Overtone spectroscopy of benzaldehyde

The vibrational overtone spectra of aryl and alkyl C-H stretch vibrations in benzaldehyde have been studied using conventional IR and thermal lensing technique at room temperature. The stretching vibrational frequencyω _e, anharmonicity constantω _e x _e and the dissociation energies of the two C-H bonds have been calculated. The bond length of C-H bond in aryl position has been estimated.     

Phase shift analysis of hyperon-nucleon elastic scattering using optimized polynomial expansion techniques

A relatively stable method of phase shift analysis of hyperon-nucleon scattering proposed by us is applied to Σ⁺ p and Λp scattering. The analytic cutt-planes of analyticity of the helicity amplitudes are mapped into the interior of unifocal ellipses. The helicity amplitudes are then expressed as accelerated convergent expansions in the mapped variable. A definite economy is observed in the number of free parameters for fixed energy phase shift analysis of Σ⁺ p and Λp scattering at 40 and 100 MeV and 100 MeV respectively. Twenty six more phase shifts and coupling parameters corresponding to higherJ values are also predicted.     

Overtone spectra of styrene and polystyrene in the visible and near infrared regions

Vibrational overtone spectra of styrene (liquid) and polystyrene (solid), studied by the laser-induced thermal lens (for ΔV=6) and the conventional near infrared absorption (for ΔV=3–5) techniques, are reported. For polystyrene, the overtone energy-bond length correlation predicts that the aryl CH bonds are ～0.0005 Å longer than that in benzene, while no such conclusions could be drawn on styrene. Thesp ³ CH overtones in polystyrene are observed on the low energy side of the aryl CH overtones.     

Optogalvanic detection of NaNe molecule

Summary The formation of NaNe molecule has been detected in a hollow cathode lamp containing traces of sodium and neon using the optogalvanic technique. Two broad continuum peaks have been observed in the structure. They have been analysed to result due to transitions {Na(3s) + Ne(2p ⁶)}²Σ¹→ →{Na*(3p) + Ne(2p ⁶)}²Π,²Σ and {Na*(3p) + Ne(2p ⁶)}²Π,²Σ→{Na*(5s) + Ne(2p ⁶)}²Σ¹. A third peak in between these is probably due to a two-photon transition from 3s→5s of Na in NaNe. The authors of this paper have agreed to not receive the proofs for correction.     

K0πand K*0Σ+ photoproduction off the proton

The exclusive reactions γp → K ^*0Σ⁺(1189) and γp → K ⁰π⁰Σ⁺(1189) , leading to the p 4π⁰ final state, have been measured with a tagged photon beam for incident energies from threshold up to 2.5GeV. The experiment has been performed at the tagged photon facility of the ELSA accelerator (Bonn). The Crystal Barrel and TAPS detectors were combined to a photon detector system of almost 4π geometrical acceptance. Differential and total cross-sections are reported. At energies close to the threshold, a flat angular distribution has been observed for the reaction γp → K ⁰π⁰Σ⁺ suggesting dominant s -channel production. Σ^*(1385) and higher-lying hyperon states have been observed. An enhancement in the forward direction in the angular distributions of the reaction γp → K ^*0Σ⁺ indicates a t -channel exchange contribution to the reaction mechanism. The experimental data are in reasonable agreement with recent theoretical predictions.     

Total strength of the magnetic dipole resonance in <Superscript>31</Superscript>P

The γ decay of the resonance-like structure observed in the ³⁰Si(pγ)³¹P reaction in the energy range E _p = 1.4–2.7 MeV of accelerated protons has been investigated. The excitation function of this reaction and the spectra and angular distributions of the γ rays formed in the decay of resonances with E _p = 1482, 2350, and 2505 keV have been measured. The M1 resonance on the ground and the first excited states of ³¹P with E _p = 1266 keV is identified. The total strength of the M1 resonance on the ground state of this nucleus is determined. The position and total strength of this resonance on the ground state are explained taking into account pairing forces.     

Gamma-ray spectroscopy of 25 57 Mn32 and 25 58 Mn33

The decays of ₂₅⁵⁷Mn₃₂ and ₂₅⁵⁸Mn₃₃ have been studied with the 8π Spectrometer following the reaction ⁴⁸Ca(¹³C,pxn)^{60 − x} Mn at a beam energy of 40 MeV. The level schemes of these two nuclei have been extended, and the multipolarities of the observed transitions have been determined.     

Narrowing of the vibrational spectrum under compression of liquid carbon dioxide

The broadening and shift of the Q bands of the 1388/1285-cm⁻¹ Fermi doublet of carbon dioxide have been measured by means of the spectroscopy of coherent anti-Stokes Raman scattering in a wide density range realized at compression in dense gaseous and liquid states. The spectrum of the low-frequency Q band exhibits an essential narrowing upon the compression of the liquid in the density range of 320–400 amagat from a maximum width of about 2.2 cm⁻¹ to about 1.7 cm⁻¹ determined by elastic dephasing. The observed dependence is connected with the progressive narrowing of the spectral contribution attributed to the collapsed rotational structure.     

Plasticity and strength of FCC metals with a nanotwinned submicrograined structure

The plasticizing and hardening effects associated with the existence of nanotwins with a density 1/λ (where λ is the average size (thickness) of nanotwin lamellae) in a submicrograined structure of fcc metals have been theoretically discussed in the framework of the dislocation-kinetics approach. The strength of the nanotwinned submicrocrystalline structure, which is increased as compared to the initial submicron structure, is determined, as in the case of nanograin boundaries, by the action of nanotwin boundaries as sources and barriers for moving dislocations that provide the normal Hall-Petch effect for the flow stress σ ∼ γ^−1/2. The inverse Hall-Petch effect σ ∼ γ ^p (where p > 0), as in the case of nanograin boundaries, is associated with the dislocation absorption by the twin boundaries. The related increased strain-rate sensitivity of the flow stresses is responsible for the significant increase in the uniform strain (from 2–3 to 8–9% in the case of nanotwinned copper) during tension of the specimens with nanotwinned submicrograined structures with retaining a high strength of the material.     

Collision strengths for transitions in Ni XIX

In this paper we present calculations of electron impact excitation collision strengths for transitions among the 89 fine-structure levels of the 2s²2p⁶, 2s²2p⁵3ℓ, 2s2p⁶3ℓ, 2s²2p⁵4ℓ, and 2s2p⁶4ℓ configurations of Ni XIX, for which flexible atomic code (FAC) has been adopted. Comparisons are made with the earlier available results in the literature, and the anomalies observed have been discussed.      

Charge radius change in the heavy tin isotopes until A = 132 from laser spectroscopy

Laser spectroscopy measurements have been carried out on the very neutron-rich tin isotopes with the COMPLIS experimental setup. Using the 5s ²5p ²³ P ₀ → 5s ²5p6s ³ P ₁ optical transition, hyperfine spectra of ^126-132Sn and ^{125m, 127m, 129m-131m}Sn where recorded for the first time. The variation of the mean-square charge radius ( δ〈r ²〉) between these nuclei and nuclear moments of the isomers and the odd isotopes were thus measured. An odd-even staggering which inverts at A = 130 is clearly observed. This indicates a small appearance of a plateau on the δ〈r ²〉 which has to be confirmed by measuring the isotope shift beyond A = 132. Received: 21 March 2002 / Accepted: 16 May 2002 / Published online: 31 October 2002 RID="a" ID="a"e-mail: leblanc@ipno.in2p3.fr     

Magneto-Raman scattering inp-type indium antimonide

We report for the first time stimulated magneto-Raman scattering inp-type InSb. Two different Raman scattering processes were observed. The first one has a Raman shift of about 2cm⁻¹/kG and is observed at magnetic fields up to 30kG. The other one is observable only at high magnetic fields above 30kG and shows Raman shifts between 1.2cm⁻¹ and 3.0cm⁻¹ with a tuning rate of about 0.2cm⁻¹/kG. The first process can be interpreted either as spin-flip Raman scattering by photo-excited electrons in the conduction band or as Raman scattering by holes in the valence band involving transitions from heavy to light hole states. The other Raman shift observed seems to occur on account of transitions between the heavy hole ladders.     

Calculation of magnetic multipole moment integrals using translation formulas for Slater-type orbitals

Using translation formulas for Slater type orbitals (STO’s) the infinite series through the overlap integrals are derived for the magnetic multipole moment integrals. By the use of the derived expressions the magnetic multipole moment integrals, therefore, the magnetic properties of molecules can be evaluated most efficiently and accurately. The convergence of the series is tested by calculating concrete cases. An accuracy of 10⁻⁵ for the computer results is obtained in the case 2 ^p -pole magnetic moment integrals for 1 ≤ v ≤ 5, and for the arbitrary values of internuclear distances and screening constants of atomic orbitals.     

The search for and study of the strange multibaryon states in systems with Λ-hyperon and Ks0 -meson in pA collision at momentum of 10 GeV/c

Exotic strange multibaryon states have been observed in the effective mass spectra of: Λπ^±, Λπ⁺π⁻, Λp, Λpp, Λπp, ΛΛ and ΛK _s ⁰, K _s ⁰ p, K _s ⁰π^± subsystems. The measured Λ/π⁺ ratio for average multiplicities from the pC reaction is equal to (5.3 ± 0.8) × 10⁻², and it is approximately two times larger than the Λ/π⁺ ratio simulated by the FRITIOF model and than that of experimental pp reactions at the same energy. The observed wellknown resonances Σ*⁺ (1385) and K*^± (892) from PDG are good tests of this method. The mean value of the mass for the Σ*⁻(1385) resonance is shifted to 1370 MeV/c ² and the width is two times larger than the same value from PDG. Such kind of behavior for the width and invariant mass of Σ*⁻ (1385) resonance is interpreted as an extensive contribution from stopped Ξ⁻ → Λπ⁻ and medium effect. There is enhancement of the production contribution for all observed hyperons. A few events were registered by hypothesis of light H ⁰ and heavy H ^{0, +} dihyperons. Dihyperons were observed by weak decay channels: (Σ⁻ p), (Λpπ⁻), (Λpπ⁰), and (K ⁻ pp). The text was submitted by the author in English.     

Newby shift ofK=0 rotational bands in odd-odd rare-earths

A data set of 29 experimentally determined Newby shifts in rare-earth nuclei is examined for the reliability of each values. Using this data set, Newby shifts are obtained which are free from the Coriolis and the particle-particle coupling effects. These new empirical values help resolve the failure of a recently proposed rule for the sign of the Newby shift in the {5/2[413]p − 5/2[642]n} configuration of¹⁶⁰Tb and the {5/2[402]p − 5/2[512]n} configuration of¹⁷⁴Lu. Also the Newby shifts are significantly modified in two other cases namely the {1/2[411]p − 1/2[521]n} configuration in¹⁶⁸Tm and the {1/2[541]p − 1/2[521]n} configuration in¹⁷²Lu. Only marginal changes are seen in the rest of the cases in the rare-earth nuclei.     

2p3/2?13x?1?3x?13d?1 X-ray satellites spectra in the Lα1 region of 4d transition elements

The X-ray satellite spectra arising due to 2p _3/2 ⁻¹3x ⁻¹−3x ⁻¹3d ⁻¹ (x ≡ s, p, d) transition array, in elements with Z = 40 to 48, have been calculated, using available Hartree-Fock-Slater (HFS) data on 1s ⁻¹−2p ⁻¹ 3x ⁻ and 2p _3/2 ⁻¹−3x ⁻¹,3x ⁻¹ Auger transition energies. The relative intensities of all the possible transitions have been estimated by considering cross — sections for the Auger transitions simultaneous to a hole creation and then distributing statistically the total cross sections for initial two hole states 2p _3/2 ⁻¹−3x ⁻¹ amongst various allowed transitions from these initial states to 3x ⁻¹ 3d ⁻¹ final states by Coster-Kronig (CK) and shake off processes. In both these processes initial single hole creation is the prime phenomenon. Each transition has been assumed to give rise to a Gaussian line and the overall spectrum has been computed as the sum of these Gaussian curves. The calculated spectra have been compared with the measured satellite energies in Lα₁ spectra. Their intense peaks have been identified as the observed satellite lines. The peaks in the theoretical satellite spectra were identified as the experimentally reported satellites α₃, α₄ and α₅, which lie on the high-energy side of the Lα₁ dipole line.     

Fusion cross section for the system6Li+28Si atE ∼ 36 MeV

The fusion cross section for the system⁶Li+²⁸Si has been measured atE∼36 MeV. Combining this with the data available at lower energies, the nucleus-nucleus real potentials have been determined for a range of interaction distances.     

Raman spectroscopic study of the selenite minerals—chalcomenite CuSeO3·2H2O,clinochalcomenite and cobaltomenite

Raman spectroscopy has been used to study the dimorphous selenite minerals chalcomenite, cobaltomenite and clinochalcomenite. Selenite minerals are characterised by the position of the symmetric stretching mode that is observed at higher wavenumbers than the anti‐symmetric stretching mode. The selenite ion has C_3v symmetry and four modes, 2A₁ and 2E. These modes are observed at 813, 472 cm⁻¹ (A₁) and 685, 710, 727 and 367 and 396 cm⁻¹ (E). Bands assigned to the water stretching vibrations are observed for chalcomenite at 2953, 3184 and 3506 cm⁻¹ and for clinochalcomenite at 2909, 3193 and 3507 cm⁻¹. A comparison of the Raman spectra of chalcomenite, clinochalcomenite and cobaltomenite is made. The position of these bands enabled hydrogen bond distances in the selenite structure to be estimated. Hydrogen bond distances for chalcomenite and clinochalmenite were determined to be similar. Copyright © 2008 John Wiley & Sons, Ltd.     

Solvent and pH Effects on the Fluorescence of 7-(Dimethylamino)-2-Fluorenesulfonate

A novel water-soluble solvatochromic molecule, 7-(dimethylamino)-2-fluorenesulfonate (2,7-DAFS), was prepared by a three-step reaction from 2-nitrofluorene in good overall yield. The pH and solvent effects on the UV-VIS absorption and fluorescence spectra of 2,7-DAFS have been studied. Protonation of the dimethylamino group switches the absorption from intramolecular charge-transfer (ICT) to π → π* transition. The ground state pKa value of 2,7-DAFS was determined as 4.51. The fluorescence spectrum of the excited basic form, *(DAFS), shows a structureless single band with a large Stokes shift, whereas that of the acidic form, *(⁺HDAFS), exhibits a structured band with a small Stokes shift. The emission intensities of the basic and acidic forms versus pH/Ho plots show stretched sigmoidal curves and indicate that (1) the rate of deprotonation of *(⁺HDAFS) is comparable to the fluorescence decay of the species, and (2) the efficient proton-induced quenching of *(DAFS) fluorescence occurs. The pKa* was estimated as −1.7 from the fluorescence titration curve. The fluorescence maximum of *(DAFS) is blue-shifted as the polarity of solvent decreases. However, no clear dependency of the emission intensity and spectral half width, and thus fluorescence quantum yield, on the solvent polarity was revealed. It appears that the fluorescence sensitivity of 2,7-DAFS is 15 ∼ 25 times greater than the sensitivity of a widely utilized fluorescent probe, 5-(dimethylamino)-1-naphthalenesulfonate. This higher sensitivity, together with the ease of derivatization, would provide the fluorene-based fluorescent molecules significant advantages for a variety of applications.     

Magnetoresistivity and acoustoelectronic effects in a tilted magnetic field in <Emphasis Type="Italic">p</Emphasis>-Si/SiGe/Si structures with an anisotropic <Emphasis Type="Italic">g</Emphasis> factor

Magnetoresistivity ρ _xx and ρ _xy and the acoustoelectronic effects are measured in p-Si/SiGe/Si with an impurity concentration p = 1.99 × 10¹¹ cm⁻² in the temperature range 0.3–2.0 K and an tilted magnetic field up to 18 T. The dependence of the effective g factor on the angle of magnetic field tilt θ to the normal to the plane of a two-dimensional p-Si/SiGe/Si channel is determined. A first-order ferromagnet-paramagnet phase transition is observed in the magnetic fields corresponding to a filling factor ν = 2 at θ ≈ 59°–60°.