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Robin J. Francis P. Shiv Halasyamani Dermot O'Hare 《Angewandte Chemie (International ed. in English)》1998,37(16):2214-2217
A new series of layered organically templated uranium(IV ) fluorides has been exclusively synthesized under hydrothermal conditions. The unprecedented materials contain [U2F10]2− anionic layers that are separated by charge balancing cationic templates and occluded water molecules (see structure depicted). The templates can be fully ion-exchanged for a variety of metals (Na+, K+, and Co2+) at room temperature. 相似文献
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