a circular boundary of radiusR. We show rigorously that the resistance between the central point and the boundary, averaged over all placements of the remaining sites with site density ?, is bounded above by $$\begin{array}{*{20}c} {(4\pi )^{ - 1} [\ln (4\pi \rho R^2 ) + 1] + 16[\tan ^{ - 1} 5^{ - {1 \mathord{\left/ {\vphantom {1 4}} \right. \kern-\nulldelimiterspace} 4}} + 5^{{1 \mathord{\left/ {\vphantom {1 4}} \right. \kern-\nulldelimiterspace} 4}} /(\sqrt 5 + 1)^2 ]} \\ { \simeq (4\pi )^{ - 1} \ln (4\pi \rho R^2 ) + 12.0.} \\ \end{array} $$      

The Andreev conductance in superconductor–insulator–normal metal structures

The Andreev subgap conductance at 0.08–0.2 K in thin-film superconductor (aluminum)–insulator–normal metal (copper, hafnium, or aluminum with iron-sublayer-suppressed superconductivity) structures is studied. The measurements are performed in a magnetic field oriented either along the normal or in the plane of the structure. The dc current–voltage (I–U) characteristics of samples are described using a sum of the Andreev subgap current dominating in the absence of the field at bias voltages U < (0.2–0.4)Δ_c/e (where Δ_c is the energy gap of the superconductor) and the single-carrier tunneling current that predominates at large voltages. To within the measurement accuracy of 1–2%, the Andreev current corresponds to the formula \({I_n} + {I_s} = {K_n}\tanh \left( {{{eU} \mathord{\left/ {\vphantom {{eU} {2k{T_{eff}}}}} \right. \kern-\nulldelimiterspace} {2k{T_{eff}}}}} \right) + {K_s}{{\left( {{{eU} \mathord{\left/ {\vphantom {{eU} {{\Delta _c}}}} \right. \kern-\nulldelimiterspace} {{\Delta _c}}}} \right)} \mathord{\left/ {\vphantom {{\left( {{{eU} \mathord{\left/ {\vphantom {{eU} {{\Delta _c}}}} \right. \kern-\nulldelimiterspace} {{\Delta _c}}}} \right)} {\sqrt {1 - {{eU} \mathord{\left/ {\vphantom {{eU} {{\Delta _c}}}} \right. \kern-\nulldelimiterspace} {{\Delta _c}}}} }}} \right. \kern-\nulldelimiterspace} {\sqrt {1 - {{eU} \mathord{\left/ {\vphantom {{eU} {{\Delta _c}}}} \right. \kern-\nulldelimiterspace} {{\Delta _c}}}} }}\) following from a theory that takes into account mesoscopic phenomena with properly selected effective temperature T _eff and the temperature- and fieldindependent parameters K _n and K _s (characterizing the diffusion of electrons in the normal metal and superconductor, respectively). The experimental value of K _n agrees in order of magnitude with the theoretical prediction, while K _s is several dozen times larger than the theoretical value. The values of T _eff in the absence of the field for the structures with copper and hafnium are close to the sample temperature, while the value for aluminum with an iron sublayer is several times greater than this temperature. For the structure with copper at T = 0.08–0.1 K in the magnetic field B_|| = 200–300 G oriented in the plane of the sample, the effective temperature T _eff increases to 0.4 K, while that in the perpendicular (normal) field B _⊥ ≈ 30 G increases to 0.17 K. In large fields, the Andreev conductance cannot be reliably recognized against the background of single- carrier tunneling current. In the structures with hafnium and in those with aluminum on an iron sublayer, the influence of the magnetic field is not observed.     

Light quark masses in quantum chromodynamics and chiral symmetry breaking

We derive model independent lower bounds for the sums of effective quark masses \(\bar m_u + \bar m_d \) and \(\bar m_u + \bar m_s \) . The bounds follow from the combination of the spectral representation properties of the hadronic axial currents two-point functions and their behavior in the deep euclidean region (known from a perturbative QCD calculation to two loops and the leading non-perturbative contribution). The bounds incorporate PCAC in the Nambu-Goldstone version. If we define the invariant masses \(\hat m\) by $$\bar m_i = \hat m_i \left( {{{\frac{1}{2}\log Q^2 } \mathord{\left/ {\vphantom {{\frac{1}{2}\log Q^2 } {\Lambda ^2 }}} \right. \kern-\nulldelimiterspace} {\Lambda ^2 }}} \right)^{{{\gamma _1 } \mathord{\left/ {\vphantom {{\gamma _1 } {\beta _1 }}} \right. \kern-\nulldelimiterspace} {\beta _1 }}} $$ and <F ²> is the vacuum expectation value of $$F^2 = \Sigma _a F_{(a)}^{\mu v} F_{\mu v(a)} $$ , we find, e.g., $$\hat m_u + \hat m_d \geqq \sqrt {\frac{{2\pi }}{3} \cdot \frac{{8f_\pi m_\pi ^2 }}{{3\left\langle {\alpha _s F^2 } \right\rangle ^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} }}} $$ ; with the value <α _u F ²?0.04GeV⁴, recently suggested by various analysis, this gives $$\hat m_u + \hat m_d \geqq 35MeV$$ . The corresponding bounds on \(\bar m_u + \bar m_s \) are obtained replacingm _π ² f _π bym _K ² f _K . The PCAC relation can be inverted, and we get upper bounds on the spontaneous masses, \(\hat \mu \) : $$\hat \mu \leqq 170MeV$$ where \(\hat \mu \) is defined by $$\left\langle {\bar \psi \psi } \right\rangle \left( {Q^2 } \right) = \left( {{{\frac{1}{2}\log Q^2 } \mathord{\left/ {\vphantom {{\frac{1}{2}\log Q^2 } {\Lambda ^2 }}} \right. \kern-\nulldelimiterspace} {\Lambda ^2 }}} \right)^d \hat \mu ^3 ,d = {{12} \mathord{\left/ {\vphantom {{12} {\left( {33 - 2n_f } \right)}}} \right. \kern-\nulldelimiterspace} {\left( {33 - 2n_f } \right)}}$$ .     

Self-diffusion in α-Fe2O3 natural single crystals

Measurements of¹⁸O self-diffusion in hematite (Fe₂O₃) natural single crystals have been carried out as a function of temperature at constant partial pressure a_{O 2}=6.5·10^?2 in the temperature range 890 to 1227 °C. The a_{O 2} dependence of the oxygen self-diffusion coefficient at fixed temperature T=1150 °C has also been deduced in the a_{O 2} range 4.5·10^?4 - 6.5·10^?1. The concentration profiles were established by secondary-ion mass spectrometry; several profiles exhibit curvatures or long tails; volume diffusion coefficients were computed from the first part of the profiles using a solution taking into account the evaporation and the exchange at the surface. The results are well described by $$D_O \left( {{{cm^2 } \mathord{\left/ {\vphantom {{cm^2 } s}} \right. \kern-\nulldelimiterspace} s}} \right) = 2.7 \cdot 10^8 a_{O_2 }^{ - 0.26} \exp \left( { - \frac{{542\left( {{{kJ} \mathord{\left/ {\vphantom {{kJ} {mol}}} \right. \kern-\nulldelimiterspace} {mol}}} \right)}}{{RT}}} \right)$$ From fitting a grain boundary diffusion solution to the profile tails, the oxygen self-diffusion coefficient in sub-boundaries has been deduced. They are well described by $$D''_O \left( {{{cm^2 } \mathord{\left/ {\vphantom {{cm^2 } s}} \right. \kern-\nulldelimiterspace} s}} \right) = 3.2 \cdot 10^{25} a_{O_2 }^{ - 0.4} \exp \left( { - \frac{{911\left( {{{kJ} \mathord{\left/ {\vphantom {{kJ} {mol}}} \right. \kern-\nulldelimiterspace} {mol}}} \right)}}{{RT}}} \right)$$ Experiments performed introducing simultaneously¹⁸O and⁵⁷Fe provided comparative values of the self-diffusion coefficients in volume: iron is slower than oxygen in this system showing that the concentrations of atomic point defects in the iron sublattice are lower than the concentrations of atomic point defects in the oxygen sublattice. The iron self-diffusion values obtained at T>940 °C can be described by $$D_{Fe} \left( {{{cm^2 } \mathord{\left/ {\vphantom {{cm^2 } s}} \right. \kern-\nulldelimiterspace} s}} \right) = 9.2 \cdot 10^{10} a_{O_2 }^{ - 0.56} \exp \left( { - \frac{{578\left( {{{kJ} \mathord{\left/ {\vphantom {{kJ} {mol}}} \right. \kern-\nulldelimiterspace} {mol}}} \right)}}{{RT}}} \right)$$ The exponent - 1/4 observed for the oxygen activity dependence of the oxygen self-diffusion in the bulk has been interpreted considering that singly charged oxygen vacancies V _O ^? are involved in the oxygen diffusion mechanism. Oxygen activity dependence of iron self-diffusion is not known accurately but the best agreement with the point defect population model is obtained considering that iron self-diffusion occurs both via neutral interstitals Fe _x ⁱ and charged ones.     

Analysis of the modified point-matching method in the electrostatic problem for axisymmetric particles

An integral modification of the generalized point-matching method (GPMMi) in the electrostatic problem for axisymmetric particles is developed. Scalar potentials that determine electric fields are represented as expansions in terms of eigenfunctions of the Laplace operator in the spherical coordinate system. Unknown expansion coefficients are determined from infinite systems of linear algebraic equations (ISLAEs), which are obtained from the requirement of a minimum of the integrated residual in the boundary conditions on the particle surface. Matrix elements of ISLAEs and expansion coefficients of the “scattered” field at large index values are analyzed analytically and numerically. It is shown analytically that the applicability condition of the GPMMi coincides with that for the extended boundary conditions method (ЕВСМ). As model particles, oblate pseudospheroids \(r\left( \theta \right) = a\sqrt {1 - {^2}{{\cos }^2}\theta } ,\;{^2} = 1 - {\raise0.7ex\hbox{${{b^2}}$} \!\mathord{\left/ {\vphantom {{{b^2}} {{a_2}}}}\right.\kern-\nulldelimiterspace}\!\lower0.7ex\hbox{${{a_2}}$}} \geqslant 0\) with semiaxes a = 1 and b ≤ 1 are considered, which are obtained as a result of the inversion of prolate spheroids with the same semiaxes with respect to the coordinate origin. For pseudospheroids, the range of applicability of the considered methods is determined by the condition \({\raise0.7ex\hbox{$a$} \!\mathord{\left/ {\vphantom {a b}}\right.\kern-\nulldelimiterspace}\!\lower0.7ex\hbox{$b$}} < \sqrt 2 + 1\). Numerical calculations show that, as a rule, the ЕВСМ yields considerably more accurate results in this range, with the time consumption being substantially shorter. Beyond the ЕВСМ range of applicability, the GPMMi approach can yield reasonable results for the calculation of the polarizability, which should be considered as approximate and which should be verified with other approaches. For oblate nonconvex pseudospheroids (i.e., at \({\raise0.7ex\hbox{$a$} \!\mathord{\left/ {\vphantom {a b}}\right.\kern-\nulldelimiterspace}\!\lower0.7ex\hbox{$b$}} \geqslant \sqrt 2 \)), it is shown that the spheroidal model works well if pseudospheroids are replaced with ordinary “effective” oblate spheroids. Semiaxes a_ef and b_ef of the effective spheroids are determined from the requirement of the particle volumes, as well as from the equality of the maximal longitudinal and transverse dimensions of particles or their lengths. As a result, the polarizability of pseudospheroids can be calculated by simple explicit formulas with an error of about 0.5–2%.