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1.
We report the observation of non-photochemical laser-induced nucleation (NPLIN) of sodium chlorate from its melt using nanosecond pulses of light at 1064 nm. The fraction of samples that nucleate is shown to depend linearly on the peak power density of the laser pulses. Remarkably, we observe that most samples are nucleated by the laser back into the enantiomorph (dextrorotatory or levorotatory) of the solid prior to melting. We do not observe a significant dependence on polarization of the light, and we put forward symmetry arguments that rule out an optical Kerr effect mechanism. Our observations of retention of chirality can be explained by decomposition of small amounts of the sodium chlorate to form sodium chloride, which provide cavities for retention of clusters of sodium chlorate even 18 °C above the melting point. These clusters remain sub-critical on cooling, but can be activated by NPLIN via an isotropic polarizability mechanism. We have developed a heterogeneous model of NPLIN in cavities, which reproduces the experimental data using simple physical data available for sodium chlorate. 相似文献
2.
Park JW 《The journal of physical chemistry. B》2006,110(49):24915-24922
The kinetics of cyclodextrin (CD) inclusion complexation has been usually analyzed in terms of a one-step reaction or a consecutive two-step reaction involving intracomplex structural transformation as a second step. These schemes presume the inclusion of guest molecules through only one side of the CD cavity and the formation of unidirectional CD complexes. However, there has been increasing experimental evidence for the inclusion of guests through both sides of the CD cavity and the formation of orientational isomers for noncentrosymmetric guest molecules. This article presents a novel parallel reaction scheme for CD inclusion complexation, incorporating bidirectional inclusion and the formation of orientational isomers into the scheme. It is shown that the parallel reaction scheme gives the same concentration versus reaction time relationship as the consecutive two-step reaction scheme. The experimental methods for determining the microscopic directional rate constants are presented. The kinetic parameters of the two-step reaction scheme are expressed as functions of the directional rate constants. The ratios of orientational isomers of alpha-CD-based [2]-pseudorotaxanes and the microscopic directional rate constants of the threading and dethreading reactions are estimated from the reported thermodynamic and kinetics data obtained by using either the one-step or two-step reaction scheme. It is shown that the thermodynamic preference of an isomer over the other is mainly due to the slow dethreading rate of the isomer. 相似文献
3.
Many experimental reports for the kinetics of crystal nucleation and growth, from an isothermal solution, point to a sigmoidal-like behavior for the process. Here we consider three different nucleation models from the literature and show that all lead to sigmoidal or sigmoidal-like behavior for the kinetics of nucleation. A two-step nucleation process is known to occur within certain supersaturated protein solutions, and it is demonstrated in this report how the sigmoidal law yields kinetic information for the two-step and homogeneous nucleation modes. We propose here that two-step solute-rich associates form in the solution around seed nuclei that are already present at or near the point in time when the solution is prepared. Using this hypothesis, we are able to model the time-dependent volume of the two-step phase per unit volume of solution and show that this compares well with reported experimental data. A kinetic model is given for the proposed process, which leads to a sigmoidal rate law. Additionally, a relation between the initial and final nuclei densities and the induction time is derived. As a result of this study, the conclusion is that two-step activity increases with increasing initial supersaturation or increasing salt concentration. 相似文献
4.
Non-photochemical laser-induced nucleation (NPLIN) of glacial acetic acid (GAA) is demonstrated. The fraction of samples nucleated depends linearly on peak laser power density at low powers (<100 MW cm(-2)) with a threshold of (9.0 ± 4.2) MW cm(-2); at higher laser powers the fraction reaches a plateau of 0.75 ± 0.24 (2σ uncertainties). A simple model based on polarizability of pre-nucleating clusters gives a value of the solid-liquid interfacial tension γ(SL) = 15.5 mJ m(-2). It is hoped that the results will stimulate new developments in experimental and theoretical studies of cluster structure and nucleation in liquids. 相似文献
5.
When the nucleation of a stable crystalline phase directly in a supersaturated old phase is greatly retarded, the crystal nuclei might nucleate within faster-forming particles of an intermediate phase. Here we present a theoretical investigation of the kinetics of this two-step nucleation of crystals and derive general expressions for the time dependence of the number of crystals nucleated within the particles of the intermediate phase. The results reveal that crystal nucleation can be strongly delayed by the slow growth of the particles and/or by the slow nucleation of the crystals in them. Furthermore, the linear part of the time dependence of the number of nucleated crystals is determined by the formation rate of the intermediate particles. This is in contrast with the one-step nucleation of crystals when this linear part is determined by the rate of crystal nucleation directly in the old phase. Criteria are proposed for distinction between the one- and two-step nucleation mechanisms, based on the supersaturation dependence of the delay time for nucleation. The application of the theoretical approach to the analysis of experimental data on the nucleation of crystals and other ordered aggregates of protein and other soluble materials is discussed. 相似文献
6.
The time-resolved orientational anisotropies of the OD hydroxyl stretch of dilute HOD in H(2)O confined on a nanometer length scale in sodium bis(2-ethylhexyl) sulfosuccinate (AOT) reverse micelles are studied using ultrafast infrared polarization and spectrally resolved pump-probe spectroscopy, and the results are compared to the same experiments on bulk water. The orientational anisotropy data for three water nanopool sizes (4.0, 2.4, and 1.7 nm) can be fitted well with biexponential decays. The biexponential decays are analyzed using a wobbling-in-a-cone model that involves fast orientational diffusion within a cone followed by slower, full orientational relaxation. The data provide the cone angles, the diffusion constants for motion within the cones, and the final diffusion constants as a function of the nanopool size. The two processes can be interpreted as a local angular fluctuation of the OD and a global hydrogen bond network rearrangement process. The trend in the relative amplitudes of the long and short exponential decays suggest an increasing rigidity as the nanopool size decreases. The trend in the long decay constants indicates a longer hydrogen bond network rearrangement time with decreasing reverse micelle size. The anisotropy measurements for the reverse micelles studied extrapolate to approximately 0.33 rather than the ideal value of 0.4, suggesting the presence of an initial inertial component in the anisotropy decay that is too fast to resolve. The very fast decay component is consistent with initial inertial orientational motion that is seen in published molecular-dynamics simulations of water in AOT reverse micelles. The angle over which the inertial orientational motion occurs is determined. The results are in semiquantitative agreement with the molecular-dynamics simulations. 相似文献
7.
Monte Carlo simulations of homogeneous nucleation for a protein model with an exceedingly short-ranged attractive potential yielded a nonconventional crystal nucleation mechanism, which proceeds by the formation of fractal, low-dimensional aggregates followed by a concurrent collapse and increase of the crystallinity of these aggregates to become compact ordered nuclei. This result corroborates a recently proposed two-step mechanism for protein crystal nucleation from solution. 相似文献
8.
Using computer simulations, we investigate the homogeneous crystal nucleation in suspensions of colloidal hard dumbbells. The free energy barriers are determined by Monte Carlo simulations using the umbrella sampling technique. We calculate the nucleation rates for the plastic crystal and the aperiodic crystal phase using the kinetic prefactor as determined from event driven molecular dynamics simulations. We find good agreement with the nucleation rates determined from spontaneous nucleation events observed in event driven molecular dynamics simulations within error bars of one order of magnitude. We study the effect of aspect ratio of the dumbbells on the nucleation of plastic and aperiodic crystal phases, and we also determine the structure of the critical nuclei. Moreover, we find that the nucleation of the aligned close-packed crystal structure is strongly suppressed by a high free energy barrier at low supersaturations and slow dynamics at high supersaturations. 相似文献
9.
Structure and dynamics of surfactant and hydrocarbon aggregates on graphite: a molecular dynamics simulation study 总被引:1,自引:0,他引:1
Sammalkorpi M Panagiotopoulos AZ Haataja M 《The journal of physical chemistry. B》2008,112(10):2915-2921
We have examined the structure and dynamics of sodium dodecyl sulfate (SDS) and dodecane (C12) molecular aggregates at varying surface coverages on the basal plane of graphite via classical molecular dynamics simulations. Our results suggest that graphite-hydrocarbon chain interactions favor specific molecular orientations at the single-molecule level via alignment of the tail along the crystallographic directions. This orientational bias is reduced greatly upon increasing the surface coverage for both molecules due to intermolecular interactions, leading to very weak bias at intermediate surface coverages. Interestingly, for complete monolayers, we find a re-emergent orientational bias. Furthermore, by comparing the SDS behavior with C12, we demonstrate that the charged head group plays a key role in the aggregate structures: SDS molecules display a tendency to form linear file-like aggregates while C12 forms tightly bound planar ones. The observed orientational bias for SDS molecules is in agreement with experimental observations of hemimicelle orientation and provides support for the belief that an initial oriented layer governs the orientation of hemimicellar aggregates. 相似文献
10.
Elola MD Ladanyi BM Scodinu A Loughnane BJ Fourkas JT 《The journal of physical chemistry. B》2005,109(50):24085-24099
In this work we have studied the relaxation dynamics of the many-body polarizability anisotropy in liquid mixtures of benzene (Bz) and hexafluorobenzene (Hf) at room temperature by femtosecond optical heterodyne-detected Raman-induced Kerr effect spectroscopy (OHD-RIKES) experiments and molecular dynamics (MD) simulations. The computed polarizability response arising from intermolecular interactions was included using the first-order dipole-induced-dipole model with the molecular polarizability distributed over the carbon sites of each molecule. We found good qualitative agreement between experiments and simulations in the features exhibited by the nuclear response function R(t) for pure liquids and mixtures. The long-time diffusive decay of R(t) was observed to vary substantially with composition, slowing down noticeably with dilution of each of the species as compared with that in the corresponding pure liquids. MD simulation shows that the effect on R(t) is due to the formation of strong and localized intermolecular association between Bz and Hf species that hinder the rotational diffusive dynamics. The formation of these Bz-Hf complexes in the liquid mixtures also modifies the rotational diffusive dynamics of the component species in such a way that cannot be explained solely in terms of a viscosity effect. Even though the computed orientational diffusive relaxation times associated with Bz and Hf are larger by a factor of approximately 2 than those from experiments, we found similar trends in experiments and simulations for these characteristic times as a function of composition. Namely, the collective and single-molecule orientational correlation times associated with Bz are observed to grow monotonically with the dilution of Bz, while those corresponding to Hf species exhibit a maximum at the equimolar composition. We attribute the quantitative discrepancy between experiments and simulations to the use of the Williams potential, which seems to overestimate the intermolecular interactions and thus predicts not only a slower translational dynamics but also a slower rotational diffusion dynamics than in real fluids. 相似文献
11.
With the help of ultrafast time-resolved infrared spectroscopy, we investigate rotational diffusion of cis- and trans-nitrous acid (HONO) in solid Kr at 30 K, as well as its reorientation upon the IR-driven cis-->trans isomerization. We find different mobilities for the two isomers: cis-HONO is pinned to the matrix with no decay of the anisotropy on the 100 ns time scale, whereas trans-HONO rotates around its long axis, reducing its anisotropy partially on that time scale. The long axis itself, defined by the terminal oxygen and hydrogen atoms of HONO, stays fixed on even a minute time scale. Accompanying molecular dynamics simulations reproduce the anisotropic rotational diffusion of trans-HONO correctly, although on a completely wrong time scale, whereas they would predict complete reorientation of cis-HONO within approximately 10 ps, in harsh disagreement with the experiment. We attribute the mismatch of orientational time scales to either too soft interaction potentials or to the fact that HONO occupies an interstitial rather than a monosubstitutional matrix site. The experiments furthermore show that the direction of the OH bond hardly changes during the IR-driven cis-->trans isomerization, in contrast to the intuitive picture that it is mostly the light hydrogen which moves. Rather, it is the two central nitrogen and oxygen atoms that are removed during isomerization in a hula hoop fashion, whereas the terminal atoms are still pinned to the matrix cage. 相似文献
12.
根据热力学微扰理论研究了Aa型Patchy胶体的相态结构,考察了Patch之间的缔合强度及Patch数目对体系相态结构的调控机制.利用相平衡原理给出了Patchy胶体的流体、玻璃态固体和面心立方晶体之间转变及溶胶-凝胶转变的相图,讨论了玻璃态和晶态固相的成核机制、临界现象和相变问题.研究结果表明,Patchy胶体粒子之间的缔合作用和Patch数目可以显著地调控体系的三相点、临界温度和临界密度等特征.在高温条件下,Patchy胶体以一次成核方式结晶;而在低温条件下则以两步成核方式逐步成核结晶,中间经过非晶态的玻璃态固相作为过渡.说明Patchy粒子之间的缔合作用对其相态结构具有决定性影响,因而成为调控体系聚集态结构的重要因素. 相似文献
13.
Ultrafast structural studies of laser-induced melting have demonstrated that the solid-liquid phase transition can take place on a picosecond time scale in a variety of materials. Experimental studies using ?ngstr?m wavelength X-rays from the sub-picosecond pulse source at Stanford (now retired) on non-thermal melting of semi-conductors, such as indium antimonide, employed the decay of a single Bragg-peak to measure the time component of the phase transition. These materials were found to start melting within one picosecond after the laser pulse. Recent computer simulations have described the thermal melting of ice induced by an infrared laser pulse. Here it was shown that melting can happen within a few picoseconds, somewhat slower than non-thermal melting in semi-conductors. These computer simulations are compatible with spectroscopy experiments on ice-melting, demonstrating that simulations form a very powerful complement to experiments targeting the process of phase-transitions. Here we present an overview of recent experimental and theoretical studies of melting, as well as new simulations of ice-melting where the effect of the size of the crystal on scattering is studied. Based on simulations of a near-macroscopic crystal, we predict the decay of the most intense Bragg peaks of ice following heating by laser pulse, by modeling the scattering from the melting sample in the simulations. 相似文献
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In this work, we performed Monte Carlo simulations on a lattice model for spontaneous amphiphilic aggregation, in order to study the orientational and hydrogen-bonding dynamics of water on different regions inside the micellar solution. We employed an associating lattice gas model that mimics the aqueous solvent, which presents a rich phase diagram with first- and second-order transition lines. Even though this is a simplified model, it makes possible to investigate the orientational dynamics of water in an equilibrium solution of amphiphiles, as well as the influence of the different phases of the solvent in the interfacial and bulk water dynamics. By means of extensive simulations, we showed that, at high temperatures, the behavior of the orientational relaxation and hydrogen bonding of water molecules in the bulk, first, and second hydration shells are considerable different. We observe the appearance of a very slow component for water molecules in the first hydration shell of micelles when the system reaches a high-density phase, consistent with previous theoretical and experimental studies concerning biological water. Also, at high temperatures, we find that water molecules in the second hydration shell of micelles have an orientational decay similar to that of bulk water, but with a generally slower dynamics. Otherwise, at low temperatures, we have two components for the orientational relaxation of bulk water in the low density liquid phase, and only a single component in the high density liquid (HDL) phase, which reflect the symmetry properties of the different phases of the solvent model. In the very dense region of water molecules in the first hydration shell of micelles at low temperatures, we find two components for the orientational relaxation on both liquid phases, one of them much slower than that in the single component of bulk water in the HDL phase. This happens even though our model does not present any hindrance to the water rotational freedom caused by the presence of the amphiphiles. 相似文献
17.
We present a hybrid method to investigate the isotropic-nematic (I-N) transition in athermal solutions of rod-coil copolymers. This method incorporates the scaled-particle theory for semiflexible chains with two-chain Monte Carlo simulation for the osmotic second virial coefficient and for the angle-dependent excluded volume. We compare the theoretical prediction with Monte Carlo simulations for fused rod-coil copolymers and find good agreement for both the equation of state and the orientational order parameter. The theory is also used to examine the effects of the bond length, the chain length, and the chain composition on orientational ordering in athermal solutions of rod-coil block copolymers. It predicts I-N transition in rod-coil copolymers with fixed rod length but a variable flexible tail in good agreement with experiments. 相似文献
18.
The standard industrial process of blade-coating is now being used to produce new liquid crystal displays (LCDs) in which a liquid crystal and optical layers are coated onto a substrate. Motivated by this new LCD manufacturing process, we use the Ericksen-Leslie equations to develop a simple mathematical model for blade coating of a nematic liquid crystal. The direction and uniformity of the director are important factors for the performance of the displays, particularly when this alignment is 'frozen in' within optical layers. For this reason we investigate the flow and director within a liquid crystal film both after emerging from the region under a blade (the so-called 'drag-out' problem) and before entering the region under a blade (the so-called 'drag-in' problem). We restrict our attention to thin films and small director angles, and we study two particular cases in which either orientational elasticity effects or flow effects dominate the alignment of the liquid crystal. We find that there is a unique solution of the drag-out problem, whereas there may be multiple solutions of the drag-in problem. When orientational elasticity effects dominate we obtain a simple analytical solution for the director. When flow effects dominate we find that the director is uniform in the bulk of the liquid crystal, which exhibits thin orientational boundary layers near the substrate and the free surface, within which the director orientation changes rapidly from its prescribed boundary value to the flow alignment angle. These boundary layers may be potential locations for the nucleation of defects. 相似文献
19.
The net mass transfer resistance for gas molecules permeating through zeolite membranes includes contributions from intracrystalline diffusion and contributions from interfacial effects. These interfacial effects can arise either from gas-zeolite interfaces or from interfaces that exist within zeolite crystals due to grain boundaries. We present the first atomically detailed simulations that examine interfacial mass transfer resistance due to internal grain boundaries in zeolites that are relevant for membrane applications. Our calculations examine twinned silicalite crystals in crystallographic configurations that have been identified in previous experiments. We used the dual control volume grand canonical molecular dynamics method to simulate the permeance of CH(4) and CF(4) through thin twinned silicalite crystals. The magnitudes of the grain boundary resistances are quite substantial, at least for the thin crystals that are accessible in our simulations. 相似文献
20.
The supercooling capability of aqueous NaCl and KCl solutions is investigated at containerless state by using acoustic levitation method. The supercooling of water is obviously enhanced by the alkali metal ions and increases linearly with the augmentation of concentrations. Furthermore, the supercooling depends on the nature of ions and is 2-3 K larger for NaCl solution than that for KCl solution in the present concentration range: Molecular dynamics simulations are performed to reveal the intrinsic correlation between supercoolability and microstructure. The translational and orientational order parameters are applied to quantitatively demonstrate the effect of ionic concentration on the hydrogen-bond network and ice melting point. The disrupted hydrogen-bond structure determines essentially the concentration dependence of supercooling. On the other hand, the introduced acoustic pressure suppresses the increase of supercooling by promoting the growth and coalescence of microbubbles, the effective nucleation catalysts, in water. However, the dissolved ions can weaken this effect, and moreover the degree varies with the ion type. This results in the different supercoolability for NaCl and KCl solutions under the acoustic levitation conditions. 相似文献