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1.
<正>A high-purity benzoxazine(Boz-BOA) containing benzoxazole structure was successfully synthesized by three-step synthetic method using 2-(4-aminophenyl)-1H-benzoxazole-5-amine(BOA) and ortho-hydroxybenzaldehyde.The structure of Boz-BOA was confirmed by FTIR and ~1H NMR spectra.The DSC was utilized to probe the curing behavior of Boz-BOA and exhibited a narrow melting peak and curing exothermic peak. 相似文献
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The prototype hetero-binuclear complexes containing metal-metal bonds, {CpRh[E2C2(B10H10)]}[Fe(CO)3] (Cp = Cp* = eta 5-Me5C5, E = S(5a), Se(5b); Cp = Cp = eta 5-1,3-tBu2C5H3, E = S(6a), Se(6b)) and {CpCo[E2C2(B10H10)]}[Fe(CO)3] (Cp = Cp* = eta 5-Me5C5, E = S(7a), Se(7b); Cp = Cp = eta 5-C5H5, E = S(8a), Se(8b)) were obtained from the reactions of 16-electron complexes CpRh[E2C2(B10H10)] (Cp = Cp*, E = S(1a), Se(1b); Cp = Cp, E = S(2a), Se(2b)), CpCo[E2C2(B10H10)] (Cp = Cp*, E = S(3a), Se(3b); Cp = Cp, E = S(4a), Se(4b)) with Fe(CO)5 in the presence of Me3NO. The molecular structures of {Cp*Rh[E2C2(B10H10)]}[Fe(CO)3] (E = S(5a), Se(5b)), {CpRh[S2C2(B10H10)]}[Fe(CO)3] (6a) {Cp*Co[S2C2(B10H10)]}[Fe(CO)3] (7a) and {CpCo[S2C2(B10H10)]}[Fe(CO)3] (8a) have been determined by X-ray crystallography. All these complexes were characterized by elemental analysis and IR and NMR spectra. 相似文献
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A one-pot, three-component reaction of pyridine, thiophthalimide and acyl chloride gives novel tricyclic 1,2-dihydropyridines regio- and stereoselectively, in which a mesomeric betaine would be a key intermediate for [4+2]-cycloaddition reaction with thiocarbonyl compounds. 相似文献
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Kenneth M. Doxsee Nicholas P. Wood Erin M. Hanawalt Timothy J. R. Weakley 《Heteroatom Chemistry》1996,7(5):383-389
Treatment of titanacyclobutenes with two equivalents of dichlorophenylphosphine affords diphosphacyclopentenes, two examples of which were structurally characterized by single-crystal X-ray diffraction analysis. The analogous reaction of a titanacyclobutene with dichlorophenylstibine affords the corresponding distibacyclopentene as well as a stibacyclobutene. © 1996 John Wiley & Sons, Inc. 相似文献
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A series of novel phosphonodipeptides containing a uracil or thymine group was synthesized in 54.2–74.1% yields by means of a peptide coupling reaction with DCC as the dehydrating agent and 1‐hydroxybezotriazole as the activating agent of the carboxyl group. All products were characterized by 1H NMR, 31P NMR and IR spectra, and by elemental analyses. The crystal and molecular structure of compound 6c has been determined by X‐ray diffraction. © 2000 John Wiley & Sons, Inc. Heteroatom Chem 11:422–427, 2000 相似文献
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Wei-Li Dong Jun-Ying Xu Li-Xia Xiong Zheng-Ming Li 《Journal of the Iranian Chemical Society》2013,10(3):429-437
A novel series of amides containing N-pyridylpyrazole were designed and synthesized. All of the compounds were characterized and confirmed by IR, 1H NMR, 13C NMR, MS and elemental analysis. The single crystal structure of 9d was determined by X-ray diffraction. The bioassay tests showed that the title compounds exhibited good insecticidal activities against Mythimna separata Walker, diamondback moth and Laphygma exigua Hübner. 相似文献
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Stanislav Kafka Barbara Larissegger‐Schnell Thomas Kappe 《Journal of heterocyclic chemistry》2004,41(5):717-721
The synthesis of seven mesomeric triazaphenalene betaines 4a‐g by condensation reaction of hexahydro‐2H‐pyrimido[1,2‐a]pyrimidine 1 with diethyl malonates 2a‐g or with bis(2,4,6‐trichlorophenyl)malonates 3c,f has been achieved. The guanidine 1 forms in benzene solution a salt with trimethyl methanetricarboxylate 5 which upon heating produces 4a. 相似文献
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O. V. Bykhovskaya I. M. Aladzheva D. I. Lobanov P. V. Petrovskii K. A. Lyssenko I. V. Fedyanin T. A. Mastryukova 《Russian Chemical Bulletin》2005,54(11):2642-2647
2-Oxo-1,2-azaphospholanes and 1,2-azaphospholanium salts containing an amino acid fragment were synthesized by intramolecular
P-alkylation of N-3-chloropropyl-substituted tricoordinate phosphorus amides. Hydrolysis of 2-oxo-1,2-azaphospholanes at the P-N bond gives
rise to γ-aminopropylphosphonic acid derivatives.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2557–2562, November, 2005. 相似文献
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Jung‐Won Park Deok‐Heon Kweon Young‐Jin Kang Woo Song Lee Su‐Dong Cho Yong‐Jin Yoon 《Journal of heterocyclic chemistry》2000,37(1):5-10
This paper presents the synthesis of some novel acyclonucleosides involving pyrrolo[2,3‐c]pyridazine and 4‐hydroxybutyl side chain. 相似文献
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A new ion‐pair complex [1‐(4‐nitrobenzyl)pyridinium][Ni(bdt)2] (1), in which bdt2? = 1,2‐benzenedithiolate, has been synthesized and characterized. The X‐ray structure analysis shows that the anions are centrosymmetric, the two non‐equivalent anions form different uniform‐spaced stacking pattern and the weak H‐bonding interactions of C? H…S were observed in 1. The temperature dependence of magnetic susceptibilities of 1 indicates ferromagnetic behavior in the antiferromagnetic exchange system, which may arise from spin‐canting. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
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S. V. Litvinenko Yu. M. Volovenko F. S. Babichev 《Chemistry of Heterocyclic Compounds》1992,28(11):1307-1311
A new method for the synthesis of pseudo-cross-conjugated mesomeric betainic heterocyclic compounds with an angular nitrogen atom has been developed consisting in the reaction of 1,4-dielectrophile — -carbethoxy-2-(3-chloro)quinoxalylacetonitrile with azoles. Experimental regularities have been studied and a reaction mechanism has been proposed including the stage of formation of an ylide from a quaternary azolium salt. A pseudo-crossconjugated mesomeric betainic heterocyclic compound containing a thiazole ring compound has been synthesized for the first time.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1528–1533, November, 1992. 相似文献
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Achintya K. Bandyopadhyaya Sureshbabu Narayanasamy Rolf F. Barth Werner Tjarks 《Tetrahedron letters》2007,48(26):4467-4469
Texaphyrin macrocycles that contain gadolinium or lutetium, such as motexafin gadolinium and motexafin lutetium, are versatile anticancer therapeutics and diagnostics. Gadolinium texaphyrins substituted with carborane clusters could also find application in combined gadolinium and boron neutron capture therapy (GdB-NCT). The synthesis and characterization of novel texaphyrins containing gadolinium or lutetium in the pentaaza core and two carborane clusters bound to opposite pyrrol units of the macrocycle are described. 相似文献
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Braunschweig H D'Andola G Welton T White AJ 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,12(2):600-606
A series of alpha,omega-boryl(bromo)alkanes of the general formula R2B-(CH2)n-Br (n = 3, 4, 5, 6) was obtained in high yield following a standard hydroboration protocol. Upon treatment with Mg turnings and formation of the respective Grignard species, all alkanes with n = 4 to 6 underwent an unprecedented boron-centered cyclisation reaction with formation of boratacyclopentanes, -hexanes, and -heptanes, respectively. All new compounds were isolated in high yields as colourless, crystalline materials and characterised in solution by multinuclear NMR spectroscopy. Four representative examples were chosen for X-ray diffraction studies, thus providing the first structurally characterised ring systems of that size at a tetraalkyl borate centre. 相似文献
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L. M. Bogomolova Yu. B. Pyatnova A. A. Savina V. S. Smolyakov V. P. Zvolinskii 《Chemistry of Heterocyclic Compounds》1976,12(4):382-385
New tetrahydro-1,2-oxazine-N-dithiocarboxylic acid esters were synthesized, and their structures were investigated by IR and PMR spectroscopy and mass spectrometry.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 454–458, April, 1976. 相似文献
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R. O. Kochkanyan S. S. Radkova N. L. Klyuev L. Yu. Petrovskaya S. N. Baranov 《Chemistry of Heterocyclic Compounds》1978,14(12):1372-1375
Previously undescribed pyrimidine betaines with cycloammonium and triphenylphosphonium cations were obtained. A study of the UV, IR, PMR, and mass spectra made it possible to draw a conclusion regarding the noncyclic structure of betaines stabilized by an intramolecular donor-acceptor interaction of the charge-transfer complex (CTC) type.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1687–1690, December, 1978. 相似文献
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《Tetrahedron letters》1988,29(4):491-492
A facile entry into the almost unknown azolium azolate inner salts is described, and the structure of these highly dipolar compounds is well reflected by their spectroscopic properties and reactivity towards electrophiles (MeI) and dipolarophiles (DMAD) under mild conditions. 相似文献
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I. A. Dvornikova L. L. Frolova A. V. Kuchin I. P. Beletskaya 《Russian Journal of Organic Chemistry》2007,43(3):352-358
Some new bi -and tridentate nitrogen-containing chiral ligands were synthesized on the basis of natural monoterpenoids, (+)-and (?)-myrtenals and (+)-myrtenol. A procedure was proposed for the synthesis of unsymmetrical ligands containing terpenoid and o-hydroxyphenyl fragments. 相似文献