New FIR laser lines from CHD2OH optically pumped by a cw CO2 laser

This work reports 83 new optically pumped far infrared laser lines, using deuterated methyl alcohol, CHD₂OH, as active medium. For each line we list the measured wavelength, its polarization relative to the pump line, the optimum gas pressure and the CO₂ laser pump power at the maximum absorption.     

New FIR laser lines from optically pumped methanol analogues

Several new laser lines using optically pumped deuterated methanol molecules have been discovered. These not only increase the spectral coverage of pumped methanol isotopes but may assist in the assignment of a molecular structure.     

New cw FIR laser lines from optically pumped ammonia analogues

Two new cw submillimetre lines optically pumped by the 9 μR(30) CO₂ laser have been observed for¹⁴NH₃ and assigned to thea(6,0)→s(5,0) transition and to its cascade transitions(5,0)→a(4,0) in thev ₂=1 state. In addition, six new emission lines have been observed for NH₂D, and one tentatively assigned to the (11,1)→(10,1) transition of ND₃. Methylamine has also been investigated and twenty-eight new emission lines have been discovered.     

New submillimetre laser lines from CH3OD and CD3OD

Thirteen new submillimetre emission lines have been observed when pumping CH₃OD using isotopic CO₂ lasers, and fourteen when pumping CD₃OD. Three isotopic CO₂ lasers were used¹²C¹⁶O₂,¹²C¹⁸O₂, and¹³C¹⁶O₂. The new lines were observed in a Fabry-Perot resonator. The wavelength ranges observed were from 55 to 320 m for CH₃OD and from 66 to 531 m for CD₃OD. The polarisation of the submillimetre laser lines relative to the CO₂ pump line has also been determined.     

New cw optically pumped FIR emissions in HCOOH,D2CO and CD3Br

New FIR emissions lines have been observed for HCOOH, D₂CO and CD₃Br. Assignments have been made of the HCOOH lines and for most of those of CD₃Br. For D₂CO, most of the new emissions showed a corresponding cascade transition.     

New far-infrared laser lines from CH3Cl and CH3Br optically pumped with a continuously tunable high pressure CO2 laser

In this paper we report on the detection of new far-infrared laser lines from CH₃Cl and CH₃Br optically pumped with a continuously tunable high pressure CO₂ laser. We found 80 new lines for CH₃Cl and 9 new lines for CH₃Br in the frequency region between 16 cm^–1 and 41 cm^–1, all due to stimulated Raman scattering. For the Raman gain regions bandwidths up to about 700 MHz were found. We also observed high intensity short far-infrared laser pulses of durations in the nanosecond regime.Permanent address: Physics Department, State Pedagogical University, SU-119435 Moscow, USSR     

Dispersion in a cw optically pumped FIR laser

Direct frequency measurements of a¹³CO₂/¹⁵NH₃ OPFIRL output show that laser pulling effects give shifts of a few MHz, which agree well with a density matrix calculation.     

Further investigations on ir pumping of CH3OD and CD3OD by a cw CO2 laser

Respectively, 41 and 36 new cw far-infrared lasing lines have been observed using a waveguide resonator in CH₃OD and CD₃OD pumped by a low-pressure CO₂ laser emitting in the 9.4, 10.4 m regular bands and in the 10.8 m hot band. The wavelength range was 46.6 m–1.67 mm in CH₃OD and 53.6 m–1 mm in CD₃OD.     

Relaxation oscillations in cw optically pumped CD3OD and15NH3 lasers

We report the results of heterodyne measurements of the mode quality and tuning range of a cw CO₂ laser designed for optically pumping a far-infrared (FIR) molecular laser, and describe the implications of multi-mode operation. In particular we report the observation of relaxation oscillations in the output of a FIR waveguide laser.     

Observation and assignment of submillimetre laser lines from CH3OH pumped by isotopic CO2 lasers

New laser lines have been generated using methanol when isotopically labelled CO₂ is used in the pump laser. 19 lines have been found when¹³C¹⁶O₂ is used and 29 when¹²C¹⁸O₂ is used. The wavelengths of the emission lines have been measured with a relative accuracy of 5×10^–3 using the submillimetre resonator as a scanning Fabry-Perot interferometer, and the polarizations of the lines have also been measured. Some of the laser lines have been assigned to pure rotational transitions in the excited state associated with the CO stretching mode, other lines are believed to originate from pumping in combination bands.     

New optically pumped FIR laser lines in CD3OH

In this work we report laser action in 69 new FIR laser lines in CD₃OH optically pumped by a regular cw CO₂ laser. We have performed measurements of laser wavelength, optimum pressure of the gas, relative polarization and intensity on all lines, including some previously known.     

New large offset far-infrared laser lines from CD3OH

The CD₃OH molecule has been investigated for new far-infrared laser lines by optically pumping with a cw waveguide CO₂ laser. The increased tunability (300 MHz) with respect to a conventional CO₂ laser permits to pump many new CD₃OH lines. As a consequence 108 new laser lines have been discovered, ranging from 42.9 to 1155 m in wavelength. On some lines the effect of an electric Stark field has been investigated demonstrating a laser frequency tuning. The total number of known FIR laser lines from CD₃OH is increased to about 340 making this molecule the most prolific together with CH₃OH.     

Frequency measurement of optically pumped FIR laser emissions from the CH3OD methanol isotope

A three-laser heterodyne system has been used to measure the frequencies of seven previously observed optically pumped FIR laser emissions generated by the CH₃OD methanol isotope. The frequencies, measured for the first time, are reported with fractional uncertainties up to ±2×10^-7 for laser emissions ranging in wavelength from 80.1 to 183.3 m. A previously measured FIR laser emission from CH₃OD, observed at 57.2 m, was also re-measured in this work. PACS 07.57.Hm; 42.55Lt; 42.62.Eh     

IR and FIR spectroscopy of 13CD3OH around the 10P(22) and 10P(24) CO2 laser lines: New FIR laser emissions,frequency measurements and assignments

By using high resolution infrared Fourier transform data on ¹³CD₃OH and the 10P(22) and 10P(24) lines of a waveguide CO₂ laser to optically pump this methanol isotope, eight new FIR laser lines were observed. The frequencies of five laser lines were directly measured by heterodyne detection with already known laser lines. Particularly interesting are the lines pumped by the 10P(24) line, since a triade of emissions could be completely assigned.     

Self pulsing properties of optically pumped FIR NH3 lasers

We report on measurements of periodic and chaotic self-pulsing beyond the second threshold of far-infrared NH₃ lasers. While the instabilities of the 81 m¹⁴NH₃ laser follow a simple pattern, for the 374 m¹⁵NH₃ laser different pulsing properties are found in different parameter ranges.Pulses under conditions of high pumping power are measured in detail, in view of possible applications of these coherent, high-repetition rate far-infrared pulsed lasers.     

DCOOD optically pumped by a 13CO2 laser: new terahertz laser lines

In this work we report on new optically pumped THz laser lines from deuterated formic acid (DCOOD). An isotopic ¹³CO₂ laser was used for the first time as a pump source for this molecule, and a Fabry–Perot cavity was used as a THz laser resonator. Optoacoustic absorption spectra were used as a guide to search for new THz laser lines. We could observe six new laser lines in the range from 303.8 μm (0.987 THz) to 725.1 μm (0.413 THz). The lines were characterized according to wavelength, relative polarization, relative intensity, and optimum working pressure. The transferred lamb-dip technique was used to measure the frequency absorption transition for both of these laser lines. Furthermore, we also present a catalogue of all THz laser lines generated from DCOOD.     

Large offset far infrared laser lines generation from the C-O stretching Q-branch of 13CD3OD

2 laser of wide tunability to pump ¹³CD₃OD we could observe 10 new far infrared laser lines ranging from 109 μm to 472 μm. The lines were generated by pumping infrared absorbing transitions of large offset appertaining to the C-O stretching Q-branch. All lines were characterised in wavelength, polarisation, optimum pressure of operation and precise offset measurements. Received: 17 September 1996/Revised version: 18 November 1996     

Mode selection in an unstable-resonator TEA CO2 laser by injection from a waveguide laser

The effect of injecting radiation from a cw waveguide CO₂ laser into a TEA laser through a hole in one mirror of its unstable resonator has been studied experimentally. High-power single longitudinal mode operation of the TEA laser is achieved over a wide but finite range of injection frequencies, the frequency of the single-mode pulse being that of the TEA laser cavity mode lying closest to the injected frequency. Although a simple theoretical model shows good qualitative agreement with observations it underestimates the range of injection frequencies which result in single-mode pulses unless a fast chirping of the cavity mode frequency is postulated.     

New cw FIR laser lines from optically pumped silyl fluoride (SiH3F)

FIR laser action has been observed for the first time in a molecule containing silicon: silyl fluoride, SiH₃F. Eleven new cw optically pumped lines between 187 and 1014m were detected from both open resonator and waveguide structures. Although the chlorine analogue, SiH₃Cl, showed strong absorption at every CO₂ laser frequency no FIR laser emission was detected at the pump powers available.     

New FIR laser lines and frequency measurements for optically pumped CD3OH

Twenty new cw FIR laser lines in CD₃OH, optically pumped by a CO₂ laser, are reported. The frequencies of 39 of the stronger laser lines were measured relative to stabilized CO₂ lasers with a fractional uncertainty, as determined by the reproducibility of the FIR frequency itself, of 2 parts in 10⁷.Contribution of the U.S. Government, not subject to copyright.