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1.
The thermodynamic parameters of epoxidized soybean oil (ESO) were determined by means of inverse gas chromatography (IGC) in the temperature range of 303.15 K-343.15 K. Two groups of probe solvents with different chemical natures and polarities were used to obtain information about ESO. The thermodynamic parameters—such as molar heat of sorption, weight fraction activity coefficient, Flory–Huggins interaction parameter, and partial molar heat of mixing—were obtained to judge the interactions between ESO and solvents at the studied temperatures. Also, the solubility parameters of ESO were found by plotting the graph of δ1 2/(RT) – χ 12/V1 vs. solubility parameters, δ1, of the probes. The results showed that the selected solvent ethyl acetate was a moderate solvent for ESO; n-hexane was a moderate (but close to a better) solvent; while the probes n-heptane, n-octane, n-nonane, and chloroform were excellent solvents. From the extrapolation to 298 K, the solubility parameter value of ESO was 16.70 (J/cm3)0.5.  相似文献   

2.
何庆华 《中国物理C(英文版)》2018,42(7):074004-074004
We present a new event mixing technique for measuring two-pion Bose-Einstein correlations(BEC)in reactions with only two identical bosons among three final state particles.This new mixing method contains a missing mass consistency(MMC)cut and an energy sum order(ESO)cut.Unlike the previous proposed pion energy cut,which abandons nearly half the original events,the ESO cut does not eliminate any original events and hence improves the statistics of both original events and mixed events.Numerical tests using theγp→π~0π~0p events around1 Ge V are carried out to verify the validity of the ESO cut.This cut is able to reproduce the relative momentum distribution of the original events in the absence of BEC effects.In addition,its ability to observe BEC effects is tested by an event sample in the presence of BEC effects.Simulation results show the BEC effects can be observed clearly as an enhancement in the correlation function,and the BEC parameters extracted by this event mixing cut are consistent with the input BEC parameters.  相似文献   

3.
In this paper we discuss the conditions under which coherent spontaneous emission can take place in an arbitrary sample of linear dimensions smaller than a cooperation length. These conditions guarantee that the atoms—field interaction can be treated up to the second order in the Generalized Master Equation for the atoms. An equation describing coherent spontaneous emission is derived and discussed. A comparison is made between this and other known theories.  相似文献   

4.
The evolution of the magnetic properties of Fe/Cr superlattices with a decrease in the nominal thickness of the iron layers down to atomic dimensions at which these layers are not continuous has been analyzed. Investigations have been carried out with multilayer samples with Fe-layer thicknesses in a range of 2–6 Å and Cr-layer thicknesses of 10 and 20 Å. It has been found that the system with various Fe-layer thicknesses and at various temperatures exhibits various magnetic phases—superparamagnetic, magnetically ordered, and nonergodic—characterized by the dependence of the magnetization of the sample on its magnetic prehistory. It has been shown that the observed nonergodic phase has the properties of a spin glass. A qualitative phase diagram of the magnetic states of the system has been obtained.  相似文献   

5.
Two different approaches — Källen’s and Brandt’s methods — for calculation of the Schwinger terms in the 1+1 dimensional Abelian and non-Abelian free current algebras are discussed. These methods are applied to calculation of the single and double commutators. The validity of the Jacobi identities is examined in 1+1 and 3+1 dimensions and in this way is given natural restriction on the regularization. It is shown that the Jacobi identity cannot be broken in 1+1 dimensions even using the regularization which fails in the 3+1 dimensional case. A connection between the Schwinger term and anomaly is shown in the simplest case of the Schwinger model.  相似文献   

6.
饶竹  王海霞  江林 《光谱实验室》2001,18(3):290-293
建立了以CO2为超临界流体的超临界萃取地质样品中有机物的分析方法,讨论和优化了超临界萃取条件,测定了茂名油页岩中的n-C13-n-C34,并与索式抽提结果作了对比,该方法测定茂名油页岩中的n-C15-n-C34链烷烃,相对标准偏差为(n=4)4.9%-23.8%,n-C13的相对标准偏差为9.2%(n=4),而传统经黄的索式抽提法测得的n=C15-n-C34链烷烃的相对标准偏差为11.2%-37.7%(n=4),n-C13的相对标准偏差为46.4%(n=4),本法与传统方法相比,具有高效,无热降解,无毒,选择性好,精密度好等优点,可直接用于GC,GC-MS的测定。  相似文献   

7.
Summary We present preliminary BVRI photometric data of 22 galactic globular clusters of the Southern hemisphere. The observations were carried out at the ESO Observatory, during two observing runs in August 1988 (VRI) and March 1989 (BVRI). In both periods half of the total number of nights was used to perform near-infrared (JHK) photometry of the same clusters: the goal of this quasi-contemporary photometry was to obtain a homogeneus sample of galactic clusters photometric observations, on a wavelength range as wide as possible. Paper presented at the V Cosmic Physics National Conference, S. Miniato, November 27–30, 1990.  相似文献   

8.
The massless ϕ4 theory in four Euclidean dimensions is shown not to have a multiple-instanton solution — even though it does have a single-instanton solution. Our criterion for a multiple-instanton solution of this nontopological theory is that the energy-momentum tensor of the solution be identically zero. Arguments are given that a similar result holds in any number of dimensions for a one-component scale-invariant scalar theory.  相似文献   

9.
Vertex dynamics models in two and three dimensions are applied to study grain growth including a limited mobility of triple points (two dimensions) and triple lines (three dimensions). A recent experiment on a triple node is used to validate the proposed model. The reduced triple node/line mobility in the case of a polycrystalline sample is shown to influence both, the grain growth kinetics and the grain size distribution function.  相似文献   

10.
The particle (cluster) size distribution function and the temporal variation of the middle (critical) and maximum particle dimensions have been calculated assuming that two mechanisms of mass transfer—those controlled by (i) the volume diffusion and (ii) the rate of chemical bond formation on the particle surface—are simultaneously operative. A comparison of the theoretical curves to experimental histograms shows that the proposed mechanism of particle growth can be realized in practice in the course of the Ostwald ripening.  相似文献   

11.
俞鸣人  王虹川  方志烈  侯晓远  王迅 《物理学报》1984,33(12):1713-1718
用俄歇电子能谱观察清洁InP表面在电子束照射下与真空室中H2O和O2的相互作用,发现水蒸汽所引起的电子束感应吸附氧的作用比氧气要明显得多。在吸附氧的同时,In和P的俄歇信号也发生变化,分析其过程为一种氧化过程,氧一开始先同表面的In结合成为氧化铟,随后向表面以内透入,并不断同In和P结合,氧化层的厚度随时间几乎是线性地增加的。与InP的自体氧化层的俄歇深度分布相比较,二者极为相似,所不同的是,电子束感应吸附的氧不足以使表面层中的磷全部氧化,而ESO的氧化层中磷的 关键词:  相似文献   

12.
The crystalline polysiloxane (—R2SiO—)n. where R= n-propyl, has been characterized through high-resolution X-ray diffraction patterns of the polycrystalline material and selected-area electron-beam diffraction patterns of single crystals. The smallest unit cell consistent with the diffraction data is tetragonal, with dimensions a = 9.52 ? 0.01 and c = 9.40 ± 0.05 . The probable space group is P41 (or P43).  相似文献   

13.
Physics of Particles and Nuclei Letters - Coulomb potentials for spaces with different dimensions are constructed. Space dimension dynamics is considered for two models: first—quarkonium,...  相似文献   

14.
ICP-AES同时测定镍锰钴硅铁铌硼合金中钴、铌、铁和硼   总被引:2,自引:0,他引:2  
用全谱直读ICP-AES分析技术,对试样溶解方法、元素分析谱线、共存元素干扰、背景校正、仪器分析参数等进行了研究,综合确定了最佳实验条件。将镍锰钴硅铁铌硼合金试样用硝酸、氢氟酸溶解,ICP-AES直接测定钴、铌、铁、硼。测定范围为:Co0.5%—12%、Fe0.1%—3%、Nb0.1%—5%、B0.05%—1.0%。加标回收率为96.6%—103.7%,相对标准偏差为0.37%—4.56%。方法简便、快速、准确。  相似文献   

15.
The most important properties of a laser resonator — such as theQ of the cavity, frequency shift and field amplitude distributions in the near and far field for the various oscillation modes — were quantitatively studied by means of a similarity law on a microwave interferometer with its handy dimensions (λ=3,2 cm). The results are widely in agreement with the theoretical predictions. The influence of deviations in the assumptions of the theory can also be tested, and it is possible, too, to investigate the non-ideal resonator.  相似文献   

16.
陈强  南余荣  邢科新 《物理学报》2014,63(22):220506-220506
针对部分状态不可测的永磁同步电机混沌系统, 结合自适应滑模控制和扩张状态观测器理论, 提出一种基于扩张状态观测器的永磁同步电机自适应混沌控制方法, 取消了系统所有状态完全可测的限制. 通过坐标变换, 将永磁同步电机混沌模型变为更适宜控制器设计的Brunovsky标准形式. 在系统部分状态和非线性不确定项上界均未知的情况下, 基于扩张状态观测器估计系统未知状态及不确定项, 并设计自适应滑模控制器, 保证系统状态快速稳定收敛至零点. 仿真结果表明, 该控制器能够改善滑模控制的抖振问题以及提高系统鲁棒性. 关键词: 永磁同步电机 混沌控制 扩张状态观测器 自适应滑模  相似文献   

17.
光子扫描隧道显微镜光场模拟与分析   总被引:1,自引:0,他引:1  
金振  王克逸 《光学学报》1998,18(6):42-747
采用“分割光束”的方法模拟计算了光子扫描隧道显微镜样品表面近场光强。用平面波对一维结构光盘进行的初步计算结果表明其表面近场光强分布相当复杂,一般情况下近场光强分布并不能真实地描述表面结构,近场光强受到表面结构很强的调制,当针尖与样品间距增大时,光强分布上会迭加上一些微小的波动。光强分布和样品表面结构之间会产生位移,这可能影响利用扫描近场光学显微进行纳加工和定位,将数值计算结果与他人的实验结果进行了  相似文献   

18.
The image charge potential is found for a parallel plate capacitor geometry in the infinite barrier Thomas—Fermi approximation to Poisson's equation. The material composition of the semi-infinite media are taken to be plasma-like although the jellium-dielectric interface is discussed in detail. Approximations such as single imaging (Newns) or that due to Gomer and Swanson are found to be reasonable in the center of large gaps but inaccurate for separations on the order of molecular dimensions. The dipole image potential is derived from the Green function solution for this geometry.  相似文献   

19.
《Physics letters. [Part B]》1986,182(2):169-173
Supersymmetric Yang—Mills theories in component formulation lead to coupled chiral and supersymmetry anomalies. In ten dimensions the coupled consistency conditions are solved to give the lending term for the supersymmetry anomaly.  相似文献   

20.
In this paper we classify Bianchi type VIII and IX space—times according to their teleparallel Killing vector fields in the teleparallel theory of gravitation by using a direct integration technique. It turns out that the dimensions of the teleparallel Killing vector fields are either 4 or 5. From the above study we have shown that the Killing vector fields for Bianchi type VIII and IX space—times in the context of teleparallel theory are different from that in general relativity.  相似文献   

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