Fluorescence and absorption of polystyrene exposed to UV laser radiation

We show that when polystyrene is exposed (for 15–60 sec) to a UV laser light beam (λ = 248 nm), its absorption and luminescent properties change significantly. In the irradiated polymer, optical centers are formed with absorption bands in the 280–460 nm region and fluorescence bands in the 330–520 nm region. We have established the chemical structure of the optical centers for fluorescence of polystyrene. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 1, pp. 54–58, January–February, 2006.     

Novel deep centers for high-performance optical materials

Materials exhibiting strong optical emission also exhibit strong absorption at the same wavelengths because both emission and absorption are governed by the same optical dipole and density-of-states. Laser action requires a carrier injection large enough for emission to exceed absorption at laser wavelengths. Thus, strong self-absorption at luminescent wavelengths raises the operating current of LEDs, lasers, and optical amplifiers. Here we demonstrate that, contrary to conventional expectations, materials designed with novel deep centers achieve surprisingly large optical emission while, simultaneously, the inverse process of optical absorption remains very small. A striking consequence is that materials designed with our novel deep centers achieve transparency at a carrier injection which is four-orders-of-magnitude lower than in all technologically important semiconductors. Simultaneously, and surprisingly, our novel deep centers in GaAs achieve an optical gain, Einstein B coefficient, and radiative efficiency significantly larger than in direct-band-gap materials at 1.3–1.5 μm. We engineered this dramatic reduction of the injection to achieve transparency while retaining strong optical emission in our novel material by making use of a Franck–Condon shift of absorption away from luminescent wavelengths. PACS 71.55.Eq; 71.55.-i; 78.67.-n; 81.10.-h; 85.60.Jb     

Spectroscopic characteristics of anionic centers in α-Al<Subscript>2</Subscript>O<Subscript>3</Subscript> crystals bombarded by Cu<Superscript>+</Superscript> and Ti<Superscript>+</Superscript> ions

We have studied the effect of bombardment by Cu⁺ and Ti⁺ ions with energy 30 keV on the optical absorption and luminescence of F centers in oxygen-deficient aluminum oxide. We have shown that in the induced optical absorption spectra there are six components of gaussian shape, which can be assigned to absorption bands of F⁺, F², and F₂⁺ centers. We have established that bombardment of the samples by ion beams has a weak effect on the thermoluminescence parameters in the 3.0 eV and 2.4 eV bands, while in the 3.8 eV luminescence band for F⁺ centers, the thermoluminescent response increases considerably. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 3, pp. 422–424, May–June, 2008.     

Luminescence excitation spectra and characteristics of luminescence centers with overlapping absorption bands

For an ensemble of different types of luminescence centers with overlapping absorption bands, with no restrictions on the optical densities, we have obtained relations describing the luminescence excitation spectra for each type of center. We consider transformations of the relations in some limiting cases. We suggest a procedure for using the equations obtained to determine the characteristics of the luminescence centers. Some of these procedures have been experimentally implemented in study of intrinsic radiation color centers in lithium fluoride crystals. We have determined the ratios of the luminescence quantum yields for F₂ and F₃⁺ color centers, and we have observed that a major role is played by nonradiative transitions in deactivation of the first excited singlet state of F₃⁺ centers. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 3, pp. 365–371, May–June, 2008.     

Metastable optical absorption of relaxed electronic excitations in BeO-Zn crystals

Spectra of metastable optical absorption and its relaxation kinetics have been studied in zinc-doped BeO crystals by time-resolved pulsed absorption spectroscopy. A comparison of the observed induced optical absorption of self-trapped excitons and small-radius excitons bound to the zinc impurity suggests that their hole components have similar structures and reveals distinctive features of “forbidden” optical transitions in the electronic components. Metastable optical absorption in Zn⁺ centers has been discovered. It is shown that the small-radius excitons bound to the zinc impurity form in the hole stages of thermally stimulated tunneling recombination processes involving Zn⁺ electronic centers. It has been found that the high recombination probability of the electronic and hole centers created in BeO-Zn crystals by an electron beam may be due to the high degree of their spatial correlation. Fiz. Tverd. Tela (St. Petersburg) 41, 601–605 (April 1999)     

The absorption spectrum of radiation-colored SrCl2-Ce crystals

We investigate the spectra of the x-ray radiation-induced absorption of SrCl₂−Ce crystals over the spectral range 345–830 nm and their temperature transformations in the interval from 77 to 450 K. We found that radiative color centers are characterized by a complex spectrum of induced absorption that contains wide bands of photochromic PC (750, 519, 378 nm) and PC⁺ (620, 446, 340 nm) centers and quasi-linear bands of Ce²⁺ centers. The most significant thermal transformations of radiative color centers occur in the vicinity of the thermostimulated luminescence peak of 394 K, at which the holes of the PC⁺ centers recombine with the electrons of the Ce²⁺ centers. Ivan Franko L’vov State University, 8, Kirilla i Mefodiya St., L’vov 290005, Ukraine. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 4, pp. 545–547, July–August, 1997.     

Effect of a solid substrate on orientational ordering and the process of associate formation in thin interlayers of solutions of some organic compounds

We have studied the vibronic absorption spectra of thin submicron interlayers of anisole and nitrobenzene solutions as a function of the concentration and thickness of the interlayer. We have observed isosbestic points in a series of spectra obtained for different concentrations and thicknesses. This in turn is due to the existence in the system of two types of absorbing centers, which we connect with monomers and molecular associates (dimers). We discuss the relative contribution of different types of interactions leading to dimer formation. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 4, pp. 443–446, July–August, 2006.     

Optical properties of Ce–Ti-containing silicate glasses

Silicate glasses doped with ceria and titania have been studied. Such co-doping determines the specific coloration of the glasses with adjustable absorption in the visible spectral region. Based on measurements of optical transmittance and photoluminescence and studies of electron paramagnetic resonance, it was established that the features of their optical properties are due to the formation of chromophore centers incorporating cerium and titanium ions. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 76, No. 2, pp. 202–208, March–April, 2009.     

Recombination kinetics in nonlinear defective LiB3O5 crystals

A study of recombination kinetics in LiB₃O₅ (LBO) crystals by time-resolved luminescence and absorption spectroscopy is reported. An investigation of the kinetics of transient optical absorption (TOA) and luminescence under ns-scale electron-beam excitation performed within a broad temperature range of 77–500 K and a 1.2–5-eV spectral interval has established that the specific features in the recombination kinetics observed in LBO involve electronic, B²⁺, and hole, O⁻, trapping centers. The TOA and luminescence kinetics, as well as their temperature dependence, are interpreted by a model of competing hole centers. Relations connecting the kinetics parameters and the temperature dependence to the parameters of the main LBO point defects are presented. Fiz. Tverd. Tela (St. Petersburg) 40, 2008–2014 (November 1998)     

Modeling the atomic and electronic structure of diamond nanocrystals containing [NV]<Superscript>−</Superscript> centers by the density functional method

We have used the density functional method to model the atomic and electronic structure of diamond nanocrystals passivated by hydrogen atoms and either not containing defects or containing a single [NV]⁻ center. We have shown that in all cases, after relaxation the nanocrystals are formed as diamond-like structures. We have studied the features of the electronic structure of the nanocrystals. We have analyzed in detail the mechanism for the formation of energy levels in the bandgap due to [NV]⁻ centers. We have established that the optical absorption and fluorescence spectra for the [NV]⁻ centers are mainly associated with transitions of electrons between the highest occupied β orbitals (projection of the electron spin equal to +1/2) and lower unoccupied α orbitals (projection of the electron spin equal to −1/2). The results on the localization and energy position of the states in the bandgap match data obtained for the [NV]⁻ center in bulk diamond. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 1, pp. 86–92, January–February, 2007.     

Recording of selective intracavity absorption at doubled frequencies of multimode laser radiation

We carried out measurements of the spectral distribution of wideband dye laser generation intensity within the limits and in the vicinity of an absorption line with its simultaneous recording at the frequencies of the fundamental and second harmonics of laser radiation. In the laser cavity we placed optical cuvettes with active and absorbing media, as well as selecting and nonlinear-optical elements. We show that at double frequencies the contrast of the narrow-band hole in the multimode laser generation spectrum increases. The gain in the concentration sensitivity of measurements depends in this case on the value of the absorption coefficient being determined. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70, F. Skorina Ave., 220072, Minsk, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 65, No. 4, pp. 516–521, July–August, 1998.     

Effect of neutron irradiation of colorless sapphire (leucosapphire) single crystals on their absorption and luminescence spectra

Features of the thermoradiative changes in the optical absorption and luminescence spectra of leucosapphire (colorless sapphire) crystals irradiated by neutron fluences within the range 5·10¹⁵ to 5·10¹⁹ cm⁻² have been studied in the visible region. The stepwise character of these processes was established as well as the basic steps involved in bleaching the induced color of the wafers as a result of isochronal annealing. Some anomalies have been observed in the temperature dependence of the optical density of the 460–620 nm bands, the activation energies for the color centers as well as the color center concentrations have been calculated, and the nature of the radiation-induced centers has been analyzed. An analytical expression is proposed to describe the accumulation kinetics for the centers during irradiation of the crystals by reactor neutrons. It is concluded that there is an interconnection between, for example, the 460 nm color centers and the 540 nm luminescence centers, and that there is a common mechanism for the process of radiation-induced defect formation, initially responsible for their formation in the crystal. The possible effect of reabsorption of radiation on the behavior of the Y(Φ) curve in the irradiated material is discussed. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 2, pp. 247–251, March–April, 2007.     

Interaction of Magnetization Centers of Different Signs as the Cause of the Nonmonotonic Field Dependence of the Domain Wall Velocity in Synthetic Pt/Co/Ir/Co/Pt Ferrimagnets

The purpose of the work is to find the dependence of growth rate of magnetization centers of various types on their surrounding by other nucleation centers in a synthetic Pt/Co/Ir/Co/Pt ferrimagnet with perpendicular magnetic anisotropy. The following four types of nucleation centers exist in a sample with two ferromagnetic layers of different thicknesses: P+ centers correspond to the regions where the magnetizations of the thick and thin Co layers are directed along an applied field (↑↑); P– centers are the regions where the magnetizations of the layers are opposite to an applied field (↓↓); and AP+ and AP– centers correspond to the regions where the magnetizations of the thick and thin Co layers are opposite to each other and the total magnetic moment is along (↑↓) or opposite to (↓↑) an applied field, respectively. P– nucleation centers are found to be surrounded by AP+ regions in any field and exhibit a monotonic field dependence of their boundary. The field dependence of the growth rate of AP– nucleation centers is nonmonotonic since, as the field increases, they are surrounded by AP+ nucleation centers, AP+ and P– regions, and only P– nucleation centers in strong fields.     

Intracavity UV-range laser spectrometer

We suggest a variant, which has already been implemented, of a selective intracavity laser spectrometer with intracavity nonlinear optical conversion of the frequency range of generated multimode radiation. The apparatus provides a means for transition into the UV spectral range (shorter than 300 nm) to carry out direct recording and quantative investigation of strong resonance lines of atomic absorption, which earlier were beyond the reach of the intracavity method. We measured selective absorption in spectral lines of a number of metals: FeI 296.690 nm, TiI 294.200 nm, and GaI 287.424 nm. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, 70 F. Skorina Ave., Minsk, 220072, Belarus; e-mail: Ild@imaph.bas-net.by. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 6, pp. 875–879, November–December, 1999.     

Temperature dependence of the optical absorption in a bismuth titanium oxide crystal doped by aluminum

Results of experimental investigations into the temperature dependences of the absorption of optical narrow-band quasi-monochromatic radiation of semiconductor light-emitting diodes in the visible range of the spectrum in a bismuth titanium oxide crystal doped by aluminum are presented. It is demonstrated that experimental dependences for temperatures 27–70 °C can be described by the model of defects formed by donor-trap pairs that admit tunnel electron transitions between donor and trapping centers in each pair. __________ Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 12–16, June, 2008.     

Luminescence of CsBr:Eu films grown by liquid-phase epitaxy

By liquid-phase epitaxy from an aqueous alcoholic solution, we have obtained films of the well-known storage phospor CsBr:Eu, and we have studied their cathodoluminescence and photoluminescence (PL) spectra compared with the undoped CsBr films. We have established that the structure of the photoluminescence centers of the CsBr:Eu films when excited by laser radiation in the absorption band of the Eu²⁺ ions (λ = 337 nm) includes Eu²⁺-V_Cs isolated dipole centers and CsEuBr₃ aggregate centers, and also luminescence centers based on inclusions of hydroxyl group OH⁻ with the corresponding emission bands in the 440 nm, 520 nm, and 600 nm regions. We have studied the dependence of the spectra and the intensity of the photoluminescence for CsBr:Eu films on annealing temperature in air at 423–483 K, compared with analogous dependences for CsBr:Eu single crystals obtained from the melt. We have shown that annealing the films at T = 423–463 K leads to rapid formation of CsEuBr3 aggregate luminescence centers, while for T > 473 K thermal degradation of these centers occurs. We conclude that the observed differences between the photoluminescence spectra of CsBr:Eu films and CsBr:Eu single crystals may be due to additional doping of the films with OH⁻ ions. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 2, pp. 191–194, March–April, 2006.     

Photoelectric properties of In/n-CuIn5Se8 Schottky barriers

We have grown homogeneous CuIn₅Se₈ crystals with n-type conductivity and determined the activation energy for the donor centers. We created In/n-CuIn₅Se₈ Schottky barriers and obtained the first spectral dependences of the photoconversion quantum efficiency of these structures. From the results of analysis of the photoactive absorption edge of the Schottky barriers, we have interpreted the nature of the interband optical transitions and determined the bandgap for direct and indirect transitions in CuIn₅Se₈ crystals. We have established that it is feasible to use CuIn₅Se₈ in broadband optical photoconverters. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 4, pp. 502–505, July–August, 2006.     

Spectral-Luminescent and Lasing Properties of Aminocoumarin Derivatives in Thin Polymer Films

The absorption and fluorescence spectra and the lasing ability of aminocoumarin derivatives in thin polymer layers (0.5–0.8 μm) based on the copolymer methylmethacrylate with a methacrylic acid and the copolymer methylmethacrylate with glycidylmethacrylate formed by coating of optically transparent glass substrates have been studied. It is found that the intensity of absorption and luminescence as well as the lasing resource of coumarins are determined by the structure of the latter and by the nature of the polymer medium. Compositions based on the copolymer methylmethacrylate with glycidylmethacrylate and aminocoumarin derivatives with a fluorized methyl group at the 4th molecular position can be of interest in optical technologies (light transformers, amplifiers). __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 4, pp. 464–467, July–August, 2005.     

Recombination processes in europium-doped cadmium iodide crystals

Results of comprehensive research into optical and luminescent-kinetic characteristics of europium-doped cadmium iodide crystals excited by nitrogen laser radiation, α-particles, and x-rays are presented. Crystals under study have been grown by the Bridgman–Stockbarger method. The doping EuCl₃ admixture was introduced into the charge in quantities of about 0.05 and 1.0 mol%. Impurity absorption detected in the near-edge region of the crystals is interpreted as part of the Eu²⁺ ion long-wavelength band associated with f–d-transitions. The cation impurity and matrix defects in CdI₂:Eu²⁺ crystals create complex centers responsible for emission with a maximum in the 580–600-nm region. The short component in the luminescence decay kinetics of weakly-doped crystal excited by α-particles and x-ray photons is due to the exciton emission characteristic of CdI₂. The slow component in the scintillation pulse results from recombination of charge carriers followed by creation of exciton-like states on the defect-impurity centers. Laser or x-ray excitation induces light-sum accumulation on the trapping levels at a depth of 0.2–0.6 eV that is mainly related to matrix microdefects. Trapping centers associated with the chlorine impurity are observed in the heavily-doped crystal. Photostimulated luminescence at 85 K arising at the electron stage of the recombination process is caused by recombination of electrons released from F-type centers with holes localized near the activator. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 76, No. 3, pp. 358–364, May–June, 2009.     

Polar-center phase nuclei in He+-irradiated CuO single crystals

Irradiation of various single-crystal CuO faces [ac,bc,(110)] with 4.6-MeV He⁺ ions has been found to result in reduction of CuO to Cu₂O and Cu on the irradiated and unirradiated sides, lifting of forbiddenness from optical transitions in the [CuO₄]⁷⁻ electron center in the 0.7–0.95-eV energy range, a change in dichroism near the bands corresponding to transitions in the hole centers, [CuO₄]⁵⁻, and electron centers, [CuO₄]⁷⁻, as well as in a resonant increase of absorption at 0.95–1.30 eV with an unusual polarization dependence. The results of He⁺ irradiation of CuO single crystals are discussed in terms of a model of the nucleation of the phase of polar (electron and hole) centers in copper-oxygen systems. Fiz. Tverd. Tela (St. Petersburg) 40, 419–424 (March 1998)