Uniqueness, stability and Hessian eigenvalues for two-dimensional bubble clusters

A recent conjecture on two-dimensional foams suggested that for fixed topology with given bubble areas there is a unique state of stable equilibrium. We present counter-examples, consisting of a ring of bubbles around a central one, which refute this conjecture. The discussion centres on a novel form of instability which causes symmetric clusters to become distorted. The stability of these bubble clusters is examined in terms of the Hessian of the energy. Received 8 November 2001     

Mixing and sorting of bidisperse two-dimensional bubbles

We have examined a number of candidates for the minimum-surface-energy arrangement of two-dimensional clusters composed of N bubbles of area 1 and N bubbles of area λ ( λ≤1). These include hexagonal bubbles sorted into two monodisperse honeycomb tilings, and various mixed periodic tilings with at most four bubbles per unit cell. We identify, as a function of λ, the minimal configuration for N → ∞. For finite N, the energy of the external (i.e., cluster-gas) boundary and that of the interface between honeycombs in “phase-separated” clusters have to be taken into account. We estimate these contributions and find the lowest total energy configuration for each pair (N,λ). As λ is varied, this alternates between a circular cluster of one of the mixed tilings, and “partial wetting” of the monodisperse honeycomb of bubble area 1 by the monodisperse honeycomb of bubble area λ. Received 1 August 2002 RID="a" ID="a"e-mail: paulo@ist.utl.pt     

Vitrification in a 2D Ising model with mobile bonds

A bond-disordered two-dimensional Ising model is used to simulate Kauzmann's mechanism of vitrification in liquids, by a Glauber Monte Carlo simulation. The rearrangement of configurations is achieved by allowing impurity bonds to hop to nearest neighbors at the same rate as the spins flip. For slow cooling, the theoretical minimum energy configuration is approached, characterized by an amorphous distribution of locally optimally arranged impurity bonds. Rapid cooling to low temperatures regularly finds bond configurations of higher energy, which are both a priori rare and severely restrictive to spin movement, providing a simple realization of kinetic vitrification. A supercooled liquid regime is also found, and characterized by a change in sign of the field derivative of the spin-glass susceptibility at a finite temperature. Received 3 August 2000 and Received in final form 9 March 2001     

Lower bounds for the surface energy of two-dimensional foams

Amongst the two-dimensional cellular patterns that fill a plane, dry foams at stable equilibrium typify a particular subset for which the total perimeter P of cell boundaries ( i.e., films between bubbles) has a local minimum. For a given set of bubble areas Ai (i=1,..., N), P can be written in the form P=R(SigmaN(i=1) square root Ai)/2, where R is topology dependent. We seek the set of areas Ai and the cluster topology that minimise R, and propose lower bounds for R that set lower bounds for the surface energy of i) individual bubbles, with circular edges meeting at 2pi/3 angles at vertices (Plateau cells), and ii) infinite periodic bubble clusters.     

Dynamical effects of a one-dimensional multibarrier potential of finite range

We discuss the properties of a large number N of one-dimensional (bounded) locally periodic potential barriers in a finite interval. We show that the transmission coefficient, the scattering cross section σ, and the resonances of σ depend sensitively upon the ratio of the total spacing to the total barrier width. We also show that a time dependent wave packet passing through the system of potential barriers rapidly spreads and deforms, a criterion suggested by Zaslavsky for chaotic behaviour. Computing the spectrum by imposing (large) periodic boundary conditions we find a Wigner type distribution. We investigate also the S-matrix poles; many resonances occur for certain values of the relative spacing between the barriers in the potential. Received 1st August 2001 and Received in final form 18 November 2001     

A lattice of magneto-optical and magnetic traps for cold atoms

We describe basic periodic trapping configurations for ultracold atoms above surfaces. The approach is based on a simple wire grid and can be scaled to provide large arrays of periodically arranged magnetic or magneto-optical traps. The unit cells of the trap lattices are based on crossed wire segments. By alternating the current directions in the wires of the grid it can be distinguished between 3 basic lattice configurations. As a first demonstration, we used macroscopic wires in a 2 layer configuration to realize the unit cells of the lattices. With this experimental setup, we observe two of the basic unit cells and an array of 2×2 magneto optical traps. Received 29 August 2002 / Received in final form 12 December 2002 Published online 18 February 2003     

周期孔洞区域中热力耦合问题的双尺度有限元计算

复合材料的研究中经常遇到具有周期孔洞结构的材料,由于区域的小周期性及剧烈振荡性,用传统的有限元计算方法来计算这些材料对应的问题时需要大量的计算机存储空间及计算时间.对这类材料的热力耦合问题给出了一种新型的高阶双尺度渐近解,得到了对应的均匀化常数、均匀化方程及对应的有限元算法.数值算例表明,周期单胞的局部结构对局部应力与应变有较大的影响.算法对数值模拟这类材料的力学行为是高效和可行的. 关键词： 双尺度方法 热力耦合 周期孔洞区域 有限元方法     

Stochastic resonance in ferromagnetic domain motion

A model for the motion of a single ferromagnetic domain is studied numerically and analytically. A single strip in two dimensions and pinned at two inhomogeneities is considered. We suppose two stable configurations (positively or negatively curved with pinned ends) due to the action of a bistable potential. Further, it is assumed that the domain is driven externally by periodic and noisy magnetic fields. The noise makes the domain able to flip between the two configurations. The small temporally periodic fields synchronize these flippings and the phenomenon of stochastic resonance is observed. The signal to noise ratio of the output is investigated and shows a maximum for a nonvanishing intensity of the applied noise. Its dependency on the stiffness of the domain is studied. Received 14 May 1999 and Received in final form 14 October 1999     

On charged mesoscopic metallic bubbles

We investigate the existence of stable charged metallic bubbles using the shell correction method. We find that for a given mesoscopic system of n atoms of a given metal and (positive) elementary charges, a metallic bubble turns out to have a lower total energy than a compact spherical cluster, whenever the charge number q is larger than a critical charge number q_c. For a magic number (n-q) of free electrons, the spherical metallic bubble may become stable against fission. Received: 17 November 1997 / Revised: 28 May 1998 / Accepted: 20 July 1998     

Spectroscopic detection of biological NO with a quantum cascade laser

Two configurations of a continuous wave quantum cascade distributed feedback laser-based gas sensor for the detection of NO at a parts per billion (ppb) concentration level, typical of biomedical applications, have been investigated. The laser was operated at liquid nitrogen temperature near λ=5.2 μm. In the first configuration, a 100 m optical path length multi-pass cell was employed to enhance the NO absorption. In the second configuration, a technique based on cavity-enhanced spectroscopy (CES) was utilized, with an effective path length of 670 m. Both sensors enabled simultaneous analysis of NO and CO₂ concentrations in exhaled air. The minimum detectable NO concentration was found to be 3 ppb with a multi-pass cell and 16 ppb when using CES. The two techniques are compared, and potential future developments are discussed. Received: 1 November 2000 / Revised version: 19 January 2001 / Published online: 20 April 2001     

Timescales in Reactive Chaotic Scattering

 In reactive chaotic scattering, the relative importance of the different channels, in terms of probability, is measured classically or semi-classically by integrals over finite areas in phase space. These areas arise in a finite time on a well chosen surface. This is contrasted to periodic orbit theory or spectral properties, that need a very long time to be defined, as compared to mean interaction times. Received November 7, 2001; accepted for publication December 4, 2001     

A qualitative model for the growth mechanism of silver clusters in polymer solution

A simple and high-reproducible method for the synthesis of polymer-protected silver cluster of controlled size is described. UV-visible spectroscopy has been used for investigating the influence of the aging of the protective poly(vinylpyrrolidone) layer on the cluster growth rate at different reaction temperatures and poly(vinylpyrrolidone)/ethylene glycol weight ratios. The obtained results show that the aging time of the polymeric stabilizer solution plays a fundamental role in the reproducibility of the cluster growth process. A model for the metal cluster formation-grow process is also proposed. Received 18 July 2001 and Received in final form 3 October 2001     

First principle theory for cavity solitons in semiconductor microresonators

Cavity solitons are similar to spatial solitons, appearing as localized bright dots in the transverse intensity profile of the electromagnetic field, but they arise in dissipative systems. In this paper we consider a broad-area vertical-cavity semiconductor microresonator, driven by an external coherent field, at room temperature. The active material is constituted by a Multiple Quantum Well GaAs/AlGaAs structure (MQW). We present a set of nonlinear dynamical equations for the electric field and the carrier density valid for both a passive and an active (i.e. with population inversion) configuration. The complex nonlinear susceptibility is derived on the basis of a full many-body theory, with the Coulomb enhancement treated in the Padé approximation. The linear stability analysis of the homogeneous steady states is performed with a generalised approach, and numerical simulations demonstrating the existence of spatial patterns and cavity solitons in experimentally achievable parameter regions are given for the two configurations. Received 18 January 2001     

The chirality of exceptional points

Exceptional points are singularities of the spectrum and wave functions of a Hamiltonian which occur as functions of a complex interaction parameter. They are accessible in experiments with dissipative systems. We show that the wave function at an exceptional point is a specific superposition of two configurations. The phase relation between the configurations is equivalent to a chirality which should be detectable in an experiment. Received 9 April 2001 and Received in final form 19 July 2001     

Molecular Dynamics Simulation of Icosahedral Transformations in Solid Cu-Co Clusters

We study the icosahedral transformations of solid Cu Co clusters with different initial configurations by using molecular dynamics with the embedded atom method. It is found that the formation of symmetric icosahedral cluster is strongly related to the atomic number and initial configuration. The transformation originates from the surface into the interior of the cluster and is a structural change which is rapid and diffusionless. The icosahedral clusters with any composition and configuration, such as core-shell or three-shell duster, can be prepared by the means of solid-solid phase transition in bimetallic clusters.     

The role of layer-thickness deviation in dispersion and structure of plasmons in finite superlattices

We study the effects of layer thickness variations on the collective plasmon excitation modes of finite superlattices. Unlike other symmetry lowering mechanisms, thickness variation does not strongly localize the surface modes. We find that the reason for this insensitivity lies in the fact that the collective modes of a given finite structure must evolve continuously from the single-finite-superlattice at zero thickness deviation into modes of a pair of uncoupled finite structures at large thickness variation. We also show that this behavior is analogous to the evolution of molecular orbitals from atomic orbitals as the internuclear separation is reduced, in contrast to the analogy of the superlattice modes as a stack of coupled quantum wells. This emphasizes the difference between the electromagnetic symmetry of the finite superlattice and the structural symmetry. Received 16 April 2001 and Received in final form 6 July 2001     

Density matrix renormalization group studies on one-dimensional -conjugated organic ferromagnet with side radicals

By using the density matrix renormalization group (DMRG) and the self-consistent numerical method, we obtain a high spin ground state with localized spin density describing spin localization and the soliton describing the distortion of the lattice configurations along the main chain. Different electron-phonon interactions result in different configurations of solitons. When the electron-phonon coupling along the main chain is larger than a critical value , a transition from a single soliton-like distortion to a pair of soliton-like distortions along the main chain takes place. Such critical value depends mainly on the intersite Coulomb interactions. The spin density wave along the main chain is always localized around the center of soliton-like distortions. Received 2 July 2001 and Received in final form 25 September 2001     

On the fragmentation of multiply charged sodium clusters

The fragmentation of multiply charged atomic sodium clusters of mass 200 is investigated using the Micro-canonical Metropolis Monte Carlo (MMMC) statistical technique for excitation energies up to 200 eV and for cluster charges up to +9e. In this work we present caloric curves and charged and uncharged fragment mass distributions for clusters with charges 0, 2, and 4. The caloric curves show a dip at the critical point implying a negative specific heat, as expected for finite systems, while the fragment mass distributions corroborate the picture of a phase transition from one dominant liquid-like cluster to complete vaporization. Received 7 November 2001 / Received in final form 4 April 2002 Published online 28 June 2002     

Kink solutions of the classical transverse field Ising chain

We investigate stationary and travelling wave solutions of the classical one-dimensional transverse field Ising model. Results are given on the existence, shape and stability of kink solutions and periodic solutions. We review recent analytical results (e.g., the proof of existence of a one-parameter family of stationary kink solutions and the proof of existence of travelling wave kink solutions with nonzero velocity c≠ 0) and extend them by the use of numerical methods. Small oscillations arising in the tails of travelling kink solutions are investigated numerically. In the end, stability analysis puts some light on pinning effects. Received 23 February 2001 and Received in final form 4 October 2001     

The DLCA-RLCA transition arising in 2D-aggregation: simulations and mean field theory

A sticking probability model based on the average cluster lifetime is employed for deducing a kernel capable to describe the kinetics of computer simulated irreversible aggregation processes in two dimensions. The deduced kernel describes not only the time evolution of the cluster size distribution for diffusion limited aggregation (DLCA) and reaction limited aggregation (RLCA) but also for the entire transition region between both regimes. The model predicts a crossover to diffusion limited cluster aggregation for all sticking probabilities at long aggregation times. The time needed for reaching the DLCA limit increases for decreasing sticking probability. Received 16 April 2001 and Received in final form 24 May 2001