Zur Theorie der Vorwärtsasymmetrie bei der Photospaltung des Deuterons

The forward asymmetry in the differential cross section for the photo disintegration of the deuteron has been calculated on the basis of a phenomenological theory for energies up to 80 MeV. The formulas for this asymmetry, which come from theE1-E2-andM1-M2-interference, are given, assuming the validity ofSiegert's theorem. TheE2-andM2-amplitudes are calculated approximately, using the Hulthén wavefunction with a 4% D-state admixture for the ground state and scattered waves determined by the phase shifts given by Marshak for the final states. The contribution of theM1-M2-interference turns out to be unimportant for the asymmetry, theE1-E2-interference giving the main effect. In the differential cross section,dσ/dΩ=a + b sin ² ? + c cos ? + d cos ? sin ² ?, we have obtained a very low value forc and the ratioc/d is approximately equal toa/3b. This is in contradiction to the assumptionc/d=a/b made in the previous analysis of the experimental data. This ratio seems to be insensitive to the value of the D-state admixture. For the lover energiesE _γ=10 MeV andE _γ=20 MeV the theoretical values for “d” are in agreement with the experimental ones. For the energies 54 and 80 MeV we have made a comparison of the theoretical differential cross sectiondσ/dΩ, taking into account the values for “a” and “b”, obtained in a former work ie, with the measureddσ/dΩ.     

Elektrodencharakterisierung und grenztemperatur bei der elektrochemischen messung der sauerstoffaktivität an platin

Solid electrolyte potentiometry can be a valuable tool in heterogeneous catalysis. Its applicability is restricted by the existence of a low temperature limit. The study of different pretreatments of the electrodes shows that, in the case of the cell Pt/ZrO₂ (Y₂O₃)/Pt, this limit is due to the electrochemical reaction itself. Therefore the preparation should aim at a maximum value of the three phase boundary-line gas-electrode-electrolyte to enable measurements in a catalytically interesting temperature domain.