集合预报物理基础的探讨

将集合预报中的每次积分算程视为非平衡统计物理理论中的准粒子轨迹，由此对Lorenz模型 进行了数值试验，计算了初值位于不同性质平衡态附近时准粒子数处于基态和第一激发态随 时间的演化.结果证明：(1)若动力系统在整个相空间内存在稳定的平衡态，在稳定的平衡态 附近，系统随时间长期演化行为是可预测的.(2)若动力系统在整个相空间内不存在任何稳定 的平衡态，初值位于远离非稳定的平衡态，则在1—2周内准粒子多数分布在低能量态，即预 报是最可几率的.(3)若初始状态位于非稳定平衡态附近，系统随时间的演化几乎是不可预测 的.这从理论上说明了作大量积分算程的集合预报其效果会比单一初值的单程积分要好.这就 从物理上对集合预报能提高准确率提供了一种解释. 关键词： 集合预报 Lorenz模型 正则分布 概率密度分布     

Quantum mechanical state preparation II-The statistical ensemble as a thermostat

In this sequel to an earlier paper on quantal state preparation (Park & Band, 1972), the simple model used before is adapted and somewhat generalised to enable an exact treatment of the causal evolution of a system immersed in a statistical ensemble constituted of replicas of the system itself. The ensemble is initially in a state of statistical equilibrium, but the initial state of the system is arbitrary. It is established as a purely dynamical theorem that the system is eventually coerced into the same equilibrium state as that of the replicas in the ensemble. From this general result we obtain as a special case mechanical justification for the common assumption in statistical thermodynamics that an ensemble can function as a thermostat.     

Optical properties of nonequilibrium low-dimensional systems

The optical properties of low-dimensional carrier systems ("quantum wire" type) driven away from equilibrium are studied. The frequency and wave-vector-dependent dielectric function of a quasi-one-dimensional electron system under the action of an exciting external pumping source is derived. The optical responses of the system are obtained in terms of its nonequilibrium thermodynamic state, the latter characterized resorting to a nonequilibrium statistical ensemble formalism.     

Thermodynamics of one-dimensional nonlinear lattices

Analytic equations were obtained for the thermodynamic parameters of one-dimensional lattices of particles with the Toda and Morse interaction potentials in a canonical Gibbs ensemble. For the same systems, equations were derived for molecular dynamics simulations of thermodynamic processes. Stochastic differential equations were solved with simulating the thermostat by Langevin sources with random forced. Analytic equations for thermodynamic parameters (energy, temperature, and pressure) excellently coincided with molecular dynamics simulation results. The kinetics of system relaxation to the thermodynamic equilibrium state was analyzed. The advantages of simulating the physical properties of systems in a canonical compared with microcanonical ensemble were demonstrated.     

Observation of a 1/t decay law for hot clusters and molecules in a storage ring

The exponential law is valid both for decay from a single quantum state into a continuum and for an ensemble maintained in thermal equilibrium. For statistical decay of an ensemble of isolated systems with a broad energy distribution, the exponential decay is replaced by a 1/t distribution. We present confirmation of this decay law by experiments with cluster anions in a small electrostatic storage ring. Deviations from the 1/t law for such an ensemble give important information on the dynamics of the systems. As examples, we present measurements revealing strong radiative cooling of anions of both metal clusters and fullerenes.     

Reduced density matrices of a system of N coupled oscillators 2. eigenstructure of the 1-particle matrix for the canonical ensemble

The following theorem is proved: The reduced 1-particle density matrix corresponding to an equilibrium state of a system of N coupled oscillators coincides with the density matrix of a canonical ensemble of free oscillators at some effective temperature.     

Surface pressure in clusters and small particles—is it real?

Using the methods of statistical mechanics and applying the conditions of thermal equilibrium for an ensemble of interacting molecules, it is proved that there is no excess pressure, nor internal and surface stresses, in clusters and small particles that are not subjected to the action of external forces. With this premise taken into account the thermodynamics of spherical and faceted small particles is developed. In a particle-vapour system surrounded by a rigid impervious shell, Kelvin's and Thomson's formulae and Wulff's rule are derived. For a particle-melt system at a constant external pressure it is expected that the melting points of a particle and a bulk solid should be equal. It is noted that, if a particle is not subjected to the action of external fields or bodies, its molecules occupy their natural equilibrium positions, and it is from them that deformations and internal stresses should be counted off. These equilibrium positions differ from those occupied by the same molecules in a bulk solid, which is what usually gives rise to the illusions of the stressed state of a small particle and its deformation caused by the “uncompensated” surface forces.     

On the Fluctuation Relation for Nosé-Hoover Boundary Thermostated Systems

We discuss the transient and steady state fluctuation relation for a mechanical system in contact with two deterministic thermostats at different temperatures. The system is a modified Lorentz gas in which the fixed scatterers exchange energy with the gas of particles, and the thermostats are modelled by two Nosé-Hoover thermostats applied at the boundaries of the system. The transient fluctuation relation, which holds only for a precise choice of the initial ensemble, is verified at all times, as expected. Times longer than the mesoscopic scale, needed for local equilibrium to be settled, are required if a different initial ensemble is considered. This shows how the transient fluctuation relation asymptotically leads to the steady state relation when, as explicitly checked in our systems, the condition found in (D.J. Searles, et al., J. Stat. Phys. 128:1337, 2007), for the validity of the steady state fluctuation relation, is verified. For the steady state fluctuations of the phase space contraction rate Λ and of the dissipation function Ω, a similar relaxation regime at shorter averaging times is found. The quantity Ω satisfies with good accuracy the fluctuation relation for times larger than the mesoscopic time scale; the quantity Λ appears to begin a monotonic convergence after such times. This is consistent with the fact that Ω and Λ differ by a total time derivative, and that the tails of the probability distribution function of Λ are Gaussian.     

Metastability for Markov processes with detailed balance

We present a definition for metastable states applicable to arbitrary finite state Markov processes satisfying detailed balance. In particular, we identify a crucial condition that distinguishes metastable states from other slow decaying modes and which allows us to show that our definition has several desirable properties similar to those postulated in the restricted ensemble approach. The intuitive physical meaning of this condition is simply that the total equilibrium probability of finding the system in the metastable state is negligible.     

Microscopic Analysis of Clausius–Duhem Processes

Given a thermodynamic process which carries a system from one equilibrium state to another, we construct a quantity whose average, over an ensemble of microscopic realizations of the process, depends only on these end states, even if at intermediate times the system is out of equilibrium. This result (1) can be used to express the entropy difference between two equilibrium states in terms of an irreversible process connecting them, (2) leads to two statistical statements of the Clausius–Duhem inequality, and (3) can be generalized to situations in which the system begins and/or ends in nonequilibrium states.     

Peculiarities of the rotational dynamics of an ensemble of diatomic homonuclear molecules in a strong laser field

The rotational dynamics of an ensemble of molecules in a laser field has been studied. The results obtained within the framework of the quantum-mechanical and classical approaches have been compared. The features of the rotational dynamics connected with the non-classical character of the system have been described. It was taken into account that before the interaction with a laser pulse the ensemble was in a thermodynamically equilibrium mixed state. The case of an ultrashort laser pulse has been considered as well.     

Gravitational phase transitions with an exclusion constraint in position space

We discuss the statistical mechanics of a system of self-gravitating particles with anexclusion constraint in position space in a space of dimension d. Theexclusion constraint puts an upper bound on the density of the system and can stabilize itagainst gravitational collapse. We plot the caloric curves giving the temperature as afunction of the energy and investigate the nature of phase transitions as a function ofthe size of the system and of the dimension of space in both microcanonical and canonicalensembles. We consider stable and metastable states and emphasize the importance of thelatter for systems with long-range interactions. For d ≤ 2, there is nophase transition. For d > 2, phase transitions can take place betweena “gaseous” phase unaffected by the exclusion constraint and a “condensed” phase dominatedby this constraint. The condensed configurations have a core-halo structure made of a“rocky core” surrounded by an “atmosphere”, similar to a giant gaseous planet. For largesystems there exist microcanonical and canonical first order phase transitions. Forintermediate systems, only canonical first order phase transitions are present. For smallsystems there is no phase transition at all. As a result, the phase diagram exhibits twocritical points, one in each ensemble. There also exist a region of negative specificheats and a situation of ensemble inequivalence for sufficiently large systems. We showthat a statistical equilibrium state exists for any values of energy and temperature inany dimension of space. This differs from the case of the self-gravitating Fermi gas forwhich there is no statistical equilibrium state at low energies and low temperatures whend ≥ 4. By a proper interpretation of the parameters, our results haveapplication for the chemotaxis of bacterial populations in biology described by ageneralized Keller-Segel model including an exclusion constraint in position space. Theyalso describe colloids at a fluid interface driven by attractive capillary interactionswhen there is an excluded volume around the particles. Connexions with two-dimensionalturbulence are also mentioned.     

声子库的量子态对介观电路量子特性影响的研究

考虑电子与声子间相互作用,研究了两种声子库纯初始态(正则系综与粒子数态)下耗散介观电路的动力学特性.长时间极限下(t→∞)：当环境处于热平衡态时,电路系统中的电流和电荷的平均值只与电路所处初始量子态中的平均值有关,与环境无关;环境初态为粒子数态时,电荷与电流平均值随时间的演化特性与环境初始处于热平衡态下时完全一样,表明介观电路中的电荷与电流的平均值与环境量子态的某组占有数无关.电路中电流和电荷的量子涨落不仅与系统的初态有关,还与系统所处环境的量子态及温度有关.一般地说,电路系统与环境的纠缠会 关键词： 介观耗散电路 声子库 量子初态 量子态纯度     

A definition of metastability for Markov processes with detailed balance

A definition of metastable states applicable to arbitrary finite state Markov processes satisfying detailed balance is discussed. In particular, we identify a crucial condition that distinguishes genuine metastable states from other types of slowly decaying modes and which leads to properties similar to those postulated in the restricted ensemble approach [1]. The intuitive physical meaning of this condition is simply that the total equilibrium probability of finding the system in the metastable state is negligible. As a concrete application of our formalism we present preliminary results on a 2D kinetic Ising model.     

Decay of a thermofield-double state in chaotic quantum systems

Scrambling in interacting quantum systems out of equilibrium is particularly effective in the chaotic regime. Under time evolution, initially localized information is said to be scrambled as it spreads throughout the entire system. This spreading can be analyzed with the spectral form factor, which is defined in terms of the analytic continuation of the partition function. The latter is equivalent to the survival probability of a thermofield double state under unitary dynamics. Using random matrices from the Gaussian unitary ensemble (GUE) as Hamiltonians for the time evolution, we obtain exact analytical expressions at finite N for the survival probability. Numerical simulations of the survival probability with matrices taken from the Gaussian orthogonal ensemble (GOE) are also provided. The GOE is more suitable for our comparison with numerical results obtained with a disordered spin chain with local interactions. Common features between the random matrix and the realistic disordered model in the chaotic regime are identified. The differences that emerge as the spin model approaches a many-body localized phase are also discussed.     

Study on Quantum Entanglement Between Mesoscopic Circuit and Environment at Coherent State

Taking into account the interaction between electrons and phonons, in the case without-rotating-wave approximation, we study the entangling property between the mesoscopic circuit and environment at coherent state or equilibrium state. The result indicates that, in long time limit t→∞, the averages of charge and current in the circuit only depend on the average of the system at the initial state when the environment is initially at thermal equilibrium. However, when the environment is initially at coherent state, the average of charge and current in the circuit is determined by the specific coherent state ensemble. Generally speaking, the entanglement between the circuit and environment will lead to the quantum state purity declining of the circuit, then the circuit emerges decoherent phenomenon, and so a mixed state appears. Purity changes are related to the initial quantum state of environment and circuit. With the further evolution of time, coherence will be gradually restored, but cannot return to 1.     

Nonequilibrium Measurements of Free Energy Differences for Microscopically Reversible Markovian Systems

An equality has recently been shown relating the free energy difference between two equilibrium ensembles of a system and an ensemble average of the work required to switch between these two configurations. In the present paper it is shown that this result can be derived under the assumption that the system's dynamics is Markovian and microscopically reversible.     

Form of growing strings

Patterns and forms adopted by nature are often the results of simple dynamical paradigms. Here we show that a growing self-interacting string attached to a tracking origin, modeled to resemble nascent polypeptides in vivo, develops helical structures which are more pronounced at the growing end. We also show that the dynamic growth ensemble shares several features of an equilibrium ensemble in which the growing end of the polymer is under an effective stretching force. A statistical analysis of native states of proteins shows that the signature of this nonequilibrium phenomenon has been fixed by evolution at the C terminus, the growing end of a nascent protein. These findings suggest how evolution may have built on the properties of a generic nonequilibrium growth process in favoring helical structures in nascent chains.