Effect of time dependent morphological parameters of nanoclusters on perikinetic heat conduction and induced micro-convection mechanisms of oxide based nanofluids

The article represents an experimentally supported quantitative analysis to observe the effect of time, temperature, nanoclusters’ morphology, and instantaneous volume fractions on perikinetic heat conduction and Brownian motion-based induced convection mechanisms of oxide (Al₂O₃ and TiO₂, size 25–30 nm) based nanofluids. The appropriate models of thermal conductivity have been introduced to study the effect of various parameters such as; varying volume fractions, suspensions’ stabilities, nanoclusters’ growth, temperature, and the liquid layering. The developed model could predict the thermal conductivity enhancements of nanofluids within the accuracy of ± 0.5% to ± 4.5.0% in the temperature range from 20°C to 50°C.

Abbreviations: DI: De-ionized water; DLS: Dynamic light scattering; XRD: X-rays diffraction; TEM: Transmission electronic microscope; SDBS:Sodium dodecyl benzene sulphonate.

Figure Effect of temperature on the Brownian Reynold number for Al₂O₃-H₂O and TiO₂-H₂O nanofluids.     

Progress in the Investigations of Grain Boundary Relaxation

Internal friction (or damping) is a measure of energy dissipation during mechanical vibration. The internal friction peak induced by grain boundary (GB) relaxation was discovered by Kê in polycrystals in 1947. The GB internal friction and related anelastic effects have been successfully interpreted by Zener's anelastic theory and viscous sliding model. Since then, the GB internal friction peak has been widely used to study the dynamic process of GBs, impurity segregation at GBs and relevant processes in materials science.

Previously, the GB internal friction was mostly studied with polycrystalline materials, in which mixed contributions of different types of GBs are involved. Since the microstructures and behaviors for different types of GBs are different, the detailed mechanism of the GB peak in polycryatals has not been clearly clarified.

From the beginning of the 21th century, the internal friction in bicrystals (each has a single boundary) with different misorientations and rotation axes has been systematically investigated. The results indicate that the internal friction can be used to distinguish the individual behavior of different types of GBs and applied to the practice of “GB engineering.”

Moreover, the coupling effect and compensation effect involved in GB relaxation has been recently observed and explained. The coupling effect means a correlated atomic motion occurred in GB relaxation. The compensation effect indicates that the apparent activation enthalpy is linearly related to the activation entropy in GB relaxation. These findings improve the understanding of the mechanism of GB internal friction.

This article attempts to give a comprehensive review to the investigations of GB internal friction in polycrystals, bamboo-crystals, and bicrystals. The microscopic mechanisms and the further applications of GB internal friction are discussed and prospected.     

Orbital stability of the smooth solitary wave with nonzero asymptotic value for the mCH equation

This paper is concerned with orbital stability of the smooth solitary wave with nonzero asymptotic value for the mCH equation

Under the parametric conditions a > 0 and , an interesting phenomenon is discovered, that is, for the stability there exist three bifurcation wave speeds

such that the following conclusions hold.

1. When wave speed belongs to the interval (c₁, c₂) for , the smooth solitary wave is orbitally stable.

2. When wave speed belongs to the interval (c₂, c₃) for , the smooth solitary wave is orbitally unstable.

3. When wave speed belongs to the interval (c₁, c₃) for , the smooth solitary wave is orbitally unstable.

     

Astrophysical ~(22)Mg(p,γ)~(23)Al reaction rates from asymptotic normalization coefficient of ~(23)Ne→~(22)Ne+n

The radionuclide ~(22)Na generates the emission of a characteristic 1.275 MeV γ-ray. This is a potential astronomical observable, whose occurrence is suspected in classical novae. The ~(22)Mg(p, γ)~(23)Al reaction is relevant to the nucleosynthesis of ~(22)Na in Ne-rich novae. In this study, employing the adiabatic distorted wave approximation and continuum discretized coupled channel methods, the squared neutron asymptotic normalization coefficients(ANCs)231 for the virtual decay of Ne → ~(22)Ne + n were extracted, and determined as(0.483 ± 0.060) fm~(-1) and(9.7 ± 2.3) fm~(-1) for the ground state and the first excited state from the experimental angular distributions of ~(22)Ne(d, p)~(23)Ne populating the ground state and the first excited state of ~(23)Ne, respectively. Then, the squared proton ANC of ~(23)Al_(g.s.) was obtained as C_(d5/2)~(2)(~(23)Al)(2.65 ± 0.33) × 10~3 fm~(-1) according to the charge symmetry of the strong interaction. The astrophysical S-factors and reaction rates for the direct capture contribution in ~(22)Mg(p, γ)~(23)Al were also presented. Furthermore, the proton width of the first excited state of ~(23)Al was derived to be(57 ± 14) eV from the neutron ANC of its mirror state in ~(23)Ne and used to compute the contribution from the first resonance of ~(23)Al. This result demonstrates that the direct capture dominates the ~(22)Mg(p, γ)~(23)Al reaction at most temperatures of astrophysical relevance for 0.33 T_9 0.64.     

Free-field realizations of the W,N-algebra

In this paper, we will construct free-field realizations of the W_,N algebra associated to an -valued differential operator

where is a Frobenius algebra with the uint I_n.     

λ-Deformation: A Canonical Framework for Statistical Manifolds of Constant Curvature

This paper systematically presents the λ-deformation as the canonical framework of deformation to the dually flat (Hessian) geometry, which has been well established in information geometry. We show that, based on deforming the Legendre duality, all objects in the Hessian case have their correspondence in the λ-deformed case: λ-convexity, λ-conjugation, λ-biorthogonality, λ-logarithmic divergence, λ-exponential and λ-mixture families, etc. In particular, λ-deformation unifies Tsallis and Rényi deformations by relating them to two manifestations of an identical λ-exponential family, under subtractive or divisive probability normalization, respectively. Unlike the different Hessian geometries of the exponential and mixture families, the λ-exponential family, in turn, coincides with the λ-mixture family after a change of random variables. The resulting statistical manifolds, while still carrying a dualistic structure, replace the Hessian metric and a pair of dually flat conjugate affine connections with a conformal Hessian metric and a pair of projectively flat connections carrying constant (nonzero) curvature. Thus, λ-deformation is a canonical framework in generalizing the well-known dually flat Hessian structure of information geometry.     

Single crystal growth of SiC and electronic devices

Single crystal growth of silicon carbide (Sic) and application to electronic devices are reviewed. In the crystal growth, bulk and homoepitaxial growth are picked up, and crystal quality and electrical properties are described. For electronic devices, various device processes are argued. Power devices based on Sic are stressed in this review.

Bulk single crystals of SiC can be grown by a sublimation method, and large-area 6H-SiC and 4H-SiC single crystals are obtained. The occurrence of SiC polytypes is affected by the growth condition, and can be controlled successfully by optimizing these conditions. 6H-SiC is grown on 6H-SiC (0001) Si-faces, and 4H-SiC on 6H-SiC (0001) C-faces. The crystallinity of bulk crystals is investigated by reflection high-energy electron diffraction (RHEED) and X-ray analysis, and characterization is carried out in detail by optical and electrical measurement.

Successful homoepitaxial vapor phase growth of SiC can be realized using off-axis (0001) substrates prepared by a sublimation method called “step-controlled epitaxy”. Since the crystallinity of epilayers is improved during the step-controlled epitaxy, this growth technique is a key for getting high-quality crystal surfaces. Impurity doping is controlled during homoepitaxial growth by employing impurity gases, such as N₂, trimethylaluminum (TMA), and B₂H₆. A wide-range of carrier concentrations of 5 × 10¹³～3 × 10¹⁸ cm^?3 for n-type and 5 × 10¹⁶～3 × 10²⁰ cm^?3 for p-type are realized. The impurity-incorporation mechanism in the step-controlled epitaxy is discussed based on the C/Si ratio dependence of impurity doping.

Electrical properties of SiC grown by step-controlled epitaxy are determined precisely. A high electron mobility of 720 cm²/Vs is obtained in an undoped 4H-SiC epilayer with an electron concentration of 2.5 × 10^l6 cm^?3 at 300 K. This electron mobility is about two times higher than that of 6H-Sic (～380 cm²/Vs). High breakdown fields of 1～5 × 10⁶ V/cm are obtained for both 6H- and 4H-SiC, one order of magnitude higher than those for Si. A high saturation electron drift velocity of 1.6 × 10⁷ cm/s is obtained in 4H-Sic, which may make possible high performance of high-frequency 4H-SiC power devices. Impurity levels and deep levels are investigated by Hall effect, admittance spectroscopy, and DLTS measurement. Metal/4H-SiC Schottky barrier heights are characterized and a strong dependence on metal work function without strong “pinning” is elucidated.

Device processes are described for ion implantation. Interface properties of SiO₂/SiC are characterized in detail using metal-oxide-semicond.     

Relativistic pseudo-Jahn-Teller effect in the square-planar molecules with a central atom

We consider the relativistic multi-mode pseudo-Jahn-Teller effect (²E_u + ²A_2u) × (b_ig + b_2g + e_u) for square-planar molecular complexes with a heavy central atom and the odd number of electrons.

All 32 elements of the double spin group D_4h are determined in the form of space-matrix operators. The 6 × 6 vibronic matrix is derived in the quadratic (with respect to the normal coordinates) approximation for the contributions of electrostatic (non-relativistic) Hamiltonian and in linear approximation for contribution of spin-orbital coupling. Vibronic matrix is represented on the basis of double-value irreducible representations of the symmetry group D_4h     

Hyphenation of flow analysis with spectrometric techniques

Quite often one of the biggest problems in analytical methods, including spectrometry, resides in the pre-processing of the sample, which usually must be solved manually. To solve these problems, it can be very useful to request the help of the flow techniques, which will allow to automate the methods, decrease the time of the analysis, decrease the consumption of the samples and reagents, increase the reproducibility, the sample throughput and to work continuously for a long period of time.

Between the advantages of the low separation flow techniques are their very high versatility facing the application of various treatment techniques, such as photo-oxidation, pre-concentration, clean-up, derivatization, gas diffusion, etc. Since the entire process is carried out in a completely closed system, results are obtained in a faster and more reproducible way.

In this contribution, coupling different low-resolution separation flow techniques with several very selective spectrometric instruments, like ICP–AES, ICP–MS, AFS, etc. Hyphenation with different kind of chromatographic and the capillary electrophoretic techniques is also described.     

Complex Networks and the b-Value Relationship Using the Degree Probability Distribution: The Case of Three Mega-Earthquakes in Chile in the Last Decade

Studies from complex networks have increased in recent years, and different applications have been utilized in geophysics. Seismicity represents a complex and dynamic system that has open questions related to earthquake occurrence. In this work, we carry out an analysis to understand the physical interpretation of two metrics of complex systems: the slope of the probability distribution of connectivity (γ) and the betweenness centrality (BC). To conduct this study, we use seismic datasets recorded from three large earthquakes that occurred in Chile: the Mw8.2 Iquique earthquake (2014), the Mw8.4 Illapel earthquake (2015) and the Mw8.8 Cauquenes earthquake (2010). We find a linear relationship between the b-value and the γ value, with an interesting finding about the ratio between the b-value and γ that gives a value of ∼0.4. We also explore a possible physical meaning of the BC. As a first result, we find that the behaviour of this metric is not the same for the three large earthquakes, and it seems that this metric is not related to the b-value and coupling of the zone. We present the first results about the physical meaning of metrics from complex networks in seismicity. These first results are promising, and we hope to be able to carry out further analyses to understand the physics that these complex network parameters represent in a seismic system.     

The Amplified Resonance Light Scattering Signal Detection of DNA Hybridization Using Polycyclic Aromatic Hydrocarbons as a Probe

A simple and rapid method has been developed to detect the nucleic acid–based polycyclic aromatic hydrocarbons as a probe by the amplified resonance light scattering signals of DNA hybridization. Five polycyclic aromatic hydrocarbons including naphthalene, pyrene, fluoranthene, anthracene, and phenanthrene, particularly naphthalene, with double-stranded DNA and single-stranded DNA in aqueous solution were investigated. Through amplified resonance light scattering signals, the complementary and mismatched sequences of DNA can be both detected and identified easily. Mechanism investigations by multiple spectra have shown that groove binding occurs between PAHs and double-stranded DNA.

Supplemental materials are available for this article. Go to the publisher's online edition of Spectroscopy Letters to view the supplemental file.