Spatial and temporal variations of radon concentrations in groundwater of hard rock aquifers in Madurai district,India

Radon (²²²Rn) and other radionuclides in groundwater can lead to health problems if present in higher concentrations. A study was carried out in Madurai district of Tamilnadu by collecting groundwater samples for four different seasons and aims to identify the regions with higher ²²²Rn concentration along with their spatial and seasonal variations. ²²²Rn has been compared with field parameters, log pCO₂, major ions and uranium to detect the factors responsible for the higher concentration in groundwater. The weathering process induces the release of higher uranium ions from the granitic terrain from the rock matrix which enhances the ²²²Rn levels in groundwater.     

Occurrence of the radionuclides in groundwater of crystalline hard rock regions of central Tamil Nadu,India

A study was conducted to understand the occurrence of the radionuclides in groundwater of crystalline hard rock region. Samples were collected to analyze major cations, anions, U, ²²²Rn and stable isotopes of oxygen, hydrogen. It was inferred that few samples have U and ²²²Rn concentrations higher than the permissible limit of drinking water standard. High degree of weathering of granitic rocks and long contact time of groundwater with the aquifer matrix could be the reason for enhanced U and ²²²Rn levels in groundwater. The association of U with SO₄ also proves that there exists anthropogenic influence in groundwater composition.     

222Rn and 226Ra activity concentrations in groundwaters of southern Poland: new data and selected genetic relations

Since 2008, the authors have been conducting research into ²²²Rn and ²²⁶Ra activity concentrations in shallow circulation groundwaters in southern Poland. Measurements have been performed with a liquid-scintillation method and ultra low-level liquid-scintillation spectrometers α/β Quantulus 1220. The research carried out so far has demonstrated that in the Sudetes groundwaters with high activity concentrations of ²²²Rn and ²²⁶Ra are common. In other studied areas in southern Poland no shallow circulation groundwaters with high radon or radium concentrations have been found yet. The conducted research has demonstrated that the activity concentration of ²²²Rn dissolved in shallow circulation groundwaters in the Sudetes depends chiefly on the amount of radon, which after being released as gas from reservoir rocks is dissolved in waters flowing through these rocks. At the same time, the concentration of ²²²Rn dissolved in some shallow circulation groundwaters in the Carpathians is influenced significantly by the amount of radon produced from the decay of its parent ion ²²⁶Ra²⁺ dissolved in these waters.     

Assessment of inhalation exposure potential of broken uranium ore piles in low-grade uranium mine

This paper presents the assessment of inhalation exposure potential of broken uranium ore piles in different stopes of Jaduguda uranium mines of India. ²²²Rn emanation coefficient of broken uranium ore was measured in laboratory by collecting air sample from airtight glass jar containing ore sample. An attempt was also made to correlate the emanation coefficient with ²²⁶Ra content of the ore. The ²²²Rn progeny doses estimated based on radon activity concentration of broken ore, occupancy period and equilibrium ratio in different stopes were well below the prescribed limit of International Commission on Radiological Protection. The maximum ²²²Rn progeny dose contribution from broken ore piles was worked out to be 0.22 mSv year^?1. This suggests that the broken ore piles are not the significant contributor of inhalation exposure under the existing ventilation condition of Jaduguda uranium mine.     

Radon isotope assessment of submarine groundwater discharge (SGD) in Coleroon River Estuary,Tamil Nadu,India

Submarine groundwater discharge is the fresh groundwater discharge to sea that impacts the coastal regions. Radon (²²²Rn) isotope has been used to quantify SGD in coleroon river estuary, India. Continuous ²²²Rn analyses were attempted for 10 days in groundwater and pore water samples at three different locations. ²²²Rn in groundwater ranges between 35.0 and 222.0 Bq m^?3 and in pore water between 14.0 and 150.0 Bq m^?3 irrespective of locations. The radon mass balance estimated total SGD rate ranges between 2.37 and 7.47 m days^?1. The SGD increases with distance from coast, influenced by tides and hydrological features.     

222Rn behavior at the Latera geothermal field (Northern Latium,Italy)

Permanent probes to sample soil gases were placed at the Latera geothermal field, located in the Volsini Mts., Latium, Italy. Due to high uranium concentrations in the area's alkali-potassic volcanics outcropping, quite high²²²Rn values, ranging from 9,260 up to 753,000 Bq/m³, were found. The highest radon activities match tectonic structures such as fractures and faults, and a deep high structure which constitutes the geothermal reservoir. These high radon values also conform to a major amount of⁴He and CO₂. The latter gases are enriched in the gaseous phase of the geothermal fluids, and their migration is also controlled by structural features. This suggests that the enrichment of²²²Rn in the soil gases, can be linked to a direct contribution of²²⁶Ra, carried by deep-seated fluids from the reservoir itself.     

222Rn content and234U/238U activity ratio in groundwaters

Geochemical radioanalytical studies of groundwater were performed in the valleys of Villa de Reyes and San Luis Potosi (Mexico). The experiments were designed to measure radon and uranium content and²³⁴U/²³⁸U activity ratio in groundwater samples taken from wells in these sites and at the Nuclear Center of Salazar, Mexico.²²²Rn content varied depending on the sample source, reaching a maximum value of 235 pCi/l; uranium concentration results were less than 1 g/1 and²³⁴U/²³⁸U activity ratios were close to equilibrium.     

Use of 222Rn to trace submarine groundwater discharge in a tidal period along the coast of Xiangshan, Zhejiang, China

²²²Rn is one of the operative tracers for submarine groundwater discharge (SGD), which plays a significant role in the land–ocean interaction of the estuarine and coastal regions. By the distribution pattern of ²²²Rn in atmosphere, groundwater and surface seawater, in a full tidal period (25 h) in March 2012, SGD was estimated along the coast of Xiangshan, Zhejiang, China. ²²²Rn activity in Xiangshan coast was in range of 2.4 × 10⁴–1.7 × 10⁵ Bq/m³ with an average of 9.6 × 10⁴ Bq/m³ for groundwater; 0.2 × 10²–2.8 × 10² Bq/m³ with an average of 1.1 × 10² Bq/m³ for surface seawater. ²²²Rn activities in groundwater were much greater than those in surface water, suggesting that the major source of radon came from coastal groundwater discharge. Rn fluxes of atmospheric emissions, sediment, and of ²²⁶Ra in situ decay can be negligible in this study, but the tidal effects play a crucial role in Rn fluxes. Using a radon inventory equilibrium model, we estimated that the average SGD was 13.2 cm/day and the average terrestrial SGD flux was 1.8 × 10⁸ m³/day. Furthermore, SGD may have a vital impact on the composition and structure of nutrients in seawater, and contribute to eutrophication events occurring in spring season along the coast of the East China Sea.     

Activity concentrations of 226Ra, 228Ra, 222Rn and their health impact in the groundwater of Jordan

The activity concentrations of ²²⁶Ra, ²²⁸Ra and ²²²Rn were measured in 87 groundwater samples to estimate the activity concentrations of these radionuclides and health impact due to intake of these radionuclides in groundwater of Jordan. The mean activity concentrations of ²²⁶Ra, ²²⁸Ra and ²²²Rn in groundwater were found to be 0.293?±?0.005 Bq L^?1, 0.508?±?0.009 Bq L^?1 and 58.829?±?8.824 Bq L^?1, respectively. They give a mean annual effective dose of 0.481 mSv with mean lifetime risk of 24.599?×?10^?4, exceeding the admissible limit of 10^?4. Most of the received annual effective dose (59.15% of the total) is attributed to ²²⁸Ra.

     

Distribution of uranium in groundwaters of Bathinda and Mansa districts of Punjab,India: inferences from an isotope hydrochemical study

This paper presents the isotope hydrochemical results of groundwaters from southwest Punjab for assessing the uranium contamination and evaluating the factors leading to elevated uranium concentration. A total of 35 samples covering shallow and deep zones were collected for hydrochemistry and isotopes. Uranium concentration ranges between 2.3 and 357 µg L^?1 and 66% of the samples are contaminated. Both shallow and deep zones show U contamination but high incidences are noticed in shallow zone. Hydrochemical correlations infer geological sources rather than anthropogenic sources responsible for U contamination. Isotopically there is no clear distinction between high and low U groundwater.     

Possible correlation between uranium content in host rocks and radon and daughters concentration in air for two Italian ZnS-PbS mines

Research was carried out to evaluate the possible correlation between the uranium content in host rocks and the Rn and daughters concentration in air for two Italian ZnS-PbS mines. As a great variability had been ascertained for²²²Rn and daughters concentration in the different areas, it appeared of some interest to verify whether this fact was due to a different uranium concentration in the host dolomitic rocks or simply to a ventilation problem. Some rock samples were collected in several places where also radon and daughters were drawn; uranium was determined by fluorimetry and by alpha spectrometry after a chemical separation with a Microthene-TOPO column.²²²Rn was measured by the scintillation cell method, while the decay products were determined by the Markov and Tsivoglou methods. No correlation could be found between uranium content and radon concentration, but a good linearity was detected between the uranium content and the concentration of Rn decay products (alpha potential energy).     

Radioactivity of spring and surface waters in the region of the uranium ore deposit at Žirovski vrh

Data are presented on²²²Rn,²²⁶Ra, natural uranium concentrations and gross beta activity of spring and surface waters in the region of the uranium ore deposit at Žirovski vrh. The concentrations were found to be relatively low. There is some increase in the vicinity of the explorative Uranium Mine but is, at least up till now, only of a local character.     

Radon concentration in dwellings in Aomori Prefecture, Japan

To obtain an average dose from ²²²Rn to the people in Aomori Prefecture where the first Japan"s nuclear fuel cycling facilities are now under construction, we surveyed ²²²Rn concentrations in 109 dwellings in the Prefecture from 1992 to 1996. The outdoor ²²²Rn concentrations were also measured in gardens of 15 dwellings. The ²²²Rn concentrations were measured with passive ²²²Rn detectors which used a polycarbonate film for counting a-ray and could separate concentrations of ²²²Rn from ²²⁰Rn. Counting efficiencies of the detectors were calibrated with a standard ²²²Rn chamber in the Environmental Measurement Laboratory in USA and in the National Radiological Protection Board in UK. Geometric means of ²²²Rn concentration were 13 and 4.4 Bq^.m^-3 in the dwellings and outdoor, respectively. These values were consistent to nationwide survey results in Japan. The ²²²Rn concentrations in the dwellings depended on their age. The concentrations were higher in recent dwellings than in older ones. The radiation dose from ²²²Rn was estimated, taking into account the occupancy factor for inside and outside of dwellings. The annual dose was 0.32 mSv^.y^-1, and 99% of the dose came from the exposure to ²²²Rn inside the dwelling.     

A multi-detector continuous monitor for assessment of <Superscript>222</Superscript>Rn in the coastal ocean

Summary Radon-222 is a good natural tracer of groundwater discharge and other physical processes in the coastal ocean. Unfortunately, its usefulness is limited by the time consuming nature of collecting individual samples and traditional analysis schemes. We demonstrate here an automated multi-detector system that can be used in a continuous survey basis to assess radon activities in coastal ocean waters. The system analyses ²²²Rn from a constant stream of water delivered by a submersible pump to an air-water exchanger where radon in the water phase equilibrates with radon in a closed air loop. The air stream is fed to 3 commercial radon-in-air monitors connected in parallel to determine the activity of ²²²Rn. By running the detectors out of phase, we are able to obtain as many as 6 readings per hour with a precision of approximately ±5-15% for typical coastal seawater concentrations.     

Radioactivity in groundwater along the borders of Oman and UAE

Characterizing the quality and radioactivity of groundwater is vital as it represents valuable resource in arid regions. Here we present radioactivity level in groundwater collected from wells in a region along the border between Sultanate of Oman and United Arab Emirates (UAE). The aquifers are alluvium deposits (silt, sand and gravel) and the measured groundwater radioactivity (including ²³²Th, ²³⁸U, ²³⁵U, ²²⁶Ra, ²²²Rn, gross-α and gross-β) indicates values below the WHO permissible limits for drinking water. The results also show large difference in radioactivity fingerprints, in particular for ²²⁶Ra and ²²²Rn within the investigated aquifers. The data further indicate lower radioactivity in groundwater of the alluviums compared to the carbonate aquifers in the region. This feature makes the alluvium aquifers valuable reservoirs that should be carefully exploited as a source of groundwater. As this is the first investigation on the radioactivity of groundwater in alluvial aquifers in the region, it suggests that other alluvial deposits, particularly those inland and far from the marine water intrusion or seepage from carbonate rocks would have low radioactivity fingerprints.     

Radon concentration in groundwater of Varahi and Markandeya river basins, Karnataka State, India

The present study presents an overview of the distribution of radon (²²²Rn) activity concentration in the groundwater samples and their annual effective dose exposure in the Varahi and Markandeya command areas. Radon measurement was made using Durridge RAD-7 radon-in-air monitor, using RAD H₂O technique with closed loop aeration concept. The measured ²²²Rn activities in 16 groundwater samples of Varahi command area ranged between 0.2 ± 0.4 and 10.1 ± 1.7 Bq L⁻¹ with an average value of 2.07 ± 0.84 Bq L⁻¹, well within the EPA’s maximum contaminant level (MCL) of 11.1 Bq L⁻¹. In contrast, the recorded ²²²Rn activities in 14 groundwater samples of Markandeya command area found to vary from 2.21 ± 1.66 to 27.3 ± 0.787 Bq L⁻¹ with an average value of 9.30 ± 1.45 Bq L⁻¹. 21.4% of the samples (sample no. RMR5, RMR11 and RMR12) in the Markandeya command area exceeded the EPA’s MCL of 11.1 Bq L⁻¹ and it was found that some samples in both the command areas were found to have radon values close to MCL value. The spatial variation in the radon concentration in the Varahi and Markandeya command area were delineated by constructing the contour map. The total annual effective dose resulting from radon in groundwater of both Varahi and Markandeya command areas were significantly lower than the UNSCEAR and WHO recommended limit for members of the public of 1 mSv year⁻¹.     

Development of a sparging chamber for field radon analysis

Radon-222 has become a widely used tracer of submarine groundwater discharge. However, remote field studies are often limited by the need to pump water to a spray chamber which degasses dissolved radon for subsequent analysis in the gaseous phase. We develop here a new method of degassing dissolved ²²²Rn, utilizing a stream of bubbles driven by the internal air pump of a commercial radon analyzer to achieve air:water partitioning equilibrium, eliminating the need to pump water. This system utilizes a sparging chamber, comprised of a slotted vertically-oriented pipe with bubbles produced in the bottom. A non-slotted section of the pipe at the top of the chamber forms a sealed headspace, allowing air to be circulated in a closed loop between the sparging chamber and a radon-in-air monitor. We found that such a sparging chamber needs to allow bubbles to rise through at least 45 cm of water column to function at equal efficiency as the standard protocol of the spray chamber. Under our optimized configuration, the sparging chamber operates as efficiently as the standard protocol at measuring dissolved ²²²Rn activities when encountering increasing ²²²Rn activities, and offers even greater gas exchange efficiency when dissolved ²²²Rn activities decrease. The sparging chamber offers a more field-friendly alternative to measuring ²²²Rn activities, as it eliminates the need to maintain a submersible pump throughout the measurement and it offers increased temporal resolution when variable ²²²Rn activities are expected.     

Effect of atmospheric pressure variations on the <Superscript>222</Superscript>Rn activity concentration in the air of a wine cellar

We have measured the variation of atmospheric pressure and of ²²²Rn activity concentration in the air of a wine cellar with an AlphaGAURD type ionization chamber radon monitor. We have found that the ²²²Rn activity concentration varies inversely with pressure. To explain this behavior we have done model calculations. We have compared the results of model calculations with the results of experimental measurements, and we have found that the model is capable to reproduce some part of the variation of ²²²Rn activity concentration.     

Two new methods of determining radon diffusion in fish otoliths

Otoliths are bony structures found in the ears of fish and used in the²¹⁰Pb/²²⁶Ra dating method for age determination. This paper checks the assumption that²²²Rn is not lost from or added to orange roughy fish otoliths by diffusion, which would invalidate the technique. The first method of monitoring diffusion relies on measuring the gamma activity of daughter radionuclides. Otoliths were exposed to an atmosphere enriched in²²²Rn for 10 days, and the supported gamma activity inside them measured allowing for various decay corrections. The calculated radon addition was (0.5±0.5)% of the activity of the²²⁶Ra present. The second method used an alpha spectrometer and attempted to detect²²²Rn directly outgased from otoliths in the detector vacuum chamber. The results were consistent within errors with those of the first method and showed no loss or gain of²²²Rn, supporting previous estimates of a long life-span for the orange roughy. In contrast it was found that approximately 10% of²²²Rn formed in orange roughy fish scales was lost to an evacuated environment, (hence perhaps to an aqueous environment) and that for this species it could be difficult to base a dating method on analysis of scales. Nevertheless a preliminary minimum age of 57 years was obtained. The methods could be used with non-biological samples to determine²²²Rn diffusion rates.     

222Rn gas diffusion and determination of its adsorption coefficient on activated charcoal

The adsorption coefficient is the fundamental parameter characterizing activated charcoal"s ability to adsorb ²²²Rn. The adsorption coefficient is determined for ²²²Rn activated charcoal detectors. In addition, a diffusion and adsorption model is developed for the transport of ²²²Rn in a porous bed of activated charcoal. These processes can be described by parabolic second order differential equation. The equation is numerically solved using the finite differences method. With this model, the ²²²Rn activity adsorbed in the detector is calculated for diverse situations.