超短脉冲染料放大器中的参数研究

对超短脉冲染料放大器(DLA)中放大的自发辐射(ASE)随泵浦强度变化的关系进行了实验研究,为了求得具有高储能、低自发辐射背景噪声的染料激光放大器的泵浦强度,我们用速率方程对实验结果进行了解析分析,获得了染料激光放大器的泵浦强度与染料参数(浓度、增益长度等)的近似关系式,以及相应条件下染料激光放大器储能和小信号增益的表达式,并与实验进行了比较.二者符合较好,从而为染料激光放大器的设计提供了参考.     

自动扫描环形染料激光器的调谐机制

本文描述了计算机控制环形染料激光器实现无间断自动扫描10THz的光学调谐元件设计、运转机制及实验结果。     

固溶态染料激光物质的研究

本文从不同改进的掺Rh6G聚甲基丙烯酸甲脂(PMMA)固溶态物质获得了有效的激光.热稳定性得到改善以及工作寿命得到延长.研究了它们的激射和光谱特性.     

紫外新激光染料IBOP的研究

本文介绍一种新合成的化合物IBOP.经在多种染料激光器上测试表明,其激光转换效率高,光化学稳定性好,能溶于多种溶剂.性能优于DPS等相同波段的常用激光染料.IBOP在各种溶剂中的激光调谐范围为388～428nm,激光峰值波长在400nm左右.本文给出了IBOP的荧光光谱、吸收光谱、激光特性、溶剂效应和浓度效应等数据,并作了讨论.     

互变异构激光染料奇通红发光特性研究

本文报道应用微微秒脉冲技术测量奇通红染料荧光寿命,发现该体系荧光衰减呈现双指数衰减形式,证实了奇通红染料分子的互变异构特性.     

连续波环形染料激光器的单向运转特性

本文讨论了连续波环形染料激光器的单向运转特性。采用改进的Ganiel速率方程模型,分析了在单向运转条件下泵浦光通量、染料分子密度等参量对激光光通量、激发单重态粒子集居数密度以及增益的影响;揭示了在连续波环形染料激光器中单向运转条件下存在粒子集居数密度的非对称性、激光光通量与激活介质内空间位置的相关性和增益峰值波长的扫描现象。本文给出了数值计算结果。     

参考面的选取对利用自洽法建立染料激光器锁模方程的影响

本文讨论了利用自治法建立链模方程时,各种参考面位置的选取对锁模方程的影响,找到了合理的参考面位置,据此重新建立了适用于同步锁模,混台锁模和被动锁模的锁模方程.并给出了同步锁模的数值解,它与实验结果是一致的.     

环行染料激光器用于内腔吸收光谱的研究

本文报告了利用新型连续波环行染料激光器,即使行波工作于超过阈值两倍以上,仍在大气中获得了近10~5的内腔吸收灵敏放大;并首次利用单频扫描方法,在不降低灵敏放大的同时,得到了10~(-2)的光谱分辨率。实验结果与经改进后的Brunner-Paul理论分析一致。     

Quenching of fluorescence for fluoro derivatives of the laser dye DCM in polar solutions

We used fluorescence spectroscopy and nanosecond flash photolysis to study the photophysical properties of the laser dye 4-dicyanomethylene-2-methyl-6-(p-dimethylamino)styryl-4H-pyran (DCM) and its two fluoro derivatives: (E)-2-〈2-[2-(4-dimethylaminophenyl)ethenyl]-6-trifluoromethyl-4H-4-pyranylidene〉malononitrile (DCMF3) and (E)-2-〈2-[2-(4-dimethylaminophenyl)ethenyl]-6-n-heptafluoro-propyl-4H-4-pyranylidene〉 malononitrile (DCMF7), in nonpolar n-hexane, mixtures of low-polarity toluene and polar dimethylsulfoxide (DMSO), n-propanol at room temperature and at 77 K. The fluorescence quantum yield Φ_fl of the laser dye DCM increases linearly as the polarity of the binary solvent mixture (toluene+DMSO) increases, from 0.08 in toluene to 0.80 in DMSO. The dependence of Φ_fl on the polarity of the mixture toluene+DMSO for DCMF3 and DCMF7 reaches a maximum for a small amount (∼2 vol.%) of added polar DMSO; and with further increase in the DMSO concentration (≥50 vol.%), the fluorescence of the fluoro derivatives of DCM is practically completely quenched. The quantum yield for intersystem crossing Φ_ST for DCM, DCMF3, and DCMF7 is no greater than 0.01 in solutions of different polarities. We discuss the mechanisms for nonradiative deactivation of the electronic excitation energy for the fluoro derivatives compared with DCM. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 73, No. 5, pp. 606–612, September–October, 2006.     

宽谱染料激光器的数值模型及实验验证

应用染料激光器半经典理论,数值模拟了脉冲染料激光器双频及宽谱共增益区的谱线竞争效应,与实验结果符合较好.在双频相关调谐工作条件下,调谐范围增大近25％.在宽谱工作条件下,随着输出耦合损耗增大,谱线宽度逐渐减小. 关键词： 染料激光器 半经典理论 谱线竞争     

Characteristics of xenon-lamp pumped pyrromethene 567-doped dye laser based on polymethylmethacrylater

The solid-state medium containing pyrromethene 567 (PM567) in a polymethylmethacrylate polymer host is shown to lase under the flash lamp excitation. The experimental setup is an ordinary industrial product without special design. The bulk transmission losses, the output energy, and the other lasing properties are compared. The medium with the lowest transmission loss, measured to be 0.392 %/cm at 633 nm, gives a laser output of 130 mJ with a slope efficiency of 0.082%.     

Nonlinear optical properties of an azo-based dye irradiated by picosecond and nanosecond laser pulses

The nonlinear optical properties of an azo-based dye were investigated using Z-scan technique employing 38 ps pulses at 532 and 1064 nm, and 6 ns laser pulses at 532 nm. Large nonlinear absorption and nonlinear refraction were observed at both ps and ns 532 nm in the azoic dye. When excited at ps 1064 nm, this dye displayed a large two-photon absorption cross-section (σ₂=1810 GM). Meanwhile, the optical nonlinearity mechanism was discussed in terms of molecular structure, excitation wavelength, and pulse width.     

Frequency tunability and temporal characteristics of a DAMC distributed feedback dye laser

The frequency tunablity characteristics of a simple prism configuration distributed feedback dye laser (DFDL) pumped by a low pressure nitrogen gas laser are described. Tunability is studied as a function of the refractive index of the dye solution and also as a function of the angle of the interfering beams of the pump laser. The tunability range for the dye studied is from 440 to 480 nm with a spectral width of 0·1 Å and the time duration of the DFDL pulses was 50 ps.     

Operational characteristics of a dye Q-switch for a pulsed ruby laser

This paper presents the results and analysis of experiments carried out on a dye Q-switch to evaluate its operational characteristics. The work was performed on a ruby laser, Q-switched by cryptocyanine in methanol solution. Investigations of performance with regards to pump energy, dye absorbance, output energy and timing of pulse emergence are graphically presented. These results were used to derive the efficiency of Q-switching for varying dye absorbance. Finally, optimization of the Q-switch performance for different requirements of the laser is considered.     

Oxygen sensing by fluorescence quenching of [Cu(btmgp)I]

A fluorescence study of acetonitrile solutions of bis(tetramethylguanidine)propane, copper(I)-iodide and [Cu(btmgp)I] was performed and the chemical reaction of the latter species with O₂ was investigated at room temperature. The actual quenching process via O₂ gassing was studied and an exponential dependence of the fluorescence intensity with respect to the complex concentration was observed.Furthermore the survey was deepened on time resolved fluorescence properties of solved [Cu(btmgp)I] in a wider concentration range. The applicability of this complex for O₂ sensing inside a microreactor system was proven by confocal fluorescence measurements. It was shown that the investigated system can be used for oxygen sensing in the copper concentration range from 10⁻² to 10⁻⁹ mol/l.     

飞秒激光作用下的硅表面微结构及发光特性

 采用近红外飞秒激光辐照浸泡在硫酸溶液中的N型单晶硅片,激光波长800 nm,脉宽200 fs,重频1 kHz,平均功率为100 mW,而硫酸溶液的质量分数分别选择为0.1%和1%。辐照后硅表面呈直径为5~8 mm,高度15 mm的柱型结构。分析其荧光特性,并通过比较硅材料表面微结构与激光光源、扫描参数、硅片背景环境的关系,确定最佳辐照条件为激光扫描速度750 mm/s,扫描间距5 mm/s。最终在厚度0.5 mm、直径26 mm的硅片上获得10 mm×10 mm的方形扫描区域,荧光光谱显示激光扫描后的区域在700 nm附近有很强的荧光发射。分析结果表明飞秒激光扫描改变了样品的表面微结构尺寸,增大了吸收面积,扩展了荧光激发波长,有效提高了样品的吸收效率和荧光发光相对强度(超过扫描前发光相对强度的2倍),荧光发射谱的变化是由量子限制效应和表面态模型共同作用的结果。     

腔内带圆形空心波导的可调谐窄带脉冲染料激光器

本文报道了一种腔内带圆形空心波导和掠入射光栅的可调谐窄带脉冲染料激光器;实验结果表明:该激光系统能获得基横模、窄频带和高效率的激光输出。文中对系统设计机理也进行了分析。     

Optical properties of new indotricarbocyanine dye as a limiter of laser radiation power

We present results of experimental and theoretical studies of the optical characteristics of a new indotricarbocyanine dye that is capable of effectively limiting the power of laser radiation in the visible spectral range. The spectral-luminescent and energy characteristics of the dye molecules and their absorption spectra from the excited state with nanosecond resolution are investigated experimentally. Quantum-chemical methods are used to calculate electronic absorption spectra from the ground (S₀ → S_n) and excited (S₁ → S_n) states and to determine the nature of electronic states of the molecule and the rate constants of intramolecular photophysical processes. The results of the theoretical research agree with experimental data. It is shown that the investigated dye has singlet-singlet absorption at 400–600 nm. Nonlinear absorption of the dye upon excitation by radiation of the second harmonic of a Nd:YAG laser is studied by z-scanning with an open diaphragm. The ratio of dye absorption cross sections from the excited and ground states at 532 nm is determined in the framework of a three-level model. The results are compared with those for previously studied compounds. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 4, pp. 473–480, July–August, 2007.     

NO_2分子激光诱导荧光辐射寿命和碰撞猝灭速率的实验研究

实验测定了激发波长在 591～ 594nm范围 ,压力在 0 .1～ 15Pa时 ,NO2 分子激光诱导荧光衰减曲线 ,作几何修正后应用Stern Volmer模型 ,得到了零压辐射寿命τ0 ( =1/k0 )和碰撞猝灭速率常数kq,结果与文献报道基本一致。对NO2 分子激发态能级的反常长寿命和一定压力下出现的双指数衰减等进行了较详细的讨论。     

A study on the fluorescence quenching of 9-Aminoacridine by certain antioxidants

The fluorescence quenching of 9-Aminoacridine by certain estrogens and flavonoids in water was studied using absorption, steady state and time-resolved measurements. The bimolecular quenching rate constants for the chosen estrogens and flavonoids were found to be in the range of 3.2-9.2×10¹¹ and 0.36-14.46×10¹¹ M⁻¹s⁻¹, respectively. From lifetime measurement we observed that the quenching was mainly due to static mechanism through ground state complex formation. The binding constant (K) and the number of binding sites (n) were calculated based on the fluorescence quenching data. The free energy change (ΔG_et) for electron transfer process was calculated by Rehm-Weller equation.