共查询到20条相似文献,搜索用时 16 毫秒
1.
Kalashnikova I. P. Zhukov I. V. Tomilova L. G. Zefirov N. S. 《Russian Chemical Bulletin》2003,52(8):1709-1714
Hexadecapropyloxy-substituted diphthalocyanine complexes of rare-earth elements (REE = Lu, Tm, Sm) were synthesized. The new symmetrically substituted diphthalocyanine complexes prepared starting from 4,5-dipropyloxyphthalodinitrile (phthalogen) are characterized by better solubilities compared to the known hexadecamethyl-substituted diphthalocyanine complexes of the same REE. Spectral and electrochemical characteristics of the complexes were studied. The compounds can be used as materials for high-contrast electrochromic devices. 相似文献
2.
T. Pandiyarajan B. Karthikeyan P. Venkatesan M. Ashok S. Anandan N.V. Giridharan 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,74(1):84-86
Cobalt doped zinc oxide nanoparticles were prepared through simple wet chemical method. X-ray diffraction studies confirm the prepared particles are in wurtzite structure. Scanning Electron Microscopy studies show the shape and morphology of the particles. To identify the presence of cobalt in ZnO, Energy Dispersive X-ray analysis was done. Optical absorption measurements show the presence of exciton peak at 375 nm. Photoluminescence studies were done with the excitation wavelength of 330 nm, which shows the emission because of exciton recombination and oxygen vacancy. 相似文献
3.
Khalil MM Mohamed HA El-Medani SM Ramadan RM 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2003,59(6):1341-1347
Reaction of Cr(CO)(6) with 2-(2'-pyridyl)benzimidazole (pbiH) under reduced pressure resulted in the formation of the dinuclear complex [Cr(2)(CO)(6)(pbiH)(2)]. Infra-red (IR) spectroscopy revealed the presence of terminal and bridge Cr-CO bonds. Interaction of M(CO)(6), M=Cr, Mo and W, with pbiH in the presence of 2,2'-bipyridine (bpy) gave the tetracarbonyl complexes [M(CO)(4)(pbiH)].bpy. Spectroscopic studies of the complexes indicated the presence of hydrogen bonding between the bpy nitrogen and the NH group of pbiH. Reactions of M(CO)(6) with pbiH in the presence of PPh(3) gave the tricarbonyl monosubstituted derivatives [M(CO)(3)(PPh(3))(pbiH)]. The spectroscopic studies of the complexes suggested the proposed structures. 相似文献
4.
Arthur J. Carty Shaun F. Malone Nicholas J. Taylor 《Journal of organometallic chemistry》1979,172(2):201-211
The synthesis of selenium bound selenourea complexes of methylmercury, [CH3HgSeC(NH2)2]X (X=Cl, Br, NO3, ClO4) are described. A single crystal X-Ray analysis of the nitrate salt has provided for the first time bond length data pertinent to the biologically important mercury-selenium interaction. Crystals of [CH3HgSeC(NH2)2] NO3 belong to the space group PnZic with a = 7.524(1), b = 11.204(2), c = 9.738(2)Å, and z = 4. The structure was solved and refined using 561 observed reflections measured on a Syntex P21 diffractometer to a final R value of 0.037. The mercury atom is linearly coordinated to the methyl group and the selenium atom of the selenourea with Hg-Se of 2.477(3)Å. Strong Hg-Se bonding is indicated by the X-Ray data and by the 1H - 199Hg nmr coupling constants. A comparison of spectroscopic data for analogous thio and selenourea complexes is presented. 相似文献
5.
Xuefeng Guo Deqing Zhang Huijuan ZhangQinghua Fan Wei XuXicheng Ai Louzheng FanDaoben Zhu 《Tetrahedron》2003,59(26):4843-4850
Three donor-acceptor-donor triads 1-3 consisting of tetrathiafulvalene units attached to perylene diimides by flexible and rigid spacers were synthesized and characterized. UV/vis spectroscopic and cyclic voltammetric results indicate that they all show negligible intramolecular charge transfer interaction in their ground states. As compared to the reference compound 21, triads 1-3 display reduced fluorescence and their fluorescence lifetimes are shortened, which is probably owing to the photoinduced electron transfer interactions between the PI units and TTF units. The different photophysical behaviors between 1 and 2 (and 3) might be due to their difference in the spatial separation of TTF and PI units. It is preliminarily found that the steric hindrance of the groups attached to TTF units can affect their photostability. 相似文献
6.
F. S. Hadzhieva V. F. Anufrienko T. M. Yurieva V. N. Vorobiev T. P. Minyukova 《Reaction Kinetics and Catalysis Letters》1986,30(1):85-92
The state of Cu2+ ions in Cu–Zn–Al catalysts for methanol synthesis has been studied by electron spectroscopy (5000–50000 cm–1). It has been established that low-temperature ZnO stabilizes copper in a distorted octahedral coordination as cluster structures resembling (but not similar to) CuO. The presence of Al promotes the formation of these clusters and inhibits the formation of CuO.
(5000–50000 –1) Cu2+ Cu–Zn–Al . , ZnO , ( ) CuO. , CuO.相似文献
7.
8.
Genre C Jeanneau E Bousseksou A Luneau D Borshch SA Matouzenko GS 《Chemistry (Weinheim an der Bergstrasse, Germany)》2008,14(2):697-705
We report here on the synthesis and characterisation of a first iron(II) spin-crossover coordination polymer with the dca spacer ligand, having the formula [Fe(aqin)2(dca)]ClO4.MeOH (aqin=8-aminoquinoline, dca=dicyanamide), which displays a two-step complete spin transition. Variable-temperature magnetic susceptibility measurements and M?ssbauer spectroscopy have revealed that the two relatively gradual steps are centred at 215 and 186 K and are separated by an inflection point at about 201 K, at which 50 % of the complex molecules undergo a spin transition. The two steps are related to the existence of two crystallographically inequivalent metal sites, as confirmed by the structural and M?ssbauer studies. The crystal structure was resolved at 293 K (HS form) and 130 K (LS form). Both spin-state structures belong to the triclinic P1 space group (Z=2). The complex assumes a linear chain structure, in which the active iron(II) sites are linked to each other by anionic dicyanamide ligands acting as chemical bridges. The Fe-Fe distances through the dca ligand are 8.119(1) and 7.835(1) A in the high-spin and low-spin structures, respectively. The polymeric chains extend along a (1, 0, -1) axis and are packed in sheets, between which the perchlorate anions and methanol molecules are inserted. The complex molecules are linked together by pi-stacking interactions and H-bonding between the H-donor aqin ligands and the perchlorate ions. These structural features provide a basis for cooperative interactions in the crystal lattice. Analysis of the two-step spin-crossover character in this compound suggests that covalent interactions through the spacer ligand do not provide the main mechanism of cooperativity. 相似文献
9.
Xu HJ Mack J Descalzo AB Shen Z Kobayashi N You XZ Rurack K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(32):8965-8983
The successful synthesis of tetraphenyltetraphenanthroporphyrin (TPTPhenP; 5a) in 2006 under modified Rothemund-Lindsey conditions yielded a tetraphenyl porphyrinoid with a B band redshifted to an unprecedented 576 nm. Radially symmetric fused-ring expansion of tetraphenylporphyrin with phenanthrene moieties results in very deep saddling due to steric crowding and very marked redshifts of the Q and B (or Soret) porphyrinoid absorption bands. The extent to which the TPTPhenP structure can be further modified is explored, and the optical properties of TPTPhenPs are analyzed based on a perimeter model approach that makes use of time-dependent DFT calculations and magnetic circular dichroism spectroscopy and also based on a detailed analysis of the fluorescence emission. Attempts to introduce substituents at the ortho and meta positions of the meso-phenyl groups and to insert a central metal proved unsuccessful. The synthesis of a series of TPTPhenPs with strong electron-withdrawing (-CN, -NO(2)) and -donating (-CH(3), -N(CH(3))(2)) substituents at the para positions of the meso-phenyl rings is reported. Marked redshifts of the main spectral bands were consistently observed. The most pronounced spectral changes were observed with -N(CH(3))(2) groups (5i) due to a marked destabilization of the HOMO, which has large MO coefficients on the meso-carbon atoms. Protonation of 5i at both the ligand core and at the -N(CH(3))(2) groups resulted in unprecedented Q(00) band absorption at wavelengths greater than 1200 nm. 相似文献
10.
Three conjugated polymers containing oligothiophene units (from one to three thiophene rings) and aromatic 1,3,4-oxadiazole moieties have been successfully synthesized. The polymer structures were characterized and confirmed by (1)H and (13)C NMR, FT-IR, and elemental analysis. Thermogravimetric analysis demonstrated that the polymers are highly thermal stable. Tunable absorption (from 342 to 428 nm) and fluorescence (from 411 to 558 nm) properties of polymers were observed. The electrochemical investigation indicated that the LUMO and HOMO energy levels of the new polymers could be adjusted. It was also revealed by the electrochemical analysis that the polymers have good charge injection properties for both p-type and n-type charge carriers, as well as good color tunable luminescence and film-forming properties, which makes them potentially useful for fabricating efficient light-emitting devices. 相似文献
11.
《Journal of Coordination Chemistry》2012,65(18):3322-3333
Cu(II), Co(II), Ni(II), Cd(II), and Zn(II) complexes of 6-(2-phenyldiazenyl)-7-hydroxy-4-methyl coumarin (PAHC) are characterized based on elemental analyses, infrared, 1H NMR, magnetic moment, molar conductance, mass spectra, UV-Vis analysis, thermogravimetric analysis (TGA), and X-ray powder diffraction. From the elemental analyses, it is found that the complexes have formulae [M(L)2(H2O) n ] ? xH2O (where M = Cu(II), Co(II), Ni(II), Cd(II), and Zn(II), n = 0–2, x = 1–4). The molar conductance data reveal that all the metal chelates are non-electrolytes. From the magnetic and solid reflectance spectra, it is found that the structures of these complexes are octahedral or tetrahedral. The synthesized ligand and metal complexes were screened for antibacterial activity against some Gram-positive and Gram-negative bacteria. 相似文献
12.
Gudasi KB Patil MS Vadavi RS Shenoy RV Patil SA Nethaji M 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2007,67(1):172-177
Phenylglycine hydrazide was synthesized and investigated by X-ray crystallography. It crystallizes in the monoclinic space group P121/c with cell parameters a=5.9459 (18) Angstrom, b=5.1940 (16) Angstrom, c=26.7793 (83) Angstrom and Z=2. Its conformational changes, on complexation with transition metal ions Cu(II), Co(II), Ni(II), Mn(II) and Zn(II) has been studied on the basis of elemental analysis, magnetic moment and spectral (IR, (1)H NMR, UV-vis) studies. The bidentate nature of the ligand was confirmed on the basis of a comparative IR and NMR spectral studies. The trigonal bipyramidal geometries were observed for Cu(II), Ni(II) and Co(II) complexes, while it is octahedral for the remaining complexes. The conductivity data suggest them to be non-electrolytes. 相似文献
13.
Udaykumar V. Kamble Sangamesh A. Patil Prema S. Badami 《Journal of inclusion phenomena and macrocyclic chemistry》2010,68(3-4):347-358
A novel series of 17-membered complexes [MLCl2] (M = Co2+, Ni2+ and Cu2+) have been synthesized with newly derived biologically active ligands (LI–LIV). These ligands were synthesized by the condensation of 3-subtituted-4-amino-5-hydrazino-1,2,4-triazole with bis(phthalaldehyde)ethylenediamine precursor. The structure of the complexes has been proposed by elemental analyses, IR, EPR, electronic spectral studies, conductivity, magnetic, thermal and electrochemical studies. All the complexes are soluble in DMF and DMSO and are non-electrolytes. All these Schiff bases and their complexes have been screened for their antibacterial (Escherichia coli, Staphylococus aureus, Salmonella typhi, Pseudomonas aeruginosa) and antifungal activities (Aspergillus niger, Aspergillus flavus and Cladosporium) by the Agar and Potato dextrose agar diffusion method. The DNA cleavage study was done by Agarose gel electrophoresis technique. 相似文献
14.
Michelle Guy Sally Freeman John F. Alder Simon D. Brandt 《Central European Journal of Chemistry》2008,6(4):526-534
A clandestine two-step route to psychoactive racemic phenylalkylamines utilises the Henry reaction. In the first step an aromatic
aldehyde reacts with a nitroalkane to give the nitrostyrene intermediate. In the second step the nitrostyrene is reduced to
the phenylalkylamine. An impurity profile of both steps was evaluated through the synthesis and analysis of common street
derivatives. The formation of nitrile impurities in the nitroaldol reaction and hydroxylamine impurities in the reduction
step were shown by NMR spectroscopy and GC-MS. A selection of reducing agents has been used to give the phenylalkylamines,
together with variable quantities of the partially reduced hydroxylamine product. GC-MS analysis of the hydroxylamines showed
heat-induced disproportionation which led to the detection of the corresponding oximes.
相似文献
15.
Three cyclotetrapeptides, c[Leu-d-Ala-Xaa-d-Ala], where Xaa is Leu (P1), Lys (P2) and Glu (P3) were synthesized and studied by 1H and 13C NMR and CD spectroscopy. These cyclotetrapeptides exhibit similar coupling constants, 3JHNHα, in the range of 8.56-9.93 Hz, commonly observed for β-turn structures. All amide proton chemical shifts for P1, P2 and P3 exhibited linear dependence on temperature with moderate temperature coefficients ranging from −3.1 to −9.8 ppb/K. Amide proton signal broadening was observed for all residues in P1, P2 and P3, indicating that they are solvent accessible. The number of resonance observed for P1 was half of the total counts, indicating a C2 symmetric conformation. P2 and P3 exhibit similar CD in solvents of varying dielectric constants and dilutions, with characteristic positive CD bands at ca. 210 and 222 nm, which correspond to a β-turn type structure. Small CD/temperature effect was also observed with isodichroic points, consistent with conformational stability and a well-populated cyclotetrapeptide energy state. These heterochiral cyclotetrapeptides consisting of alternating d-Ala residues adopt stabilized open β-turn conformations and may be useful as a ligand template for further functionalization. 相似文献
16.
Helena Riihimki Pekka Suomalainen Heidi K. Reinius Johanna Suutari Sirpa Jskelinen A. O. I. Krause Tapani A. Pakkanen Jouni T. Pursiainen 《Journal of molecular catalysis. A, Chemical》2003,200(1-2):69-79
In earlier hydroformylation studies modification of the rhodium catalyst with o-methyl-substituted or o-ethyl-substituted phosphane ligands have increased regioselectivity to branched aldehydes. The promising results achieved created a need for further studies. Hence, a wider group of o-substituted arylphosphane ligands, e.g. (2-cyclohexylphenyl)diphenylphosphane, (2-isopropylphenyl)diphenylphosphane, (2-methylnaphthyl)diphenylphosphane, (2,5-dimethylphenyl)diphenylphosphane and (2-phenylphenyl)diphenylphosphane were synthesized and tested in rhodium-catalyzed hydroformylation to support the previous findings. Characterization of the ligands was made by NMR spectroscopy (1H, 31P{1H}, 13C{1H}, HSQC, COSY-90 and COLOC). Additional parameters for evaluation of the stereoelectronic properties of the ligands were provided by quantum mechanical calculations and by synthesizing Rh(acac)(CO)(PR3) complexes. In the rhodium-catalyzed hydroformylation of propene and 1-hexene the ligands increased the formation of branched aldehydes compared to triphenylphosphane. Additionally the increasing size of the o-alkyl-substituent was found to effect favorably to the iso-selectivity. 相似文献
17.
《Journal of Coordination Chemistry》2012,65(7):1180-1186
Ligand bridged homodinuclear derivatives of bismuth(V) of the type, (1a–1d) [where R =–C(CH3)2CH2CH(CH3)–(1a),–CH(CH2CH3)CH2–(1b),–CH(CH3)CH(CH3)–(1c),–CH(CH3)CH2–(1d)] have been synthesized by reactions of equimolar oxobis(triphenylbismuth)dichloride, {[Ph3Bi]2O}Cl2 with glycols, HOROH in the presence of NaOMe. Reactions of sodiumtetraisopropoxoarsonate, NaAs(OPri)4 with in 1 : 1 molar ratio yielded homodinuclear alkoxo derivatives of arsenic(III) containing glycols, (2a–2d). All compounds were characterized by elemental analysis, molecular weight determinations, IR and NMR (1H and 13C) spectral studies. 相似文献
18.
Dułak M Bergougnant R Fromm KM Hagemann HR Robin AY Wesołowski TA 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,64(2):532-548
Experimental (IR and Raman) and theoretical (Kohn-Sham calculations) methods are used in a combined analysis aimed at refining the available structural data concerning the molecular guests in channels formed by stacked dibenzo-18-crown-6 (DB18C6) crown ether. The calculations are performed for a simplified model comprising isolated DB18C6 unit and its complexes with either H2O or H3O+ guests, which are the simplest model ingredients of a one-dimensional diluted acid chain, to get structural and energetic data concerning the formation of the complex and to assign the characteristic spectroscopic bands. The oxygen centers in the previously reported crystallographic structure are assigned to either H2O or protonated species. 相似文献
19.
The synthesis of layered donor/acceptor-materials based on perylenes (1a–c) and ter(thiophen)es (2a, 2b), ordered by hydrogen bonding moieties is reported. Based on the successful (selective) chlorination of 3,4:9,10-perylene tetracarboxylic dianhydride (3) to obtain a perylene derivative with only four chlorine atoms, subsequent functionalization with different hydrogen-bonding moieties is achieved via the azide/alkyne click reaction as proven by extensive ESI-TOF measurements. The perylene- (1a–c) and terthiophene- (2a, 2b) compounds are useful as acceptor and donor parts, respectively, in organic solar cells as proven via UV–vis and fluorescence measurements. Charge transfer between donor and acceptor parts (2a/1b) was determined as 41% via fluorescence resonance energy transfer (FRET), proving the association of the two components via the attached hydrogen bonding moieties. These measurements indicate that the mixture 2a/1b displays large potential for use as a layered ordered material with controlled spacings for organic solar cells based on a thereby facilitated charge-transfer. 相似文献
20.
G Stavropoulos K Karagiannis D Vynios D Papaloannou D W Aksnes N Age Fr?ystein G W Francis 《Acta chemica Scandinavica (Copenhagen, Denmark : 1989)》1991,45(10):1047-1054
An efficient solid-phase synthesis of the TRH analogue Glp-His(Nim-Trt)-Hyp-OH is described. Na-Fmoc protected amino acids and DCC/HOBt activation were employed. The bulky and mild-acid-sensitive 2-chlorotrityl resin, utilised as the solid support, completely suppressed dioxopiperazine formation. The tripeptide is a key intermediate in the synthesis of TRH analogues incorporating cis- and trans-4-hydroxy-L-proline. The tripeptide was converted, with inversion of configuration at C-4 of the Hyp residue, to Glp-His(Nim-Trt)-cHyp lactone in the presence of triphenylphosphine-diethyl azodicarboxylate (TPP-DEAD). One-pot MeOH-TPP-DEAD transesterification of the lactone, followed by Nim-detritylation, provided Glp-His-cHyp-OMe. This ester gave the corresponding amide and acid on ammonolysis and saponification, respectively. A high-field 1H NMR investigation of Glp-His-cHyp-OH and its diastereomer Glp-His-Hyp-OH, obtained by Nim-detritylation of the key tripeptide, showed that the configuration at C-4 of the prolyl residues is critical for the determination of the preferred three-dimensional structure of the molecules. 相似文献