共查询到17条相似文献,搜索用时 78 毫秒
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本文进行了Yb3+∶FAP与Yb3+∶YAG的对比分析,指出了在激光核聚变领域中Yb3+∶FAP是很有希望的增益介质,针对Yb3+∶FAP吸收光谱宽度很小(4nm)对泵浦源要求苛刻,采用Yb3+∶CS-FAP即以部分Sr2+代替Ca2+造成Yb3+周围环境多样性增加、增加谱宽.参考分析了Ca3(PO4)2-CaF2体系的相图,推测出生长CS-FAP晶体的配料区间,给出了生长晶体的原料制备方法,采用氮气流动、白宝石片封闭保温罩的观察孔和观察窗上贴石英片相结合有效地缓解了在晶体生长过程中组分挥发、开裂、以及氟化物腐蚀窗口等一系列问题.生长工艺参数为:提拉速度1~3mm/h,旋转速度10~20r/min,在流量为20ml/min的流动N2中生长,采用尺寸为60×40mm的Ir坩埚进行生长,线圈尺寸为内径130mm×130mm×8圈,外径155mm×95mm×6圈.得到了尺寸为10mm×20mm的高质量晶体.用X射线粉末衍射分析证明所生长的晶体结构正确. 相似文献
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采用顶部籽晶熔盐法,以K2WO4为助熔剂生长出铒、镱共掺钨酸钆钾[Er,Yb:KGd(WO4)2简称Er,Yb:KGW]激光晶体。XRD分析结果表明晶体为低温相Er,Yb:KGW晶体,即β-Er,Yb:KGW晶体。通过差热分析测量,确定其相变温度和熔点分别为1020℃和1080℃。测量了晶体190-2000nm的室温透过光谱,结果表明除980nm的吸收谱带是Er^3+离子和Yb^3+离子的共同谱带之外,其余均属于Er^3+离子。 相似文献
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采用提拉法生长了Yb3+掺质浓度为5;原子分数、 50;原子分数和100;原子分数的Yb:Y3Al5O12(Yb: YAG)晶体,系统地分析了不同Yb3+掺质浓度晶体的吸收光谱和荧光光谱.从吸收峰和吸收系数可以看出采用940nm LD泵浦三种不同浓度的Yb:YAG晶体都比较合适.随着Yb3+离子掺质浓度的增高,晶体中出现的自吸收现象越为明显.通过对三种不同Yb掺质浓度晶体激光性能参数的计算,得出高掺质浓度Yb:YAG和YbAG晶体是有前景的激光增益介质. 相似文献
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温梯法生长大尺寸Yb:YAG晶体 总被引:2,自引:2,他引:2
应用温梯法生长出直径为76mm的Yb:YAG晶体。运用ICP-AES测定了Yb^3 离子在Yb:YAG晶体中的分凝系数约为1.1。室温下,测定了晶体在190~1200nm之间的吸收光谱,发现了吸收峰中未知的色心吸收,色心的形成机制有待于进一步研究。 相似文献
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Yb:YAP晶体的光谱性能研究 总被引:1,自引:0,他引:1
应用中频感应加热提拉法生长出掺杂浓度为10;原子分数的Yb:YAP晶体,研究了室温下Yb:YAP晶体的吸收和发射光谱特性以及荧光寿命.Yb:YAP晶体在959nm处有最强吸收,吸收截面约为1.51 × 10-20 cm2,在1040nm处的发射截面为0.6 ×10-cm2,激光上能级荧光寿命为1.2 ms,此处自吸收较小,是实现激光输出的候选波长.研究了氧气退火对Yb:YAP晶体的光谱性能的影响.Yb:YAP晶体轴向效应明显,b轴将是作为激光输出的首选方向.比较了Yb:YAP晶体和Yb:YAG晶体的光谱性能参数. 相似文献
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研究了Er:Yb:YCa4O(BO3)3(简称Er:Yb:YCOB)的多晶制备和单晶生长,用提拉法生长出光学质量优良的Er:Yb:YCOB单晶,测量了其吸收光谱和荧光光谱,分析了其能级和泵浦原理,并进行了以激光二极管为抽运源的激光试验,实现了Er:Yb:YCOB晶体的在1.55μn附近110mW的激光输出,且斜效率达18.9%。 相似文献
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用提拉法成功生长出了Yb,Er,Ho∶ GSGG晶体,对其光谱性能进行了研究.测量了晶体在320~3000 nm波段内的吸收光谱.用970 nm激光激发,测量了晶体的稳态和瞬态荧光光谱,拟合得到2.7~3 μm激光上下能级寿命,用F-L公式计算了晶体的发射截面.与Er∶ GSGG和Yb,Er∶ GSGG晶体的光谱参数进行了比较,结果表明,Yb,Er,Ho∶GSGG是一种更适合LD泵浦,实现低阈值、高效率2.79 μm激光输出的新型激光晶体. 相似文献
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Yb:YAG闪烁晶体的UV发光特性 总被引:1,自引:0,他引:1
通过对不同掺杂浓度Yb:YAG晶体的透过光谱、激发光谱、发射光谱和衰减时间的测量,研究了Yb:YAG晶体的UV发光特性和发光机制.Yb:YAG晶体在紫外波段具有宽的激发带和发射带.最强的发射峰位于320~350nm波长范围,此即为Yb:YAG晶体的闪烁发光峰;次强的发射峰位于500nm附近.Yb:YAG晶体的UV发光衰减时间小于50ns.Yb:YAG晶体的UV发光行为是电子从Yb3+离子的4f壳层向配体O2-的满壳层的分子轨道迁移的结果,属于电荷迁移(CT)发光. 相似文献
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J. Li J. Y. Wang X. F. Cheng X. B. Hu X. Q. Wang 《Crystal Research and Technology》2003,38(10):890-895
The Yb:YAl3(BO3) 4 crystals with different Yb3+ doping concentration have been grown by the flux method. The lattice parameters and decomposition of the Yb:YAl3(BO3)4 crystal with different Yb3+ doping concentration were measured by X‐ray and DTA method. The transmission and fluorescence spectra of Yb3+:YAl3(BO3)4 crystal have been measured. The growth defects of YbxY1‐xAl3(BO3)4 crystals were also detected by using the chemical etching method. The results show that the ytterbium concentration influences these properties of Yb:YAl3(BO3)4. As the Yb3+ concentration increased, the crystal lattice parameter was decreased. At high doping level, the absorption peak concerned at about 980 nm shift to short wavelength. It is also found that the perfection of Yb:YAl3(BO3) 4 crystal with low Yb3+ doping concentration is better than that with high Yb3+ concentration. (© 2003 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
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Zhong De‐gao Teng Bing Cao Li‐feng Chao Wang He Lin‐xiang Li Jian‐hong Zhang Shi‐ming Li Yu‐yi 《Crystal Research and Technology》2013,48(6):369-373
Yb: LuPO4 crystals with the size up to 6×2×0.5mm3 were grown by the flux growth process using lead pyrophosphate Pb2P2O7 as the high‐temperature solvent. The crystal structure of Yb: LuPO4 crystals at room temperature was refined by using single crystal X‐ray diffraction data. Crystal structure analysis showed that Yb: LuPO4 crystals possessed the tetragonal xenotime structure. The polarized absorption spectra of Yb: LuPO4 were tested at room temperature. The results showed that the absorption spectral region of Yb: LuPO4 crystal was well matched for pumping with readily available diode lasers. 相似文献
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Jing Li Guogang Xu Shujuan Han Jiandong Fan Jiyang Wang 《Journal of Crystal Growth》2009,311(17):4251-4254
Single crystal of Yb:LuAl3(BO3)4(Yb:LuAB) was grown by the flux method for the first time. The cell parameters of the grown crystal were estimated by X-ray diffraction analysis. The result indicates the symmetry of trigonal space group R32, with lattice parameters a=b=9.26372 Å, c=7.21405 Å, V=536.14 Å3, and Z=4. The absorption and emission spectra of Yb:LuAB crystal at room temperature has also been studied. The fluorescence lifetime for Yb:LuAB crystal is about 1.48 ms. The heat capacity was measured from 25 to 500 °C. Its second harmonic generation efficiency in LuAl3(BO3)4 crystal is 3–4 times that of KDP crystal. These results show that Yb:LuAB crystal would be a potential self-frequency-doubling laser crystal. 相似文献
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Li Yu‐yi Teng Bing Zhong De‐gao Wang Chao Zhang Shi‐ming Yang Li‐ting Yu Meng‐hua Quan Xin‐yu Chen Chen Wu Yun‐long 《Crystal Research and Technology》2014,49(12):939-942
A new kind of 5 at% Yb‐doped Lu0.5Y0.5PO4 crystals were firstly grown by spontaneously nucleated high‐temperature solution method using lead pyrophosphate (Pb2P2O7) as the solvent. The X‐ray powder diffraction (XRPD) patterns recorded at room temperature showed the crystals possessed tetragonal xenotime structure. The polarized absorption spectra and the fluorescence spectra of Yb:LuxY1‐xPO4 were measured at room temperature, respectively. The results show that Yb:LuxY1‐xPO4 mixed crystal will be a promising laser material if the crystal size and quality is further improved. 相似文献