Effective nonlinear optical properties of shape distributed composite media

The effective linear and nonlinear optical properties of metal/dielectric composite media, in which ellipsoidal metal inclusions are distributed in shape, are investigated. The shape distribution function P(L _x, L _y) is assumed to be 2Δ^-2θ(L _x - 1/3 + Δ/3)θ(L _y - 1/3 + Δ/3)θ(2/3 + Δ/3 - L _x - L _y), where θ( ^{. . .} ) is the Heaviside function, Δ is the shape variance and L_i are the depolarization factors of the ellipsoidal inclusions along i-symmetric axes (i = x, y). Within the spectral representation, we adopt Maxwell-Garnett type approximation to study the effect of shape variance Δ on the effective nonlinear optical properties. Numerical results show that both the effective linear optical absorption α ∼ ωIm() and the modulus of the effective third-order optical nonlinearity enhancement |χ⁽³⁾ _e|/χ⁽³⁾ ₁ exhibit the nonmonotonic behavior with Δ. Moreover, with increasing Δ, the optical absorption and the nonlinearity enhancement bands become broad, accompanied with the decrease of their peaks. The adjustment of Δ from 0 to 1 allows us to examine the crossover behavior from no separation to large separation between optical absorption and nonlinearity enhancement peaks. As Δ → 0, i.e., the ellipsoidal shape deviates slightly from the spherical one, the dependence of |χ⁽³⁾ _e|/χ⁽³⁾ ₁ on Δ becomes strong first and then weak with increasing the imaginary part of inclusions' dielectric constant. In the dilute limit, the exact formula for the effective optical nonlinearity is derived, and the present approximation characterizes the exact results better than old mean field one does. Received 10 December 2002 Published online 4 June 2003 RID="a" ID="a"e-mail: lgaophys@pub.sz.jsinfo.net     

Third-order nonlinear optical response of Au:SiO 2 thin films: Influence of gold nanoparticle concentration and morphologic parameters

We report a study on the third-order nonlinear optical properties of nanocomposite thin films composed of gold particles embedded in a silica host matrix. Samples of various metal volume fractions, ranging from 8 to 35%, are synthesized by the sputtering technique. Some of them are annealed. Nonlinear optical measurements, which are performed by using the z-scan technique, reveal both a very large nonlinear absorption and a weak nonlinear refraction close to the surface plasmon resonance frequency of the particles. We especially study the effect of the metal concentration and the influence of thermal treatment on the real and imaginary components of the third-order nonlinear susceptibility. Our results reveal that, as the metal concentration reaches a few percent, the mutual electromagnetic interactions between particles greatly enlarge the nonlinear optical response of the material and can not be neglected in the theoretical analysis. Moreover, the thermal treatment leads, for a given concentration, to a significant increase of the nonlinear response, which is ascribed to a modification of the material morphology. We finally point out that the material nonlinear properties are very sensitive to the incident wavelength through the local field enhancement phenomenon. Received 12 December 2001     

Temperature and spatial diffusion of atoms cooled in a 3D lin ⊥lin bright optical lattice

We present a detailed experimental study of a three-dimensional lin⊥lin bright optical lattice. Measurements of the atomic temperature and spatial diffusion coefficients are reported for different angles between the lattice beams, i.e. for different lattice constants. The experimental findings are interpreted with the help of numerical simulations. In particular we show, both experimentally and theoretically, that the temperature is independent of the lattice constant. Received 5 July 2001 and Received in final form 13 August 2001     

Onset of instabilities in self-pulsing semiconductor lasers with delayed feedback

We consider the deterministic dynamics of a semiconductor laser with saturable absorber that is subject to delayed optical feedback. Alone, both the saturable absorber and delayed feedback cause the CW output to become unstable to periodic output via Hopf bifurcations. We examine the combined effects of these two destabilizing mechanisms to determine new conditions for the Hopf bifurcations. We also describe the transient as the unstable CW output evolves to the oscillatory state. A main result is that the presence of a saturable absorber can increase the sensitivity of the laser to delayed feedback. Received 1st August 2001 and Received in final form 28 November 2001     

Wavelength dependence of nonlinear absorption in a bis-phthalocyanine studied using the Z-scan technique

The wavelength dependence of the nonlinear absorption of a bis-phthalocyanine, Nd(Pc)₂, dissolved in dimethyl formamide was studied in the rising part of the Q-band using the open aperture Z-scan technique, to determine the wavelength region over which the nonlinear absorption changes from reverse saturable absorption to saturable absorption. It was found that the sample could be used as a reverse saturable absorber, and hence as an optical limiter, up to a wavelength of about 604 nm. The imaginary part of the third order susceptibility was also calculated for these wavelengths. Resonant enhancement of the imaginary part of the third order susceptibility was clearly observed. Received: 26 April 2002 / Revised version: 30 June 2002 / Published online: 20 December 2002 RID="*" ID="*"Corresponding author. Fax: +91-484/576-714, E-mail: kpu@cusat.ac.in RID="**" ID="**"Present address: Optical Sciences Center, University of Arizona, Tucson, USA     

Sum rules for arbitrary-order harmonic generation susceptibilities

Dispersion theory for harmonic generation susceptibilities is considered with the aid of complex analysis. New sum rules are obtained for the powers of arbitrary-order harmonic generation susceptibilities. The theory is based on the holomorphic properties and asymptotic behaviour of nonlinear susceptibilities. The present sum rules are reportedly important in nonlinear optical spectra analysis. Received 19 September 2002 Published online 31 December 2002     

Multi-component structure of nonlinear excitations in systems with length-scale competition

We investigate the properties of nonlinear excitations in different types of soliton carrying systems with long-range dispersive interactions. We show that length-scale competition in such systems, universally results in a multi-component structure of nonlinear excitations which may lead to a new type of multistability: coexistence of different nonlinear excitations at the same value of the spectral parameter (i.e., velocity in the case of anharmonic lattices or frequency in nonlinear Schr?dinger models). Received 31 August 2000 and Received in final form 14 December 2000     

Solitary waves in the Madelung's fluid: Connection between the nonlinear Schrödinger equation and the Korteweg-de Vries equation

An investigation to deepen the connection between the family of nonlinear Schr?dinger equations and the one of Korteweg-de Vries equations is carried out within the context of the Madelung's fluid picture. In particular, under suitable hypothesis for the current velocity, it is proven that the cubic nonlinear Schr?dinger equation, whose solution is a complex wave function, can be put in correspondence with the standard Korteweg-de Vries equation, is such a way that the soliton solutions of the latter are the squared modulus of the envelope soliton solution of the former. Under suitable physical hypothesis for the current velocity, this correspondence allows us to find envelope soliton solutions of the cubic nonlinear Schr?dinger equation, starting from the soliton solutions of the associated Korteweg-de Vries equation. In particular, in the case of constant current velocities, the solitary waves have the amplitude independent of the envelope velocity (which coincides with the constant current velocity). They are bright or dark envelope solitons and have a phase linearly depending both on space and on time coordinates. In the case of an arbitrarily large stationary-profile perturbation of the current velocity, envelope solitons are grey or dark and they relate the velocity u₀ with the amplitude; in fact, they exist for a limited range of velocities and have a phase nonlinearly depending on the combined variable x-u_{0 s} (s being a time-like variable). This novel method in solving the nonlinear Schr?dinger equation starting from the Korteweg-de Vries equation give new insights and represents an alternative key of reading of the dark/grey envelope solitons based on the fluid language. Moreover, a comparison between the solutions found in the present paper and the ones already known in literature is also presented. Received 20 February 2002 and Received in final form 22 April 2002 Published online 6 June 2002     

Pump-probe spectroscopy of atoms cooled in a 3D lin lin optical lattice

We describe the pump-probe spectroscopy of atoms cooled in a 3D lin⊥lin optical lattice. Our pump-probe configuration consists of two laser fields detuned with respect to the lattice fields. This scheme allows to clearly identify in the probe transmission spectrum the Brillouin and Raman resonances, by studying their positions as functions of the angle between the pump and probe beams. We describe these resonances in detail, and compare the experimental results to the theoretical predictions. Our conclusions are supported by transport-spectroscopy measurements, which allow to distinguish between contributions to the light scattering from propagating and non-propagating atoms. Received 8 April 2002 / Received in final form 9 September 2002 Published online 12 November 2002     

Nonlinear frequency conversion in 2D χ (2) photonic crystals and novel nonlinear double-circle construction

The analytic solution to the wave equation for small-signal sum-frequency process is derived in 2D χ ⁽²⁾ photonic crystals with use of the Green function method. It is predicted that the sum-frequency electrical field at quasi-phase matching (QPM) resonance is proportional to the angle-dependent effective crystal length. This implies that multiple wavelength QPM frequency conversion with controllable intensity output can be realized in a single 2D χ ⁽²⁾ photonic crystal. It is revealed that efficient frequency conversion requires both the QPM and the proper structure matching. A novel double-circle construction, different from the conventional Ewald construction, is presented to reflect important QPM processes. It is also shown that the QPM resonance tuning of second-harmonic generation can operate over the whole transparent wavelength range of crystals. Received 19 April 2001     

Electromagnetically induced transparency in asymmetric double quantum wells

We show how to compute nonlinear optical absorption spectra of an Asymmetric Double Quantum Well (ADQW) in the region of intersubband electronic transitions. The method uses the microscopic calculation of the dephasing due to electron-electron and electron-phonon scattering rates and the macroscopic real density matrix approach to compute the electromagnetic fields and susceptibilities. The polarization dephasing and the corrections to the Rabi frequencies due to the electron-electron interaction are also taken into account. For a proper choice of the QW widths and of the driving fields we obtain electromagnetically induced transparency. This transparency has a very narrow linewidth when a single driving field is applied resonant to the transition between the second and the third subband. In the case of two resonant driving fields or of a driving field resonant between the first and third subband we obtain a large transparency enhancement over the entire absorption spectrum. Results are given for GaAs/GaAlAs QWs and experiments are proposed. Received 21 June 2001 and Received in final form 21 January 2002     

Statistical confidentiality tests for a quantum transmission using continuous variables

We describe a cryptographic protocol consisting of two entangled beams of squeezed light which makes use of statistical tests to deduce the secret key bit. The sender (Alice) encrypts a secret key by modulating the phase of the beam sent in public by the receiver (Bob) who keeps the other beam private. The knowledge of the degree of non classical correlation between the beam quadrature components measured in private and in public allows only Bob to decrypt the secret key. With a view towards absolute security, we formally prove that any external intervention from an eavesdropper (Eve) during the communication process introduces necessarily some modification susceptible to be detected. Statistical confidentiality tests are proposed to detect the presence of Eve. Received 12 July 2001 and Received in final form 11 November 2001     

Collective quantum tunneling of strongly correlated electrons in commensurate mesoscopic rings

We present a new effect that is possible for strongly correlated electrons in commensurate mesoscopic rings: the collective tunneling of electrons between classically equivalent configurations, corresponding to ordered states possessing charge and spin density waves (CDW, SDW) and charge separation (CS). Within an extended Hubbard model at half filling studied by exact numerical diagonalization, we demonstrate that the ground state phase diagram comprises, besides conventional critical lines separating states characterized by different orderings (e.g. CDW, SDW, CS), critical lines separating phases with the same ordering (e.g. CDW-CDW) but with different symmetries. While the former also exist in infinite systems, the latter are specific for mesoscopic systems and directly related to a collective tunnel effect. We emphasize that, in order to construct correctly a phase diagram for mesoscopic rings, the examination of CDW, SDW and CS correlation functions alone is not sufficient, and one should also consider the symmetry of the wave function that cannot be broken. We present examples demonstrating that the jumps in relevant physical properties at the conventional and new critical lines are of comparable magnitude. These transitions could be studied experimentally e.g. by optical absorption in mesoscopic systems. Possible candidates are cyclic molecules and ring-like nanostructures of quantum dots. Received 27 November 2000     

Nonlinear optical characterization of cluster dynamic in water in oil microemulsion by a pump probe laser beam technique

We present a new pump probe laser beams configuration for the nonlinear optical characterization of microemulsions. We detect the variation of the on-axis optical intensity of the probe beam as generated by the concentration profile induced in an optically thin film of microemulsion by the pump beam. A mathematical model has been introduced to describe the phenomenon. The technique allows the determination of both Kerr-like optical nonlinearity and time constants and, therefore, it gives information both on cluster dimension and their shape. We discuss its application to WAD (water/AOT/decane, where AOT denotes sodium-bis-di-ethyl-sulfosuccinate) with the application of a strong electric field of optical source. Comparison between theoretical predictions and experimental results confirms the presence of giant optical nonlinearity in the absence of turbidity divergence. Chainlike shape of clusters, of the kind already reported with the application of strong electric field, could justify this result. Received 26 October 2002 RID="a" ID="a"e-mail: vicari@na.infn.it     

Constrained order in frustrated 2D optical patterns

In 2D optical patterns obtained in a Liquid Crystal Light Valve with optical feedback, we show a new kind of geometrical frustration which comes from the imposed form of the boundaries. The circular section of the incoming laser beam presents a symmetry which belongs to the O(2) group, whereas the optical feedback selects patterns with a symmetry restrained to a dihedral subgroup of O(2). By imposing boundaries which respect the symmetry of the dihedral group, we lift the frustration and obtain perfectly ordered patterns. Received 19 January 2001 and Received in final form 2 June 2001     

The large probability of the 0+ ground states

We investigate the dominance of 0⁺ states as the lowest states in shell model calculations with random two-body interactions in a single j-shell. We have found an explanation of the large probability of the 0⁺ ground state. Received: 1 May 2001 / Accepted: 4 December 2001     

Aging and non-linear glassy dynamics in a mean field model

The mean field approach of glassy dynamics successfully describes systems which are out-of-equilibrium in their low temperature phase. In some cases an aging behaviour is found, with no stationary regime ever reached. In the presence of dissipative forces however, the dynamics is indeed stationary, but still out-of-equilibrium, as inferred by a significant violation of the fluctuation dissipation theorem. The mean field dynamics of a particle in a random but short-range correlated environment, offers the opportunity of observing both the aging and driven stationary regimes. Using a geometrical approach previously introduced by the author, we study here the relation between these two situations, in the pure relaxational limit, i.e. the zero temperature case. In the stationary regime, the velocity (v)-force (F) characteristics is a power law v∼F ⁴, while the characteristic times scale like powers of v, in agreement with an early proposal by Horner. The cross-over between the aging, linear-response regime and the non-linear stationary regime is smooth, and we propose a parametrization of the correlation functions valid in both cases, by means of an “effective time”. We conclude that aging and non-linear response are dual manifestations of a single out-of-equilibrium state, which might be a generic situation. Received 7 May 2000 and Received in final form 22 August 2000     

Surface and flexoelectric polarization in a nematic liquid crystal 5CB

The temperature dependence of the surface polarization has been measured for both the planar and homeotropic orientation of a nematic liquid crystal at a solid substrate. A conventional liquid crystal 5CB, pure and doped with an azo-dye, was used in cells with controlled asymmetry for light absorption. The measurements have been made by a pyroelectric technique using short pulses of a YAG laser to create a temperature increment. The latter, in turn, was measured independently by a novel time-resolved “optical thermometer” technique monitoring temperature-dependent birefringence by a He- Ne laser beam. In accordance with the symmetry of the order parameter, the surface polarization has different sign for the two orientations, its magnitude ranges from -4 to +2pC/m. The same technique has been used for the measurement of the flexoelectric polarization in hybrid cells. The sum of the flexoelectric coefficients is e ₁ + e ₃ = - 13pC/m at 25°C. Received 28 February 2000 and Received in final form 5 September 2000     

Scattering of a sound wave by a vibrating surface

We report an experimental study of the scattering of a sound wave of frequency f by a surface vibrating at frequency F. Both the Doppler shift at the vibrating surface and acoustic nonlinearities in the bulk of the fluid, generate the frequencies f±nF (n integer) in the spectrum of the scattered wave. We show that these two contributions can be separated because they scale differently with respect to the vibration frequency and to the distance between the vibrating scatterer and the detector. We determine the parameter ranges in which one or the other mechanism dominates and present quantitative studies of these two regimes. Received 2 December 2002 / Received in final form 27 March 2003 Published online 4 June 2003 RID="a" ID="a"e-mail: fauve@physique.ens.fr RID="b" ID="b"UMR 8550     

Polyelectrolyte chains in poor solvent. A variational description of necklace formation

We study the properties of polyelectrolyte chains under different solvent conditions, using a variational technique. The free energy and the conformational properties of a polyelectrolyte chain are studied by minimizing the free energy F_N, depending on N(N - 1)/2 trial probabilities that characterize the conformation of the chain. The Gaussian approximation is considered for a ring of length 2⁴ < N < 2⁸ and for an open chain of length 50 < N < 200 in poor- and theta-solvent conditions, including a Coulomb repulsion between the monomers. In theta-solvent conditions the blob size is measured and found in agreement with scaling theory, including charge depletion effects, expected for the case of an open chain. In poor-solvent conditions, a globule instability, driven by electrostatic repulsion, is observed. We notice also inhomogeneous behavior of the monomer-monomer correlation function, reminiscence of necklace formation in poor-solvent polyelectrolyte solutions. A global phase diagram in terms of solvent quality and inverse Bjerrum length is presented. Received 7 June 2001 and Received in final form 17 October 2001