Lifetime measurement in the α system (C3Δ3-X3Δ3) of TiO

The radiative lifetimes of two rotational levels of the v′ = 2 level of the C³Δ₃ state of TiO have been measured using laser-induced fluorescence and delayed coincidence counting. Individual rotational levels are excited and observed. The measured lifetimes are τ_{J = 17} = 28.21 + 0.15 nsec and τ_{J = 87} = 29.74 ± 0.86 nsec. Argon-TiO collision cross sections have been determined for the two rotational levels and are found to differ by 30%.     

Long-wavelength magneto-absorptions in HgTe

Long-wavelength (submillimeter plus millimeter) magneto-absorption experiments on HgTe have been performed at quasi-continuous wave-lengths ranging from 218.0 to 1730.9 microm in the Faraday geometry up to 65 kOe at 4.2 K. The transitions between the magnetic levels of Γ₈ and those from the acceptor levels to the Γ₈ levels are observed. The experimental results are analysed on both the assumptions of the nonlocal potential effects and the local potential ones. The Luttinger parameters for both cases are as follows: γ₁ = ? 14.0, γ₂ = ? 7.8, γ₃ = ? 7.4 and k = ? 10.0 for the non-local potential approximation and γ₁ = ? 15.6, γ₂ = ? 9.6, γ₃ = ? 8.6, and k = ? 11.2 for the local potential approximation.     

The pentad rotation-vibrational states of 12CD4: Wavenumber analysis of infrared and Raman spectra of the ν1, ν3, 2ν2, ν2 + ν4, and 2ν4 bands

The so-called pentad of ¹²CD₄ consists of the vibrational states v₁ = 1(symmetry A₁), v₃ = 1(F₂), v₂ = 2(A₁ + E), v₂ = v₄ = 1(F₁ + F₂), and v₄ = 2(A₁ + E + F₂). All states are located in the 1950 to 2250-cm^?1 region and all are strongly interacting. In the present work we have assigned more than 5000 infrared rotation-vibrational transitions and 163 isotropic Raman transitions from the vibrational ground state to the pentad. We have used infrared and Raman spectra of a resolution better than 0.01 cm^?1. From the experimental wavenumbers 2567 pentad rotation-vibrational energy levels with J ≦ 20 have been determined. These levels are reported in the paper. The levels have been used for refinements of the spectroscopic constants of two physically different effective Hamiltonians for the pentad states. For all levels with J ≦ 12 an unweighted standard deviation of 0.004 cm^?1 is obtained for both Hamiltonians, whereas the standard deviation increases more or less rapidly with J above 12 due to the imperfections of the Hamiltonians. The values of the spectroscopic constants of both Hamiltonians (85 and 106, respectively) are reported and the effects of the approximations are discussed.     

Millimeter wave spectra of OPF3 in the vibrationally excited state v6 = 2

Millimeter wave spectra have been recorded for the excited vibrational state v₆ = 2 of OPF₃. A full analysis of these spectra yields new rovibrational parameters and also the vibrational separation of the l = 0 and l = 2 levels, given by x_ll = 16 134 ± 390 MHz. The results are compared with the v₆ = 1 state.     

Extended assignment and analysis of the ν2 and ν4 infrared bands of 12CH4

Infrared spectra of the ν₂ and ν₄ bands of ¹²CH₄ have been assigned up to J′ = 20 in the ν₄ band and J′ = 17 in the ν₂ band. Assignments are presented for over 1000 transitions ranging from 1123 to 1712 cm^?1, which involve 652 upper-state energy levels of the two bands. The 652 upper-state levels have been fitted with a weighted standard deviation of 0.0026 cm^?1, almost all levels being reproduced to within their experimental error, by a Hamiltonian for the coupled upper states containing 28 refining parameters and 4 fixed parameters. Calculated relative intensities are also tabulated and discussed in relation to recent experimental intensity measurements.     

Implementation of a quantum adiabatic algorithm for factorization on two qudits

Implementation of an adiabatic quantum algorithm for factorization on two qudits with the number of levels d ₁ and d ₂ is considered. A method is proposed for obtaining a time-dependent effective Hamiltonian by means of a sequence of rotation operators that are selective with respect to the transitions between neighboring levels of a qudit. A sequence of RF magnetic field pulses is obtained, and a factorization of the numbers 35, 21, and 15 is numerically simulated on two quadrupole nuclei with spins 3/2 (d ₁ = 4) and 1 (d ₂ = 3).     

Vibrational intensity distributions in the photoelectron spectrum of hydrogen

The intensity distribution over the H₂⁺ vibrational levels up to v = 15 has been measured for H₂ photoelectron spectra at a photon wavelength of 584 Å. The data show reasonable agreement with recent calculations only in the range v = 0 through 8; the higher levels are populated significantly lower than predicted by theory.     

High-spin states in 34CI

High-spin yrast states in ³⁴Cl have been studied with the reactions ³¹P(α, nγ)³⁴Cl at E_α = 11.7?16.3 MeV and ²⁴Mg(¹²C, pnγ)³⁴Cl at E(¹²C) = 32–35 MeV. Ambiguities in the ³⁴Cl level scheme for levels at E_x = 4.82 and 5.32 MeV have been resolved through combination of threshold measurements with the ³¹P + α reaction and gamma-gamma coincidence and E_γ-measurements with the ²⁴Mg + ¹²C reaction. Gamma-gamma coincidence and in-beam γ-γ angular correlation experiments have been performed employing a Compton-suppression spectrometer with a solid angle of 120 msr.Unambiguous spin-parity assignments of J^π = 6^?, 5⁺ and 7⁺ to the ³⁴Cl levels at E_x = 4.74, 4.82 and 5.32 MeV, respectively, are obtained.Previously unreported levels of high spin are found at E_x = 7.25 and 7.80 MeV with J^π = (9⁺) and (8⁺); τ_m = 200 ± 70 fs and 100 ± 70 fs, respectively. Excitation energies, mean lives, branching ratios and multipole mixing ratios are reported. The experimental results are compared with large-scale shell-model calculations. The high-spin yrast levels can be characterized by a rather simple shell-model structure.     

M-dependence of collisional transfer of rotational energy in OCS mixtures

Collision-induced transitions between rotational levels of OCS in the ground vibrational state have been investigated by steady-state microwave double resonance, with the M sublevels separated by a Stark field. The (2 ← 1)_P-(1 ← 0)_S, (3 ← 2)_P-(1 ← 0)_S, and (4 ← 3)_P-(1 ← 0)_S systems have been studied for pure OCS and for mixtures with excess CH₃OH, He, and H₂. For four-level systems having dipolar connections (ΔJ = 1; ΔM = 0, ± 1; parity ± ? ?) between pump and signal levels, it is found for OCS and the OCS-CH₃OH mixture that the dipole-type ΔJ = 1 transitions always dominate the collisional transfer, but for the OCS-He and OCS-H₂ mixtures that ΔJ = 2 quadrupole-type transitions are dominant. For all four collision partners, significant ΔJ = 2 and ΔJ = 3 collisional transfer is observed in some systems, indicating the presence of high-order terms in the collisional interaction.     

Polarization spectroscopy of Na2 A1Σu+-b3Πu ← X1Σg+ intercombination bands

The A¹Σ_u⁺ ∼ b³Π_u perturbation of Na₂ in several high vibrational levels has been studied by polarization spectroscopy. Deperturbed molecular constants are given for the mutually interacting v_A = 26 ∼ v_b = 28 and v_A = 34 ∼ v_b = 34 vibrational levels.     

New observations and analyses of the laser excited fluorescence of the A1Σu+-X1Σg+ bands of the Na2 molecule

A medium power (～50 mW, 6328 Å) HeNe laser is used to excite the A¹Σ_u⁺-X¹Σ_g⁺ fluorescence of the Na₂ molecule in a crossed heat pipe oven. The spectrum in the region 5800–8500 Å is recorded both photographically (3.4 M Ebert) and photoelectrically (GaAs detector) with an emphasis on accurate relative intensities and on the observation of higher vibrational levels in the ground state close to the dissociation limit. P and R doublets in four series originating from (v′ = 14, J′ = 45), (v′ = 16, J′ = 17), (v′ = 22, J′ = 86), and (v′ = 25, J′ = 87) levels are observed and identified. The first two series, known from earlier work, are extended further to longer wavelengths to include 13 to 17 additional ground-state vibrational levels. The latter two series are observed for the first time. They originate from higher J′ levels and span a wide range of v″ levels (0 ≤ v″ ≤ 48). Effective RKR potentials for specific J″ (= 17, 45, 86, and 87) quantum numbers of the ground state are constructed and from them the true (rotationless) potential energy curve (for X¹Σ_g⁺) is derived which (a) reproduces the RKR curve previously given by Kusch and Hessel and (b) extends the curve from 5.77 to 7.26 Å (outer turning point). The dissociation energy D_e is estimated from these data to be 6022 ± 21 cm^?1.     

Equilibrium deformations for the Ra-Th region of nuclei

New parameters of the single-particle Nilsson potential for the Ra-Th region have been found. They are: κ_p = 0.0561, μ_p = 0.702, κ_n = 0.0588, μ_n = 0.442. The fit is made to the experimental single-particle energy levels in the new quadrupole and hexadecapole equilibrium deformation points, obtained by the shell-correction method with a simple consistency condition. The equilibrium deformations calculated by this method are in good agreement with the experimental data. Experimental values of the quadrupole moments of ²²²Rn, ²²²Ra and ²²⁴Ra are reproduced for the first time within the Nilsson-plus-Strutinsky method.     

Torsion-rotation levels of the OH stretch fundamental of CD3OH

The infrared absorption of CD₃OH in the OH stretch region has been observed at 0.025-cm^?1 resolution. Seventeen excited-state torsion-rotation levels E′_nτK have been determined with the aid of combination differences and Loomis-Wood diagrams. Of these levels, seven belong to n = 2 and nine to n = 1. No levels for which n = 0 could be determined. Analysis of the observed levels yields a hindering potential barrier in the excited state of 407 cm^?1.     

A comprehensive model to predict the microwave spectrum of propyne in the region 17–70 GHz for the ground and v10 = 1, 2, 3, 4, 5 vibrational states

A comprehensive model for predicting rotational frequency components in various v₁₀ vibrational levels of propyne was developed. A number of components of the rotational spectra in the ground and v₁₀ = 1, 2, 3, 4 excited vibrational states of propyne in the frequency range 17–70 GHz have been obtained. Molecular constants for these vibrationally excited states have been determined from more than 100 observed rotational transitions. From these experimentally observed components and a model based upon first principals for C_3v molecules, rotational constants have been expressed in a form which enables one to predict rotational components for vibrational levels for propyne up to v₁₀ = 5. The model also appears to be useful in predicting rotational components in more highly excited vibrational levels but data were not available for comparison with the theory. Experimentally measured frequencies are presented and compared with those calculated using the results of basic perturbation theory.     

Vibration-rotation energies of harmonic and combination levels in tetrahedral XY4 molecules: Analysis of the 2ν2 and ν2 + ν4 bands of 12CH4

The theory and the extrapolation method described in the previous paper are used to analyze the v₂ = 2 and v₂ = v₄ = 1 levels of ¹²CH₄. In addition to the well-known parameters of the ground, v₂ = 1, and v₄ = 1 states, the computation of energy levels involves only 6 new parameters for 2ν₂ and 13 for ν₂ + ν₄ up to the fourth order of approximation. These parameters have been determined from Raman and infrared data. Forty-four Raman lines observed by Berger in the region from 3060 to 3090 cm^?1 have been assigned to the 2ν₂ band. The standard deviation obtained by fitting 39 of these transitions with the 6 corresponding parameters is 0.025 cm^?1. The calculated frequencies of ν₂ + ν₄ are compared with moderate resolution ir spectra recorded in our laboratory and the recent spectra of Hunt et al. Totally polarized weak Raman lines observed by Berger in the region from 2850 to 2900 cm^?1 have been assigned to the ν₂ + ν₄ band arising through a second-order Coriolis interaction with the ν₁ band. A project of a comprehensive treatment of the energy levels of methane between 2550 and 3650 cm^?1 is discussed.     

Relative intensities in x-ray photoelectron spectra. Part II

Experimental data on the relative intensities of X-ray photoelectron lines of some elements with 22 ? Z ? 56, and the calculations for the photoionization cross-sections for inner levels of some elements with 21 ? Z ? 63 are reported. The relationship between photoionization relative cross-sections and line relative intensities is examined. Theoretical values of the photoionization cross-sections were used in the calculations of relative intensities of molecular valence levels for AO₄^x? (A = Cl, S, P, Se, As), AF₆^x? (A = S, Si, Al), COS, CS₂ and H₂S.     

Investigation of the 3.46 MeV isomeric level of 38K with the 24Mg(16O,pnγ)38K reaction

The τ_{$\text{1}\text{2}$} = 22 μs isomeric level of ³⁸K at an excitation energy of 3458.0 ± 0.2keVf is strongly populated in the ²⁴Mg(¹⁶O, pnγ)³⁸K reaction. Delayed γ-rays are studied with Ge(Li), Si(Li), and NaI detectors. Accurate excitation energies, branching ratios and lifetimes of levels involved in the decay of the isomeric state are determined. The isomeric level predominantly decays by a dipole transition of 38.03±0.03 keV with a total conversion coefficient of α_T = 0.42 ± 0.15. Mean lives of ³⁸K levels are measured with the recoil-distance method. The results are τ_m = 10.1 ± 0.9 ps, 1.41 ± 0.14 ns and 101 ± 15 ps for the levels at excitation energies of 0.46, 2.65 and 3.42 MeV, respectively. It is suggested that the (1f_{$\text{7}\text{2}$})² structure of a low-lying J^π = 7⁺ state in combination with the selection rules for γ-decay in a self-conjugate nucleus is responsible for the isomerism.     

Millimeter wave spectrum of acetonitrile oxide,CH3CNO,in the ν10 vibrational manifold: The ground state and the state v10 = 1

The pure rotational spectrum of CH₃CNO was measured in the frequency range 75 to 230 GHz. For the ground state, transitions were measured for J between 9 and 28 and for K from 0 to 12. In the v₁₀ = 1 state the measurements range from J = 0 to 19 and from K = 0 to 11. Numerous perturbations are observed, apparently due to accidental resonances with levels in other vibrational states. The contributions due to ΔK = 2, Δl = 2 matrix elements (l-type resonance and l-type doubling) are accounted for by matrix diagonalization, and the effects due to accidental resonances are presented graphically.