The electronic structure of Rhodium: Angle-resolved studies of photoelectron and secondary electron emission

We report electron spectroscopic studies of the Rh(111) surface, with the aim to obtain bulk band-structure information. We have measured normal photoemision using tunable synchrotron radiation in the range of photon energies between 11 eV and 55 eV, and angle-dependent photoemission along the LUX and LKL azimuths using the He resonance lines (=21.2 eV, 40.8 eV). To complement these data, we studied angleresolved secondary electron emission after excitation with electrons and photons. We derive parts of the one-electron energy dispersionE(k) along L, and determine the energies of several bulk critical points (in eV):E(> ₇₊/₈₊)=–2.75±0.10,E(> ₈₊=–0.85±0.10,E(> _7–=16.1±0.5,E(> _6–/> _8–)=20.5±0.5,E(X ₇₊)=–5.0±0.1,E(L ₆₊)=–5.6±0.5,E(L ₆₊/L ₄₊₊₅₊)=–2.65±0.10,E(L ₆₊)=9.0±0.5 eV. Our results are compared to several available band structure calculations.     

From monotonic to oscillatory decay of correlations: Analytical approximation for the two-dimensional,one-component plasma

An approximate evaluation of the pair distribution and the structure factor is performed analytically for the two-dimensional, one-component plasma at any value of the coupling constant. The approximate distribution remains positive and satisfies three sum rules, including the compressibility one. When 0 or 2, exact results are found. At=2 the transition from monotonie (<2) to oscillatory (>2) decay of correlations takes place. Comparison with the Monte Carlo simulations shows good agreement for 0<<4.     

Elastic constants and quadrupolar interactions in the (LaCe)B6 series

Elastic constants of (La_1–xCe_x)B₆(x=0.01, 0.03, 0.1) dilute alloys have been determined by ultrasonic measurements at temperatures between 0.5 K and 4.2 K. The temperature dependence ofc ₄₄ and (c ₁₁–c ₁₂)/2 is in excellent agreement with calculations including magnetoelastic and interionic quadrupolar interactions. The single ion coupling constantsg (=₃, ₃) are independent of concentration. The systematic concentration dependence of quadrupolar coupling constants g'g(x) from the dilute (x=0.01) alloy to the compound CeB₆ (x=1) has been studied. Evidence of Grüneisenparameter coupling in the bulk modulus but no indication for a ₈ ground state splitting or a quadrupolar Kondo effect has been found. In addition the magnetic field dependence of elastic constants up to 6.5 Tesla was investigated.     

Solvable isotherms for a two-component system of charged rods on a line

The Coulomb system consisting of an equal number of positive and negative charged rods confined to a one-dimensional lattice is studied. The grand partition function can be calculated exactly at two values of the coupling constant=q ²/k _B T (q denoting the magnitude of the charges). The exact results lead to the conjecture that in the complex scaled fugacity plane, all the zeros of the grand partition function lie on the negative real axis for<2, on the point=–1 for=2, and on the unit circle for>2. In addition, for>4, we conjecture in general and prove at=4 that the zeros pinch the real axis in the thermodynamic limit, with an essential singularity in the pressure at the reduced density 1/2.     

Higher order differential calculus on SL q(N)

Let be a bicovariant first order differential calculus on a Hopf algebra . There are three possibilities to construct a differential N ₀-graded Hopf algebra which contains as its first order part. In all cases is a quotient = /J of the tensor algebra by some suitable ideal. We distinguish three possible choices _u J, _s J, and _W J, where the first one generates the universal differential calculus (over ) and the last one is Woronowicz' external algebra. Let q be a transcendental complex number and let be one of the N ²-dimensional bicovariant first order differential calculi on the quantum group SL _q(N). Then for N 3 the three ideals coincide. For Woronowicz' external algebra we calculate the dimensions of the spaces of left-invariant and bi-invariant k-forms. In this case each bi-invariant form is closed. In case of 4D _± calculi on SL _q(2) the universal calculus is strictly larger than the other two calculi. In particular, the bi-invariant 1-form is not closed.     

Thickness dependence of the spin- and angle-resolved photoemission of ultrathin,epitaxial Ni(111)/W(110) layers

The thickness dependence of the magnetic band structure of ultrathin, epitaxial Ni(111)/W(110) layers has been studied by spin and angle-resolved photoemission spectroscopy. The changes of the spin-resolved photoemission intensities upon reducing the layer thickness depend strongly on the wavevector along the -L line of the Brillouin zone. The measured exchange splitting atk 1/3(-L) andk 1/2(-L) is found to be independent of the layer thickness for layers consisting of 3 or more atomic layers, while decreases rapidly with the layer thickness atk2/3(-L). This behavior is very similar to the temperature dependence of the spin-resolved photoemission spectra of bulk Ni(111) at the samek-points.     

Differential algebras for quantum groups of type B, C, and D

We study higher order bicovariant differential calculi on the quantum groups O_q(N) and Sp _q (N). We show that the second antisymmetrizer exterior algebra _u is the quotient of the universal exterior algebra _u by the principal ideal generated by . Here denotes the unique up to scalars biinvariant 1-form. Moreover is central in _u and _u is an inner differential calculus. We show that the quadratic dual to the left-invariant algebra _{s L} is isomorphic to the reflection equation algebra. Let be an arbitrary left-covariant first order differential calculus. We show that the dimension of the space of left-invariant 2-forms in the universal exterior algebra equals the number of linearly independent quadratic-linear relations in the quantum tangent space.     

Pseudo-Jahn-Teller effect in tetragonal local centers

The shape of the light absorption band by a local tetragonal center at the transition _{1 5}(x, y) is investigated in a semiclassical approximation. In addition to interaction with fully-symmetric (₁), Jahn-Teller (₃, ₄) vibrations, inter-action is also taken into account with vibrations ₅, which admix an electron level ₄(z) to the electronic state ₅, which is separated from ₅ by the energetic gap . An analytic computation of the band shape is performed in the first order of the expansion of the form function in ^–1. An asymmetric two-hump band is obtained, where the long-wave maximum always has higher intensity than the shortwave maximum.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 62–67, December, 1987.     

The crystal structure of copper dipyridine dibromide Cu(C5H5N)2Br2

The X-ray structural analysis of copper dipyridine dibromide was carried out. The substance is monoclinic, its space group isP2₁/n, having the lattice constantsa=8.30 kXU,b=17.72 kXU,c=4.04 kXU,=96°,Z=2. The localization of the heavy atoms was carried out by means of the projections of the Patterson functionsP(u, v) andP(v, w), which provided the bases for determining the signs of the majority of structure factors. The projections of the electron density(x, y) and(y, z) were calculated on the basis of these data. The positions of the atoms were refined three times by methods of differential syntheses and by geometrical analysis. The structure of CuPy₂Br₂ is very close to that of CuPy₂Cl₂ [1], [2], differing from it primarily in the orientation of the symmetry elements with respect to the crystallographic axes. In both structures the copper atom is octahedrally coordinated with four halogen and two nitrogen atoms. The nitrogen atoms and two bromine atoms are bound to the copper covalently in the structure of the bromine derivative, as follows from the length of the bonds (Cu-N 1.99 kXU, Cu-Br, 2.46 kXU), while the remaining two bromine atoms are bound to the copper by weaker bonds and mediate the chain formation of molecules in the direction of thec axis.

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Cu(C₅H₅N)₂Br₂

. , 2₁/ ==8,30 kX,b=17,72 kX,=4,04 kX,=96°,z=2. (, v) P(v, w), . (, ) (, z). . CuPy₂Br₂ u₂1₂, . . , (-N 1,99 kX, u-r 2,46 kX), .

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The authors thank M. Serátor for supplying the crystal samples and for initiating the work, the management of the Institute of Technical Physics, Czechoslovak Academy of Sciences, in Prague and especially Dr. A. Línek for making it possible to calculate some of the Fourier maps on the special computer Elika and finally A. lechtová for carefully calculating the Fourier maps and structure factors.

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The first stage of this work was reported on at the 3rd State Conference on Inorganic Chemistry, held in Bratislava from June 29th to July 4th, 1959.     

Charge Fluctuations in the Two-Dimensional One-Component Plasma

We study, via computer simulations, the fluctuations in the net electric charge in a two-dimensional, one component plasma (OCP) with uniform background charge density –e in a region inside a much larger overall neutral system. Setting e=1, this is the same as the fluctuations in N , the number of mobile particles of charge e. As expected, the distribution of N has, for large , a Gaussian form with a variance which grows only as ^||, where || is the length of the perimeter of . The properties of this system depend only on the coupling parameter =kT, which is the same as the reciprocal temperature in our units. Our simulations show that when the coupling parameter increases, ^() decreases to an asymptotic value ^()^(2)/2 which is equal (or very close) to that obtained for the corresponding variance of particles on a rigid triangular lattice. Thus, for large , the characteristic length _L=2^/ associated with charge fluctuations behaves very differently from that of the Debye length, _D1/ , which it approaches as 0. The pair correlation function of the OCP is also studied.     

The lateral photovoltaic effect in CdS-Cu2S heterojunction solar cell

The lateral photovoltaic effect has been observed in CdS-Cu₂S thin-film solar cells. The effect is more pronounced on the CdS side than on the Cu₂S side of the cells. On the CdS side, where the contacts were formed by soldering Cu wire by indium and then applying Ag paint, the photovoltage developed were found to increase as the point of illumination was moved towards the contact. The spectral response of photovoltage for coevaporated cells shows a peak at=0.5m (2.45 eV). But for topotaxial cells two peaks, one at=0.5m and the other at=0.65m (1.89eV) were observed. A band model has been proposed for the heat-treated optimized cells.     

Dynamics of the magnetization in the heavy fermion system CeCu6

We have studied CeCu₆ by inelastic neutron scattering. We found both quasielastic and also inelastic transitions, which we interpret as residual crystal field transitions. The quasielastic linewidth is a strongly nonlinear function of temperature, with approximately _QE=5.0 meV at 300 K, with a crossover _QE=kT at about 13 K and with a residual value of _QE=(0)=0.50 meV forT=0 K. Below 5 K the quasielastic intensityI _QE decreases linearly with temperature. _stI _QE/T is in good agreement with direct measurements of the static susceptibility. The data are fully consistent with a nonordering groundstate of CeCu₆.     

SPA-LEED studies of growth of Ag on Ag(111) at low temperatures

The surface morphology after deposition of Ag on Ag(111) at low temperatures (130–200 K) has been studied in detail with SPA-LEED (Spot-Profile Analysis of Low-Energy Electron Diffraction). The surface roughness and the mean terrace size have been quantitatively determined under various conditions. At 130 K the surface roughness increases with coverage exactly according to the relation = ^1/2, which indicates that the inter-layer diffusion can be neglected at 130 K. Although the mean terrace length decreases with increasing coverage (following an approximate power law of ^–2/3) for all studied coverages, it is much larger than expected for a pure random or Poisson-growth mode without any diffusion of the adatoms. Therefore, Ag grows on Ag(111) at this temperature without interlayer diffusion but with intra-layer diffusion. The intralayer diffusion barrierE _d has been determined by measuring the temperature dependence of the two-dimensional island density according to the nucleation theory (supposing a critical nucleus size of one). The obtained valueE _c=0.18 eV agrees with the theoretical calculations and previous measurements. Furthermore, from comparing measured and Monte-Carlo-simulated (MC) surface roughness at different deposition temperatures we obtain E=0.05 eV as a lower limit for the additional barrier at steps.     

General relativity is a gauge type theory

It is shown that the Einstein-Maxwell theory of interacting electromagnetism and gravitation, can be derived from a first-order Lagrangian, depending on the electromagnetic field and on the curvature of a symmetric affine connection on the space-time M. The variation is taken with respect to the electromagnetic potential (a connection on a U(1) principal fiber bundle on M) and the gravitational potential (a connection on the GL(4, R) principal fiber bundle of frames on M). The metric tensor g does not appear in the Lagrangian, but it arises as a momentum canonically conjugated to . The Lagrangians of this type are calculated also for the Proca field, for a charged scalar field interacting with electromagnetism and gravitation, and for a few other interesting physical theories.     

Monte Carlo study of the generalized reaction-diffusion lattice-gas model system

The reaction-diffusion lattice-gas model is an interacting particle system out of equilibrium whose microscopic dynamics is a combination of Glauber (reaction) and Kawasaki (diffusion) processes; the Glauber ratec(s; x) at sitex when the configuration iss satisfies detailed balance at temperatureT, while the Kawasaki ratec(s; x, y) between nearest-neighbor sitesx andy satisfies detailed balance at a different temperatureT. We report on the phase diagram of that system as obtained from a series of Monte Carlo simulations of steady states in two-dimensional lattices with arbitrary values forT,T, and; this generalizes previous analytical and numerical studies for and/orT. When the rates are implemented by the Metropolis algorithm, the system is observed to undergo various types of first- and second-order (nonequilibrium) phase transitions, e.g., one may identify Onsager (equilibrium) as well as Landau (mean-field) types of continuous phase transitions.Dedicated to Joel L. Lebowitz on the occasion of his 60th birthday.     

Radiation effects in the production and decay of ψ mesons by leptons

A new expression _e is obtained for resonance in the reaction e⁺e^– ar ^+– with allowance for the radiative corrections, which also contain the emission of hard photons by the final leptons and the final value of the energy resolution E. An expression is obtained for the total probability of radiative lepton decay. A numerical analysis of the experimental data is made for the reaction ^+–, and the parameters e⁺e^– (3, 1) e⁺e^–, and _e ² /, _e, and are determined for (3, 1) resonance-with allowance for the radiative corrections.This paper was read (November 17–21, 1975) at a session on high-energy physics of the Department of Nuclear Physics of the Academy of Sciences of the USSR.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 29–34, March, 1977.     

Characterization of the KNSBN: Cu crystal with two-wave coupling at visible and infrared wavelengths

We have optically characterized the newly-developed photorefractive crystal KNSBN: Cu by two-wave coupling at visible and near-infrared wavelengths. The effective electrooptic coefficients(k _g)r ₁₃ and(k _g)r ₃₃, the effective charge carrier densityN _eff, the dark conductivity _d, the product of mobility and electron-trap recombination time _R, the formation and decay rate of index grating and the absorption coefficient of the crystal were determined from visible to near-infrared wavelengths. Their wavelength dependences were also studied. It is interesting to notice that the KNSBN: Cu crystal has a very largeN _eff and large gain coefficient for ordinary ray (o-ray) in the visible region, and the photorefractive properties of the crystal are very different in the visible and near-infrared spectral regions.     

Monte Carlo simulation of phase separation and clustering in the ABV model

As a model for a binary alloy undergoing an unmixing phase transition, we consider a square lattice where each site can be either taken by an A atom, a B atom, or a vacancy (V), and there exists a repulsive interaction between AB nearest neighbor pairs. Starting from a random initial configuration, unmixing proceeds via random jumps of A atoms or B atoms to nearest neighbor vacant sites. In the absence of any interaction, these jumps occur at jump rates _A and _B, respectively. For a small concentration of vacancies (c _v=0.04) the dynamics of the structure factorS(k,t) and its first two momentsk ₁(t),k ₂ ² (t) is studied during the early stages of phase separation, for several choices of concentrationc _B of B atoms. Forc _B=0.18 also the time evolution of the cluster size distribution is studied. Apart from very early times, the mean cluster sizel(t) as well as the moments of the structure function depend on timet and the ratio of the jump rates (= _B/ _A) only via a scaled timet/(). Qualitatively, the behavior is very similar to the direct exchange model containing no vacancies. Consequences for phase separation of real alloys are briefly discussed.     

Mutual information functions versus correlation functions

This paper studies one application of mutual information to symbolic sequences: the mutual information functionM(d). This function is compared with the more frequently used correlation function(d). An exact relation betweenM(d) and(d) is derived for binary sequences. For sequences with more than two symbols, no such general relation exists; in particular,(d)=0 may or may not lead toM(d)=0. This linear, but not general, independence between symbols separated by a distance is studied for ternary sequences. Also included is the estimation of the finite-size effect on calculating mutual information. Finally, the concept of symbolic noise is discussed.     

Estimating the strength of chaos from the power spectrum

It is rigorously proved that for nonlinear dynamical systems whose time dependence is described by one dimensional, everywhere expanding maps, the width of broadband noise in the power spectrum is bounded by the generalized entropiesK ₂ andK ₃, which measure the strength of chaos in this system asK ₂2K ₃.Dedicated to Professor Harry Thomas on the occasion of his 60th birthday