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1.
The temperature dependence of the superconducting critical current density Jc(T) in zero applied field from 4.2 K to Tc has been measured for 15 films of Nb-Ge with varying composition, deposition conditions, and radiation damage. The results show (i) the enhanced superconductivity observed in stoichiometric Nb3Ge as well as nonstoichiometric films is “bulk like” rather than filamentary, (ii) a simple correlation of the form Jc(0)∝eTcT0 which is reasonably independent of how the Tc has been achieved, and (iii) some additional evidence that the enhanced Tc of the films is not due to their chemical composition alone.  相似文献   

2.
Measurements of the temperature dependence of the upper critical field, Hc2(T), for a series of V100?xGax materials are presented for 20.5 ≤ × ≤ 29.6. Fits of the data to conventional theory for a paramagnetically limited, dirty, type II superconductor show: 1) a maximum in Tc and Hc2(0) for x ? 25; 2) a constant (dHc2dT)T = Tc for x ≤ 25; 3) a slowly increasing value of λso with increasing x up to x ~ 25; and 4) good agreement with stoichiometric ordered and thermally disordered V3Ga. Above x ? 25 broader transitions are observed. For x = 25, Tc = 15.3 K, (dHc2dT)T=Tc = 4.3 TK, λso = 0.3 and Hc2(0) = 23.4 tesla. The effects of inclusion of strong-coupling in the theory are discussed briefly.  相似文献   

3.
4.
Bulk material of Nb3 (Ge0.8Nb0.2) with A15 structure and a superconducting transition temperature Tc of 6.5 K has been implanted with Ge, Si, Ar and O ions and subsequently annealed at high temperatures. After annealing between 700 and 750°C the Ge implanted samples showed a strong increase in Tc up to 16.2 K. With Si ions only a Tc of 13 K was obtained, with Ar and O ions Tc remained below 9 K. From X-ray measurements carried out on high Tc Ge implanted samples it could be concluded that the implanted surface layer grows up to a high degree epitaxially on the single crystallites of the bulk material. The lattice constant a0 of the implanted film was reduced by 0.02 Å with respect to the bulk material. This reduction in a0 is stronger than expected from the transition temperature of the implanted surface layer.  相似文献   

5.
We show that thermodynamic properties can be used to determine whether, the degradation in Tc with increasing disorder observed in some A-15 compounds, is due to a reduction in electronic density of states and/or electron-phonon interaction or is due instead to an increase in Coulomb repulsion μ1 coming from increased localization as suggested by Anderson et al.  相似文献   

6.
Experimental data on the superconducting temperature, and low temperature specific heat, together with X-ray and neutron investigations are reported for two sets of NbxSn1?x, samples with the A15 type structure. The first one, intended for a study of the effect of stoichiometry, consists of cast alloys with lattice constants ranging from 5.273 to 5.289 Å, γ's from 4.9 to 9mJK2 g-at and Tc's from 6 to 17.9 K. The second one consists of nearly stoichiometric sintered alloys with lattice constants ranging from 5.288 to 5.291 Å, γ's from 5.6 to 13.5 mJK2 g-at and Tc's close to 18 K. The martensitic transformation ratio has been determined by neutron diffraction in the latter set and the values 32, 77 and 95% were obtained. The analysis of the specific heat jumps at Tc shows that the superconducting Tc of the tetragonal phase is 17.9 K and both Tc and γ are reduced in the cubic phase.Phonon information inferred from specific heat data are indicative of a structure with a typical energy of 9 meV in the density of states. The agreement with spectra obtained by inelastic neutron scattering is good.  相似文献   

7.
We study the maximum occuring in x(k, T) for fixed k at a temperature Tmax > Tc. We examine the predictions of both Ornstein-Zernike and ?-expansions for the position of this maximum. These are compared with the exact results fot the two-dimensional Ising model.  相似文献   

8.
The forced volume magnetostriction has been measured as a function of composition and temperature in amorphous (Fe1?xCox)90Zr10 alloys. The maximum value of δωδH (T = 0 K), equal to 285 × 10-10 Oe-1, has been observed for Fe90Zr10 alloys. The effect of pressure on the magnetization σ0 at T = 0 K was calculated from δωδH data. The pressure dependence of the Curie temperature Tc and σ0 behaves in a similar way as those observed for crystalline NiPd and NiRh alloys.  相似文献   

9.
Tc measurements for V1?xTixHy show that a decrease in Tc always occurs upon hydrogenation, but with slopes (?Tc?y)x that change with x. A phenomenological model is suggested, associating the Tc decrease in most of the range of x to changes in nominal number of conducting electrons and in the volume induced by the hydrogenation. The model roughly accounts for the variations in Tc in the V-rich alloys. It fails to explain the Tc variation at the Ti end.  相似文献   

10.
Measurements on the superconducting critical temperature Tc and critical field, Hc, of ZnCr and ZnMn alloys, down to 0.037°K are presented.The variation of Tc with increasing concentration depends strongly on Tcp/θ, with θ a characteristic temperature, while effects of Hc are similar to previously studied alloys.  相似文献   

11.
The neutron scattering from a single crystal of LiTaO3 (Curie temperature 907°K) has been measured at 760, 820, 885 and 940°K, and has been remeasured at 298°K. Least squares structural refinement of the five data sets shows that as the temperature approaches Tc the oxygen atom approaches the position x, 13, 112, with respect to Ta at the origin, in space group R3c. The temperature variation of the oxygen y- and z-coordinates is very similar to that of the spontaneous polarization. The lithium atom position below Tc remains essentially invariant as a function of temperature. At Tc, the oxygen atom occupies the position x, 13, 112, the lithium atom becomes disordered and distributed over the positions 00z and 0, 0, 12-z, and the tan alum atom becomes located at an inversion center, in space group R3c. The lithium atom sites above Tc lie 0.374 Å on either side of the oxygen atom plane at z = 14.  相似文献   

12.
13.
The dynamic properties of an n-component phonon system in d dimensions, which serves as a model for a structural phase transition of second order, are investigated. The symmetry group of the hamiltonian is the group of orthogonal transformations O(n). For n ≥ 2 a continuous symmetry is broken for T<Tc, where Tc is the transition temperature. We derive the hydrodynamic equations for the generators of this group, the 12n (n ? 1) angular-momentum variables. Besides the usual hydrodynamics of a phonon system, there are 12n (n ? 1) additional independent diffusive modes for T > Tc. In the ordered phase we find 2 (n ? 1) propagating modes with linear dispersion and quadratic damping. Formally the hydrodynamics is similar in the isotropic Heisenberg ferromagnet (n = 2) or the isotropic antiferromagnet (n ≥ 3). The relaxing modes for T < Tc require special care. We study the critical dynamics by means of the dynamical scaling hypothesis and by a mode-coupling calculation, both of which give the critical dynamical exponent z = 12d. The results are compared with the 1/n expansion. It is shown that for large n there is a non-asymptotic region characterized by an effective exponent z? = φ/2ν, where φ is the crossover exponent for a uniaxial perturbation, and ν the critical exponent of the correlation length.  相似文献   

14.
Auger and photoemission studies for Y(Rh1?xRux)4B4 superconductors elucidate the mechanism for the abrupt drop in Tc near x=0.5. The B p-states admix more strongly with Ru than Rh d-states, thereby yielding low-Tc values for Ru-rich compounds due to broadening of the d-band feutures. These effects underlie a previous suggestion that the preservation of Rh4 tetrahedral units is essential for high-Tc values in ternary boride compounds.  相似文献   

15.
Spin lattice relaxation T1 of naturally abundant 13C nuclei in squaric acid was measured close to the antiferroelectric-paraelectric phase transition temperature Tc = 373 K. A rapid increase in 1T1 is observed close to Tc coming from above, which follows the power law 1T1 ~ ε?1.4 where ε = (T ? Tc)Tc. This behaviour is explained on the basis of the two-dimensional character of the fluctuations.  相似文献   

16.
17.
We have determined the behavior of the density of states in the mixed state of superconducting alloys for TTc. The local density of states tends towards the BCS expression with the order parameter playing the role of the energy gap. The singularities are smeared out by the spatial average. The effective normal core radius of a vortex diverges like (1 ? TTc)?13 for TTc unlike the coherence length which diverges like (1 ? TTc)?12.  相似文献   

18.
The Glauber dynamics of an Ising spin glass with infinite-range interactions and additional static field, h, is investigated near the freezing temperature, Tf. We obtain critical slowing down at and below the de Almeida-Thouless instability line, hc(T), to order (1?T/Tf)3 with algebraic decay of the spin correlations ~t, where ν=12 at Tf and ν≤12 for T<Tf.  相似文献   

19.
It is shown that both the Tc and Tm dependences on the deformations and composition for the A-15 compounds can be described at least qualitatively in the quasi-one-dimensional model developed by the authors previously. The mechanism for the superconductivity is supposed to be the same as in the BCS theory. The upper critical field near Tc is obtained.  相似文献   

20.
The dependence of the superconducting transition temperature Tc on Ce impurity concentration n is reported for various (La, Th)Ce systems. These results document for the first time the evolution of the superconducting— normal phase boundary (Tc vs n curve) as an impurity undergoes magnetic- nonmagnetic transition which for Ce impurities in (La, Th)Ce systems proceeds with increasing Th concentration. Observed for only the second time, re-entrant Tc vs n curves are reported for two La-rich La, Th host compositions.  相似文献   

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