共查询到20条相似文献,搜索用时 399 毫秒
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ZhenLingLIU ZhongJianJIA XuanTIAN HongWANG 《中国化学快报》2004,15(2):197-199
Two new dihydroagarofuran sesquiterpenes with a novel substitution pattern:1α-(α-methyl)-butanoyl-2α,15-diacetoxy-4β-hydroxy-9β-(β-)furancarboxy-β-dihydroagarofuran (1) and 1α,2α-di-(α-methyl)-butanoyl-4β-hydroxy-9β-(β-)furancarboxy-15-acetoxy-β-dihydro-agaro-furan (2) were isolated from Euonymus nanoides. Their structures were elucidated by means of ^1H and ^13C NMR spectroscopic studies, including 2D NMR technique. 相似文献
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由具有2位氢的3-氨基-2-烯丙亚胺与N-氯或N-溴琥珀酰亚胺以甲苯作溶剂在常温下反应,制备了-些未见文献报道的2-氯和2-溴-3-氨基-2-烯丙亚胺,化合物结构均经元素分析,^1H NMR,^13C NMR和MS确证。 相似文献
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Nian Yun YANG Shi Hui QIAN Jin Ao DUAN Ping LI Li Juan TIAN 《中国化学快报》2005,16(9):1223-1226
Two new germacrane sesquiterpenes: 3,8,14-trihydroxy- 1 (10)E,4Z, 11 (13)-germacra- trien-12, 6-olide, 8-(2-methyl-4-hydroxyl-2E-butenoyl), 3,14-diacetoxy (eupalinolide A, 1), and 3,8,14-trihydroxy-1(10) E, 4E, 11(13)-germacratrien-12,6-olide, 8-2-methyl-4-hydroxyl-2E- butenoyl), 3,14-diacetoxy (eupalinolide B, 2) were isolated from Eupatorium lindleyanum. Their structures were elucidated by means of ^1H and ^13C NMR spectroscopic analysis, including 2D NMR technique. 相似文献
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为了发展转变点温度(Tc)高的有机磁性分子,设计合成了4,5-四硫富瓦烯-双(2,3,6,7-二苯基-氮杂环庚烷-1-氧化物)。反应混合物均经硅胶柱和设备HPLC分离和纯化,产物的结构由MS、^1^HNMR、^1^3CNMR等确定。 相似文献
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一维有机半导体(BEDT-TTF)~2HgCl~3·TCE与二维有 机超导体β-(BEDT-TTF) ~2I~3 总被引:1,自引:0,他引:1
用电化学结晶方法合成出一种新的导电分子晶体(BEDT-TTF)~2HgCl~3·TCE,[(BEDT-TTF)=双亚乙基二硫四硫富瓦烯,TCE=1,1,2-三氯乙烷]。用四圆X衍射方法确定了它的晶体结构,测得(BEDT-TTF)~2HgCl~3·TCE单晶在bc平面的ln(R/R~0)与T^-^1呈线性关系。(BEDT-TTF)~2HgCl~3·TCE晶体中,(BEDT-TTF)^+^0^.^5阳离子自由基沿b方向等距并肩排列,由S…S分子间相互作用维系,形成一维导电结构;阴离子(HgCl~3)^-也沿b方向形成一维聚合体(HgCl~3)~n^n^-,因而(BEDT-TTF)~2HgCl~3·TCE属一维半导体。为了研究导电分子晶体的导电性与结构的关系,制备了有机超导体β-(BEDT-TTF)~2I~3,讨论了β-(BEDT-TTF)~2I~3的导电性优于(BEDT-TTF)~2HgCl~3·TCE的结构原因。 相似文献
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CHUNG ILL-Min ALl Mohd CHUN Se-Chul LEE Sun-Joo SAN Ka-Yiu CHRISTIE A. M. Peebles AHMAD Ateeque 《中国化学》2007,25(11):1695-1699
Two new compounds cadin-2-en-1β-ol-1β-D-glucuronopyranoside (1), guaia-l,7-dien-3β,13-diol-13α-D- glucofuranoside (2) along with three known compounds have been isolated from the culture hairy roots of Catharanthus roseus. Their structures have been elucidated with the help of 500 MHz NMR using 1D and 2D spectral methods: viz: ^1H and ^13C NMR, ^1H-^1H COSY, ^1H-^13C HETCOR and DEPT aided by ELMS, FAB-MS, HR-FABMS and IR spectroscopy. 相似文献
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TiO2/S2O8^2—固体超强酸催化长叶烯异构化反应 总被引:5,自引:0,他引:5
采用TiO2/S2O8^2-固体超强酸催化长叶烯异构化反应,考察了催化剂制备方法及处理催化剂所用的(NH4)2S2O8溶液浓度、催化剂的焙烧温度、用量、反应温度及反应时间等对催化性能的影响,得出最佳反应条件。TiO2/S2O8^2-固体超强酸对长叶烯异构化反应具有很高的催化活性和选择性,主产物为异长叶烯,得率高达约96%。 相似文献
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本文对5-甲硫基-3-N-苯基-2,3-2(H)-1,3,4,2-噻二唑磷茂啉的磷烯正离子等三个相关分子的平衡几何构型进行了从头算解析能量梯度方法的全优化计算. 优化结果表明, 二配位磷烯正离子与相应的三配位磷母体分子的结构有本质的差异.形成二配位磷烯正离子后,磷所在的五员环形成共轭体系而使原来的单键键长变短, 原来的双键键长变长, 且使原来不共面的五员环共面. 在优化的平衡几何处进行单点CI计算的结果表明, 基态分子中磷原子上的正电荷的相对多少次序与实验测得的摩尔电导率及^3^1P NMR谱的化学位移的相对大小次序完全一致. 相似文献
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Seven new sesquiterpenoids, namely eupatochinilides Ⅰ-Ⅶ (1-7), together with eight known compounds, euponin (8), mollisorin A (9), niveusin B (10), 8β-(4'-acetoxy-tiglyloxy)-3β-hydroxy-6Hβ,7Hα-germacra-1(10)E,4E,11(13)-trien-6,12-olide (11), eupalinifide B (12), 8β-(4'-hydroxytigloyloxy)-5-desoxy-8-desacyleuparotin (13), 3-deacetyeupalinin A (14), and 15-hydroxyleptocarpin (15), were isolated from the ethanolic extract of the whole plant of Eupatorium chinense L. Their structures and stereochemistry were established by spectroscopic methods and GIAO based ^13C NMR chemical shift calculations. 相似文献
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合成了一种新的含取代苄基三苯基镌的马来二氰基二硫烯镍配合物[ClBzTPP]2[M(mnt)2]·H2O([ClBzTPP]’代表对氯苄基三苯基锑阳离子,mnt^2-代表马来二氰基二硫烯阴离子).配合物为三斜晶系,空间群Pi,晶胞参数为a=1.0585(2)nm,b=1.1089(2)nm,c=1.1570nm,α=81.98(1)°,β=84.95(1)°,γ=84.45(1)°,V=1.3691(4)nm^3,Z=1,最终一致性因子R=0.0584.该配合物由2个[ClBzT—PP]^+阳离子,1个[M(mnt)2]^2-阴离子和1个H2O组成.其结构特点是配合物中的[C1BzTPP]’阳离子和Ni(mnt)2^2-阴离子沿c轴方向堆积成柱,并通过C—H…S,C—H…π,C—H…Ni氢键和π-π堆积作用形成了二维网状结构. 相似文献
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Jun Xi LIU Xiao Ning WEI Yan Ping SHI Run Hua LU 《中国化学快报》2005,16(12):1618-1620
Two new eremophilane sesquiterpene lactones, 1β-angeloyloxy-6β, 10β-dihydroxy-8β- methoxyeremophila-7(ll)en-8α,12-olide and 1β-angeloyloxy-6β,10α-dihydroxy-8α-methoxyeremo- phila-7( 11)en-8β, 12-olide were isolated from the extract of the whole plant of Ligularia myriocephala Ling. Their structures and stereochemistry were elucidated by various spectroscopic methods including intensive 2D-NMR techniques (COSY, gHMQC, gHMBC and ^1H-^1H NOESY) and HR-ESIMS. 相似文献