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SynthesisandStructureof[Et_4Nj]_2[Mo_6O_(19)H_4]andValenceDeterminationofMolybdenumNIUShu-yun;ZHANGHeng-bin;YANGGuang-di;NIEF... 相似文献
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SynthesisandCrystalStructureof[Tris(2-benzimidazylmethyl)amine][Imidazole]Copper(Ⅱ)PerchlorateZhouWei-Hong;LiuXiao-Lan;MiaoFa... 相似文献
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SynthesisandCrystalStructuralCharacterizationof(NH_4)_5H_3Mn_3V_(12)O_(40)·15H_2OWANGZuo-Ping;LIUJing-fuandWANGEn-bo(Depatmen... 相似文献
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ApplicationoftheReactionsofFerrocene(Ⅰ)SaltswithBis[dicarbonyl(η ̄5-cyclopentadienyl)iron]andBis[dicarbonyl(η ̄4-butadiene)coba... 相似文献
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SynthesisandCrystalStructureofPyridine-2-thiolato-MolybdenumComplex[Et_4N][Mo(CO_4)(pyS)]YuPei-Hua;HuangLiang-Ren;ZhuangBo-Tao... 相似文献
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SynthesisandStructureof[(C_2H_5)_4N][Mo_3(μ_3-O)(μ-Cl)_3(μ-CH_3CH_2COO)_3Cl_3]ZhuangHong-Hui;WuDing-Ming;HuangJian-Quan;HuangJin-L... 相似文献
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SynthesisandCrystalStructureof3,3-Diphenylnaphtho[1,2-b]furan-2(3H)-oneMengJi-Ben;WenZhong;WangYong-Mei;WangRu-Ji;WangHong-Ge... 相似文献
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杂多化合物的衍生物由于具有潜在的多功能催化性能 ,长期以来一直受到人们的关注 [1~ 3 ] .将有机或有机金属基团引入杂多化合物中以修饰杂多阴离子的部分外部骨架结构 ,对研究杂多化合物的性质和应用及新型催化剂的开发具有重要意义[4,5 ] .在杂多化合物表面引入适当的有机基团还可改善其溶解性能及其它物理性质 ,从而拓宽其应用范围 .研究结果表明 ,这类化合物还具有很好的抗病毒和抗肿瘤活性 [6,7] .Klemperer等 [8] 合成的 [( η5 - C5 H5 ) Ti PW11O3 9] 4 -将多酸与金属有机化合物有机地融为一体 ,从而开辟了多酸金属有机化学的新… 相似文献
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In the presence of Bu4NBr acting as phasetransfer reagent, organothiophosphoryl polyoxotungstate derivatives α-[RP(S)]2PW9O54^5- (R=C6Hs, C6H11) have been obtained by reaction of the trivacant β-[PW9O34]^9- anions with electrophilic C6H5P(S)Cl2 or C6H11P(S)Cl2 in acetonitrile. These new organic-inorganic hybrid anions have been characterized by elemental analysis, IR, ^31P and ^183W NMR spectroscopy. The collective application of the spectroscopy data of these new species indicates that the hybrid anion consists of an α-[PW9O34] framework on which are grafted two RP(S) groups through P-O-W bridges. The five-line ^183W spectra indicate that the hybrid anions possess Cs symmetry in acetonitrile. 相似文献
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十一钨钛硅酸盐的合成,表征及电化学性质 总被引:1,自引:0,他引:1
合成了钛取代杂多硅钨酸盐K6SiW11TiO40·16H2O(SiW11Ti),并用元素分析、红外光谱、紫外-可见光谱和183WNMR谱进行表征.对其溶液电化学性质进行了讨论.其还原过程包括钛的单电子还原和钨的双电子两质子加合过程.在弱酸性溶液中SiW11Ti对NO-2的还原有良好的催化作用 相似文献
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Synthesis,CharacterizationandCatalyticActivityofPolyoxometalatesDerivedfromα-P_2W_(15)O_56~(12-)LigandMENGLu,andLIUJing-fu(Depa... 相似文献
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The First KEGGIN-Anion with Tetrahedral Coordination of Copper(II)-Oxygen: [α-Cu0,4(H2)0.6O4W12O36]6? The solution of the CuII-containing heteropolyanion was prepared starting from an aqueous solution of Na2WO4, adjusting to pH 5–6 by adding slowly a solution of Cu(NO3)2 in HNO3. The addition of the corresponding amount of N(CH3)4Br to the concentrated solution led to the crystallization of the greenish-yellow mixed crystals (TMA)6[α-Cu0.4(H2)0.6O4W12O36] · 9 H2O. After repeated recrystallization it has been investigated by chemical, spectroscopic (IR/Raman, UV, 183W/1H-NMR, ESR) and X-ray diffraction methods (monoclinic; space group P21; a = 13.117(4), b = 21.466(4), c = 13.223(3) Å, β = 91.60°; Z = 2; Dc = 3.041 g · cm?3; R = 8.0%). The distances of the four “tetrahedral” oxygen atoms to the position (0, 0, 0) range from 1.67 to 1.93 Å. The alternative occupation of the central KEGGIN position with copper(II) and two protons, respectively, accounts for the different distances. The prepared solid solution represents the first example for the tetrahedral copper(II)-oxygen coordination in any heteropolyanion compound. 相似文献
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JianGONG ChangLuSHAO LunYuQU 《中国化学快报》2004,15(3):333-334
A new organophosphazene polyoxotungstate, [(N3P3)(SiW11O39H2)3]^12-, has been prepared by reaction of hexachlorocyclotriphosphazene with undecatungstosilicate, and characterized by elemental analysis, infrared spectroscopy, and multinuclear ^31p NMR. 相似文献
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Laurence Carlton Lebohang V. Mokoena Manuel A. Fernandes 《Magnetic resonance in chemistry : MRC》2013,51(4):199-202
Tungsten‐183 NMR data are reported for the complexes cis‐[W(CO)4(PPh3)(4‐RC5H4N)] (R = H, Me, Ph, COMe, COPh, OMe, NMe2, Cl, NO2). The 183W chemical shift (obtained by indirect detection using 31P) is found to correlate with the Hammett σ function for the group R, with 183W shielding increasing approximately linearly with the donor strength of the pyridine over a range of 93 ppm. The X‐ray structures of cis‐[W(CO)4(PPh3)(4‐MeOC5H4N)] and cis‐[W(CO)4(PPh3)(4‐PhCOC5H4N)] are also reported. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
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Mohamed Haouas Julien Trébosc Catherine Roch‐Marchal Emmanuel Cadot Francis Taulelle Charlotte Martineau‐Corcos 《Magnetic resonance in chemistry : MRC》2017,55(10):902-908
The potential of high‐field NMR to measure solid‐state 95Mo and 183W NMR in polyoxometalates (POMs) is explored using some archetypical structures like Lindqvist, Keggin and Dawson as model compounds that are well characterized in solution. NMR spectra in static and under magic angle spinning (MAS) were obtained, and their analysis allowed extraction of the NMR parameters, including chemical shift anisotropy and quadrupolar coupling parameters. Despite the inherent difficulties of measurement in solid state of these low‐gamma NMR nuclei, due mainly to the low spectral resolution and poor signal‐to‐noise ratio, the observed global trends compare well with the solution‐state NMR data. This would open an avenue for application of solid‐state NMR to POMs, especially when liquid‐state NMR is not possible, e.g., for poorly soluble or unstable compounds in solution, and for giant molecules with slow tumbling motion. This is the case of Keplerate where we provide here the first NMR characterization of this class of POMs in the solid state. Copyright © 2017 John Wiley & Sons, Ltd. 相似文献