Theory for the nonlinear optical response at noble-metal surfaces with nonequilibrium electrons

We present a theory for the electron-temperature dependence T _el of optical second harmonic generation (SHG). Such an analysis is required to study the dynamics of metallic systems with many hot electrons not at equilibrium with the lattice. Using a tight-binding theory for the nonlinear susceptibility χ ⁽²⁾(ω,T _e1) and the Fresnel coefficients we present results for the SHG intensity I ⁽²⁾(ω,T _e1) and its dependence on T _el for Cu. Note, χ ⁽²⁾(ω,T _e1) rather than the Fresnel coefficients determines essentially this temperature dependence. Most interestingly we find frequency ranges where I ⁽²⁾(ω,T _e1) increases for small light intensities, while it decreases for large light intensities. Our theory yields also that SHG probes effects due to hot electrons more sensitively than linear optics. The results of our calculations are compared with recent experiments on Cu and Au.     

Sputtering of metals at ion-electron irradiation

It has been found that, in contrast to the commonly accepted opinion, simultaneous irradiation by 15-keV Ar⁺ ions and 2.5-keV electrons at temperatures above 0.5T _m (T _m is the melting temperature) induces much larger sputtering of metallic copper, nickel, and steel than irradiation only by Ar⁺ ions. The effect increases with the temperature. At T = 0.7T _m, the sputtering coefficients in the case of ion-electron irradiation are more than twice as large as the sputtering coefficients in the case of irradiation by Ar⁺ ions. The experiments on the sublimation of copper show that the sublimation rate in the case of the heating of a sample by an electron beam is higher than that in the case of heating in an electric vacuum oven. The revealed effects are explained by the electron-induced excitation of adatoms (atoms stuck over the surface, which appear owing to ion bombardment). Excited adatoms have a smaller binding energy with the surface and are sputtered more easily.     

High spin states in153Er

High spin states in¹⁵³Er have been populated in the¹⁴⁴Sm(¹²C, 3n)¹³³Er reaction. Excitation functions, lifetimes, angular distributions,γ-γ coincidences and internal conversion coefficients were measured. Three isomeric states at 2.75 MeV (T _1/2=400 ns), 2.95 MeV (T _1/2～10 ns) and 5.2 MeV (T _1/2=200 ns) have been observed. A fourth isomer seems to be weakly excited above 6.8 MeV. The level scheme proposed is discussed in term of the nuclear shell model.     

Low-temperature pyroelectricity

The current state of the set of problems associated with the study and application of the pyroelectric effect at low (T<30 K) temperatures is outlined. The reasons for the qualitatively different temperature dependences of the total pyroelectric coefficient γ^σ(T) in linear pyroelectrics and ferroelectrics are discussed. An analysis is given of the reasons why the theoretical temperature dependences obtained for the primary pyroelectric coefficient γ^ε(T) adequately describe the experimental γ^σ(T) dependences for all materials studied. In this connection, the correctness of determining the secondary pyroelectric coefficient γ^S(T) from the macroscopically measured coefficients of thermal expansion is considered. The potential of thermodynamically nonequilibrium polar media and low-temperature pyroelectric materials is substantiated. The review consists of the following sections: (1) an introduction; (2) the theory of low-temperature pyroelectricity; (3) experimental procedures; (4) discussion of the experimental data: (A) perfect single crystals, (B) the problem of the secondary pyroelectric coefficient, (C) imperfect single crystals; (5) pyroelectric materials for low-temperature applications; and (6) a conclusion.     

Density of states and specific heat of elastic vibrations in layer structures

On the basis of a determination of normal modes in materials consisting of periodic arrangements of macroscopic layers (of period d), the low frequency density of states and the corresponding low temperature specific heat were calculated numerically. The average temperature dependence of the latter changes in the vicinity of a characteristic temperature T₀ (proportional to 1/d), from a low temperature (α₀T³)- to a higher temperature (αT³+βT²)- law. Depending on the material parameters, β may be positive (especially if Stonely waves are present) or negative. The coefficients α and α₀ can differ by a factor larger than 2. Characteristics of thick and thin layers and the implications of the results on the interpretation of experimental data are discussed.     

Investigation of the 6Li(d, α)4He reaction between 1.5 and 11.5 MeV

The differential cross section σ₀(θ) and the analysing powers T₁₁(θ), T₂₀(θ), T₂₁(θ) and T₂₂(θ) of the reaction ⁶Li(d, α)⁴He have been measured for twelve energies between 1.5 and 11.5 MeV at c.m. angles between 3.5° and 90°. The results were fitted with Legendre polynomials. The energy dependence of the resulting coefficients indicates resonance-like behaviour at several energies corresponding to excitation between 22 and 32 MeV in ⁸Be. The reaction ⁶Li(d, α)⁴He shows excellent features as an analyser for deuteron vector and tensor polarization over the whole energy range investigated.     

Conversion coefficients and E0 transitions in102, 104, 106Pd

In in-beam (p, p′) experiments, electron and γ-spectra were measured in the electron energy range of 500-1840 keV for¹⁰²Pd and¹⁰⁴Pd, and 600–1580 keV for¹⁰⁶Pd. The conversion coefficients of all transitions in this range were obtained with accuracies of about 20%, in some favourable cases 10%. Special attention was given to 0⁺′-0⁺ transitions from the two-phonon triplets to the ground states with the following results for the branching ratios 0⁺′-0⁺ (ground state) to 0⁺′-2⁺ (one-phonon state):¹⁰²Pd:T _k (E0)/T _γ (E2)<(2.1±3.6)·10^{?7 104}Pd:T _k (E0)/T _γ (E2)=(6.0±1.4)·10^{?5 106}Pd:T _k (E0)/T _γ (E2)=(6.0±2.0)·10^?4     

Pressure dependence of phase transitions in K2SnCl6 from NQR frequency measurements

The influence of hydrostatic pressure 0 ? p ? 4 kbar on the ³⁵Cl NQR in K₂SnCl₆ was studied in the temperature range 238 K ? T ? 300 K. The phase transition temperatures T_C1 and T_C2 were determined from changes in the NQR line pattern.The phase boundaries in the p-T diagram are straight lines in the region studied. The pressure coefficients are given by dT_C1/dP = 1.35 (10) K kbar^?1 and dT_C2/dP=?1.25 (20) K kbar^?1.     

Temperature dependence of spin diffusion coefficient and T2 for dilute 3He in solid 4He

Spin diffusion coefficients D and NMR line widths 1/T₂ have been measured as a function of temperature for ³He in solid ⁴He at fractional concentrations down to 10^-4. Minima are seen in D and T₂ and the existence of impuritons is confirmed.     

Testing effective nucleon-nucleon forces to describe diagonal spin-transfer coefficients for the scattering of polarized protons with the excitation of the 1+ levels in 12C

The diagonal coefficients of spin-transfer D _ii in the small-angle inelastic scattering of polarized protons with the excitation of the two lowest 1⁺ levels in ¹²C are analyzed. The isoscalar (T = 0, E* = 12.71MeV) and isovector (T = 1, E* = 15.11 MeV) transitions are considered. The coefficients D _ii are calculated within DWBA using different effective nucleon-nucleon (NN) interactions between an incident proton and the nucleons of the nucleus. We consider the Franey-Love interaction and the Geramb effective interactions based on the Paris NN potential, and also the effective NN potential based on the chiral perturbation theory, etc. The impact of the wave function antisymmetrization is studied from the coefficients D _ii in a system that includes a projectile and nucleons of the nucleus, along with the impact of other effects.     

Pyroelectric properties of lithium triborate in the temperature range from 4.2 to 300 K

Temperature dependences of pyroelectric coefficients γ^T and γ^S corresponding to the mechanically free (T) and clamped (S) states of a lithium triborate (LBO) sample are studied and found to be nonmonotonic. It is proposed that the anomalies are associated with an increase in anharmonism of the lithium sublattice of LBO long before its transition to the superionic state. The spontaneous polarization at T=200 K is estimated to be 0.25 C/m². In the structural motif, the mesotetrahedra responsible for the emergence of spontaneous polarization of LBO are singled out.     

Sum rules involving coefficients of fractional parentage

Some sum rules involving the coefficients of fractional parentage are obtained. It is shown how these may be used to obtain expressions for the number of independent states in the (jⁿ)^J,T configuration.     

The properties of the (H2O)6 water cluster that depend on its density during temperature transitions

Water clusters (H₂O)₆ are simulated by the Monte Carlo method with the Metropolis function at various temperatures (T ₁ = 273 K, T ₂ = 298 K, and T′₁= 373 K) and densities (ρ₁ = 0.9998 g/cm³, ρ₂ = 0.9167 g/cm³, and ρ₃ = 0.00059 g/cm³) of the system. It is established that the number of retained most probable configuration types at ρ₁ = 0.9998 g/cm³ during temperature transitions from T ₁ = 273 K to T ₂ = 298 K and from T′₁ = 373 K to T ₂ = 298 K is smaller than at ρ₃ = 0.00059 g/cm³. This result was acquired on the background of the following invariable parameters of the system with the same temperature transitions for each of three values of density: (i) the average number of retained most probable configuration types, (ii) the average fraction of weight coefficients of the most probable configuration types, and (iii) the average potential energy. The configuration type that was retained among the most probable configuration types of the system for all values of density (ρ₁ = 0.9998 g/cm², ρ₂ = 0.9167 g/cm³, and ρ₃ = 0.00059 g/cm³) of the system for temperature transitions from T ₁ = 273 K to T ₂ = 298 K and from T′₁ = 373 K to T ₂ = 298 K was also revealed.     

Shock-tube study of HCN self-broadening and broadening by argon for the P(10) line of the ν1 band at 3 μm

A tunable infrared diode laser was used to measure the fully resolved absorption line shape of the P(10) line in the ν₁ band (10°0–00°0) of HCN for shock-heated mixtures of HCN-Ar at temperatures of 1000, 1500 and 2000 K. The temperature dependence of the collision-broadening coefficients 2γ (cm^-1 atm^-1, FWHM) were inferred for both self-broadening and broadening by argon. For the assumed form 2γ = 2γ₀(T₀/T)ⁿ the exponent n was determined to be 0.63 ± 0.06 with 2γ₀ = 0.11 cm^-1atm^-1 and T₀ = 300 K for argon-broadening in the range 300 < T < 2000 K, and 1.2 ± 0.6 with 2γ₀ = 0.68 cm^-1atm^-1 and T₀ = 1000 K for self-broadening in the range 1000 < T < 2000 K.     

Internal conversion coefficients ofM4 transitions in125m, 127m, 129mTe decay

The internal conversion coefficients have been measured using a high resolution low energy Ge(Li) detector for the followingM4 transitions:¹²⁵Te: 109.27keV transitionα _T =357±11; RG method,¹²⁷Te: 88.26 keV transitionα _T =484±23; XPG method,¹²⁹Te: 105.50keV transitionα _T =213±10; XPG method. It is observed that these values are lower by 2.5–3.6% as compared with Hager and Seltzer's calculations. A comparison between experimental and theoreticalα _T andα _T values for elevenM4 transitions shows that the experimental values are systematically lower.     

Magnetostriction and other magnetic properties of Co-Ni based amorphous alloys

The magnetostriction coefficients λ_s of (Co_1−xNi_x)₇₅Si₁₅B₁₀ amorphous alloys have been determined in the range 0 ⩽ x ⩽ 0.41. The dependence of the magnetostriction on temperature T has been related to that of the magnetic polarization J_s in a phenomenological way as λ_s(T) = α[J_s(T)]³ + β[J_s(T)]². The compositional dependence of the coefficients α and β has been obtained.From the studies of the magnetostriction in the region close to the Curie temperature it has been possible to evaluate the magnetostriction critical exponent K.     

Surface self-diffusion studied by microscopic measurements of crystallite profile evolutions

Dendritic gold crystallites on graphite are heated in ultra high vacuum up to less than 0.5 of the melting point (T_m). Electron microscopy shows that the gold crystallites change their shapes by surface self-diffusion. The dendritic contours round off while the crystallite remains very flat (20 to 40 Å). The increase with time of the radii of dendrite tips is measured statistically. Such an evolution can be described by analogy to the blunting of either metal tips (Nichols and Mullins) or monoatomic cleavage tips (Höche and Bethge). Using this result, a new technique to measure surface self-diffusion coefficients (D) is proposed. Test measurements have shown that this is an interesting, very sensitive method to measure D (down to 10^?13 cm^?2 s^?1) which enables measurements to be made in an unusual low temperature range (0.25 T_m < T < 0.5T_m). In special cases the dendrites are split by the surface self-diffusion which is qualitatively in agreement wih the theory.     

Formation of intersystem crossing transitions in Pd(II) and Pt(II) porphyrins: Nonplanar distortions of the macrocycle and charge transfer states

We found new bands in the absorption spectra of Pt(II) and Pd(II) complexes of octaethylporphyrin and tetraphenylporphyrin that differ in the nature, number, and position of their side substituents. The bands are observed at 295 K in the range 570–690 nm and are attributed to spin-forbidden transitions from the ground S ₀ state to the excited T ₁ and T ₂ triplet states (the internal heavy atom effect). We determined the frequency distribution, number, and nature of these transitions, as well as their extinction coefficients (? = 6.0–210.0 M^?1 cm^?1), using computer decomposition of complex contours into Gaussian components and additional data obtained from the phosphorescence and phosphorescence excitation spectra of these complexes (295–77 K). In comparison to Pd complexes of porphyrins with planar macrocycles, nonplanar distortions of the tetrapyrrole macrocycle in the ground S ₀ state of the sterically hindered PdOETPP molecule cause a bathochromic shift of the bands of the electronic spin-forbidden S ₀ → T ₁ and S ₀ → T ₂ transitions, as well as an increase in their extinction coefficients. For the PdOEP-Ph(o-NO₂) molecule, which contains the electron acceptor nitro group, an absorption band attributed to an electronic transition from the ground state S ₀ to a charge transfer state (λ_max = 905 nm, ? = 10.0 M^?1 cm^?1) is observed at 295 K.     

Classification of <Emphasis Type="Italic">T</Emphasis>-odd asymmetries for prescission and evaporated light particles in ternary and quaternary nuclear fission induced by cold polarized neutrons

A unified mechanism of the emergence of T-odd ROT- and TRI-asymmetries is proposed for describing experimental T-odd asymmetry coefficients D(θ) in the angular distributions of prescission alphaparticles that are emitted in true ternary and quaternary nuclear fission reactions induced by cold polarized neutrons. The mechanism is related to the different ways in which the Coriolis interaction of the total spin of a polarized compound fissile nucleus with the orbital moment of alpha-particles affects even (for ROT-asymmetries) and odd (for TRI-asymmetries) components of the amplitude of an undisturbed angular distribution of emitted alpha-particles. Coefficients D_ROT(θ) and D_TRI(θ) derived with this mechanism for T-odd ROT- and TRI-asymmetries successfully describe the dependences of corresponding experimental coefficients for ²³⁵U and ²³⁹Pu nuclei over the range of angles θ, and for the ²³³U nucleus in the angular range of 60° < θ < 110°. It is explained why only ROT-type T-odd asymmetries emerge for evaporated neutrons and γ-quanta emitted by fission fragments in similar reactions if we allows for the Coriolis interaction of the total spin of the compound fissile nucleus with the orbital moments of the fission fragments and the wriggling vibrations of the above nucleus near its scission point.