共查询到20条相似文献,搜索用时 15 毫秒
1.
Xuyun Wang Xiaohong Wang Jian Cui Jun Zhang 《Journal of Macromolecular Science: Physics》2013,52(3):475-485
This study presents the comparison of the experimental results and theoretical predictions of the piloted ignition of black PMMA. The model for theoretical calculations included heat, momentum, mass transfer equations and reaction kinetics both in the gas phase and the solid phase, to comprehensively describe the piloted ignition. The experimental samples were thick black PMMA pieces, with the ignition time and the critical surface temperatures at ignition measured using a cone heater under different external radiation heat fluxes. The predictions from the calculations showed good agreement with the experiment at high heat flux, but the deviation was distinct at low heat fluxes, especially for the critical surface temperatures. The fail of the prediction at low heat fluxes was regarded, by analysis, as the result of the neglecting of the decomposition energy term of PMMA in the energy balance equation. 相似文献
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A predictive simulation of the autoignition process of non-premixed methane in a turbulent jet configuration was performed. Closure for the chemical source-term was obtained using Conditional Source-term Estimation with Laminar Flamelet Decomposition (CSE-LFD). The ambient oxidizer conditions – the high pressure and moderate temperatures characteristic of compression ignition engines – were chosen with the intent to validate the combustion model used under engine-relevant conditions. Validation was obtained by comparison of the predicted ignition delay to experimental results obtained from a shock-tube facility at several initial temperatures. Overall, the combination of full chemistry that has been carefully tuned to predict autoignition of premixed methane–air mixtures under similar temperature/pressure conditions with the CSE-LFD model is able to successfully predict the autoignition delay time of methane–air jets well within the scatter in the experimental data. 相似文献
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Y. Nakamura T. Kashiwagi S.L. Olson K. Nishizawa O. Fujita K. Ito 《Proceedings of the Combustion Institute》2005,30(2):2319-2325
Numerical computations and a series of experiments were conducted in microgravity to study the ignition characteristics of a thin polymethylmethacrylate (PMMA) sheet (thicknesses of 0.2 and 0.4 mm) using a CO2 laser as an external radiant source. Two separate ignition events were observed, including ignition over the irradiated surface (frontside ignition), and ignition, after some delay, over the backside surface (backside ignition). The backside ignition was achieved in two different modes. In the first mode, after the laser was turned off, the flame shrank and stabilized closer to the fuel surface. This allowed the flame to travel from the frontside to the backside through the small, open hole generated by the laser’s vaporization of PMMA. In the second mode, backside ignition was achieved during the laser irradiation. The numerical calculation simulating this second process predicts fresh oxygen supply flows from the backside gas phase to the frontside gas phase through the open hole, which mixes with accumulated hot MMA fuel vapor which is ignited as a second flame in the frontside gas phase above the hole. Then, the flame initiated from the second ignition travels through the hole to ignite the accumulated flammable mixture in the backside gas phase near the hole, attaining backside ignition. The first backside ignition mode was observed in 21% oxygen and the second backside ignition mode in 35%. The duration of the laser irradiation appears to have important effects on the onset of backside ignition. For example, in 21% oxygen, the backside ignition was attained after a 3 s laser duration but was not observed after a 6 s laser duration (within the available test time of 10 s). Longer laser duration might prevent two-sided ignition in low oxygen concentrations. 相似文献
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Olivier Colin Martin Ritter Corine Lacour Karine Truffin Sophie Mouriaux Sergey Stepanyan Bertrand Lecordier Pierre Vervisch 《Proceedings of the Combustion Institute》2019,37(4):4875-4883
The cycle to cycle combustion variability which is observed in spark-ignition engines is often caused by fluctuations of the early flame development. LES can be exploited for a better understanding and mastering of their origins. For that purpose appropriate models taking into account energy deposition, mixture ignition and transition to propagation are necessary requirements. This paper presents first DNS and LES of spark ignition with a real automotive coil and simplified pin-pin electrodes. The electrical circuit characteristics are provided by ISSIM while the energy deposition is modelled by Lagrangian particles. The ignition model is first evaluated in terms of initial spark radius on a pin-pin ignition experiment in pure air performed at CORIA and EM2C laboratories, showing that it pilots the radius of the torus formed by the initial shock wave. DNS of a quiescent lean propane/air mixture are then performed with this ignition system and a two-step mechanism. The impact of the modelled transferred energy during glow phase as well as the initial arc radius on the minimum ignition energy (MIE) are examined and compared to experimental values. Replacing the two-step chemistry by an analytically reduced mechanism leads to similar MIE but shows a different ignition kernel shape. Finally, LES of turbulent ignition using a Lagrangian arc model show a realistic prediction of the arc shape and its important role on the energy transfer location and thus on the flame kernel shape. 相似文献
5.
T. Jaravel J. Labahn B. Sforzo J. Seitzman M. Ihme 《Proceedings of the Combustion Institute》2019,37(4):5065-5072
Ensuring robust ignition is critical for the operability of aeronautical gas-turbine combustors. For ignition to be successful, an important aspect is the ability of the hot gas generated by the spark discharge to initiate combustion reactions, leading to the formation of a self-sustained ignition kernel. This study focuses on this phenomena by performing simulations of kernel ignition in a crossflow configuration that was characterized experimentally. First, inert simulations are performed to identify numerical parameters correctly reproducing the kernel ejection from the ignition cavity, which is here modeled as a pulsed jet. In particular, the kernel diameter and the transit time of the kernel to the reacting mixture are matched with measurements. Considering stochastic perturbations of the ejection velocity of the ignition kernel, the variability of the kernel transit time is also reproduced by the simulations. Subsequently, simulations of a series of ignition sequences are performed with varying equivalence ratio of the fuel-air mixture in the crossflow. The numerical results are shown to reproduce the ignition failure that occurs for the leanest equivalence ratio (). For higher equivalence ratios, the simulations are shown to capture the sensitivity of the ignition to the equivalence ratio, and the kernel successfully transitions into a propagating flame. Significant stochastic dispersion of the ignition strength is observed, which relates to the variability of the transit time of the kernel to the reactive mixture. An analysis of the structure of the ignition kernel also highlights the transition towards a self-propagating flame for successful ignition conditions. 相似文献
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A theoretical model for wood pyrolysis including char surface oxidation is presented. The main objective is to expose the physical mechanisms governing glowing ignition. By “glowing ignition,” we mean the onset of surface combustion. The char surface oxidation, which can lead to glowing ignition, is considered at the surface boundary condition. Two regimes of char surface oxidation, namely, kinetic and diffusion-controlled, are distinguished. Depending on the char surface oxidation resistances, the char surface oxidation as either kinetic- or diffusion-controlled can be identified. A criterion for glowing ignition is developed based on a surface energy balance. A numerical result shows that according to the present glowing ignition criteria, an inflection point of the surface temperature history can indicate glowing ignition. Generally, a good agreement between theoretical and experimental results at glowing ignition is obtained. 相似文献
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Experimental analysis of a double-spark ignition system 总被引:1,自引:0,他引:1
The spark that ignites the combustible mixtures is a discharge produced between the electrodes of a spark plug, connected
to the secondary of a coil at the high voltage. Optimum combustion requires a steady spark, in a volume as large as is possible,
and with maximum energy. We propose a solution to increase the plasma volume and present electrical discharge parameters as
a function of inter-electrode distances, pressures in the test-reactor and the width of the electrical pulses of the power
supply. 相似文献
10.
R. Sadanandan D. Markus U. Maas H. Seyfried M. Aldén 《Proceedings of the Combustion Institute》2007,31(1):719-726
Experimental and numerical investigations of the ignition of hydrogen/air mixtures by jets of hot exhaust gases are reported. An experimental realisation of such an ignition process, where a jet of hot exhaust gas impinges through a narrow nozzle into a quiescent hydrogen/air mixture, possibly initiating ignition and combustion, is studied. High-speed laser-induced fluorescence (LIF) image sequences of the hydroxyl radical (OH) and laser Schlieren methods are used to gain information about the spatial and temporal evolution of the ignition process. Recording temporally resolved pressure traces yields information about ambient conditions for the process. Numerical experiments are performed that allow linking these observables to certain characteristic states of the gas mixture. The outcome of numerical modelling and experiments indicates the important influence of the hot jet temperature and speed of mixing between the hot and cold gases on the ignition process. The results show the quenching of the flame inside the nozzle and the subsequent ignition of the mixture by the hot exhaust jet. These detailed examinations of the ignition process improve the knowledge concerning flame transmission out of electrical equipment of the type of protection flameproof enclosure. 相似文献
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Osamu Moriue Masato Mikami Naoya Kojima Christian Eigenbrod 《Proceedings of the Combustion Institute》2005,30(2):1973-1980
Spontaneous ignition of single n-heptane droplets in a constant volume filled with air is numerically simulated with the spherical symmetry. The volume is closed against mass, species, and energy transfer. The numerical model is fully transient. It continues calculation even after the droplet has completely vaporized, and therefore can predict pre-vaporized ignition. Initial pressure and initial air temperature are fixed at 3 MPa and 773 K, respectively. The droplet is initially at room temperature, and its diameter is between 1 and 100 μm. When the overall equivalence ratio is fixed to be sufficiently large, there exists no ignition limit in terms of initial droplet diameter d0, and the ignition delay takes a minimum value at certain d0. In such a case, transition from the heterogeneous ignition to the homogeneous ignition with decreasing d0 is observed. When d0 is fixed to be so small that the ignition would not occur in an infinite volume of air, the ignition delay takes a minimum value at certain , which is less than unity. Two-stage ignition behavior is investigated with this model. Ignition delay of a cool flame has the dependence on d0 that is similar to that of ignition delay of a hot flame when is unity. When is almost zero, the ignition limit for cool flame in terms of d0 is not identified unlike that for hot flame. 相似文献
13.
Robert D. Stachler Joseph K. Lefkowitz Joshua S. Heyne Scott D. Stouffer Timothy M. Ombrello Joseph D. Miller 《Proceedings of the Combustion Institute》2019,37(4):5039-5046
Understanding of ignition processes is central to design for reliable and safe aerospace combustor systems. Ignition is influenced by many factors including combustor geometry, flow conditions, fuel composition, turbulence intensity, ignition source, and energy deposition method. A toroidal jet-stirred reactor (TJSR) utilizes bulk fluid motion, presence of recirculation zones, a bulk residence time, and turbulence intensities which emulate characteristics relevant to cavity stabilized and swirl stabilized combustors. In this work, a TJSR was used to quantify ignitability and time-to-ignition of premixed ethylene and air. The effects of inlet temperature, residence time, and reactivity were studied on forced ignition processes. Experimental conditions ranged from residence times of 15–35?ms, mixture temperatures of 340–450?K, and equivalence ratios of 0.5–1 using capacitive spark-discharge ignition. The minimum equivalence ratio for ignition (MER), or the equivalence ratio at 50% probability, shows an inverse relationship with mixture temperature and residence time. Prior theory of real engine combustor performance for lean light off, proposed by Ballal and Lefebvre, was compared to the MER and displayed similar trends to the model. Spatially integrated OH* chemiluminescence was used to measure time to ignition within the reactor. Reduction in ignitibility was experienced as the time-to-ignition approached the residence time stressing the importance of device flow time scales in relation to kernel growth dynamics and ignition probability. 相似文献
14.
Three-dimensional DNS of two-phase flows with the point-source approximation and with complex chemistry for n-heptane has been used to extract physical information on the structure of igniting kernels following localised heat deposition in turbulent monodisperse sprays. Consistent with experiment, small sparks fail to ignite and sprays ignite later than premixed gaseous mixtures. Reaction rates are intense in spherical zones near droplets and much lower in the interdroplet spacing, resulting in a highly wrinkled flame surface. The propagation of these reaction zones was observed. The flame shows a locally non-premixed character, with reactions proceeding at a wide range of mixture fractions, which increases as evaporation progresses. The distribution of various chemical species is presented. The results constitute a database for model validation and physical analysis. 相似文献
15.
Jianghui Luo Qianjin Lin Wenxiang Xia Yizhuo He Mei Mei Lixin Lu Yang Liu Chun Zou 《Proceedings of the Combustion Institute》2021,38(4):5475-5484
Pressurized oxy-fuel combustion has been attracting increasing attentions due to its improved efficiency and low cost. The present study reports ignition delay times (IDTs) of pyridine under O2/CO2 atmospheres within a temperature range from 1202 to 1498 K at pressures from 2.2 to 10 bar for equivalence ratios of 0.5, 1.0, and 2.0. The experimental results were compared with the IDTs of pyridine under O2/Ar atmospheres from MacNamara et al.. The comparison results indicate that the IDTs of pyridine under O2/CO2 atmospheres are evident longer than those under O2/Ar atmospheres even at low pressure. A modified kinetic model (HUST pyridine Model) was proposed based on our previous mechanism. HUST pyridine Model predicted well the IDTs under both O2/CO2 and O2/Ar atmospheres obtained in shock tubes and the species profiles under both O2/CO2 and O2/N2 atmospheres obtained in plug flow reactors. HUST pyridine Model, Alzueta Model, and Pyridine LTO Model were evaluated. The results show that the performance of HUST pyridine Model is much better than Alzueta Model, and Pyridine LTO Model. The main reason is that the net reaction rate of C5H5N + O = C5H4N + OH in HUST pyridine Model is much faster than that in Aluzeta Model. The effect of CO2 on the ignition of pyridine at elevated pressures has been analyzed in detail. The oxidation pathways of pyridine are also analyzed at different pressures. 相似文献
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A general concept of fast ignition by a hydrodynamic pulse is developed. The main statements of the concept are formulated
having in mind the need to ignite the pre-compressed thermonuclear fuel of the inertial confinement fusion (ICF) target. Initially,
combustion must be initiated inside the hydrodynamic flow during its action on the target. The conditions for propagating
a self-sustaining thermonuclear-detonation wave from an igniter on the thermonuclear fuel of the ICF-target must be provided.
For this, the deuterium–tritium (DT) igniter placed in the forward part of the hydrodynamic flow should not only be heated
up to thermonuclear temperature, but also compressed to a density close to the density of the ICF-target fuel. It is shown
that the detonation of the multilayer conical target (containing DT-ice and a heavy pusher) enables fast ignition of the ICF
target fuel of 200–500 g/cm3 density at an implosion velocity of 300–500 km/s. 相似文献
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F. Collin-Bastiani O. Vermorel C. Lacour B. Lecordier B. Cuenot 《Proceedings of the Combustion Institute》2019,37(4):5057-5064
In order to guarantee good re-ignition capacities in case of engine failure during flight, it is of prime interest for engine manufacturers to understand the physics of ignition from the spark discharge to the full burner lightning. During the ignition process, a spark plug delivers a very short and powerful electrical discharge to the mixture. A plasma is first created before a flame kernel propagates. The present work focuses on this still misunderstood first instants of ignition, i.e., from the sparking to the flame kernel formation. 3D Direct Numerical Simulations of propane-air ignition sequences induced by an electric discharge are performed on a simple anode-cathode set-up. An Analytically Reduced Chemistry (ARC) including 34 transported species and 586 irreversible reactions is used to describe the coupled combustion and plasma kinetics. The effect of plasma chemistry on the temperature field is found to be non-negligible up to a few microseconds after the spark due to endothermic dissociation and ionization reactions. However, its impact on the subsequent flame kernel development appears to be weak in the studied configuration. This tends to indicate that plasma chemistry does not play a key role in ignition and may be omitted in numerical simulations. 相似文献
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气凝胶独特的物理特性使得它能在空间探测中被广泛应用。气凝胶超低的密度、极低的热导率以及多孔网络结构使得它能成功地应用在超高速宇宙尘埃粒子捕获、高效热防护、低温推进剂存储、太空服制造等空间探测任务中。对气凝胶在空间探测中的应用情况进行了综述。 相似文献