Non-steady-state photo-EMF in nanostructured GaN and polypyrrole within porous matrices

We report an experimental investigation of the non-steady-state photoelectromotive force in nanostructured GaN within porous glass and polypyrrole within chrysotile asbestos. The samples are illuminated by an oscillating interference pattern created by two coherent light beams and the alternating current is detected as a response of the material. Dependences of the signal amplitude versus temporal and spatial frequencies, light intensity, and temperature are studied for two wavelengths λ=442 and 532 nm. The conductivity of the GaN composite is measured: σ=(1.1–1.6)×10⁻¹⁰ Ω⁻¹ cm⁻¹ (λ=442 nm, I ₀=0.045–0.19 W/cm², T=293 K) and σ=(3.5–4.6)×10⁻¹⁰ Ω⁻¹ cm⁻¹ (λ=532 nm, I ₀=2.3 W/cm², T=249–388 K). The diffusion length of photocarriers in polypyrrole nanowires is also estimated: L _D=0.18 μm.     

Twisted lines and small-scale structures in generation spectra of Yb-doped media excited by focused radiation of LiF:F 2 + color center laser

Spectral lines of Yb lasing in 1.03–1.05 μm region structured by 50–200 μm spots were found at focusing a pulsed LiF:F₂⁺ color center laser of 0.5–5.0 GW/cm² intensity on highly doped Yb:YAG or Yb:glass plates in a resonator. Small spots at the spectrograph located ≈ 1 m apart from the resonator indicated a “sub-diffraction” directivity of Yb generation, 1–2 orders better than the diffraction limit 10⁻³–10⁻² rad determined by the pumped volume dimensions. Observed features of Yb emission are explained assuming off-axis oscillations in Yb laser on phase-synchronized photons due to a strong spatial-angular selection of radiation in the resonator. Propagation of near diffraction free beams at angles to the axis built at the spectrograph slit for every 10–15 ns pulse of Yb generation a magnified “image” of a structure of generating channels in the active medium. This image projection brought a corresponding structure of spots in Yb spectra. It was found that channels may be formed due to a high-frequency spatial modulation (micrometers scale) of the refractive index profile in samples caused by the oscillating amplitude of thermoelastic stresses in the pumped medium. Obtained data demonstrate a possibility to study (with high spatial and temporal resolution) non-equilibrium stales of materials in small volumes using laser radiation emerging from these objects. This study results evidence for the novel concept of the spatial distribution of electromagnetic field of a photon: not in the form of a “travelling” wave but in the form of a wave with maxima and nodes located at fixed positions along the photon propagation direction.     

Laser interferometry of acoustic fields generated by high-current electron beams in solids

We have developed a method for detecting acoustic fields in solids irradiated with dense electron beams. The method is based on laser Michelson interferometry. The electron source is a high-current DZhIN electron accelerator. The detection system features a short baseline Michelson interferometer located inside the experimental chamber with the sample, a stabilized initial beam pathlength difference within the interferometer, high temporal resolution, an analog-to-digital converter with output to a personal computer, and a program for reducing the interferometer data. We can measure both long pulses with minimum displacements of 10⁻¹⁰ m and durations of 10⁻⁸ sec, and flexure waves with large-amplitude displacements of 10⁻⁵ m and oscillation periods of 10⁻³ sec. We present results from studies of flexure waves in thin plates and rods of copper, silicon, alkali-halide crystals, quartz glasses, and D16T aluminum alloy irradiated by nanosecond high-density electron beams. Institute of High-Current Electronics, Siberian Branch of the Russian Academy of Sciences. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 82–92, November, 1997.     

Transformation of beams of dia-, para-, and ferromagnetic particles by the magnetic field of a linear current

Some possibilities of transformation and trapping of beams of small (10⁻¹–10⁻⁴ cm) dia-, para-, and ferromagnetic particles by the magnetic field of a linear, constant current are investigated. Zh. Tekh. Fiz. 67, 138–141 (August 1997)     

Plasma-emitter electron accelerators

This paper considers the physical processes associated with the extraction of electrons from the gas discharge plasma in plasma emitters where the emission boundary is stabilized with a fine grid. The ways of improving the uniformity of the emission current density distribution are discussed. Accelerators designed on the basis of plasma emitters are capable of producing pulsed beams of current 10–10³ A, current density 0.1–1.0 A/cm², pulse duration 10⁻⁷–10⁻³ s, and cross-sectional area up to 10⁴ cm². Institute of High-Current Electronics, Siberian Division of the Russian Academy of Sciences. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 92–96, April, 2000.     

Spectrofluorimetric Assessment of Doxycycline Hydrochloride in Pharmaceutical Tablets and Serum Sample Based on the Enhancement of the Luminescence Intensity of the Optical Sensor Sm<Superscript>3+</Superscript> Ion

A simple and sensitive spectrofluorimetric method for determination of trace amount of doxycycline hydrochloride (DC) in pharmaceutical tablets and serum samples was developed. In ammonia buffer solution of pH 8.9 the doxycycline hydrochloride can remarkably enhance the luminescence intensity of the Sm³⁺ ion in Sm³⁺- DC complex at λ_ex = 400 nm. The produced luminescence intensity of Sm³⁺- DC complex in DMSO is in proportion to the concentration of DC and used as optical sensor for its determination. The dynamic range for the determination of DC is 1 × 10⁻⁸ – 5 × 10⁻⁶ mol L⁻¹ and in case of quantum yield calculations is 7 × 10⁻⁹ – 5 × 10⁻⁶ mol L⁻¹ with detection limit of 6.5 × 10⁻¹⁰ mol L⁻¹. The enhancement mechanism of the luminescence intensity in the Sm³⁺- DC system has been also discussed. A comparison with other spectrofluorimetric methods for tetracycline derivatives in which Eu³⁺ ion is used instead of Sm³⁺ ion is also studied.     

Concentration self-quenching in solid solutions of complex organic molecules under intense excitation

A theoretical study was carried out to investigate concentration self-quenching which is nonlinear in intensity in a molecular system caused by nonradiative electronic excitation energy transfer to relatively long-lived acceptors that are formed in a solution and whose function is performed by molecules that have acquired the triplet state. It is shown that at ratios of constants of radiative and nonradiative transitions typical of complex molecules at concentrations of ∼10⁻³–10⁻² mole/liter substantial (2- to 10-fold) fluorescence takes place at intensities of excitation of ∼10⁴–10³ of the intensity of saturation for a singlet subsystem. Polarization characteristics of the system are analyzed. Belarusian State University, 4, F. Skorina Ave., 220050, Minsk, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 6, pp. 729–733, November–December, 1997.     

The temperature and light intensity dependence of photorefraction in LiNbO3

In the paper the dependence of the photorefraction (PhR) in LiNbO₃ and LiNbO₃−Fe (0.1 wt%, 0.3wt%) crystals on light intensity (within 10¹⁶–10²³ quanta·cm⁻²·s⁻¹ at wavelengths 496.5 nm and 600 nm) and temperature (in the region 100–500 K) is studied. For all the crystals the limiting values of PhR are similar and atT=293 K Δn _sat ^lim ≈3·10⁻³. In LiNbO₃ the temperature dependence of PhR in the range 100–500 K requires to take into account at least two trapping centres.     

High-intensity and high-brightness source of moderated positrons using a brilliant γ beam

Presently, large efforts are conducted toward the development of highly brilliant γ beams via Compton back scattering of photons from a high-brilliance electron beam, either on the basis of a normal-conducting electron linac or a (super-conducting) Energy Recovery Linac (ERL). Particularly, ERLs provide an extremely brilliant electron beam, thus enabling the generation of highest-quality γ beams. A 2.5 MeV γ beam with an envisaged intensity of 10¹⁵ photons s⁻¹, as ultimately envisaged for an ERL-based γ-beam facility, narrow band width (10⁻³), and extremely low emittance (10⁻⁴ mm² mrad²) offers the possibility to produce a high-intensity bright polarized positron beam. Pair production in a face-on irradiated W converter foil (200 μm thick, 10 mm long) would lead to the emission of 2×10¹³ (fast) positrons per second, which is four orders of magnitude higher compared to strong radioactive ²²Na sources conventionally used in the laboratory. Using a stack of converter foils and subsequent positron moderation, a high-intensity low-energy beam of moderated positrons can be produced. Two different source setups are presented: a high-brightness positron beam with a diameter as low as 0.2 mm, and a high-intensity beam of 3×10¹¹ moderated positrons per second. Hence, profiting from an improved moderation efficiency, the envisaged positron intensity would exceed that of present high-intensity positron sources by a factor of 100.     

Effect of alkali-metal doping on photoluminescence of CdS films

It is established that doping of CdS polycrystalline films with alkaline metals (Li, Na, K, Cs) results in an increase of luminescence intensity by 3–5 times compared with pure films. This increase is accounted for by the placement of alkaline-metal ions in V _Cd ²⁻ cation vacancies, which are nonradiative recombination centers in these films. From the dependences of the luminsecence intensity of the doped films on the synthesis conditions (deposition temperature, concentration of doping impurities, type of doping metal), the parameters that ensure the maximum luminescence intensity of the films are determined as T_dep ≈ 450°C and C_Me = 1·10⁻⁵ at %. The luminescence intensity decreases by 1–3% upon exposure of the films to UV light (λ_max = 365 nm, I = 10²¹ quanta·sec·cm⁻¹) for several hours. This is indicative of the stability of these films against UV radiation. __________ Translated from Zhurnal Prikladnoi Spektroskopii Vol. 74, No. 3, pp. 362–366, May–June, 2007.     

Low-Noise single-frequency He-Ne laser with stable output power at a wavelength of 1.52 µm

The results of investigation of the energy and spectral characteristics of a He-Ne laser (λ_rad=1.52 μm) with transverse microwave discharge are presented. A single-frequency generation mode at a pressure above 6.0 mm Hg was obtained with radiation power 7.0 mW and low level of amplitude noise (10⁻⁵ Hz^−1/2). Active stabilization of the laser power was carried out, which allows reduction in radiation intensity fluctuations from 1–5 to 0.1 %. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 67, No. 1, pp. 127–128, January–February, 2000.     

The Co-luminescence Effect of Eu–Gd–Ofloxacin–SDBS System and its Analytical Application

A fluorescence enhancement phenomenon in the europium (Eu)–Ofloxacin (OF)–Sodium Dodecyl Benzene Sulfonate (SDBS) fluorescence system was observed when Gd³⁺ was added. The fluorescence intensity of the systems was measured (λ _ex/λ _em = 280/612 nm) at pH 7.8. Under optimum conditions, a linear relationship between the enhanced fluorescence intensity and the Eu³⁺ concentration in the range of 5.0 × 10⁻¹⁰ ∼ 2.0 × 10⁻⁷ mol·L⁻¹ was observed. The detection limit of Eu³⁺ was 1.46 × 10⁻¹⁰ mol·L⁻¹ (S/N = 3). This method was used for the determination of trace amounts of europium in synthetic rare earth samples with satisfactory results. In addition, the interaction mechanism is also studied.     

Fluorescence Enhancement Effect for the Determination of Polychlorinated Biphenyls with Bovine Serum Albumin

A sensitive and selective method for the trace determination of 3, 3’, 4, 4’-tetrachlorobiphenyl (PCB77) by using bovine serum albumin (BSA) as a fluorescence probe was introduced. Under optimum conditions, the enhanced fluorescence intensity was proportional to the concentration of polychlorinated biphenyls in the range of 8.9 × 10⁻⁸–5.0 × 10⁻⁶ mol L⁻¹ for PCB77, and 5.0 × 10⁻⁷–5.0 × 10⁻⁶ mol L⁻¹ for 2, 2’, 5, 5’-tetrachlorbiphenyl (PCB52). The detection limits (S/N = 3) of PCB77 and PCB52 were 2.6 × 10⁻⁸ mol L⁻¹ and 2.9 × 10⁻⁷ mol L⁻¹, respectively. Furthermore, the fluorescence enhancement mechanism was discussed in detail. Results indicated that fluorescence enhancement of the system originated from the formation of BSA-PCBs complexes. In addition, PCBs were mainly bound to the tyrosine residues in BSA molecules.     

Europium-sensitized Chemiluminescence of System Tetracycline–H<Subscript>2</Subscript>O<Subscript>2</Subscript>–Fe(II)/(III) and Its Application to the Determination of Tetracycline

Chemiluminescence (CL) of the reaction system tetracycline–H₂O₂–Fe(II)/(III)–Eu(III) was used for the determination of tetracycline hydrochloride in water, pharmaceutical preparations, and honey. The CL spectrum registered for this system shows emission bands typical of Eu(III) ions, with a maximum at λ ∼ 600 nm, corresponding to the electronic transitions of ⁵D₀ → ⁷F₁ and ⁵D₀ → ⁷F₂. A strong chemiluminescence intensity characteristic of europium(III) ions in the system tetracycline–H₂O₂–Fe(II)/(III)–Eu(III), as contrasted to the emission of the system tetracycline–H₂O₂–Fe(II)/(III) without Eu(III), proves that the Eu(III) ion plays the role of a chemiluminescence sensitizer, accompanying tetracycline oxidation in the Fenton system (H₂O₂–Fe(II)/(III)). A linear dependence was observed for the integrated CL light intensity on the tetracycline concentration in the range of 2 × 10⁻⁷ to 3 × 10⁻⁵ mol l⁻¹ with the detection limit of 5 × 10⁻⁸ mol l⁻¹ in aqueous solution.     

Fluorescence Enhancement of the Silver Nanoparticales – Curcumin - Cetyltrimethylammonium Bromide-nucleic Acids System and its Analytical Application

It is found that silver nanoparticles (AgNPs) can further enhance the fluorescence intensity of curcumin (CU) - cetyltrimethylammonium bromide (CTAB) – nucleic acids and improve its anti-photobleaching activity. Under optimum conditions, the enhanced fluorescence intensity is proportion to the concentration of nucleic acids in the range of 2.0 × 10⁻⁸–1.0 × 10⁻⁶ g mL⁻¹ for fish sperm DNA (fsDNA), 2.0 × 10⁻⁸–1.0 × 10⁻⁶ g mL⁻¹ for calf thymus DNA (ctDNA), 1.0 × 10⁻⁸–1.0 × 10⁻⁶ g mL⁻¹ for yeast RNA (yRNA), and their detection limits (S/N = 3) are 8.0 ng mL⁻¹, 10.5 ng mL⁻¹ and 5.8 ng mL⁻¹, respectively. This method is used for determining the concentration of DNA in actual sample with satisfactory results. The interaction mechanism is also studied.     

Dual-beam laser analyzer for inhomogeneities in active regions of multielement photodetectors

We describe equipment and a procedure for measuring inhomogeneities in active regions of solar cells, photoelectric transducers, and multielement photodetectors, based on a computer-controlled dual-beam laser scanner including a Pentium III personal computer, an HP-34401A digital multimeter with RS-232 serial interface;, a platform movable along the Y coordinate with the sample multielement photodetector to be tested and a microprobe device for picking up the photocurrents, an optical head with laser photodiodes in the visible (λ₁ = 0.68 μm) and IR (λ₂ = 0.82 μm) ranges scanning along the X coordinate, and a control unit for focusing the laser beams λ₁, λ₂, stabilizing the laser radiation power, and controlling the step motors for the X,Y coordinates. The equipment and procedure enable laser scanning of sample multielement photodetectors, with external dimensions 10 × 10 μm2 to 150 × 150 mm², along the X, Y coordinates at a maximum rate of 100 mm/sec; minimum radiation power of the laser diodes, 10 mW; range of laser beam diameters, 2–50 μm; range of scanning steps along the X, Y coordinates, 5–100 μm; current sensitivity 1·10⁻⁸ A, voltage sensitivity 1·10⁻⁷ V; measurement and analysis accuracy at least 0.5%; storage of color plots of the inhomogeneities in the active regions of the multielement photodetectors on the hard disk of the personal computer, with output of analysis results to a monitor and color printer, 32 color gradations. Software written in Delphi 7.0. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 2, pp. 277–280, March–April, 2006.     

Searches for gamma-quanta from local sources by a wide-angle imaging telescope

Summary A new Cherenkov imaging telescope SHALON equipped with a very high-definition camera (144 pixels, imaging 7.2⁰×7.2⁰) takes data since 1993 at a mountain altitude of 3338 m. We discuss some results of the observations of the indicated gamma-ray sources and the discrimination methods between gamma-rays and protons. Selection of showers produced by gamma-quanta from a background of showers produced by protons has been made according to the following criteria: 1) alpha<20⁰; 2) length/width>1.6 for γ; 3) Cherenkov light intensity in pixels with max light to the light in the light pixels near around is >0.2 for γ and <0.6 for p; 4) Cherenkov light intensity in pixels with max light to all light in imaging excluding in centre is >0.8 for γ and <0.8 for p; 5) distance for γ is <3.5 pixels.I _Crab=(0.95±0.18)·10⁻¹² cm⁻²c⁻¹.I _Mark421=(0.98±0.36)·10⁻¹² cm⁻²c⁻¹. Paper presented at the Special Session on ground-based gamma-ray astronomy of the XXIV International Cosmic-Ray Conference, Rome, August 28–September 8, 1995.     

Survey of the Star-Formation Regions Associated with Infrared Sources Observed in the <Emphasis Type="Italic">J</Emphasis> = 1−0 Line of the CO Molecule and Its Isotopes. Results of Observations Performed in the C<Superscript>18</Superscript>O(J = 1−0) Line

We present results of observations of 23 compact cores of molecular clouds associated with IRAS “ cold” infrared sources. The observations were performed in the J = 1−0 line of the C¹⁸O molecule on a 13.7-meter radio telescope of the Purple Mountain Observatory, China. The C¹⁸O (J = 1−0) line was detected in the emission of 21 objects. Column densities of the C¹⁸O and H₂ molecules towards the maximum of integral intensity of the C¹⁸O emission were estimated in the approximation of local thermodynamic equilibrium and amounted to (2.5–10.4) · 10¹⁵cm⁻² and (1.5–6.1) · 10²² cm⁻², respectively. The kinetic temperatures determined for these maxima from the CO lines vary from 14 to 45 K. For six objects, whose mapping has been almost completed, the dimensions of the C¹⁸O emission regions are estimated to range from 0.5 to 1.2 pc. The masses of these objects lie in the range of (390–1750) M_⊙ and are close to the estimates following from the virial theorem. The range of average densities of the objects is (0.3–1.4) · 10⁴ cm⁻³. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 48, No. 7, pp. 553–562, July 2005.     

Nonlinear response of photorefractive lithium tantalate and niobate at acoustic frequencies

An amplification of the intensity of pump oscillations is observed experimentally at frequencies from 100 Hz to 1 kHz during photoinduced light scattering and holographic-type parametric scattering in photorefractive lithium tantalate and niobate. Possible ways are analyzed for explaining the existence of a photorefractive response in these crystals over times of 10⁻²–10⁻³ s, which are five orders of magnitude shorter than the Maxwell time. Zh. éksp. Teor. Fiz. 112, 1490–1498 (October 1997)