Der Quartett-Zustand desR-Zentrums in Kaliumchlorid-Kristallen

Optical absorption and paramagnetic resonance of KCl crystals containing preferentiallyR-centers have been studied during and after excitation with 430 mμ or 365 mμ light at 90 °K. A partly metastable, partly stable state has been detected and identified as the quartet state of theR-center, which proves to be an association of threeF-centers forming an equilateral triangle in the (111) plane of the crystal as proposed byvan Doorn andHaven andPick. — The crystals used were additively colored to 6.6·10¹⁷ F-centers/cm³ and illuminated withF-band light at room temperature until theR/M-ratio reached its maximum value. During light excitation the optical spectrum in the region of theR-bands shows characteristic small changes. A part of these changes disappears spontaneously with a time constant τ=14.5 sec when the light excitation is removed (“temporary bleaching”). The remaining part has a similar spectral distribution. It is completely stable in the dark, but can be bleached within a few seconds by illumination with 840 mμ light. — Electron spin resonance of the crystal under light excitation shows in addition to theF-center line a seven-line spectrum with strong angular dependence, if the field is rotated in a (110) plane. The maximum splitting is 674 G, the width of the individual lines 35.5 G. The angular dependence of the spectrum can be fitted to a fine-structure spin Hamiltonian

$$H = g\mu _B \vec H_0 \vec S + D[S_z^2 - \tfrac{1}{3}S(S + 1)]$$     

Elektronenspinresonanz- und optische Untersuchungen zur FarbzentrenreaktionF⇄F′ in KCl-Kristallen

Simultaneous measurements of optical absorption and electron spin resonance of additively colored KCl crystals have been carried out during the optical bleaching ofF-centers at ?90°C. TheF-center resonance signal does not change in its significant properties e.g. line shape, line width,g-value, and saturation behavior, but it decreases proportional to the decrease of the opticalF-center absorption band. No ESR-signal due to theF′-center could be observed. The time dependence of theF?F′-center conversion has been investigated by ESR and optical measurements. It does not give any indication of a paramagnetism of theF′-center, too. The kinetics of the thermal decay of theF′-center at ?90°C have been studied. One can interpret the time dependence of this process, if one assumes that the mean lifetime of anF′-center depends on the distance of the nearest halogen ion vacancy. The expectation of life of theF′-centers therefore increases during the thermal decay, as the mean distance between remainingF′-centers and vacancies increases.     

The emission spectrum of the NS molecule

The investigation of the emission spectrum of NS molecule has been carried out by using a Littrow-type quartz spectrograph and a two meter normal incidence type vacuum spectrograph. Theγ-system (² σ-² π), in which only the bands havingv′=0 and 1 were known previously, has been extended tov′=4. TheδG values of the upper state do not show much regularity indicating some perturbation in this state. The vibrational constants for theΒ-system (² δ-² π) have also been modified slightly by observing more bands for this system. Four new systems, all of which have the ground state as their common lower state, have been observed in the ultraviolet and the vacuum ultraviolet regions.     

Volumenänderung durch Gitterverzerrung um ein F-Zentrum in Alkalihalogenidkristallen

The lattice-distortions in the vicinity of anF-centre in alkalihalide crystals and the volume change arising from the lattice distortions around this defect are being calculated. Only theF-centre ground state is considered and the effect of lattice vibrations is neglected. The interaction of theF-electron with the ions is described in terms of effective potentials, and a vacancy-centered wave function is calculated for theF-electron. In calculating the lattice distortions, an approximative procedure is adopted in which only the ions in the vicinity of anF-centre receive an atomistic treatment whereas the remainder of the crystal is treated as an elastic continuum. The volume change caused by the lattice distortions around anF-centre is calculated, using a method ofFischer andHahn which does not require an exact knowledge of the asymptotic strainfield around the point defect. The ions of the first, second and third shell around theF-centre-vacancy are found to be displaced in an outward direction. For the volume-change perF-centre the following values were obtained: 0.26a ³ in NaCl, 0.31a ³ in KCl and 0.35a ³ in KBr,a being the interionic distance. In order to check the validity of some of the approximations employed in the calculations, the volume changes caused by substitution of alien alkali- or halideions are computed and are found to be in good agreement with experimental data.     

Possible violation of the δS=δQ selection rule in leptonic decays of σ+-hyperons

We have found a possible example of the rare decayσ ⁺ →nΜ ⁺ Ν, which violatesδS=δQ. The positive decay track of theσ ⁺ comes to rest in the hydrogen bubble chamber and decays into ane ⁺. This track has all the characteristics of a stoppingΜ ⁺. The decay neutron fortuitously scatters twice, producing two recoil protons. The only other possible interpretation of the event isσ ⁺→nγ(π ⁺ →Μ ⁺ Ν), where theπ ⁺ →Μ ⁺ Ν decay produces no deflection (θ<0.1 rad) and no significant change in curvature. Using thep-wave radiative decay predictions ofBarshay et al. we calculate that the integrated branching ratio for such “accidental” events isγ(σ ⁺ →nγ(π ⁺ →Μ _stop ⁺ Ν))/γ(σ ⁺ →nπ ⁺)=1.6×10^?6. Most of the contribution to this “accidental” branching ratio comes from radiative decays where theπ ⁺ mesons have ranges less than 1 mm (p _π<20 MeV/c). If one excludes thoseΜ's with ranges less than 1.2 cm the above “accidental” branching ratio becomes 5.5×10^?7. With this figure we estimate that we should have seen 6.5×10^?2 events of this type thusfar in our experiment. The neutron momentum does not help in deciding between the two hypotheses. We therefore assign a confidence level of 7% for the radiative hypothesis. For the leptonic hypothesis we obtain an estimate of the branching ratio,γ(σ ⁺ →nΜ ⁺ Ν)/γ(σ ⁺ →nπ ⁺)=5×10^?5. If one further accepts theσ ⁺ →nπ ⁺ Ν event reported byBarbaro-Galtieri et al. and theσ ⁺ →ne ⁺ Ν event reported byNauenberg et al., one obtains theδS=?δQ leptonic branching ratio [γ(σ ⁺ →nΜ ⁺ Ν)+γ(σ ⁺ →ne ⁺ Ν)]/γ(σ ⁺ →nπ ⁺)=(4±3)×10^?5.     

Kern-Isomerie bei In116

The short lived indium isomer produced by thermal neutron capture is confirmed to be In¹¹⁶. A new determination of half-live andγ energy yieldsT _1/2=(2.17α0.07) sec andE _γ=(164±1) keV. From measurement of theK shell conversion coefficient follows that the multipolarity of the transition isE 3, leading to a spin and parity assignment of 8^? for the isomeric level.     

Neutroneneinfangs-Gammaspektrum und Niveauschema von Erbium 167

The (n, γ)-spectrum of Er 167 was investigated by means of the Risø bent crystal spectrometer. The energies and intensities of 47 transitions were measured. 22 of them were fitted into a level scheme. The rotational bands of theK=7/2⁺[633],K=1/2^?[521], andK=5/2^?[512] states were found up to the spin valuesI=11/2⁺, 9/2^?, and 7/2^?. Gammavibrational states of these Nilsson orbitals were determined or proposed. The energy of theK=5/2^?[523] state was suggested. Branching ratios of gamma transitions were compared with theoretical predictions.     

Meson-baryon scattering with SU (3) invariant interactions

The static model invariant under SU₃ is discussed. The baryons and mesons are assigned according to the “eightfold way”, and the Low equation for the scattering matrix is derived. The scattering matric has been diagonalized for arbitrary mixing ofF- andD-type coupling and the crossing matrix has been calculated. To determine the mixing of the two couplings photoproduction cross sections have been calculated. From the comparison of theK ⁺ Λ andK ⁺ Σ0 production cross sections with experiment it follows that α=D/F=3.5. For this value of α the model predicts the 3/2 decublet resonance in very good agreement with the experimental situation.     

Determination of the πN charge exchange scattering amplitude from the experimental data at high energies

The difference between theπ ⁺ p andπ ^? p diffraction peaks is used for an estimate of the imaginary part of the charge exchange scattering amplitude. The imaginary part has a narrow peak in the forward direction and passes over to negative values at a momentum transfert of about ?0.15(GeV/c)². If the charge exchange amplitude is dominated by the contribution of theρ Regge pole, the peak is mainly due to thet-dependence of the residue function and a narrow forward peak is expected in the charge exchange angular distribution.     

Messung der Hyperfeinstrukturaufspaltung des4F9/2-Grundzustandes im Co59-I-Spektrum und Bestimmung des Quadrupolmomentes des Co59-Kernes

The hyperfine structure splittings of the electronic ground statea ⁴ F _9/2 in the Co⁵⁹-I-spectrum have been measured with a magnetic atomic-beam resonance-apparatus. From these splittings the magnetic dipole and electric quadrupole interaction constants are found to beA (a ⁴ F _/2)=(450,284±0,01) Mc/sec,B (a ⁴ F _9/2)= (139,63±0,5) Mc/sec. Taking into account the mixture of thea ⁴ F _9/2 state with states of the same 3d ⁷ 4s ²-electron-configuration, an electric quadrupole moment of Co⁵⁹ ofQ=(0,404±0,04) 10^?24 cm² was obtained. No Sternheimer-correction has been included.     

Study of the atom-phonon coupling model for (SC) partition function: first order phase transition for an infinite linear chain

In spin-conversion (SC) compounds containing molecules organized around an iron (II) ion the fundamental level of the ion is low spin (LS), S = 0, and its first excited one is high spin (HS), S = 2. This energy diagram is due to the ligands field interaction on 3d electrons and to the spin pairing energy. Heating the compound increases the magnetic susceptibility which corresponds to a change of populations of both levels and consequently a change of spin value of the molecules. This mechanism, called spin conversion (SC), can be accompagnied by thermal hysteresis observed by studying magnetic susceptibility or high spin fraction. In that case one considers that the (SC) takes place through a first-order phase transition due to intermolecular interactions. In the atom-phonon coupling model the molecules are considered as two-level systems, or two-level atoms, and it is assumed that the elastic force constant value of the spring which links two atoms first neighbours is depending on the electronic states of both atoms. In this study we calculate the partition function of a linear chain of N atoms (N ≤ 16) and we describe the role of phonons and that of the parameter Δ which corresponds to the distance in energy between both levels. The chain free-energy function is F _atph . We introduce for the chain a free-energy function defined by the set (F _HS , F _LS , F _barr ) and we show that F _atph tends towards the previous set when N → ∞. The previous set allows to describe a first order phase transition between a (LS) phase and a (HS) one. At the crossing point between the function F _LS and F _HS , and around this point, there is an intermediate free-energy barrier which prevents the chain to change phase which can lead to thermal hysteresis. The energy gap between the free-energy function F _atph and that defined by the set (F _HS , F _LS , F _barr ) is small. So we can expect that a nanoparticule takes for free-energy function that defined by the set and then displays a thermal hysteresis.     

Winkelverteilungen elastisch an Edelgas-Atomstrahlen gestreuter Elektronen; Spinpolarisation eines an Argon gestreuten 40 eV-Elektronenstrahls

Various non-leptonic decay modes of baryons are calculated in a simple quark model. Form factors for various matrix elements are taken both from experiment and the quark model. Additionally theK→2π andK→3π decay modes are computed in the same model. The theory has theΔ I=1/2 rule and static SU⁶ built-in. A relation between the∑ ⁺→N ⁺ π ⁺ decay, not calculable in the model, and theK→3π decay is given via an effective six quark interaction. Agreement with experiment is order of magnitude for the baryonic decays and worse for theK decays.     

On the calculation of the two-point function for the thirring-model by the method of functional integration

By the method of functional integration the two-point functionS _F for the spinor model with the interaction\( - \lambda (\bar \psi \psi )^2 \) is calculated in a two-dimensional space-time. After Fourier-transformationS _F (p) results as a power series with respect to 1/√λ. If we change the order of terms, we get a series in powers of γp. Each coefficient is a series in powers of 1/√λ. The first terms of this series are considered as a good approximation for bigλ. By reasons of convergence of the integrals we must displace the expansion centre of the series in powers ofγ p fromp ²=0 top ²=a ².     

Low-energy Ce spin excitations in CeFeAsO and CeFeAsO<Subscript>0.84</Subscript>F<Subscript>0.16</Subscript>

We use inelastic neutron scattering to study the low-energy spin excitations of polycrystalline samples of nonsuperconducting CeFeAsO and superconducting CeFeAsO_0.84F_0.16. Two sharp dispersionless modes are found at 0.85 and 1.16 meV in CeFeAsO below the Ce antiferromagnetic (AF) ordering temperature of T _N ^Ce ? 4 K. On warming to above T _N ^Ce ? 4 K, these two modes become one broad dispersionless mode that disappears just above the Fe ordering temperature T _N ^Fe ? 140 K. For superconducting CeFeAsO_0.84F_0.16, where Fe static AF order is suppressed, we find a weakly dispersive mode center at 0.4 meV that may arise from short-range Ce-Ce exchange interactions. Using a Heisenberg model, we simulate powder-averaged Ce spin wave excitations. Our results show that we need both Ce spin wave and crystal electric field excitations to account for the whole spectra of low-energy spin excitations.     

Nuclear magnetic relaxation of spin<Emphasis Type="Italic">I</Emphasis>=1/2 scalar coupled to a quadrupolar nucleus in the presence of cross-correlation effects

The rigorous treatment of relaxation for the dipolar-multipolarAX spin system (I=1/2,S>1/2) in the presence of the dipolarI-S coupling, anisotropy chemical shift and quadrupolar interaction ofS spin is proposed. The calculations of the spin evolution under the relaxation Hamiltonian are based on the second-order time-dependent perturbation theory and are carried out in the operator representation. For this task the double commutator identities of the type [[I _±S _z ⁿ ,A _q ^μp ]A _?q ^μp ] and [[I _zS _z ⁿ ,A _q ^μp ]A _?q ^μp. ] are derived. The fist-order differential equations for the evolution of longitudinal two-spin orderI _zS _z ⁿ , z=magnetization ofS spinS _z ⁿ and coherences <I _±S _z ⁿ > in the spin systemIS with scalar coupling between spin 1/2 and quadrupolar spinS>1/2 were obtained. These equations are used to get equations for the evolutions of each component of the multiplet structure of spinI. The imaginary part of the cross-correlation spectral density function and indirect spin-spin coupling Hamiltonian are taken into account. Equations for the longitudinal components of theI spin spectrum in the presence of cross-correlation effects were obtained also. Longitudinal and transverse relaxation times and cross-relaxation times in the presence of cross-correlation D-CSA, Q-CSA, Q-D were analyzed.     

Pion-pion interaction andK 2x03C0;x03C0;x03C0;-decay

The enhancement of theK _2π ⁺ -decay compared to theK _2π ⁰ -decay is discussed on the basis of the\(|\mathop {\Delta {\rm I}}\limits^ \to | = \tfrac{1}{2}\)-rule. The enhancement factor is calculated by dispersion methods which yield an expression depending only on the phase shift of the two pion system in theJ=0,I=0,2 state. This expression has been studied in the framework of simple models for the two-pion interaction in order to obtain a survey of the possibilities for the cause of the anomalous large ratioK _2π ⁺ /K _2π ⁰ . Only characteristic cases have been considered and, as far as possible, experimental results of theπ-π-interaction are taken into account.     

Der Zerfall des Cu61

Theγ-ray-spectrum of Ni⁶¹ associated with the E.C. andΒ ⁺-decay of Cu⁶¹ has been measured with a Ge(Li)-counter. The observed 14 newγ-ray-transitions led to a new level-scheme for this decay with Ni⁶¹-Ievels at: 67.7, 282.9, 656.0, 907.9, 1099.8, 1132.7, 1186.8, 1610.6, 1730.8 and 2128.0 keV. Five of these levels were known from earlier investigations of Cu⁶¹-decay, but all of them could be identified with some of previously reported levels found in scattering experiments. As far as possible spin and parity assignments have been made and are compared with the results of scattering experiments.     

Effect of the Lattice and Spin-Phonon Contributions on the Temperature Behavior of the Ground State Splitting of Gd<Superscript>3+</Superscript> in SrMoO<Subscript>4</Subscript>

The temperature behavior of the EPR spectra of the Gd³⁺ impurity center in single crystals of SrMoO₄ in the temperature range T = 99–375 K is studied. The analysis of the temperature dependences of the spin Hamiltonian b ₂ ⁰ (T) = b₂(F) + b₂(L) and P ₂ ⁰ (T) = P₂(F) + P₂(L) (for Gd¹⁵⁷) describing the EPR spectrum and contributing to the Gd³⁺ ground state splitting ΔE is carried out. In terms of the Newman model, the values of b₂(L) and P₂(L) depending on the thermal expansion of the static lattice are estimated; the b₂(F) and P₂(F) spin-phonon contributions determined by the lattice ion oscillations are separated. The analysis of b ₂ ⁰ (T) and P ₂ ⁰ (T) is evidence of the positive contribution of the spin-phonon interaction; the model of the local oscillations of the impurity cluster with close frequencies ω describes well the temperature behavior of b₂(F) and P₂(F).     

Mechanisms of ionization of <Emphasis Type="Italic">F</Emphasis><Subscript>2</Subscript>-centers in laser media on the basis of LiF crystals

F₂ color centers with a superhigh concentration (5000-cm^–1 absorption coefficient at 450 nm) were formed by high-density electron beams in a layer of LiF crystals of micrometer thickness. The F₂-centers excited by high-power nanosecond wide-band optical pulses (the “soft” pumping regime) efficiently amplified the laser radiation and showed high stability under these conditions. A low stability of F₂-centers to laser radiation (the “hard” excitation regime) is explained by the dissociation of (F ₂ ⁺ , F^–) pairs induced by two-step ionization of F₂-centers: (2hν > 4.5 eV) → F₂ → (F₂)* → F ₂ ⁺ + e; F + e → F^–; F ₂ ⁺ + F^– → 3F.     

Winkelkorrelationsmessungen an >30y Holmium 166 und Bestimmung desg R -Faktors des 4+-Rotationsniveaus von Erbium 166

The spins of several excited states of Er¹⁶⁶ have been investigated byγγ-angular correlation measurements. The spin sequence 0+, 2+, 4+, 6+ for the ground state rotational band was presumed to be correct. Unique assignments were derived for the states of 1076 keV, 1377 keV and 1785 keV asI=5, 7 and 6 respectively. These results are in agreement with the spins proposed byGallagher jr. andSoloviev. The multipolarities of theγ-transitions of 408 keV, 709 keV, 811 keV and 831 keV were derived as 95%E1+(5±1)%M2, 99·6%E1+(0·4±0·5)%M2, 99·1%E2+(0·9±0·3)%M1, and 96·1%E2+(3·9±1)%M1 respectively. The unusual mixing ratios of the transitions of 811 keV and 831 keV can be understood as a consequence of theK-selection rule. Eachγ-transition from the 1785 keV state should be stronglyK-forbidden and one expects a half-life ofT _1/2≈3·10^?9s. A measurement of the time spectrum of the coincidences between theβ-radiation and the high energyγ-lines gave however:T _1/2(1785 keV state)≦3·10^?10s. The rotation of the angular correlation between the 184 keV line and theγ-group at 820 keV has been measured in an external magnetic field of 53000 gauss as:ω·τ(4+)=0·083±0·006. This value contains small corrections for an additional rotation of the angular correlation of the 831 keV–184 keV triple cascade in the 6+state and for a small attenuation by internal fields. WithT _1/2(4+state)=1·23·10^?10s, andβ=7·08 one gets for theg-factorg _R=+0·266±0·024 in good agreement with recent results for the 2+ state.