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1.
Excitation energies from ground state for 86 fine-structure levels as well as oscillator strengths and radiative decay rates for all fine-structure transitions among the levels of the terms (1s22s22p6)3s2(1S), 3s3p(1,3Po), 3s3d(1,3D), 3s4s(1,3S), 3s4p(1,3Po), 3s4d(1,3D), 3s4f(1,3Fo), 3p2(1S, 3P, 1D), 3p3d(1,3Po, 1,3Do, 1,3Fo), 3p4s(1,3Po), 3p4p(1,3S, 1,3P, 1,3D), 3p4d(1,3Po, 1,3Do, 1,3Fo), 3p4f(1,3D, 1,3F, 1,3G) and 3d2(1S, 3P, 1D, 3F,1G) of Cr XIII are calculated using extensive configuration-interaction (CI) wave functions obtained with the CIV3 computer code of Hibbert. The important relativistic effects in intermediate coupling are included through the Breit-Pauli approximation via spin-orbit, spin-other-orbit, spin-spin, Darwin and mass correction terms. Small adjustments to the diagonal elements of the Hamiltonian matrices have been made. The mixing among several fine-structure levels is found to be very strong. Our excitation energies, including their ordering, are in excellent agreement (better than 0.5%) with the available experimental results. From our transition probabilities, we have also calculated radiative lifetimes of some fine-structure levels. Our calculated lifetime for the longer-lived level 3s3p(3P1) is found to be in excellent agreement with the experimental result of Curtis compared to other theoretical calculations.  相似文献   

2.
Excitation energies from ground state for 97 fine-structure levels as well as oscillator strengths and radiative decay rates for all electric-dipole-allowed and intercombination transitions among the fine-structure levels of the terms belonging to the (1s 22s 22p 6)3s 23p, 3s 3 p 2, 3s 23d, 3p 3, 3s3p3d, 3p 23d, 3s3d 2, 3s 24s, 3s 24p, 3s 24d, 3s 24f, and 3s3p4s configurations of Co XV are calculated, using extensive configuration-interaction (CI) wave functions, obtained with the CIV3 computer code of Hibbert. The important relativistic effects in intermediate coupling are included through the Breit-Pauli approximation via spin-orbit, spin-other-orbit, spin-spin, Darwin and mass correction terms. Small adjustments to the diagonal elements of the Hamiltonian matrices have been made. Our calculated excitation energies, including their ordering, are in excellent agreement with the experimental results and the experimentally compiled energy values of the National Institute for Standards and Technology (NIST) wherever available. The mixing among several fine-structure levels is found to be very strong, with most of the strongly mixed levels belonging to the (1s 22s 22p 6)3p 23d and 3s3d 2 configurations. The strong mixing among several fine-structure levels makes it very difficult to identify them uniquely. Perhaps, that may be the reason for the lack of both experimental and theoretical results for these levels. We believe that our extensive calculated values can guide experimentalists in identifying the fine-structure levels in their future work. From our radiative decay rates we have also calculated radiative lifetimes of some fine-structure levels. In this calculation we also predict new data for several fine-structure levels where no other theoretical and/or experimental results are available.  相似文献   

3.
We have done relativistic calculations for the evaluation of energy levels, oscillator strengths, transition probabilities and lifetimes for Cr VIII ion. Use has been made of configuration interaction technique by including Briet-Pauli approximation. The energies of various levels from the ground state to excited levels of 3s3p6, 3s23p43d, 3s23p44s, 3s23p44d of Cr VIII are given in LSJ coupling scheme after fine-tuning and are compared with the experimental results compiled in the NIST Data Base. Many new lines have been predicted which have not appeared so far in the NIST Data.  相似文献   

4.
The electric dipole transition probabilities, oscillator strengths and lifetimes have been calculated using the weakest bound electron potential model theory (WBEPMT) for singly ionized magnesium. In the calculations both multiplet and fine structure transitions are studied. We have employed both the numerical Coulomb approximation (NCA) method and numerical non-relativistic Hartree-Fock (NRHF) wave functions for expectation values of radii. The calculated oscillator strengths and lifetimes have been compared with MCHF results given by Fischer et al. (2006). A good agreement has been obtained with the MCHF results. Moreover, some new transition probabilities, oscillator strengths and lifetime values, not existing in the data bases for highly excited levels in singly ionized magnesium, have been obtained using this method.  相似文献   

5.
We use an analytic potential model adjusted to experimental energy levels to generate wave functions for the valence and excited states of the isoelectronic ions P III, S IV, Cl V, and Ar VI of the aluminum sequence. Using these wave functions in conjuction with the Born approximation and the LS-coupling scheme, we calculate optical oscillator strengths for various excitations of the valence electron. Good agreement is obtained with experimental and theoretical data.  相似文献   

6.
The weighted oscillator strengths (gf) and the lifetimes for Si II presented in this work were carried out in a multiconfiguration Hartree–Fock relativistic (HFR) approach. In this calculation, the electrostatic parameters were optimized by a least-squares procedure, in order to improve the adjustment to experimental energy levels. This method produces gf-values that are in better agreement with intensity observations and lifetime values that are closer to the experimental ones. In this work we presented all the experimentally known electric dipole Si II spectral lines.  相似文献   

7.
8.
The weighted oscillator strengths gf and the lifetimes for S XIV presented in this work have been calculated in a multiconfigurational Hartree–Fock relativistic approach. In this calculation, the electrostatic parameters were optimized by a least-squares procedure in order to improve the adjustment to experimental energy levels. This method produces gf values that are in better agreement with observed line intensities and lifetime values closer to the experimentally determined ones. In this work we presented all the experimentally known electric dipole S XIV spectral lines. Published in Zhurnal Prikladnoi Spektroskopii, Vol. 76, No. 3, pp. 473–476, 2009.  相似文献   

9.
The semi-empirical weighted oscillator strengths (gf) and the lifetimes presented in this work for all experimentally known electric dipole S V spectral lines and energy levels were carried out in a multiconfiguration Hartree–Fock relativistic (HFR) approach. In this calculation, the electrostatic parameters were optimized by a least-squares procedure, in order to improve the adjustment to experimental energy levels. This method produces lifetime values and gf values that are in agreement with intensity observations used for the interpretation of spectrograms of solar and laboratory plasmas.  相似文献   

10.
The weighted oscillator strengths (gf) and the lifetimes for Si I presented in this work were carried out in a multiconfiguration Hartree-Fock relativistic approach. In this calculation, the electrostatic parameters were optimized by a least-squares procedure, in order to improve the adjustment to experimental energy levels. This method produces gf-values that are in better agreement with intensity observations and lifetime values that are closer to the experimental ones. In this work we present all the experimentally known electric dipole Si I spectral lines.  相似文献   

11.
The weighted oscillator strengths (gf) and the lifetimes for Si XII and Si XIII presented in this work were carried out in a multiconfiguration Hartree-Fock relativistic (HFR) approach. In this calculation, the electrostatic parameters were optimized by a least-squares procedure, in order to improve the adjustment to experimental energy levels. This method produces gf-values that are in better agreement with intensity observations and lifetime values that are closer to the experimental ones. In this work we present all the experimentally known electric dipole Si XII and Si XIII spectral lines.  相似文献   

12.
The gamma decay of the22Ne(p, y)23Na resonances in the proton energy rangeE p=1.0→2.0 MeV has been investigated with a 20cm3 Ge(Li) detector. Implanted targets were used. The absolute strengths of the strongest resonances were determined and the branching ratios of twenty resonance levels and several bound states are reported. Mean lifetimes of the levels atE x=2.078 MeV (18.7±3.5 fs), 2.393 MeV (580 ?190 +370 fs), 2.641 MeV (88 ?14 +20 fs), 2.985 MeV (4.0 ?1.0 +1.3 fs), 3.679 MeV (24 ?4 +5 fs), 3.915 MeV (7.4 ?2.0 +2.5 fs) and 4.775 MeV (<2.0 fs) were obtained from measurements of the gamma ray Doppler shifts.  相似文献   

13.
李永强  吴建华  袁建民 《物理学报》2008,57(7):4042-4048
利用Debye模型,研究了等离子体屏蔽效应对热等离子体中原子能级和振子强度的影响.通过在MCDF模型中引入等离子体屏蔽效应,计算了MnXXII-BrXXII等11个类Be离子在等离子体环境下2s2—[2s1/2,2p1/21和2s2—[2s1/2,2p3/21跃迁的能级和振子强度.计算结果表明,等离子体屏蔽效应使得类Be离子2s2—[2s1/2,2p1/21跃迁的激发能量增大,从而导致谱线蓝移现象;并且随着屏蔽效应的不断增强,蓝移的程度会逐渐加大.屏蔽效应对于2s2—[2s1/2,2p3/21跃迁的振子强度也有类似的影响. 关键词: Debye 等离子体屏蔽 跃迁能级 振子强度  相似文献   

14.
We report a large scale configuration interaction calculation of Cl V by taking account of relativistic effect through the Breit-Pauli approximation. Excitation energies of the lowest 49 fine structure levels relative to the ground state are found to be in good agreement with the NIST recommended data. Oscillator strengths, line strengths and radiative rates for the optically allowed and intercombination transitions among these levels and life times for some relatively longer lived fine structure levels are also reported for this ion. We confirm the interesting result that the life times for the multiplets of and are of the order of microseconds.Received: 28 May 2003, Published online: 12 August 2003PACS: 32.10.Fn Fine and hyperfine structure - 32.70.Cs Oscillator strengths, lifetimes, transition moments - 95.30.Ky Atomic and molecular data, spectra, and spectral parameters (opacities, rotation constants, line identification, oscillator strengths, gf values, transition probabilities, etc.)  相似文献   

15.
Summary Optical-oscillator strengths, of both the length and the velocity forms, for the inner-shell excitation 1s 22s 22p 63s 2 S e→1s 22s 22p 53s 2 2 P o transition, which leads to autoionization (Auger transition), in P V, S VI, Cl VII, Ar VIII and K IX ions of the sodium isoelectronic sequence have been calculated using the approach suggested by one of us (Tiwary) in the case of the Fe XVI ion. Our present calculated results demonstrate that the Tiwary approach is capable of yielding encouraging results. A part of this work was done while the author was Research Director and Professor, CNRS Laboratory, University of Paris-Sud, Paris and Observatoire de Paris, Meudon, Paris, France.  相似文献   

16.
The weighted oscillator strengths (gf) and the lifetimes presented in this work were carried out in a multi configuration Hartree-Fock relativistic (HFR) approach. In this calculation, the electrostatic parameters were optimized by a least-squares procedure, in order to improve the adjustment to experimental energy levels. This method produces gf-values that are in better agreement with intensity observations and lifetime values that are closer to the experimental ones. In this work, we presented all the experimentally known electric dipole S IX and S X spectral lines.  相似文献   

17.
利用组态相互作用理论和参数外推法,计算了KrVI离子4s~24p—4s4p~2、4s~24p—4s~24d和4s4p~2—4p~3跃迁的能级、谱线波长和振子强度。与已有实验结果比较表明:波长的理论计算值与观测值在0.7A内很好符合,振子强度的理论计算值较大的跃迁均是实验中观测到的跃迁。  相似文献   

18.
Measurement of a radiative lifetime of 9.6 ± 1.0 nsec for the SiOA1Π-state is reported. RKR Franck-Condon factors have been computed and, with these, absolute oscillator strengths are calculated. A band system at ∼ 3022Å has been found that may be due to SiO+, but the band is not resolved at our experimental resolution, and identification remains uncertain. The upper state of the carrier of this spectrum has a radiative lifetime of 8.3 ± 0.8 nsec.  相似文献   

19.
Relative line strengths have been calculated for transitions between states of the 4p 4 5p and 4p 4 5s configurations in Kr II. The wavefunctions are obtained in intermediate coupling, including an effective correction for configuration interaction. Absolute values for the line strengths are determined using the coulomb approximation. Lifetimes for the upper 4p 4 5p levels are given together with available experimental results for comparison.  相似文献   

20.
Relative line strengths have been calculated for transitions between states of the 4p 4 5p and 4p 4 5s configurations in Kr II. The wavefunctions are obtained in intermediate coupling, including an effective correction for configuration interaction. Absolute values for the line strengths are determined using the coulomb approximation. Lifetimes for the upper 4p 4 5p levels are given together with available experimental results for comparison.  相似文献   

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