Ω− produced in K−p reactions at 4.2 GeV/c

Forty $\text{Ω}{}^{\mathrm{?}}$ events have been observed in a large (133 events/βb) experiment at 4.2 GeV/c incident K^? momentum. Thirty nine of the events come from the three-body reaction $\text{K}{}^{\mathrm{?}}\text{p}\text{→Ω}{}^{\mathrm{?}}\text{K}{}^{\mathrm{+}}\text{K}{}^0$. The $\text{Ω}{}^{\mathrm{?}}$ is mainly produced in the forward hemisphere (direction of the incident K^?). The lifetime is measured to be τ = (0.75 _+0.14?0.11 × 10^?10 sec substantially less than the Particle Data Group value of (1.3 _?0.3^+0.2) × 10^?10 sec. The mass is determined to be 1671.7 ± 0.6 MeV, in good agreement with other determinations. The decay asymmetry parameter α (for the decay mode $\text{Ω}{}^{\mathrm{?}}\text{→ Λ}\text{K}{}^{\mathrm{?}}$) is found to be ?0.2 ± 0.4.     

Electronic conductivity of AgI using D.C. polarization and charge transfer techniques

A Study of electronic conductivity using the d.c. polarization technique has been carried out in α and β-AgI which shows the former is a hole and the latter an electron conductor. Activation energies of undoped and Cu-doped single crystals and polycrystalline β-AgI were found to be 0.46 eV, 0.34 eV and 0.44 eV respectively and can be related to electron trap depths. The electron transference number ($\text{σ}{}_{\mathrm{\theta }}\text{σ}{}_{\mathrm{t}}$) for polycrystalline β-AgI was found to be 0.008 at 306 K. The activation energy for hole conduction in α-AgI was determined to be 0.97 eV in agreement with previous XPS studies.Transient measurements have also been conducted using the charge transfer technique in double cells of polycrystalline β-AgI. The carrier concentration C_θ and electron mobility μ_θ, have thus been estimated to be 1.8 × $\text{10}{}^{15}\text{cm}{}^3$ and 5.14 × 10^?5$\text{cm}{}^2\text{V}$?sec. respectively at 306 K, while the double layer capacitance was 0.496 $\text{μF}\text{cm}{}^2$.     

X-ray compressibility measurements of the graphite intercalates KC8 and KC24

The isothermal compressibilities of pristine graphite and stages 1 and 2 potassium-graphite have been measured at room temperature. Diamond anvil X-ray diffraction techniques were employed to determine the c-axis lattice constant as a function of hydrostatic pressure up to 12 kbar. The compressibilities $\text{k}{}_{\mathrm{c}}\text{?}\text{1}\text{C}{}_{33}$ were found to be (2.73±0.09)×10^-12, (2.13±0.09)×10^-12, (5.3±0.8)×10^-12 and $\text{(1.6±0.2)×10}{}^{-12}\text{cm}{}^2\text{dyn}$ for graphite, KC₈, stage 2 KC₂₄ and stage 3 KC₂₄, respectively. The compressibility of KC₈ was comparable to that of RbC₈ deduced from neutron scattering experiments.     

Half-lives of two-neutron-hole O2+ states in 206Pb and 208Po

Half-lives of O₂⁺ states in ²⁰⁶Pb and ²⁰⁸Po, 770±40 and 465±20ps, respectively, are determined using direct-timing techniques. The corresponding monopole strength parameter values,$\text{ρ(}{}^{206}\text{Pb}\text{) = 0.034±0.002}$ and $\text{ρ(}{}^{208}\text{Po}\text{)=0.030?0.037}$, indicate that the O₂⁺ states in both nuclei are mainly of similar two-neutron-hole character.     

Electron paramagnetic resonance of 61Ni+ in CuGaS2

EPR of ⁶¹Ni⁺ doped CuGaS₂ at 4.2 K leads to the following experimental data: $\text{g = 1.918 ± 0.006 A  < 12 × 10}{}^{-4}\text{cm}{}^{-1}\text{, g}{}_{\mathrm{\perp }}\text{= 2.328±0.006 A}{}_{\mathrm{\perp }}\text{= (65±2) × 10}{}^{-4}\text{cm}{}^{-1}$. High axial field splitting of ²T₂ state stabilizes the center against Jahn-Teller interaction. Covalency reduction factor k is 0.76.     

Isospin impurity of 64Ga ground state

It is well known that the observation of a nonzero Fermi matrix element for a β-transition between states that differ in isospin can provide information about the relative isospin purity of the states involved. We have determined the log ft value for the 0⁺ → 0⁺ (ΔT ≠ 0) β-transition in ${}^{64}\text{Ga}\text{→}{}^{64}\text{Zn}$ decay as 6.516 ± 0.020. From this log ft value, we have deduced |M_F| = (43.4 ± 1.1) × 10^?3, |α| = (21.7 ± 0.6) × 10^?3 and |〈V_CD〉| = 41.7 ± 1.1 keV, where M_F,α² and 〈V_CD〉 represent the Fermi matrix element, isospin impurity and Coulomb matrix element, respectively. The Coulomb matrix element of 41.7 keV found for ⁶⁴Ga is one of the largest known from β-decay experiments. The experimental procedure involved a careful measurement of the intensity of the annihilation radiation relative to that of the other γ-rays from ⁶⁴Ga decay. As a by-product, we have obtained an improved ⁶⁴Ga decay scheme. We have also summarized the existing information on the isospin impurities of nuclear states as deduced from β-decay experiments.     

The adsorption of acetylene on W(100) at room temperature: An electron spectroscopic study

The adsorption of acetylene on W(100) at room temperature has been studied by AES, ELS, thermal desorption, mass spectrometry, work function and LEED in one vacuum chamber. AES line profile analysis shows that there are at least two adsorption processes occurring at room temperature. Further, it is possible to explain all the AES results by assuming non-sequential adsorption into just two states, denoted by α and β. This picture was substantiated and embellished by comparison with other standard surface techniques. The α-state comprises either a C₂H₂ unit with an activation energy for desorption of $\text{2.3}\text{eV}\text{molecule}\text{(53}\text{kcal mole}{}^{\mathrm{?1}}\text{)}$ or CH units bounded through the carbon of the β-state. Saturation coverage for the α-state is 3 × 10¹⁴ molecules cm^?2. The β-state is dissociative at low acetylene exposures and comparison between a carbon covered surface and the β-state suggest the latter to be dissociative up to saturation. There also appears to be ca. 10¹⁴ hydrogen atoms cm^?2 on W(100) on room temperature acetylene saturation, the carbon content of the β-state being 9 × 10¹⁴ atoms cm^?2. The residual C?C bond from the molecule in the β-state remains unknown. No sign of ordering in the adsorbed species was detected, save the possibility of (1 × 1) in the β-state. Acetylene adsorption at 580 K showed hydrogen from the β-state to block acetylene adsorption by 15% at saturation. A two-site adsorption model for the β-state is proposed to explain the results. The α-state is bonded through the carbon of the β-state and it is speculated that the former adsorbs onto “β” domains where there is a critical minimum size for the latter.     

The Pn values of the 235U(nth, f) produced precursors in the mass chains 90, 91, 93–95, 99, 134 and 137–139

The first results are reported on the P_n values obtained with the recoil focussing parabolatype mass separator for unslowed fission products Lohengrin installed at the Grenoble high flux reactor. The mass chains studied were 90, 91, 93, 94, 95, 99, 134, 137, 138 and 139. Both the neutron and the β activities were measured simultaneously. The technique used to measure the neutron and the β activities and the method of analyzing the experimental data are discussed in detail. The present work led to: (i) three new periods corresponding to the new isotopes of selenium (${}^{91}\text{Se}\text{, T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 0.27±0.05}\text{sec}$), strontium (⁹⁹Sr, 0.6±0.2 sec) and telurium (¹³⁸Te, 1.3±0.3 sec); (ii) accurate periods of ${}^{99}\text{Y}\text{(T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 1.45±0.22}\text{sec}\text{)}\text{and}{}^{134}\text{Sn}\text{(0.7±0.2}\text{sec}\text{)}$; (iii) four new delayed neutron precursors consisting of ⁹¹Se, ⁹⁴Kr, ⁹⁹Sr and ¹³⁸Te; (iv) six new P_n values corresponding to the precursors ${}^{91}\text{Se}\text{(P}{}_{\mathrm{<mtext>n</mtext>}}\text{= (21±10)\%),}{}^{94}\text{Kr}\text{((5.7±2.2)\%),}{}^{99}\text{Sr}\text{((3.4±2.4)\%),}{}^{99}\text{Y}\text{((1.2±0.8)\%),}{}^{134}\text{Sn}\text{((17±13)\%)}\text{and}{}^{138}\text{Te}\text{((6.3±2.1)\%)}$; (v) a precise P_n value of the precursor ¹³⁷Te ((2.5±0.5)%); (vi) a redetermination of the P_n values of the precursors ^{90, 91}Br, ⁹³Kr, ^{93, 94, 95}Rb and ^{137, 138, 139}I. The results of this work are discussed and compared with the existing data. The low level sensitivity of the present detection system is determined to be $\text{P}{}_{\mathrm{<mtext>n</mtext>}}\text{(m)Y}{}_{\mathrm{q}}\text{(m) ? 0.4 × 10}{}^{\mathrm{?6}}\text{n}\text{/}\text{f}$ (where Y_q(m) is the cumulative yield for the mass m and the ionic charge q).     

Reactive scattering of small molecules from platinum crystal surfaces: D2CO,CH3OH,HCOOH, and the nonanomalous kinetics of hydrogen atom recombination

The decomposition of D₂CO, CH₃OD and HCOOH on Pt(110) and of D₂CO on Pt(S)-[9(111) × (100)] was studied by molecular beam relaxation spectroscopy. D₂CO and CH₃OD evolved CO and H₂ via a desorption limited sequence of elementary steps. The rate constant for CO desorption from Pt(110) was 6 × 10¹⁴exp(? 35.5 $\text{kcal}\text{gmol}$ · RT) s^?1, and from Pt(S)-[9(111) × (100)] it was 1 × 10¹⁵ exp(?36.2 $\text{kcal}\text{gmol}\text{·RT}$) s^?1. On Pt(110) the rate constant for hydrogen formation was 10^{0 ± 1}exp(?24 $\text{kcal}\text{gmol}\text{·RT}$) $\text{m}\text{?}{}^2\text{atom}$ · s. On Pt(S)-[9(111) × (100)] two pathways for H₂ formation existed with rate constants of 8.7 × 10^?2exp( ?24.9 $\text{kcal}\text{gmol}\text{· RT}$) $\text{cm}{}^2\text{atom}$· s and 3.2 × 10^?3 exp(?19.5 $\text{kcal}\text{gmol}\text{·RT}$) $\text{cm}{}^2\text{atom}\text{·}$ s. These pre-exponential factors are in order of magnitude agreement with values typical of hydrogen recombination on other metals. When a small amount of sulfur ( ~ 0.1 ML) was adsorbed on the stepped Pt surface, only one pathway for H₂ formation existed due to blockage of stepped sites. A similar result was obtained when a beam of CO was impinged on the surface. Formic acid decomposed via a branched process to form primarily CO₂ and H₂.     

Results on the production cross sections π−p → neutrals and π− p→ χ↳2γ0n at 3.8, 6, 8 and 12 GeV/c

The ratio between the cross sections for the reactions $\text{π}{}^{\mathrm{?}}\text{p→}\text{χ}\text{?}{}_{\mathrm{2\gamma }}{}^0\text{n}$ and π^?p → η_→2γ n has been measured to be (2.4 ± 0.9) × 10^?2, (2.1 ± 0.6) × 10^?2 and (2.8 ± 1.3) × 10^?2 at 3.8,6,8 and 12 GeV/c incident momentum respectively.At the same momenta the cross section for π^t- p → neutrals is (1.48 ± 0.09) mb, (0.86 ± 0.05) mb, (0.64 ± 0.04) mb and (0.42±0.03) mb.     

Isospin dependence of the nuclear level density

Experiments on $\text{(ft)}{}^{\mathrm{+}}\text{/(}\text{ft)}{}^{\mathrm{?}}$ for mirror Gamow-Teller β-decay are reanalyzed in the light of recent work and new values for the Kubodera, Delorme and Rho second class parameters are deduced: ξ = ? (0.8 ± 2.0) × 10^?3MeV^?1; λ = (3.4 ± 3.9) × 10^?3. These values are compared with recent correlation experiments.     

Stroboscopic observation of quadrupole hyperfine interactions

A stroboscopic technique for the observation of quadrupole hyperfine interactions of isomeric nuclear states has been successfully developed. The inherent precision and resolution of this technique have been demonstrated by measuring the quadrupole hyperfine frequency for ${}^{69}\text{Ge(}\text{9}\text{2}{}^{\mathrm{+}}{}_1\text{, τ = 4.0μ)}$ in Zn metal at several temperatures; ω₀ = [19.67 ± 0.06] × 10⁶s^?1 (at 623 ± 3 K).     

High spin states in 57Co

High spin states of ⁵⁷Co have been studied via prompt γ-ray spectroscopy in the reactions ⁴⁸Ti(¹²C, p2n) and ⁵⁴Fe(α, p) at 26–48 MeV and 12–24 MeV, respectively. The energies and decay modes of these levels were determined from the analysis of γ-ray singles and γ-γ coincidence spectra, excitation functions, angular distributions and correlations. The relevant lifetimes were measured by the Doppler-shift attenuation method. The new levels established in this work are at 4037, 4814 and 5918 keV with the most probable J^π assignment of $\text{15}\text{2}{}^{\mathrm{?}}$, if $\text{17}\text{2}{}^{\mathrm{?}}$ and $\text{19}\text{2}{}^{\mathrm{?}}$, respectively. The previously known level at 2524 keV was assigned to have $\text{J}{}^{\mathrm{\pi }}\text{=}\text{13}\text{2}{}^{\mathrm{?}}$. These together with the known $\text{9}\text{2}{}^{\mathrm{?}}$(1224 keV) and $\text{11}\text{2}{}^{\mathrm{?}}$(1690 keV) levels constitute the yrast states of ⁵⁷Co. The measured lifetimes of the above six levels are (in order of increasing energies) 0.085±0.030, 0.32±0.10, 0.16±0.06, 0.10_?0.07^+0.06, 1.5_?0.5⁴ and 0.17_?0.07^+0.08 ps, respectively. Comparisons with some theoretical calculations are presented.     

Infrared bands of 12C2HD

The rotational structure of about 40 bands of ¹²C₂HD observed in the region 6000?600 cm^?1 has been measured and interpreted with the purpose of determining a comprehensive set of molecular constants for this isotopic variety of acetylene. Combining these data with the results for ¹²C₂H₂ and ¹²C₂D₂, a reevaluation of the equilibrium internuclear distances for the acetylene molecule has been made: $\text{r}{}_{\mathrm{e}}\text{(CH) = 1.06215 ± 17 × 10}{}^{\mathrm{?5}}\text{A}\text{?}$ and $\text{r}{}_{\mathrm{e}}\text{(CC) = 1.20257 ± 9 × 10}{}^{\mathrm{?5}}\text{A}\text{?}$ were obtained. This paper presents all the molecular constants derived in this study.     

Direct observations of the behavior of single silicon atoms on a metal surface

The behavior of single silicon adatoms on the W {110} plane has been successfully studied for the first time. Single atom diffusion parameters are found to be E_d = 0.70 ± 0.07 eV, and $\text{d}{}_0\text{= 3.08 × 10}{}^{\mathrm{?4}}\text{× 10}{}^{\mathrm{\pm 1.28}}\text{solcm}{}^2\text{s}$. The field desorption behavior of Si atoms is similar to that of metal adatoms. SiSi adatom-adatom interaction shows nonmonotonic distance dependence, but the repulsive region around 3.2 Å is much weaker than those found in metal adatom interactions.     

Etude de l'autodiffusion dans la phase cubique centree de l'europium et du gadolinium

The self-diffusion coefficient follows a relation of the form : D = (1,0_?0.4^+0.7)exp (?shape=case>34400RT±700)

$\text{cm}{}^2\text{sec}$

for b.c.c. europium D = (1,0_?0.3^+0.5) × 10^?2 exp(?

$\text{32700 ±4000}\text{RT}\text{)}$

$\text{cm}{}^2\text{sec}$

for β-b.c.c. gadolinium.Whereas europium has normal self-diffusion parameters, β-b.c.c. gadolinium must be set in the class of the anomalous b.c.c. rare-earth metals.From these results we conclude that there exists no evident connexion between the instability of the 4f shell and the activation energies anomalously low in the b.c.c. phases of the rare-earth metals.     

Line broadening and oscillator strength measurements for the nitric oxide γ(0,0) band

The effective collision diameters for line broadening by several foreign gases and the oscillator strength for the NO γ(0,0) band have been determined with the use of high-resolution absorption spectra and a detailed computer model. Effective optical collision diameters between NO and foreign gases are as follows: N₂ 1.13 nm; CO₂, 1.17 nm; CO, 1.15 nm: CH₄, 1.10 nm; and Ar, 1.04 nm. The measured oscillator strengths are (3.72±0.4) × 10^-4 for the $\text{A}{}^2\text{Σ}{}^{\mathrm{+}}\text{? X}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ transition, and (3.57±0.4) × 10^-4 for the $\text{A}{}^2\text{Σ}{}^{\mathrm{+}}\text{? X}{}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ transition.     

Electrical and structural properties of iron-doped β-alumina

β-alumina containing 50 w/o Fe exhibits high electronic conductivity when sintered in air but Mössbauer studies have shown the presence of Fe₃O₄. Single-phase β-alumina containing 50 w/o Fe could be prepared by sintering at 1400°C for 4–4.5 h followed by annealing at 1300°C for 96 h encapsulated with coarse β-alumina powder enriched with Na₂CO₃. Mössbauer spectroscopy indicated that all iron was present as Fe(III). Complex-plane impedance data showed a maximum bulk $\text{σ}{}_{\mathrm{25°C}}\text{= 5.56 × 10}{}^{-4}\text{(Ω cm)}{}^{-1}$ with little electronic conductivity. Reduction treatments on Fe-doped β-alumina utilizing H₂:N₂ gas were successful in producing a mixed conductor containing Fe(II) and Fe(III) but also produced a distorted β-alumina lattice. This material exhibited an electronic conductivity $\text{σ}{}_{\mathrm{e,25°C}}\text{= 2 × 10}{}^{-4}\text{(Ω cm)}{}^{-1}$ and a bulk ionic conductivity $\text{σ}{}_{\mathrm{b,25°C}}\text{= 1.35 × 10}{}^{-4}\text{(Ω cm)}{}^{-1}$.     

Electron capture decay of 245Bk (4.90 d) and 246Bk (1.80 d)

The electron capture decay schemes of ²⁴⁵Bk and ²⁴⁶Bk have been investigated by measuring the γ-ray and conversion-electron spectra of mass-separated ²⁴⁵Bk and ²⁴⁶Bk samples. The γ-ray spectra were measured with a 25 cm³ Ge(Li) spectrometer and the conversion-electron spectra were measured with a cooled Si (Li) detector. Multipolarities of most of the transitions in ²⁴⁵Cm and ²⁴⁶Cm were deduced. The half-lives of ²⁴⁵Bk and ²⁴⁶Bk were determined by following the decay of the 252.85 and 798.7 keV photopeaks and were found to be 4.90 ± 0.03 d and 1.80 ± 0.02 d, respectively. The α/(α+EC) ratio for the ²⁴⁵Bk decay was measured to be (1.2 ± 0.1) × 10^?3. On the basis of the present investigation the following non-rotational states were identified in ²⁴⁵Cm: $\text{7}\text{2}{}^{\mathrm{+}}$ [624], 0; $\text{5}\text{2}{}^{\mathrm{+}}$[622], 252.85; $\text{1}\text{2}{}^{\mathrm{+}}$ 355.95; $\text{3}\text{2}{}^{\mathrm{?}}$ vibrational, 633.65; and $\text{1}\text{2}{}^{\mathrm{+}}$[620], 740.95 keV. The $\text{3}\text{2}{}^{\mathrm{?}}$ state at 633.65 keV is int as a K_π = 2^? phonon coupled to the i$\text{7}\text{2}{}^{\mathrm{+}}$[624] single-particle state. Our measurements of ²⁴⁶Bk γ-ray and conversion-electron energies and intensities confirm previous level assignments in ²⁴⁶Cm.     

Transition rates in97Tc

The de-excitation of the 215 keV $\text{7}\text{2}{}^{\mathrm{+}}$ and 324 keV $\text{5}\text{2}{}^{\mathrm{+}}$ levels in⁹⁷Tc, as observed in ⁹⁷Ru decay, was studied by means of internal conversion electron spectroscopy and the delayed electron-electron coincidence technique. From L-subshell intensity ratios, the E2 content in the 108 and 215 keV transitions were found to be (65 ± 12)% and (7 ± 4)%, respectively. The obtained level mean-lives were 0.75 ± 0.09 ns for the 324 keV level and 74 ± 15 ps for the 215 keV level.