共查询到20条相似文献，搜索用时 15 毫秒
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Prof. Run-Cang Sun 《ChemSusChem》2020,13(17):4385-4393
Lignin is a primary component of lignocellulosic biomass and an underutilized feedstock in the growing pulping and biofuel industries. Currently, over 50 million tons of industrial lignin are produced annually from pulping and bioethanol processes in the world. Around 95 % of industrial lignin is burned as fuel in heat and power plants due to its complicated, destructive, and condensed structures hindering direct industrial utilization, while the remaining 5 % of lignin is used for potential applications, such as additives, binders, dispersants, and surfactants, through modification. Meanwhile, different biorefinery processes also produce a considerable amount of lignin with various structural features and properties. The development of technologies for its structural characterization is currently desirable for lignin valorization, which will improve the techno-economics of applications of lignins in industries. 相似文献
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This Minireview provides a comprehensive discussion on the potential of using acid hydrotropes for sustainably fractionating lignocelluloses for biorefinery applications. Acid hydrotropes are a class of acids that have hydrotrope properties toward lignin, which helps to solubilize lignin in aqueous systems. With the capability of cleaving ether and ester bonds and even lignin-carbohydrate complex (LCC) linkages, these acid hydrotropes can therefore isolate lignin embedded in the plant biomass cell wall and subsequently solubilize the isolated lignin in aqueous systems. Performances of two acid hydrotropes, that is, an aromatic sulfonic acid [p-toluenesulfonic acid (p-TsOH)] and a dicarboxylic acid [maleic acid (MA)], in terms of delignification and dissolution of hemicelluloses, and reducing lignin condensation, were evaluated and compared. The advantages of lignin esterification by MA for producing cellulosic sugars through enzymatic hydrolysis and lignin-containing cellulose nanofibrils (LCNFs) through mechanical fibrillation from the fractionated water insoluble solids (WIS), and for obtaining less condensed lignin with light color, were demonstrated. The excellent enzymatic digestibility of maleic acid hydrotropic fractionation WISs was also demonstrated by comparing with WISs from other fractionation processes. The recyclability and reusability of acid hydrotropes were also reviewed. Finally, perspectives on future research needs to address key technical issues for commercialization were also provided. 相似文献
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Andrew W. Tricker Michael J. Stellato Dr. Thomas T. Kwok Nicholas S. Kruyer Zhongzhen Wang Prof. Sankar Nair Prof. Valerie M. Thomas Prof. Matthew J. Realff Prof. Andreas S. Bommarius Prof. Carsten Sievers 《ChemSusChem》2020,13(17):4624-4632
This work compares the structure of industrially isolated lignin samples from kraft pulping and three alternative processes: butanol organosolv, supercritical water hydrolysis, and sulfur dioxide/ethanol/water fractionation. Kraft processes are known to produce highly condensed lignin, with reduced potential for catalytic depolymerization, whereas the alternative processes have been hypothesized to impact the lignin less. The structural properties most relevant to catalytic depolymerization are characterized by elemental analysis, quantitative 13C and 2 D HQSC NMR spectroscopy, gel permeation chromatography, and thermogravimetric analysis. Quantification of the β-O-4 ether bond content shows partial depolymerization, with all samples having less than 12 bonds per 100 aromatic units. This results in theoretical monomer yields of less than 5 %, strongly suggesting the alternative fractionation processes generate highly condensed lignin structures that are no more suitable for catalytic depolymerization than kraft lignin. However, the different thermal degradation profiles suggest there are physicochemical differences that could be leveraged in other valorization strategies. 相似文献
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Jiayun Xu Dr. Chenyu Li Prof. Dr. Lin Dai Prof. Chunlin Xu Prof. Yongda Zhong Prof. Faxin Yu Prof. Dr. Chuanling Si 《ChemSusChem》2020,13(17):4284-4295
Lignin, as the most abundant aromatic biopolymer in nature, has attracted great attention due to the complexity and richness of its functional groups for value-added applications. The yield of production of lignin and the reactivity of prepared lignin are very important to guarantee the study and development of lignin-based chemicals and materials. Various fractionation techniques have been developed to obtain high yield and relatively high-purity lignin as well as carbohydrates (hemicelluloses and celluloses) and to reduce the condensed and degraded nature of conventional biorefinery lignin. Herein, novel and efficient biomass fractionation and lignin fractionation towards lignin valorization are summarized and discussed. 相似文献
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Z. Jumanova T. Sdykov E. Seitmuratov G. N. Dalimova 《Chemistry of Natural Compounds》2006,42(6):724-726
Lignins, p-coumaryl, guaiacyl, and syringyl structural units, which are characteristic of annual grassy and perennial bushy
plants, were found chromatographic analysis in the nitrobenzene oxidation products of natural and dioxanelignin rice husk
and straw.
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Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 590–591, November–December, 2006. 相似文献
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Prof. Zhuohua Sun Dr. Jinling Cheng Prof. Dingsheng Wang Prof. Tong-Qi Yuan Prof. Guoyong Song Prof. Katalin Barta 《ChemSusChem》2020,13(19):5199-5212
The lignin-first strategy has emerged as one of the most powerful approaches for generating novel platform chemicals from lignin by efficient depolymerization of native lignin. Because of the emergence of this novel depolymerization method and the definition of viable platform chemicals, future focus will soon shift towards innovative downstream processing strategies. Very recently, many interesting approaches have emerged that describe the production of valuable products across the whole value chain, including bulk and fine chemical building blocks, and several concrete examples have been developed for the production of polymers, pharmaceutically relevant compounds, or fuels. This Minireview provides an overview of these recent advances. After a short summary of catalytic systems for obtaining aromatic monomers, a comprehensive discussion on their separation and applications is given. This Minireview will fill the gap in biorefinery between deriving high yields of lignin monomers and tapping into their potential for making valuable consumer products. 相似文献
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Dr. Tengfei Li Jia Yi Mo Dr. David M. Weekes Dr. Kevan E. Dettelbach Ryan P. Jansonius Prof. Glenn M. Sammis Prof. Curtis P. Berlinguette 《ChemSusChem》2020,13(14):3622-3626
The photoelectrochemical decomposition of lignin model compounds at a BiVO4 photoanode is demonstrated with simulated sunlight and an applied bias of 2.0 V. These prototypical lignin model compounds are photoelectrochemically converted into the corresponding aryl aldehyde and phenol derivatives in a single step with conversion of up to ≈64 % over 20 h. Control experiments suggest that vanadium sites are electrocatalytically active, which precludes the need for a redox mediator in solution. This feature of the system is corroborated by a layer of V2O5 deposited on BiVO4 serving to boost the conversion by 10 %. Our methodology capitalizes on the reactive power of sunlight to drive reactions that have only been studied previously by electrochemical or catalytic methods. The use of a BiVO4 photoanode to drive lignin model decomposition therefore provides a new platform to extract valuable aromatic chemical feedstocks using solar energy, electricity and biomass as the only inputs. 相似文献
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Dr. Zhengwen Cao Yun Xu Dr. Pengbo Lyu Dr. Michael Dierks Dr. Ángel Morales-García Prof. Dr. Wolfgang Schrader Prof. Dr. Petr Nachtigall Prof. Dr. Ferdi Schüth 《ChemSusChem》2021,14(1):373-378
The present study describes an interesting and practical catalytic system that allows flexible conversion of lignin into aromatic or aliphatic hydrocarbons, depending on the hydrogen partial pressure. A combination of experiment and theory shows that the product distribution between aromatics and aliphatics can be simply tuned by controlling the availability of hydrogen on the catalyst surface. Noticeably, these pathways lead to almost complete oxygen removal from lignin biomass, yielding high-quality hydrocarbons. Thus, hydrogen–lignin co-refining by using this catalytic system provides high flexibility in hydrogen storage/consumption towards meeting different regional and temporal demands. 相似文献
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Dr. Mahlet Garedew Fang Lin Dr. Bing Song Dr. Tamara M. DeWinter Prof. James E. Jackson Prof. Christopher M. Saffron Prof. Chun Ho Lam Prof. Paul T. Anastas 《ChemSusChem》2020,13(17):4214-4237
Lignin valorization is essential for biorefineries to produce fuels and chemicals for a sustainable future. Today's biorefineries pursue profitable value propositions for cellulose and hemicellulose; however, lignin is typically used mainly for its thermal energy value. To enhance the profit potential for biorefineries, lignin valorization would be a necessary practice. Lignin valorization is greatly advantaged when biomass carbon is retained in the fuel and chemical products and when energy quality is enhanced by electrochemical upgrading. Though lignin upgrading and valorization are very desirable in principle, many barriers involved in lignin pretreatment, extraction, and depolymerization must be overcome to unlock its full potential. This Review addresses the electrochemical transformation of various lignins with the aim of gaining a better understanding of many of the barriers that currently exist in such technologies. These studies give insight into electrochemical lignin depolymerization and upgrading to value-added commodities with the end goal of achieving a global low-carbon circular economy. 相似文献
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Dr. Xu Du Haichuan Zhang Dr. Kevin P. Sullivan Prof. Parikshit Gogoi Prof. Yulin Deng 《ChemSusChem》2020,13(17):4318-4343
Lignin is the largest source of renewable aromatic compounds, making the recovery of aromatic compounds from this material a significant scientific goal. Recently, many studies have reported on lignin depolymerization and upgrading strategies. Electrochemical approaches are considered to be low cost, reagent free, and environmentally friendly, and can be carried out under mild reaction conditions. In this Review, different electrochemical lignin conversion strategies, including electrooxidation, electroreduction, hybrid electro-oxidation and reduction, and combinations of electrochemical and other processes (e. g., biological, solar) for lignin depolymerization and upgrading are discussed in detail. In addition to lignin conversion, electrochemical lignin fractionation from biomass and black liquor is also briefly discussed. Finally, the outlook and challenges for electrochemical lignin conversion are presented. 相似文献
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Prof. Dr. Mikhail Yu. Balakshin Dr. Ewellyn A. Capanema Dr. Irina Sulaeva Dr. Philipp Schlee Dr. Zeen Huang Martin Feng Dr. Maryam Borghei Prof. Dr. Orlando J. Rojas Prof. Dr. Antje Potthast Prof. Dr. Thomas Rosenau 《ChemSusChem》2021,14(4):1016-1036
Sugar-based biorefineries have faced significant economic challenges. Biorefinery lignins are often classified as low-value products (fuel or low-cost chemical feedstock) mainly due to low lignin purities in the crude material. However, recent research has shown that biorefinery lignins have a great chance of being successfully used as high-value products, which in turn should result in an economy renaissance of the whole biorefinery idea. This critical review summarizes recent developments from our groups, along with the state-of-the-art in the valorization of technical lignins, with the focus on biorefinery lignins. A beneficial synergistic effect of lignin and cellulose mixtures used in different applications (wood adhesives, carbon fiber and nanofibers, thermoplastics) has been demonstrated. This phenomenon causes crude biorefinery lignins, which contain a significant amount of residual crystalline cellulose, to perform superior to high-purity lignins in certain applications. Where previously specific applications required high-purity and/or functionalized lignins with narrow molecular weight distributions, simple green processes for upgrading crude biorefinery lignin are suggested here as an alternative. These approaches can be easily combined with lignin micro-/nanoparticles (LMNP) production. The processes should also be cost-efficient compared to traditional lignin modifications. Biorefinery processes allow much greater flexibility in optimizing the lignin characteristics desirable for specific applications than traditional pulping processes. Such lignin engineering, at the same time, requires an efficient strategy capable of handling large datasets to find correlations between process variables, lignin structures and properties and finally their performance in different applications. 相似文献
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Alessandra De Santi Dr. Maxim V. Galkin Dr. Ciaran W. Lahive Dr. Peter J. Deuss Prof. Dr. Katalin Barta 《ChemSusChem》2020,13(17):4468-4477
A mild lignin-first acidolysis process (140 °C, 40 min) was developed using the benign solvent dimethyl carbonate (DMC) and ethylene glycol (EG) as a stabilization agent/solvent to produce a high yield of aromatic monophenols directly from softwood lignocellulose (pine, spruce, cedar, and Douglas fir) with a depolymerization efficiency of 77–98 %. Under the optimized conditions (140 °C, 40 min, 400 wt % EG and 2 wt % H2SO4 to pinewood), up to 9 wt % of the aromatic monophenol was produced, reaching a degree of delignification in pinewood of 77 %. Cellulose was also preserved, as evidenced by a 85 % glucose yield after enzymatic digestion. An in-depth analysis of the depolymerization oil was conducted by using GC-MS, HPLC, 2 D-NMR, and size-exclusion chromatography, which provided structural insights into lignin-derived dimers and oligomers and the composition of the sugars and derived molecules. Mass balance evaluation was performed. 相似文献
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Dr. Zhi-Min Zhao Dr. Zhi-Hua Liu Dr. Yunqiao Pu Dr. Xianzhi Meng Prof. Jifei Xu Prof. Joshua S. Yuan Prof. Arthur J. Ragauskas 《ChemSusChem》2020,13(20):5423-5432
Biological lignin valorization represents a promising approach contributing to sustainable and economic biorefineries. The low level of valuable lignin-derived products remains a major challenge hindering the implementation of microbial lignin conversion. Lignin's properties play a significant role in determining the efficiency of lignin bioconversion. To date, despite significant progress in the development of biomass pretreatment, lignin fractionation, and fermentation over the last few decades, little efforts have gone into identifying the ideal lignin substrates for an efficient microbial metabolism. In this Minireview, emerging and state-of-the-art strategies for biomass pretreatment and lignin fractionation are summarized to elaborate their roles in modifying lignin structure for bioconversion. Fermentation strategies aimed at enhancing lignin depolymerization for microbial utilization are systematically reviewed as well. With an improved understanding of the ideal lignin structure elucidated by comprehensive metabolic pathways and/or big data analysis, modifying lignin chemistry could be more directional and effective. Ultimately, together with the progress of fermentation process optimization, biological lignin valorization will become more competitive in biorefineries. 相似文献
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Dr. Yannick Mathieu Dr. Juan D. Vidal Dr. Lourdes Arribas Martínez Dr. Nerea Abad Fernández Prof. Sara Iborra Prof. Avelino Corma 《ChemSusChem》2020,13(17):4743-4758
During oxidative depolymerization of lignin in aqueous alkaline medium using molecular oxygen as oxidant, the highly functionalized primary phenolic monomers are not stable products, owing to various not fully identified secondary reaction mechanisms. However, better understanding of the mechanisms responsible for the instability of the main part of the products of interest derived from lignin is of much interest. Evaluation of their individual reactivities under oxidative conditions should significantly help to find a better way to valorize the lignin polymer and to maximize the yields of target value-added products. Consequently, the main objective of this study is to assess the individual stabilities of some selected lignin-based phenolic compounds, such as vanillin, vanillic acid, and acetovanillone, together with some other pure chemical compounds such as phenol and anisole to give an insight into the mechanisms responsible for the simultaneous formation and repolymerization of those products and the influence of the oxidation conditions. Various complementary strategies of stabilization are proposed, discussed, and applied for the oxidative depolymerization reactions of a technical lignin extracted from pinewood with a high content of β-O-4 interconnecting bonds to try to obtain enhanced yields of value-added products. 相似文献
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Dr. Chen Qu Keigo Ito Dr. Isamu Katsuyama Dr. Tomohiko Mitani Dr. Keiichiro Kashimura Prof. Takashi Watanabe 《ChemSusChem》2020,13(17):4510-4518
Model erythro, phenolic, and nonphenolic lignin β-O-4 dimer compounds are treated with copper oxide and H2O2 at the electronic field maximum position of a single-mode 2.45 GHz microwave system equipped with a cavity resonator. The products obtained through microwave heating and oil-bath heating with the same reaction vessel and temperature profile are quantitatively compared. Dimer degradation is found to proceed through consecutive elementary reactions. The phenolic dimer is dehydroxylated and this is followed by the spontaneous cleavage of Cα−Cβ and C−O−C bonds to produce guaiacol, vanillin, and vanillic acid. The reaction of the nonphenolic dimer produces veratric acid, veratraldehyde, and guaiacol. Microwave irradiation accelerates cleavage of the side chain and the oxidation of vanillin to vanillic acid. However, no acceleration of veratraldehyde oxidation to veratric acid or aromatic ring cleavage to produce dicarboxylic acids is observed. The selective acceleration of elementary reactions during the degradation of model lignin compounds indicates that microwaves interact with reaction intermediates that are sensitive to electromagnetic waves. 相似文献