The Electrodynamics of Granular High-Temperature Superconducting Media

The electrodynamic properties of granular high-temperature superconducting media are studied. Relations for the surface resistance and impedance of a high-temperature superconducting medium are derived. The temperature and frequency dependence of the phase velocity and group velocity and depth of penetration of the electromagnetic field into the Josephson medium are calculated. The possibility of using high-temperature superconducting films as high-efficiency shields is shown. The shielding properties are improved appreciably with increase in the critical current density of the high-temperature superconducting film. The shield thickness is several microns or several fractions of a micron for a critical current density of >10⁷ A/m². The results obtained can be used in designing superhigh-frequency shields, microstrip lines, and other devices based on high-temperature superconducting Josephson media.     

Phase formation in liquid-solid alloys under direct current

Influence of direct electric current on the phase formation in liquid-solid alloys (with primary crystals separated by a liquid phase) of the Bi-Cd eutectic system has been investigated. It is established that a direct current with a density j ～ 5 × 10⁵ A/m² significantly affects the processes of dissolution and structure formation in the alloys studied.     

Structural state of second-generation HTSCs obtained by laser ablation

The structure of buffer layers and deposited YBa₂Cu₃O _x (Y123) films with a high critical current density (～10⁶ A/cm²) has been investigated by different methods. These superconducting films and buffer layers are found to have a fine-grained structure, which, along with the high texture of Y123 films of the (001) type, is believed to be responsible for the high critical current density. An unusual texture is revealed in buffer layers, which differs from that of substrates and Y123 films. The superconducting films deposited on buffer CeO₂ layers exhibit a system of orthogonal lines; in the case under consideration, this is a manifestation of a domain structure with Y123 particles at boundaries.     

Electrical assisted laser floating zone (EALFZ) growth of 2212-BSCCO superconducting fibres

The new electrical assisted laser floating zone (EALFZ) technique was used to grow superconducting fibres of Bi₂Sr₂CaCu₂O₈ (2212-BSCCO). The application of an electrical current through the crystallization interface proved to advantageously modify the phase nature and texture of 2212-BSCCO polycrystalline fibres compared to conventionally laser floating zone (LFZ) grown ones. The current application during the growth induces a selective and more intense ionic migration along the fibre axis. As a result, an increase in superconducting phase fraction and a decrease of residual melt were observed together with grain alignment intensification. The main outcome in the superconducting properties is the improvement of the critical current density at 77 K, from 1.2 × 10³ A/cm², in the LFZ fibres, to 2.8 × 10³ A/cm², in the EALFZ processed ones.     

Pressure-induced phase transformation in In2Bi

We have made measurements of the pressure dependence of the superconducting transition temperature, T_c, for In₂Bi and related alloys. For In₂Bi- phase alloys, a large discontinuity in T_c is seen at 15–20 kbar, which we associate with a phase transformation first seen by Bridgman [1]. Our measurements suggest that this transformation is produced by the decomposition of In₂Bi into In₅Bi₃ and an In-rich phase. In the low pressure phase, T_c shows a minimum at 9–15 kbar whereas it depends linearly on pressure in the high pressure phase with ?T_c/?P equal to -4.9 × 10^-5 K bar^-1.     

准分子激光扫描消融淀积大尺寸超导薄膜

利用我们设计的一套光学变换传输系统实现了激光束在超导靶上一定范围内扫描消融来淀积高T_c超导薄膜。实验表明用这种激光扫描消融方法可使大尺寸超导薄膜的厚度均匀性得到较大的改善。我们采用激光扫描半径为9mm在12mm×33mm的Y-ZrO₂基片上淀积出零电阻温度T_c≥90K,临界电流密度J_c(零磁场,77K)≥1×10⁶A/cm²,薄膜c轴择优取向,厚度均匀性较好的YBa _关键词：     

Weak link problem and intragrain current density in polycrystalline Bi1Ca1Sr1Cu2Ox and Tl2Ca2Ba2Cu3O10

Polycrystalline sintered specimen were investigated by means of ac susceptibility and inductive critical current measurements. Main objects are whether the new highT _c oxides have a weakly coupled intergranular structure and to get information about the intragrain critical current density. The Tl₂Ca₂Ba₂Cu₃O₁₀ specimen shows a connective nature similar to YBa₂Cu₃O₇ with low intergrain currents (100 A/cm² at 100K,B=0 T) and high intragrain ones (4.5·10⁵ A/cm² at 100K,B=0 T). The investigation of the Bi₁Ca₁Sr₁Cu₂O_x specimen becomes complex due to the presence of two superconducting phases and the low intragrain critical current density of the lowerT _c phase.     

MgB2 coated conductors directly grown on flexible metallic Hastelloy tapes by hybrid physical–chemical vapor deposition

MgB₂ coated conductors (CCs), which can avoid the low packing density problem of powder-in-tube (PIT) processed wires, can be a realistic solution for practical engineering applications. Here we report on the superior superconducting properties of MgB₂ CCs grown directly on the flexible metallic Hastelloy tapes without any buffer layer at various deposition temperatures from 520 to 600 °C by using hybrid physical–chemical vapor deposition (HPCVD) technique. The superconducting transition temperatures (T_c) are in the range of 38.5–39.4 K, comparable to bulk samples and high quality thin films. Clear (101) and (002) reflection peaks of MgB₂ are observed in the X-ray diffraction patterns without any indication of chemical reaction between MgB₂ and Hastelloy tapes. From scanning electron microscopy, it was found that connection between MgB₂ grains and voids strongly depend on the growth temperature. A systematic increase in the flux pinning force density and thereby the critical current density with decreasing growth temperature was observed for the MgB₂ CCs. The critical current density (J_c) of J_c(5 K, 0 T) ～10⁷ A/cm² and J_c(5 K, 2.5 T) ～10⁵ A/cm² has been obtained for the sample fabricated at a low growth temperature of 520 °C. The enhanced J_c (H) behavior can be understood on the basis of the variation in the microstructure of MgB₂ CCs with growth temperature.     

Synthesis of superconductor MgCNi3 with carbon nanotubes

MgCNi3, an intermetallic compound superconductor with a cubic perovskite crystal structure, has been synthesized using fine Mg and Ni powders and carbon nanotubes （CNTs） as starting materials by the conventional powder metallurgy method. The composition, microstructure and superconductivity are characterized using x-ray diffraction （XRD）, energy dispersive x-ray （EDX） analysis, scanning electron microscopy （SEM）, and superconducting quantum interference device （SQUID） magnetometer. The results indicate that the phases of the synthesized samples are MgCNi3 （major phase） and traces of C and MgO. The MgCNi3 particle sizes range from several hundreds of nanometres to several micrometres. The onset superconducting transition temperature Tc of the MgCNi3 sample is about 7.2 K. The critical current density Jc is about 3.44 × 10^4 A/cm^2 calculated according to the Bean model from the magnetization hysteresis loop of the slab MgCNi3 sample at 5 K and zero applied field.     

Improved critical current capability of V3Ga formed in a V-6Ga/Cu-15 Ga composite

Single filament V₃Ga composite wires were prepared by imbedding cores of pure V and V-6.1 at.% Ga in a Cu-15.4 at.% Ga matrix. The parabolic growth rate of V₃Ga was enhanced by alloying the core, and the superconducting critical current density was nearly doubled. At 4.2 K J_c exceeded 10⁵ A/cm² in transverse magnetic fields up to 140 kG.     

Preparation and characterisation of electrodeposited amorphous Sn-Co-Fe ternary alloys

Electrochemical deposition was investigated as a process to obtain alloys of Sn-Co-Fe, which to date have not been reported in the literature. A constant current technique was used to electrochemically deposit tin-cobalt-iron alloys from a gluconate electrolyte. The gluconate system was chosen as an electrolyte, which could potentially provide an environmentally safe process. The effect of plating parameters such as current density, deposition time, temperature and pH are discussed. Results are reported for current density and plating time using an electrolyte temperature of 20-60 °C and pH of 7.0 in relation to phase composition, crystal structure and magnetic anisotropy of the deposited alloys.Investigations were conducted using ⁵⁷Fe conversion electron Mössbauer spectroscopy (CEMS), ¹¹⁹Sn CEMS, transmission Mössbauer Spectroscopy and XRD. The ⁵⁷Fe and ¹¹⁹Sn CEMS spectra and XRD showed that the dominant phase in the deposits was amorphous Sn-Co-Fe. The relative area of the 2nd and 5th lines of the sextets representing the magnetic iron containing phases was found to decrease continuously with increasing current density while at the same time no significant changes in the magnetic anisotropy was found with plating time. Magnetically split ¹¹⁹Sn spectra reflecting a transferred hyperfine field were also observed.A range of good quality amorphous Sn-Co-Fe ternary alloys was obtained over a range of operating conditions from an environmentally acceptable gluconate electrolyte.     

钛离子辐照对MgB2超导薄膜的载流能力和磁通钉扎能力的影响

利用混合物理化学气相沉积法(hybrid physical-chemical vapor deposition, HPCVD)可以制备出高性能的MgB₂超导薄膜, 再对薄膜进行钛(Ti)离子辐照处理.经过辐照处理后的样品被掺入了Ti元素, 与未处理的干净MgB₂样品相比,其超导转变温度没有出现大幅度的下降, 而在外加磁场下的临界电流密度得到了明显的提高,同时样品的上临界磁场也得到了提高. 在温度5 K, 外加垂直磁场为4 T的情况下, Ti离子辐照剂量为1× 10¹³/cm²的样品的临界电流密度达到了1.72× 10⁵ A/cm², 比干净的MgB₂要高出许多,而其超导转变温度仍能维持在39.9 K的较高水平.     

利用电泳法在金属基底上制备MgB2超导厚膜

利用电泳技术在高熔点金属基底Ta，Mo和W上制备MgB₂超导厚膜.厚膜中的MgB2晶粒结合紧密，粒度小于1μm，呈随机取向生长.电阻测量表明沉积在Ta，Mo，W上的MgB₂厚膜的超导起始转变温度分别为36.5K，34.8K，33.4K，对应的转变宽度为0.3K，1.5K和2.0K.三种基底上制备的MgB₂厚膜的临界电流密度在不同温度下随外磁场的变化情况 基本相同，MgB₂/Mo厚膜的临界电流密 关键词： 2超导厚膜')" href="#">MgB₂超导厚膜 电泳 金属基底     

High current densities at 20T in long (20m) tapes of CVD-prepared Nb3Ge

Critical current densities J_c as a function of magnetic field have been measured on tapes of chemically vapor deposited (CVD) Nb₃Ge that are up to 20m long. Values of J_c exceed 5 × 10⁴ A/cm² at 20T. Such high critical current densities are encouraging for use of this material in producing a 20T superconducting magnet.     

Electromagnetic properties of bulk Bi-Pb-Sr-Ca-Cu-O superconductor at low magnetic fields

Magnetization and critical current density measurements have been performed on a Bi_1.7Pb_0.3Sr₂Ca₂Cu₅O _y bulk material as the functions of magnetic field and temperature. The diamagnetic shielding effect has been discussed from the initial magnetization curve. The lower critical field of bulk granular superconductor (H _g) and the lower critical field of superconducting grains (H _c1) are estimated from magnetization curves. They are both linearly decreasing functions of temperature: (dH _g/dT) and (dH _c1/dT) are –0.4 and –1.8 G/K respectively. The transport critical current density drops drastically by a factor of 4 at a magnetic field of about 20G. The magnetization J _c of superconducting grains derived from the remanent magnetization is about 10⁶ A/cm² at 77 K, zero field, much greater than the transport J _c. The experimental results reveal that the transport J _c is dominated by weaklink current between grains. The magnetization J _c versus temperature has been obtained from the remanent flux at zero magnetic field and is a linearly decreasing function of temperature within experimental error.     

Macrostructure of high-temperature superconducting YBaCuO thin films grown by laser ablation

The superconducting parameters and macrostructure of YBaCuO thin films grown by laser ablation on SrTiO₃ substrates are influenced by the substrate temperature during growth. In a study of this influence it is found that the macrostructure has significant bearing on the superconducting parameters of the films and on the critical current, in particular. For J _c⩽10⁵ A/cm² the films have a distinctly pronounced granular structure, while for J _c>10⁵ A/cm² the films do not have any kind of block structure. Zh. Tekh. Fiz. 68, 48–51 (February 1998)     

EDXRF measurements on gold diffusion-doped Bi1.8Pb0.35Sr1.9Ca2.1Cu3Oy

Gold (Au) diffusion in superconducting Bi_1.8Pb_0.35Sr_1.9Ca_2.1Cu₃O_y was investigated over the temperature range 500-800 °C by the energy dispersive X-ray fluorescence (EDXRF) technique. It is found that the Au diffusion coefficient decreases as the diffusion-annealing temperature decreases. The temperature dependences of Au diffusion coefficient in grains and over grain boundaries are described by the relations D₁=6.7×10⁻⁵exp(−1.19 eV/k_BT) and D₂=9.7×10⁻⁴exp(−1.09 eV/k_BT), respectively. The diffusion doping of Bi-2223 by Au causes a significant increase of the lattice parameter c by about 0.19%. For the Au-diffused samples, dc electrical resistivity and transport critical current density measurements indicated the critical transition temperature increased from 100 to 104 K and the critical current density increased from 40 to 125 A cm⁻², in comparison with those of undoped samples. From scanning electron microscope (SEM) and X-ray diffraction (XRD) measurements it is observed that Au doping of the sample also improved the surface morphology and increased the ratio of the high-T_c phase to the low-T_c phase. The possible reasons for the observed improvement in microstructure and superconducting properties of the samples due to Au diffusion are also discussed.     

Synthesis and superconducting properties of Nd0.33Eu0.08Gd0.58Ba2Cu3O z materials

We have studied the effect of the ratio of different rare-earth element on the superconducting properties and phase formation of (Nd_0.33Eu_0.08Gd_0.58)Ba₂Cu₃O _z ceramic. Bulk NEG samples were prepared using the solid-state reaction process. The superconducting transition for Nd_0.33Eu_0.08Gd_0.58Ba₂Cu₃O _z is T _c ≈90 K and the value of the critical current density (J _c ) is 13.9 A/cm² at 77 K under zero magnetic fields. This value is twice as high when compared with the (J _c ) value of YBCO systems (J _c = 7.31 A/cm²). The obtained bulk sample was used for the production of superconducting Ag-sheathed tapes by OPIT method including hot rolling. The critical current density of the obtained tape (337 A/cm²) is one order higher than the one of the bulk sample.      

Properties of Nb3Ge tapes for high field magnets

A laboratory process for long Nb₃Ge tapes fabrication by chemical vapor deposition (CVD) has been set up. The Nb₃Ge tapes which were fabricated offer the possibility of high current and high field operation at 4.2 K since the values of critical current densities, J_c, measured in high magnetic fields at 20T and 4.2K exceed 5 × 10⁴ A cm^?2 which is the generally accepted criterion for producing a superconducting magnet.     

原位法MgB_2-B_4C复相超导体合成及相含量调控研究

以B4C和Mg为原料合成的MgB2-B4C复相超导体具有高的临界电流密度(Jc)和高的超导转变温度(Tc),是一种有潜力的实用MgB2超导材料,其成相机理对复相MgB2超导体的相含量调控和磁通钉扎研究具有重要意义。结合经典烧结理论,研究了B4C-Mg真空固相烧结制备MgB2-B4C复相超导体的超导相形成和晶粒生长过程,给出了B4C-Mg的金斯特林格扩散模型和MgB2晶粒生长过程。通过选择B4C原料粒径,MgB2-B4C复相超导体超导相体积相含量在18%-88%范围可控。相含量88%的MgB2-B4C复相超导体临界转变温度达33.5K,转变宽度1.5K。10 K环境6T外场下电流密度可以达到1×104A/cm2,表明MgB2-B4C复相超导体具有良好的磁通钉扎行为。