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1.
Heterocyclic nitro compounds 总被引:1,自引:0,他引:1
M. S. Pevzner T. N. Kulibabina N. A. Povarova L. V. Kilina 《Chemistry of Heterocyclic Compounds》1979,15(8):929-932
2.
L. I. Bagal M. S. Pevzner V. Ya. Samarenko A. P. Egorov 《Chemistry of Heterocyclic Compounds》1970,6(5):650-652
Reaction of 1-methyl-3,5-dinitro-1,2,4-triazole with alcohols or phenols in the presence of bases (tertiary amines) leads to replacement of the nitro group in the 5-position by an alkoxy or phenoxy group.For part IV, see [1].Translated from Khimiya Geterotsiklicheskikh Soedinenii, Vol. 6, No. 5, pp. 702–704, May, 1970. 相似文献
3.
T. P. Kofman T. L. Uspenskaya N. Yu. Medvedeva M. S. Pevzner 《Chemistry of Heterocyclic Compounds》1976,12(7):821-824
A number of triazolylpropanones were synthesized by oxidation of 1-(2-hydroxypropyl)-3-nitro-5-R-1,2,4-triazoles obtained by condensation of 3-nitro-5-R-1,2,4-triazoles with propylene oxide. Similar triazolylbutanones were obtained by reaction of 3-nitro-5-R-1,2,4-triazoles with methyl vinyl ketone.See [1] for communication XIX.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 991–994, July, 1976. 相似文献
4.
L. I. Bagal M. S. Pevzner A. P. Egorov V. Ya. Samarenko 《Chemistry of Heterocyclic Compounds》1970,6(7):928-931
Depending on the conditions and nature of the hydrazine derivative, the reaction of 1-methyl-3,5-dinitro-1,2,4-triazole (I) with hydrazine leads either to the replacement of one of the nitro groups by a hydrazine residue or to its reduction to an amino (hydroxylamino) group. In both cases, the reaction takes place in position 5 of the triazole ring. The reaction of I with acetylhydrazine gives 5-azido-1-methyl-3-nitro-1,2,4-triazole.For Communication V, see [11].Translated from Khimiya Geterotsiklicheskikh Soedinenii, Vol. 6, No. 7, pp. 997–1000, July, 1970. 相似文献
5.
Heterocyclic nitro compounds 总被引:1,自引:0,他引:1
Reaction of 1-methyl-3, 5-dinitro-1, 2, 4-triazole with aliphatic amines results in the replacement of the nitro group in the 5-position of the triazole ring by the amino group. Some reactions of the compounds obtained have been investigated.For part II, see [1]. 相似文献
6.
L. I. Bagal M. S. Pevzner V. Ya. Samarenko A. P. Egorov 《Chemistry of Heterocyclic Compounds》1970,6(12):1588-1591
The reaction of 3(5)-nitro-1,2,4-triazole with hydrogen halides (HCl and HBr) leads to replacement of the nitro group by chlorine and bromine. In 1-methyl-3,5-dinitro-1,2,4-triazole the nitro group in the 5 position is replaced. Nucleophilic substitution of halogen in 1-methyl-3-nitro-5-halotriazoles leads to the formation of the corresponding 1-methyl-3-nitro-5-substituted 1,2,4-triazoles.See [1] for Communication VI.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1701–1703, December, 1970. 相似文献
7.
The kinetics of the reaction of 1-methyl-3-nitro-5-chloro-1,2,4-triazoles and 1-methyl-3-nitro-5-bromo-1,2,4-triazoles with hydroxide ions were studied. The reaction leads to replacement of the halogen or nitro group, and the ratio of the rates of substitution is 301. The mutual influence of the halogen and nitro group on the rate of substitution as a function of their position in the ring was examined.See [1] for communication XIV.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 848–851, June, 1972. 相似文献
8.
Heterocyclic nitro compounds 总被引:1,自引:0,他引:1
M. S. Pevzner T. N. Kulibabina L. A. Malinina 《Chemistry of Heterocyclic Compounds》1979,15(4):451-455
1,2,4-Triazole, 3(5)-R-1,2,4-triazoles (R=CH3, CL, Br, NO2), and their N-trimethylsilyl derivatives were nitrated with nitronium salts. The products were N-nitro-1,2,4-triazoles, which split out the nitro group under the influence of acids and undergo rearrangement to 3-nitrotriazoles when they are heated in inert solvents. When R=NO2, a dinitrotriazole is not formed, and the starting 3-nitro-1,2,4-triazole is recovered.See [1] for communication 21.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 550–554, April, 1979. 相似文献
9.
V. V. Mel'nikov V. V. Stolpakova M. S. Pevzner 《Chemistry of Heterocyclic Compounds》1971,7(3):377-380
The MO LCAO method with the Hückel approximation was used to calculate the -electron densities, the bond orders, and the energies of the -electron interaction of a number of 1,2,4-triazole derivatives. The results obtained agree satisfactorily with the chemical and physicochemical properties of the triazoles.See [1] for communication IX.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 409–413, March, 1971. 相似文献
10.
M. S. Pevzner E. Ya. Fedorova I. N. Shokhor L. I. Bagal 《Chemistry of Heterocyclic Compounds》1971,7(2):252-254
The dipole moments of some 3(5)-nitro-1,2,4-triazoles in dioxane were measured. Hydrogen is attached to the N1 heteroatom in nitrogen-unsubstituted 3-nitrotriazoles. The dipole moments of the triazoles in chloroform are lower than in dioxane.See [1] for communication VIII.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 275–278, February, 1971. 相似文献
11.
T. P. Kofman N. Yu. Medvedeva T. L. Uspenskaya M. S. Pevzner 《Chemistry of Heterocyclic Compounds》1977,13(9):1026-1029
Ketones of the 3-nitro-5-R-1,2,4-triazole series react with hydrazoic acid in concentrated sulfuric acid to give triazolyl-substituted acetamides. Acid hydrolysis of the latter leads to 1-aminoalkyl-3-nitro-5-R-1,2,4-triazoles. Intramolecular cyclization with the elimination of HNO2 and the formation of 2-nitro-5,6-dihydro-1H-imidazo[2,3-b]-1,2,4-triazole was noted in the case of 1-(2-aminoethyl)-3,5-dinitro-1,2,4-triazole.See [1] for communication XX.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1271–1273, September, 1977. 相似文献
12.
The IR and Raman spectra of a number of anions of the nitro derivatives of 1,2,4-triazole were investigated. On the basis of the position of the absorption maxima of the asymmetric and symmetric t vibrations of the nitro group, it is assumed that the nitro groups in the 3 and 5 positions of the triazole ring are coplanar, which should lead to an increase in the participation of the nitro group in the de localization of the negative charge of the anion. Shifts of the frequencies as a function of the nature of the cation (NH4, Na, K, Cs) were not detected in the IR spectra of the crystalline salts. In addition, the IR spectra of the crystalline salts are similar (with respect to the frequencies) to the spectra of aqueous solutions of the salts, which may serve as proof of the identical structure of the anions in crystals and aqueous solutions.See [1] for communication XII.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 120–123, January, 1972. 相似文献
13.
The kinetics of the substitution of a nitro group by a hydroxyl group in 1-methyl-3-nitro-,1-methyl-5-nitro-, and 3-nitro-4-methyl-1,2,4-triazoles as well as in a series of 1-methyl-3-R-5-nitro-1,2,4-triazoles were studied. The activation parameters of the reaction were determined. There is a linear correlation dependence between log k and the m substituent constants in the investigated series.See [1] for communication XIII.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 568–571, April, 1972. 相似文献
14.
M. S. Pevzner P. A. Ivanov N. V. Gladkova O. N. Sushchenko V. P. Tverdokhlebov Z. S. Myasnikova 《Chemistry of Heterocyclic Compounds》1980,16(2):189-194
1-Hydroxymethyl derivatives of tetrazoles were obtained by the reaction of 1,2,4-triazole and 3-nitro-5-substituted triazoles
with formaldehyde in water. The hydroxy groups were replaced by chlorine, and the hydroxymethyltriazoles were acetylated and
tosylated. The chloro and tosyl groups are readily replaced by iodine by the action of potassium and ammonium iodide in acetone.
See [1] for communication 24.
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 251–256, February, 1980. 相似文献
15.
M. E. Konshin 《Chemistry of Heterocyclic Compounds》1970,6(9):1160-1161
A method for the synthesis of 9-arylamino--quinindanes from anilides of cyclopentylideneanthranilic acid has been devised. A number of previously undescribed compounds have been obtained, and their properties have been examined.For Parts I and II, see [1].The name -quinindanes has been suggested for 2, 3-trimethylenequinolines [2].Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1242–1243, September, 1970. 相似文献
16.
The and isomers of 1-allyl-3-methyl-4-(3-alkyl-1-propynyl)-4-piperidols were synthesized by the condensation of the and isomers of 1-allyl-3-methyl-4-ethynyl-4-piperidol with piperidine (morpholine) and paraformaldehyde in anhydrous dioxane in the presence of cuprous chloride.See [1] for Communication I.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1652–1653, December, 1970. 相似文献
17.
18.
Naturally-occurring nitro compounds display great structural diversity, and a wide range of biological activities. This review summarizes current information on the structures of naturally-occurring nitro compounds and on the biosynthesis of the nitro group. 相似文献
19.
I. L. Knunyants L. S. German I. N. Rozhkov B. L. Dyatkin 《Russian Chemical Bulletin》1966,15(2):226-228
Conclusions By the reduction of polyfluoronitroalkanes fluorine-containing hydroxylamines, oximes, amines, and nitroso compound were prepared. 相似文献
20.
V. V. Shaburov O. V. Vasil'eva A. V. El'tsov 《Chemistry of Heterocyclic Compounds》1974,10(3):320-323
Benzothiazole-2-diazonium tetrafluoroborate and its 6-bromo, 6-methyl, and 6-methoxy derivatives are relatively stable and have high electrophilicities. They are rapidly converted in weakly alkaline media to the corresponding anti-diazotates, from which primary nitrosoamines can be obtained by acidification. 相似文献